Magnetic Properties of a Layered Cobaltite Sr<Subscript>1–<Emphasis Type="Italic">x</Emphasis></Subscript>Y<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>CoO<Subscript>3–δ</Subscript> (<Emphasis Type="Italic">x</Emphasis> = 0.1)

The structure, the magnetic and magnetotransport properties of perovskite Sr_0.9Y_0.1CoO_2.63 have been studied. The sample is shown to have a two-phase structure. The main phase has a tetragonally distorted unit cell and is described by space group I4/mmm. The broadening of the reflections with indices corresponding to doubling unit cell parameter c indicates the absence of the rigorous translation symmetry along axis c. The existence of the broadened superstructure reflection observed in the diffraction pattern at small angles at temperature lower than 400 K is explained by the existence of the monoclinic phase whose content is significantly lower than that of the tetragonal phase, but is dominant in the Sr_0.8Y_0.2CoO_3–δ composition. The spontaneous magnetization appears as the monoclinic phase forms. The magnetic structure is mainly G-type antiferromagnetic with magnetic moments 1.5μ_B in the layers of CoO₆ octahedra and 2μ_B in the anion-deficit CoO_{4 + γ} layers. The conduction of the Sr_0.9Y_0.1CoO_2.63 composition has a semiconducting character. The magnetoresistance is 57% in a field of 14 T at a temperature of 5 K and strongly decreases with the temperature increase.     

Ordered phases of lithium nickelite Li<Subscript>1−<Emphasis Type="Italic">x</Emphasis>−<Emphasis Type="Italic">z</Emphasis></Subscript>Ni<Subscript>1+<Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript>2</Subscript>

A symmetry analysis of ordering in lithium nickelite Li_1?x?zNi_1+xO₂ (Li_1?x?z□_yNi_1+xO₂) was performed with regard to the substitution of Li and Ni atoms and the occurrence of structural vacancies □ in the metal sublattice. For all the ordered phases, the k ₉ ⁽³⁾ ray of the Lifshitz {k₉} star is present in the order-disorder transition channel. This ray determines the consecutive alternation of atomic planes filled with only Ni atoms or only Li atoms and vacancies in the \([1\bar 11]_{B1} \) direction. It was shown that the rhombohedral ordered LiNiO₂ phase is formed in the defect-free lithium nickelite, whereas a family of three monoclinic Li₃□Ni₄O₈ (C2/m space group) and Li₂□Ni₃O₆ (C2/m and C2 space groups) superstructures arises as the concentration of structural vacancies increases. For all the superstructures, the order-disorder phase-transition channels were determined and the distribution functions of Li and Ni atoms have been calculated. The long-range order parameters describing each superstructure were found as functions of the Li_{1?x? z}Ni_1+xO₂ composition.     

Analysis of structural defects in the CdSe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>S<Subscript>1 – <Emphasis Type="Italic">x</Emphasis></Subscript> nanocrystals

Spectral dependence of the absorption coefficient of the CdSe _x S_{1 – x} nanocrystals in silicate glass with different perfections of crystalline lattice is experimentally studied. A dependence of the concentration of defects on the time of thermal processing is obtained. It is demonstrated that the defect elimination results from thermal activation process.     

<Emphasis Type="Italic">J</Emphasis>/<Emphasis Type="Italic">ψ</Emphasis> suppression and <Emphasis Type="Italic">p</Emphasis><Subscript><Emphasis Type="Italic">T</Emphasis></Subscript> spectra in RHIC and LHC energy collisions

