Degradation behavior and products of malathion and chlorpyrifos spiked in apple juice by ultrasonic treatment

Apple juice (13 °Brix) spiked with malathion and chlorpyrifos (2–3 mg l⁻¹ of each compound) was treated under different ultrasonic irradiations. Results showed that ultrasonic treatment was effective for the degradation of malathion and chlorpyrifos in apple juice, and the output power and treatment time significantly influenced the degradation of both pesticides (p < 0.05). The maximum degradations were achieved for malathion (41.7%) and chlorpyrifos (82.0%) after the ultrasonic treatment at 500 W for 120 min. The degradation kinetics of both pesticides were fitted to the first-order kinetics model well (R²  0.90). The kinetics parameters indicated that chlorpyrifos was much more labile to ultrasonic treatment than malathion. Furthermore, malaoxon and chlorpyrifos oxon were identified as the degradation products of malathion and chlorpyrifos by gas chromatography–mass spectrometry (GC–MS), respectively. The oxidation pathway through the hydroxyl radical attack on the PS bond of pesticide molecules was proposed.     

Hetero-/homogeneous combustion of hydrogen/air mixtures over platinum at pressures up to 10 bar

The hetero-/homogeneous combustion of fuel-lean hydrogen/air premixtures over platinum was investigated experimentally and numerically in the pressure range 1 bar  p  10 bar. Experiments were carried out in an optically accessible channel-flow catalytic reactor and included planar laser induced fluorescence (LIF) of the OH radical for the assessment of homogeneous (gas-phase) ignition, and 1-D Raman measurements of major gas-phase species concentrations for the evaluation of the heterogeneous (catalytic) processes. Simulations were performed with a full-elliptic 2-D model that included detailed heterogeneous and homogeneous chemical reaction schemes. The predictions reproduced the measured catalytic hydrogen consumption, the onset of homogeneous ignition at pressures of up to 3 bar and the diminishing gas-phase combustion at p  4 bar. The suppression of gaseous combustion at elevated pressures bears the combined effects of the intrinsic homogeneous hydrogen kinetics and of the hetero/homogeneous chemistry coupling via the catalytically produced water over the gaseous induction zone. Transport effects, associated with the large diffusivity of hydrogen, have a smaller impact on the limiting pressure above which gaseous combustion is suppressed. It is shown that for practical reactor geometrical confinements, homogeneous combustion is still largely suppressed at p  4 bar even for inlet and wall temperatures as high as 723 and 1250 K, respectively. The lack of appreciable gaseous combustion at elevated pressures is of concern for the reactor thermal management since homogeneous combustion moderates the superadiabatic surface temperatures attained during the heterogeneous combustion of hydrogen.     

Double-quantum NMR spectroscopy of P species submitted to very large CSAs

We introduce an original pulse sequence, , which is a block super-cycled sequence employing as basic element a π pulse sandwiched by ‘window’ intervals. This homonuclear dipolar recoupling method allows the efficient excitation of double-quantum coherences between spin-1/2 nuclei submitted to very large chemical shift anisotropy. We demonstrate that this technique can be employed in double-quantum ↔ single-quantum ³¹P homonuclear correlation experiment at high magnetic field (B₀  14 T) and high MAS frequencies (ν_R  30 kHz). The performances of are compared to those of the double-quantum recoupling methods, such as BABA and bracketed fp-RFDR, which were already employed at fast MAS rates. The sequence displays a higher robustness to CSA and offset than the other existing techniques.     

Calculation of axial optical forces exerted on medium-sized particles by optical trap

Optical trapping has become an efficient technique of trapping and manipulating micrometer and sub-micrometer dimension particles. Particles in the range between the applicable regime of ray optics theory (ROT) and the Rayleigh regime (so-called medium-sized particles) are focused on. By using ROT and the generalized Lorenz–Mie theory (GLMT), axial optical forces and their dependences on particle sizes and beam waists are presented. Furthermore, by comparing the numerical results of these two theories, the applicability of the GLMT to particles of arbitrary size and the limit of ROT in the region of small particles are analyzed. A new criterion of the applicable region of ROT is obtained, i.e. the relative particle size β=2πa/λ20, where a is the particle radius and λ is the wavelength of light. The theoretical results will be of great help to the design and optimization of the most efficient optical trap.     

