Electronic density oscillations in gold atomic chains assembled atom by atom

Linear Au chains two to 20 atoms long were constructed on a NiAl(110) surface via the manipulation of single atoms with a scanning tunneling microscope. Differential conductance (dI/dV) images of these chains reveal one-dimensional electronic density oscillations at energies 1.0 to 2.5 eV above the Fermi energy. The origin of this delocalized electronic structure is traced to the existence of an electronic resonance measured on single, isolated Au atoms. Variations in the wavelength in dI/dV images of an eleven-atom chain taken at different energies revealed an effective electronic mass of 0.4+/-0.1 times the mass of a free-electron.     

Electronic oscillations in paired polyacetylene chains

An interacting pair of polyacetylene chains are initially modeled as a couple of undimerized polymers described by a Hamiltonian based on the tight-binding model representing the electronic behavior along the linear chain, plus a Dirac’s potential double well representing the interaction between the chains. A theoretical field formalism is employed, and we find that the system exhibits a gap in its energy band due to the presence of a mass-matrix term in the Dirac’s Lagrangian that describes the system. The Peierls instability is introduced in the chains by coupling a scalar field to the fermions of the theory via spontaneous symmetry breaking, to obtain a kink-like soliton, which separates two vacuum regions, i.e., two spacial configurations (enantiomers) of the each molecule. Since that mass-matrix and the pseudo-spin operator do not commute in the same quantum representation, we demonstrate that there is a particle oscillation phenomenon with a periodicity equivalent to the Bloch oscillations.     

A study of atom zigzag chains on the surface of Tungsten

Nishigaki and Nakamura have observed zigzag chains on the central (011) face of tungsten after field evaporation at T #62; 140 K. In this paper, a study of the formation, disappearance and structure of such chains is described. Tungsten tips of small radii down to 60 Å were used. Chains of 3 to 9 spots, that are clearly visible, are found even at 90 K. Four different structure models of the zigzag chains are discussed, including the multibranch model proposed by the Japanese authors. The interpretation of our experimental results shows fairly clearly that the real zigzag chain structure is a special non-dense structure. It must be formed by a local displacement of the tungsten adatoms in the field. Without the field, a zigzag chain is transformed into a two-dimensional cluster of the nearest neighbour atom by a small increase in temperature. If the field is reintroduced, the cluster can revert to the initial zigzag structure. The zigzag structure is interpreted as being caused by forces of repulsion between the atom dipoles.     

碳原子线的电子传输特性

单分子电子器件的电子传输特性是当前分子电子学领域研究的热点.本文采用第一原理的ab inito法与格林函数方法,对Au电极-碳原子线-Au电极体系的电子结构以及电子传输等特性进行了分析,给出了C5、C10与C15原子线的电导 -电压曲线与伏安曲线.研究结果表明:碳原子线与Au电极之间的"接触"(结合)既有共价键的成分,又有离子键的成分;碳原子线的电导率及伏安特性具有特殊的量子效应和尺寸效应.     

Electronic structure of linear chains of fullerenes

The band structure of linear chains of fullerene molecules is calculated as a function of the intermolecular π-electron overlap integral T, which increases under increasing external pressure. Chains consisting of neutral (C₆₀) and charged (C ₆₀ ⁻ ) molecules are studied. It is shown that there is a sharp transition from a metal (or narrow-gap semiconductor) to an insulator (with band gap ∼1 eV)with increasing T. The proposed model makes it possible to describe the formation of solid-carbon struc-tures, containing chains of covalently bound fullerene molecules, with different pressure-dependent semiconductor properties. Pis’ma Zh. éksp. Teor. Fiz. 65, No. 8, 647–650 (25 April 1997)     

氢原子电子云密度分布分析

通过数值计算形象地分析了氢原子中电子概率密度的分布情况,对此做了一些有别于传统认识的讨论,并由此引出了对粒子运动和波函数概率解释的认识。     

Relativistic effects in one-dimensional hydrogen atom

The dependence of stationary levels of a Dirac particle in the regularized Coulomb potential V _??(z) = ?q/(|z| + ??) on the cutoff parameter ?? is studied. It is shown that, in 1 + 1 D, the energy spectrum of a Dirac particle in such a potential reveals some specific features which nonanalytically depend on the coupling constant q and are essentially relativistic in nature. These properties turn out to be most important for ?? ? 1, explicitly demonstrating the existence of a physically reasonable energy spectrum for an arbitrarily small ?? > 0 and, at the same time, the absence of regular limit ?? ?? 0 (hence, the absence of a well-defined spectral problem for the Dirac equation without regularization for arbitrary q in 1 + 1 D).     

Narrowing the length distribution of Ge nanowires

Synthesis of nanostructures of uniform size is fundamental because the size distribution directly affects their physical properties. We present experimental data demonstrating a narrowing effect on the length distribution of Ge nanowires synthesized by the Au-catalyzed molecular beam epitaxy on Si substrates. A theoretical model is developed that is capable of describing this puzzling behavior. It is demonstrated that the direction of the diffusion flux of sidewall adatoms is size dependent and has a major effect on the growth rate of differently sized nanowires. We also show that there exists a fundamental limitation on the maximum nanowire length that can be achieved by molecular beam epitaxy where the direction of the beam is close to the growth axis.     

Interaction of positrons with niobium atom chains in Nb3Al

The angular correlation of annihilation in Nb₃Al is investigated. The results indicate that positrons may be trapped by deformed sections of Nb atomic chains. It is concluded that the Fermi level for d-electrons of such chains is located near the boundary of the Brillouin zone.     