In a hydrodynamic model, we have studied J/ψ production in Au+Au/Cu+Cu collisions at RHIC energy, GeV. At the initial time, J/ψ’s are randomly distributed in the fluid. As the fluid evolves in time, the free streaming J/ψ’s are dissolved if the local fluid temperature exceeds a threshold temperature T _J/ψ . Sequential melting of charmonium states (χ _c , ψ ^′ and J/ψ), with melting temperatures , T _J/ψ ≈2T _c and feed-down fraction F≈0.3, explains the PHENIX data on the centrality dependence of J/ψ suppression in Au+Au collisions. J/ψ p _T spectra and the nuclear modification factor in Au+Au collisions are also well explained in the model. The model however overpredicts the centrality dependence of J/ψ suppression in Cu+Cu collisions by 20–30%. The J/ψ p _T spectra are underpredicted by 20–30%. The model predicts that in central Pb+Pb collisions at LHC energy,  GeV, J/ψ’s are suppressed by a factor of ∼10. The model predicted a J/ψ p _T distribution in Pb+Pb collisions at LHC is similar to that in Au+Au collisions at RHIC.     

Magnetostriction of Fe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>S (<Emphasis Type="Italic">x</Emphasis> = 0.27) crystals

The magnetostriction of Fe _x Mn_{1 − x} S (x = 0.27) single crystals in strong magnetic fields up to 120 kOe has been investigated. It has been found that the magnetostriction reaches colossal values (±3 × 10⁻⁴) atypical of compounds of 3d elements. It has been found that the magnetostriction changes sign when varying temperature and magnetic field; this behavior indicates an important role of the spin-phonon interactions in the formation of the magnetic order in solid solutions of iron-manganese sulfides.     

Short-Range order of TlIn<Subscript>1–<Emphasis Type="Italic">x</Emphasis></Subscript>Sn<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Te<Subscript>2</Subscript> thin films

The formation of the short-range order structure of amorphous nanometer-thick TlIn_1–x Sn _x Te₂ films (х = 0.02–0.09) obtained via vacuum deposition onto substrates of fresh KCl and KJ chips and celluloid at a temperature below Т = 213 K is studied by high-energy electron diffraction. Both freshly deposited films and films held in vacuum (10^–2 Pa) at room temperature in darkness for several months are studied. The effect of the tin concentration on the interatomic distances, the coordination numbers, and the time of amorphous phase stability of TlIn_1–x Sn _x Te₂ films due to a great spread in bond lengths and bond angles is established.     

Si–Si optical phonon behavior in localized Si clusters of Si<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Ge<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript> alloy nanocrystals

Raman spectra acquired from Si _x Ge_1−x -nanocrystal-embedded SiO₂ films show dependence of the Si–Si optical phonon frequency on Si content. The frequency upshifts, and peak intensity increases as the silicon concentration increases. For a given Si content, the frequency remains unchanged with annealing temperature. Spectral analysis and density functional theory calculation reveal that the optical Si–Si phonon is related to the formation of localized Si clusters surrounded by Si/Ge atomic layers in the Si _x Ge_1−x nanocrystals and the intensity enhancement arises from the larger cluster size. The synergetic effect of surface tensile stress and phonon confinement determines the Si–Si optical phonon behavior.     

High-temperature study of SrFe<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Mo<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript>3−<Emphasis Type="Italic">z</Emphasis></Subscript> perovskites

The structure of high-temperature SrFe_{1 − x} Mo _x O_{3 − z} (0 ≤ x ≤ 0.5) phases was studied. Such studies are necessary to understand the mechanism of oxygen transport in membrane materials used for high-temperature oxygen separation.     

Optical properties and ferromagnetism of ternary Cd<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Te nanocrystals

Cd_1−x Mn _x Te (x = 0, 0.1, 0.2) nanocrystals have been synthesized by mechanical alloying (MA) Cd, Mn, and Se elemental powders. XRD patterns and HRTEM images confirmed the formation of cubic Cd_1−x Mn _x Te nanocrystals. All the diffraction peaks from elemental Cd, Mn, and Te powders disappeared completely in those XRD patterns of as-milled Cd_1−x Mn _x Te nanocrystals for more than 20 h. When the MA process was carried out for 40 h, typical zinc blende structure diffraction mode was exhibited in the XRD pattern. Subsequently, capping the surface of as-milled Cd_1−x Mn _x Te nanocrystals with long chain trioctylphosphine/trioctylphosphine oxide/nitric acid (TOP/TOPO/NA) molecules has achieved colorful dispersion solution, which shows similar optical properties to those CdTe nanocrystals prepared by wet chemical process. The grain size is within the range of 2–8 nm for the capped Cd_1−x Mn _x Te nanocrystals being ball milled for 40 h. The PL excitation peak red shifts to longer wavelength side with increasing Mn concentration. Pure CdTe nanocrystals show ferromagnetism behavior at room temperature, the saturation magnetization value and magnetic hysteresis loop increase with the content of substituting Mn ions within the Cd_1−x Mn _x Te nanocrystals.     