Exotic phases of finite temperature gauge theories

We calculate the phase diagrams at high temperature of SU(N) gauge theories with massive fermions by minimizing the one-loop effective potential. Considering fermions in the adjoint (Adj) representation at various N we observe a variety of phases when N_f2 Majorana flavours and periodic boundary conditions are applied to fermions. Also the confined phase is perturbatively accessible. For N=3, we add Fundamental (F) representation fermions with antiperiodic boundary conditions to adjoint QCD to show how the Z(3)-symmetry breaks in the confined phase.     

Phase transition in the spanning-hyperforest model on complete hypergraphs

By using our novel Grassmann formulation we study the phase transition of the spanning-hyperforest model of the k-uniform complete hypergraph for any k2. The case k=2 reduces to the spanning-forest model on the complete graph. Different k are studied at once by using a microcanonical ensemble in which the number of hypertrees is fixed. The low-temperature phase is characterized by the appearance of a giant hyperforest. The phase transition occurs when the number of hyperforests is a fraction (k−1)/k of the total number of vertices. The behaviour at criticality is also studied by means of the coalescence of two saddle points. As the Grassmann formulation exhibits a global supersymmetry we show that the phase transition is second order and is associated to supersymmetry breaking and we explore the pure thermodynamical phase at low temperature by introducing an explicit breaking field.     

Morphological and electro-optical responses of dichroic polymer dispersed liquid crystal films

Dichroic polymer dispersed liquid crystal (DPDLC) films containing different concentration of dichroic dye have been prepared by polymerization induced phase separation technique using nematic liquid crystal material in UV curable polymer NOA 65 and anthraquinone dichroic dye. The effects of applied voltage and temperature on the LC droplet morphology and its optical characteristics were studied in detail. Liquid crystal droplets containing low concentration of dye (0.25%) in polymer matrix exhibit bipolar configuration at lower applied voltage (10 V) whereas at relatively higher voltage (15 V) maltese type liquid crystal droplets were seen. In addition, low concentration DPDLC film shows better optical transmission and higher contrast ratio.     

Wave properties of an annular periodic multilayer structure containing the single-negative materials

The optical properties of an annular periodic multilayer structure containing two kinds of single-negative materials are theoretically investigated based on the transfer matrix method of the cylindrical waves. At the azimuthal mode number m1 and near the magnetic plasma frequency and the electronic plasma frequency for the TE wave and TM wave, respectively, we find that there is an additional high-reflectance band and some reflection dips exist when the plasma frequency is located in the photonic band gap. These two special features arising from the higher order azimuthal mode of the cylindrical waves are not seen in the planar one-dimensional Bragg reflector consisting of the single-negative materials. Such filtering responses provide a feasible way of designing a narrowband resonator without physically introducing any defect layer in the structure.     

Wavelength and temperature dependence properties of human blood-serum

For biological importance and general scientific interest, the present paper studies the physical properties dependent on wavelength and temperature, for six different samples of human blood-serum, at two different laser wavelengths (514.5 and 632.8 nm). The properties are described in terms of scalar quantities, viz. refractive index or optical permittivity, optical and dielectric dispersion. A modified and high accurate laser Mach–Zehnder interferometric technique is used for measurement of the refractive index (n) and its gradient with temperature (dn/dT). The values of n and dn/dT are applied to calculate the optical permittivity () and its gradient with temperature d/dT. The refractive properties such as the variation of n, , −dn/dT and, −d/dT as a functions of wavelengths are determined. On the other hand, the optical properties such as reflectance, transmittance and absorptance as a function of light incident angle, temperature and wavelength are studied. Additionally the following dielectric parameters are calculated: specific refractivity, specific dispersivity, polarizability per unit volume, wave impedance, volume expansion coefficient and the electric susceptibility.     

