共查询到20条相似文献,搜索用时 15 毫秒
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设计了一种单阀外循环接口,采用静态溶解度测定方法,联用在线超临界流体色谱,准确测定了芘在超临界二氧化碳中的溶解度.通过釜内磁力搅拌和接口外循环的双重作用,促进芘在超临界二氧化碳中的溶解平衡过程,确保在测定芘溶解度时体系已达到溶解平衡状态,确定了溶解平衡时间,消除了联用体系中因芘的溶解度过高而产生的体系堵塞问题. 相似文献
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Solubility of several anthraquinone derivatives in supercritical carbon dioxide was readily available in the literature, but correcting ability of the existing models was poor. Therefore, in this work, two new models have been developed for better correlation based on solid–liquid phase equilibria. The new model has five adjustable parameters correlating the solubility isotherms as a function of temperature. The accuracy of the proposed models was evaluated by correlating 25 binary systems. The proposed models observed provide the best overall correlations. The overall deviation between the experimental and the correlated results was less than 11.46% in averaged absolute relative deviation (AARD). Moreover, exiting solubility models were also evaluated for all the compounds for the comparison purpose. 相似文献
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Qi Long REN Mci HUANG Bao Gen SU Ping Dong WU National Laboratory of Secondary Resources Chemical Engineering Zhejiang University Hangzhou 《中国化学快报》2000,11(9)
IntroductionTile 1host collllllollly IIscd 1llobilc phase ill sllpercritical-fluid cllrolllalography (SFC) iscarbon dioxide. t'!llicll is a 11ollpolar solvellt. Nollpolar colnpollllds of low Inoleclllarweight are well dissolx,ed alld ellltcd, b[lt tile solllbility decreases as tile polarity or tilellloleclllar t',eigllt illcrcases. 1llvestigators folllld that by adding a slllall amollnt of polarcosolvcnt to 11Ollpolar SCFs tile solllbility of a polar sllbstallce illcrcascs sigllificantly'.… 相似文献
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Peng BIE Hai Jian YANG Yu BAI 《中国化学快报》2006,17(6):743-746
Liquid and supercritical carbon dioxide (scCO2) have attracted much attention as “green” replacement for organic solvents, offering economical and environmental benefits due to its favorable physical and chemical properties, such as recyclability, ease … 相似文献
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近年来,超临界二氧化碳(sc-CO2)在聚合反应中的应用受到了越来越多的关注。本文主要综述了以sc-CO2为反应介质的自由基聚合、阳离子聚合、过渡金属催化聚合、热致开环聚合、溶胶-凝胶聚合以及氧化耦合聚合的研究概况。一系列研究结果表明sc-CO2是非常有前途的反应溶剂,在高分子合成领域将会有更加广阔的应用前景。 相似文献
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本文主要介绍了超临界近5年来超临界二氧化碳中的有机反应研究的最新进展,包括加氢反应、氧化反应、羰基化反应、碳碳键形成反应、酯化反应和酶催化反应的研究现状;同时,还介绍了超临界二氧化碳作为反应底物用于合成碳酸酯和氨基甲酸酯的研究进展;并对未来的发展进行了展望。 相似文献
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Inga A. Ronova Lev N. Nikitin Ekaterina A. Sokolova Irina Bacosca Ion Sava Maria Bruma 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(10):929-936
Two series of polyheteroarylenes have been investigated with regard to their physical properties before and after swelling with supercritical carbon dioxide. The study of the dependence of glass transition temperature and free volume of polymers on their conformational rigidity showed that the process of swelling in supercritical carbon dioxide is influenced by the voluminous side groups and by the high boiling solvent N-methylpyrolidinone used for the preparation of the polymers which facilitates the formation of crosslinks or complexes with the macromolecular chains. 相似文献
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A general,green and efficient method for the synthesis of transdiiodoalkenes in CO2(sc) has been developed.Trans-diiodoalkenes were obtained stereospecifically in quantitative yields via diiodination of both electron-rich and electron-deficient alkynes in the presence of KI,Ce(SO4)2 and water in supercritical carbon dioxide [CO2(sc)]at 40℃. 相似文献
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超临界CO2在高分子合成与制备中的应用 总被引:6,自引:0,他引:6
介绍超临界二氧化碳流体作为介质在高分子合成与制备中的研究进展。文中表明,可在超临界二氧化碳中实施氟代单体的自由基溶液聚合、甲基丙烯酸甲酯的分散聚合、丙烯酸的沉淀聚合、丙烯酰胺的反相乳液聚合以及异丁基乙烯基醚的阳离子聚合等多种聚合反应,可用超临界二氧化碳溶胀聚合法制备梯度共混物。此外,超临界二氧化碳还可用于聚合物分级和聚合物微孔、微纤与微球材料的制备等,显示出超临界二氧化碳是一种对环境无污染且价廉的 相似文献
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Organic reactions in supercritical carbon dioxide (scCO2) have facilitated great progress in recent years . ScCO2, as an environmentally friendly reaction medium, may be a substitute for 1 volatile and toxic organic solvents and show some special advantages. Firstly, CO2 is inexpensive, nonflammable, nontoxic and chemical inert under many conditions. Secondly, scCO2 possesses hybrid properties of both liquid and gas, to the advantage of some reactions involving gaseous reagents. Control o… 相似文献
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