Rubidium-cation conductivity of Rb<Subscript>3–2<Emphasis Type="Italic">x</Emphasis></Subscript>Pb<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>PO<Subscript>4</Subscript> solid solutions

New Rb₃PO₄-based ceramic materials with high rubidium-cation conductivity in the Rb_3–2x Pb _x PO₄ system have been synthesized and studied. Introduction of Pb²⁺ cations leads to a sharp increase in the conductivity of rubidium orthophosphate due to formation of cation vacancies and, at temperatures 350–550°C, also due to the stabilization of high-temperature cubic modification Rb₃PO₄. At high temperatures, the electrolytes prepared have very high ion conductivity higher than 10^–1 S cm^–1 at 700°C, which is higher than the values previously obtained in similar systems with additions of tin and cadmium ions. The factors influencing the transport properties of the materials under study are discussed.     

Electronic structure and ground state parameters of Ru<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript><Emphasis Type="Italic">Me</Emphasis><Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Al refractory alloys

The electronic structure and ground state parameters of B2 RuAl-based refractory alloys have been investigated in the framework of the density functional theory using the exact muffin-tin orbital method in combination with the coherent potential approximation. It has been demonstrated that the number of states at the Fermi level for the Ru_{1 − x} Me _x Al alloys as a function of the alloying metal content has a minimum, which indicates a change in the Fermi surface topology and the presence of specific features in the behavior of elastic constants. It has been concluded that the electronic structure of the alloys can be described in terms of the rigid band model. The nonlinear variations of the lattice parameters of the alloys has been explained.     

Magnetocapacitance effect in Gd<Subscript> <Emphasis Type="Italic">x</Emphasis> </Subscript>Mn<Subscript>1–<Emphasis Type="Italic">x</Emphasis> </Subscript>S

The capacitance and dielectric loss tangent of Gd_xMn_1–xS (x ≤ 0.2) solid solutions have been measured at a frequency of 10 kHz without magnetic field and in a magnetic field of 8 kOe in the temperature range of 90–450 K. An increase in the permittivity and a dielectric loss maximum have been detected in the low-temperature region. It has been found that the temperature of the maximum of the imaginary part of the permittivity shifts to higher temperatures with increasing concentration. The magnetocapacitance effect has been revealed for two compositions. The dielectric loss has been described in the Debye model with “freezing” dipole moments and in the orbital-charge ordering model.     

Long-range magnetic order in Li<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Na<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Cu<Subscript>2</Subscript>O<Subscript>2</Subscript>

Single crystals of Li _x Na_{1 ? x} Cu₂O₂ solid solutions have been grown from the melt and crystal lattice parameters have been studied. It is found that the solid solution of this system exists in the region x ≤ 0.25. Specific heat and magnetic susceptibility are investigated on monocrystalline samples with x = 0.07, 0.14, and 0.21. Long-range magnetic order in these compounds is formed at T = 13.8, 4.1, and 14.8 K, respectively. It is found that the Néel temperature T _N in these compounds increases with Li content.     

Magnetic and magnetoresistive properties of Gd<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript>1–<Emphasis Type="Italic">x</Emphasis></Subscript>Se selenides

Gd _x Mn_1–x Se (0 ≤ х ≤ 0.15) solid solutions are synthesized on the basis of manganese monoselenide. Their magnetic and electrical properties are studied in the temperature range of 80–900 K in magnetic fields up to 10 kOe. An FCC lattice with the Fm3m space group and antiferromagnetic ordering of the magnetic moments of manganese ions is found. A monotonic reduction in the Néel temperature and an increase in the effective magnetic moment along with the gadolinium concentration are observed. Anomalies in the temperature dependence of electrical resistivity and a shift in the temperatures of anomalies in a magnetic field are found.     