Radial distribution of the atom concentration in a nitrogen discharge plasma

The radial distribution profile of the atom concentration in a nitrogen discharge plasma has been determined by means of the Lewis-Rayleigh afterglow radiation. The profile has been investigated in dependence of the pressure and of the discharge current.     

Electronic properties of Fibonacci and random Si-Ge chains

In this paper we address a theoretical calculation of the electronic spectra of an Si-Ge atomic chain that is arranged in a Fibonacci quasi-periodic sequence, by using a semi-empirical quantum method based on the Hückel extended model. We apply the Fibonacci substitutional sequences in the atomic building blocks A(Si) and B(Ge) through the inflation rule or a recursion relation. In our ab initio calculations we use only a single point, which is sufficient for considering all the orbitals and charge distribution across the entire system. Although the calculations presented here are more complete than the models adopted in the literature which take into account the electronic interaction only up to the second and third neighbors, an interesting property remains in their electronic spectra: the fractality (which is the main signature of this kind of system). We discuss this fractality of the spectra and we compare them with the random arrangement of the Si-Ge atomic chain, and with previous results based on the tight-binding approximation of the Schr?dinger equation considering up to the nearest neighbor.     

Electronic and transport properties of artificial gold chains

We study the electronic and transport properties of artificial Au atomic chains on a NiAl(110) surface template using state-of-the-art first principles calculations. Au chains display remarkable one-dimensional electronic properties that can be tuned by the selective adsorption of small molecules: a single CO group is shown to modulate the electronic wave functions, acting as a "chemical scissor" along the chain, to strongly modify the coherent transport properties of the system, and to help design one-dimensional nanodevices through artificial profiling of energy barriers.     

Cooperative effects in the two atom resonance fluorescence spectrum

We consider the resonance fluorescence spectrum of two similar interacting atoms in the limit of high photon densities. The excitation spectrum of the symmetric modes contains two sidebands in addition to the usual three peaks which are analogous to those of the isolated atom. These two new sidebands are due entirely to the cooperative behaviour of the two atoms and vanish when the atoms are far apart. The energy shifts and spectral widths for these two sidebands are two and five times larger than those for the isolated atom respectively. The probability of occurrence of these sidebands depends on the parameters V_AB/Ω and γ²₀/Ω², where V_AB is the dipole-dipole interaction energy, γ₀ is the spontaneous emission probability and Ω is the Rabi frequency. The asymmetric broadening of both sidebands depends on the parameter γ₀/Ω. The possibility to measure the dipole-dipole energy through the observation of these sidebands is discussed.     

Nonperturbative entangling gates between distant qubits using uniform cold atom chains

We propose a new fast scalable method for achieving a two-qubit entangling gate between arbitrary distant qubits in a network by exploiting dispersionless propagation in uniform chains. This is achieved dynamically by switching on a strong interaction between the qubits and a bus formed by a nonengineered chain of interacting qubits. The quality of the gate scales very efficiently with qubit separations. Surprisingly, a sudden switching of the couplings is not necessary. Moreover, our gate mechanism works for multiple gate operations without resetting the bus. We propose a possible experimental realization in cold atoms trapped in optical lattices and near field Fresnel trapping potentials.     

On nonlinear effects in magnetic chains

The effect of phonon unharmonism and nonlinearity in exchange integrals on soliton excitations in ferromagnetic chains in the classical and long-wave limit are studied. It has been first shown that the unharmonic effect leads to a system of coupled Boussinesque and nonlinear Schrödinger equations allowing two types of soliton solutions. The nonlinear effect on the other hand results nonlinear Schrödinger equation with saturable nonlinearity admitting stable solitons in higher dimensional models.     

Analysis of the angular distribution of Auger electrons in a Xe atom

The angular distribution of Auger electrons, and the numerically calculated anisotropy parameters of the angular distribution α for (M₃ → N₂N₃), (M₃ → N₃N₃), (M₄ → N₁N₃), (M₄ → N₄N₅), (M₄ → N₅N₅), and (M_4,5 → O_{2, 3}O_{2, 3}) transitions in a Xe atom are given. The matrix elements are calculated by using the nonrelativistic Hartree-Fock method in LS coupling and the relativistic Hartree-Fock-Dirac method in both jj coupling (the single-configuration approximation) and intermediate coupling (the multiconfiguration approximation).     

Mixed spectrum of correlated pulse sequences with application to linear atom chains

Line and continuous components of the power spectrum of a sequence of pulses with correlation between pulse shape and pulse separation interval are given. From these results the spectral properties of a diatomic chain are obtained straightforwardly.     

Probing the natural broadening of hydrogen atom spectrum based on the minimal length uncertainty

The natural broadening of hydrogen atom spectrum based on the minimal length uncertainty is calculated. We will show that the natural broadening of hydrogen atom spectrum receives any correction.     

Anabiosis of phase distribution of a three-level atom

We study the phase probability distribution of a three-level atom interacting with a cavity field in the presence of two-photon detuning and decoherence. Anabiosis of the phase probability distribution is observed due to the presence of the Stark shift. The simulation demonstrates that there is an enhancement of the phase sensitivity as soon as the two-photon detuning is considered. The W-Wigner function is also examined and it is shown that the nonclassical effect is apparent, however, for a small value of the decoherence factor.