Elasticity moduli of Cd<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Hg<Subscript>1–<Emphasis Type="Italic">x</Emphasis></Subscript>Te solid solutions

Results of investigations into the temperature dependences (4.2–300 K) of the low-frequency ultrasound velocity in Cd _x Hg_1–x Te single crystals are presented. The elastic moduli and the Debye temperatures are calculated for different solid solution compositions. Based on the data obtained, possible stresses are estimated on the heteroboundary of the materials with a number of substrates.     

High-temperature heat capacity of orthovanadates Ce<Subscript>1–<Emphasis Type="Italic">x</Emphasis> </Subscript>Bi<Subscript> <Emphasis Type="Italic">x</Emphasis> </Subscript>VO<Subscript>4</Subscript>

Orthovanadates Ce_1–xBi_xVO₄ (1 ≥ x ≥ 0) have been produced by solid-phase synthesis from initial oxides CeO₂, Bi₂O₃, and V₂O₅ upon step-by-step burning. The high-temperature heat capacity of Ce_1–xBi_xVO₄ has been measured by differential scanning calorimetry. The experimental data on C_p = f(T) were used to calculate the thermodynamic properties (the enthalpy changes, the entropy changes, and the Gibbs energy).     

Magnetic capacitance of the Gd<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Bi<Subscript>1–<Emphasis Type="Italic">x</Emphasis></Subscript>FeO<Subscript>3</Subscript> thin films

The capacitance, inductance, and dissipation factor of the Gd _x Bi_1–x FeO₃ films were measured in the temperature range of 100 K < T < 800 K in magnetic fields of up to 8 kOe at frequencies of 0.1–100 kHz. The magnetic susceptibility maxima in the low-temperature region and dependences of the relaxation time and inductance on prehistory of the films cooled in zero and nonzero magnetic fields are established. The giant increase in magnetic capacitance in the external bias electric field is found. The results obtained are explained by the domain structure transformation in external electric and magnetic fields.     

Physical properties of Fe<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Dy<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Si crystals

The results of experimental investigation of magnetic and electric properties of Fe_1?x Dy _x Si crystals are reported. It is shown that the magnitude and position of the anomaly observed in the temperature dependences of magnetization are controlled to a considerable extent by the external magnetic field. It is found that the introduction of Dy ions leads to a weak magnetoresistive effect.     

Metallic-like conductivity of asymmetric <Emphasis Type="Italic">p</Emphasis>-In<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Ga<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>As quantum wells

The temperature dependence of the conductivity of the two-dimensional hole gas in an asymmetric GaAs/In _x Ga_{1 ? x} As/GaAs quantum well has been investigated. It is shown that fast spin relaxation leads to metallic-like behavior of the temperature dependence of the conductivity.     

One Dimensional Models with a Singular Potential of the Type −<Emphasis Type="Italic">αδ</Emphasis>(<Emphasis Type="Italic">x</Emphasis>)+<Emphasis Type="Italic">βδ</Emphasis>′(<Emphasis Type="Italic">x</Emphasis>)

We study a one-dimensional singular potential plus two types of regular interactions: constant electric field and harmonic oscillator. In order to search for the bound state energies, we shall use the Lippman-Schwinger Green function technique. Another direct method will be mentioned for the harmonic oscillator. In the electric field case the unique bound state coincides with that found in an earlier study as the field is switched off. For non-zero field the ground state is shifted and positive energy “quasibound states” appear. The harmonic oscillator demonstrates the general result that for a symmetric potential the odd states are not altered whereas the even states energies are lowered or raised accordingly as the delta perturbation is attractive or repulsive. No states are created or annihilated.