Estimation of relative order tensors, and reconstruction of vectors in space using unassigned RDC data and its application

Advances in NMR instrumentation and pulse sequence design have resulted in easier acquisition of Residual Dipolar Coupling (RDC) data. However, computational and theoretical analysis of this type of data has continued to challenge the international community of investigators because of their complexity and rich information content. Contemporary use of RDC data has required a-priori assignment, which significantly increases the overall cost of structural analysis. This article introduces a novel algorithm that utilizes unassigned RDC data acquired from multiple alignment media (nD-RDC, n  3) for simultaneous extraction of the relative order tensor matrices and reconstruction of the interacting vectors in space.Estimation of the relative order tensors and reconstruction of the interacting vectors can be invaluable in a number of endeavors. An example application has been presented where the reconstructed vectors have been used to quantify the fitness of a template protein structure to the unknown protein structure. This work has other important direct applications such as verification of the novelty of an unknown protein and validation of the accuracy of an available protein structure model in drug design. More importantly, the presented work has the potential to bridge the gap between experimental and computational methods of structure determination.     

Stability of soliton lattice phase in the bilayer quantum Hall state under tilted magnetic fields

The bilayer quantum Hall (QH) state at the filling factor ν=1 shows various fascinating quantum phenomena due to the layer degree of freedom called ‘pseudospin’. We report an experimental evidence of the soliton lattice (SL) phase, which is a domain structure of pseudospin, by the appearance of a local maximum of magnetoresistance near the ν=1 QH state. We investigate the stability of the SL phase by changing B and the total electron density n_T. Detailed magnetotransport measurements under tilted magnetic fields were carried out to obtain a B–n_T plane phase diagram containing the C, IC and SL phases. We found the SL phase is only stable at low n_T region. Namely, the C–SL–IC phase transition occurs only at low n_T region as B increases. On the contrary, the C–IC phase transition directly occurs without passing through the SL phase at high n_T region.     

Critical Casimir amplitudes for n-component models with -symmetry breaking quadratic boundary terms

Euclidean n-component ⁴ theories whose Hamiltonians are O(n) symmetric except for quadratic symmetry breaking boundary terms are studied in the film geometry . The boundary terms imply the Robin boundary conditions at the boundary planes at z=0 and at z=L. Particular attention is paid to the cases in which m_j of the n variables associated with plane take the special value corresponding to critical enhancement while the remaining ones are larger and hence subcritically enhanced. Under these conditions, the semi-infinite system with boundary plane has a multicritical surface–bulk point, called m_j-special, at which an O(m_j) symmetric critical surface phase coexists with the O(n) symmetric bulk phase, provided d is sufficiently large. The L-dependent part of the reduced free energy per cross-section area behaves asymptotically as Δ_C/L^d−1 as L→∞ at the bulk critical point. The Casimir amplitudes Δ_C are determined for small =4−d in the general case where m_c,c components _α are critically enhanced at both boundary planes, m_c,D+m_D,c components are enhanced at one plane but satisfy asymptotic Dirichlet boundary conditions at the respective other, and the remaining m_D,D components satisfy asymptotic Dirichlet boundary conditions at both . Whenever m_c,c>0, the corresponding small- expansions involve, besides integer powers of , also fractional powers ^k/2 with k3 modulo powers of logarithms. Results to order ^3/2 are given for general values of m_c,c, m_c,D+m_D,c, and m_D,D. These are used to estimate the Casimir amplitudes Δ_C of the three-dimensional Heisenberg systems with surface spin anisotropies for the cases with (m_c,c,m_c,D+m_D,c)=(1,0), (0,1), and (1,1).     

Exceptional sensitivity to neutrino parameters with a two-baseline Beta-beam set-up

We examine the reach of a Beta-beam experiment with two detectors at carefully chosen baselines for exploring neutrino mass parameters. Locating the source at CERN, the two detectors and baselines are: (a) a 50 kton iron calorimeter (ICAL) at a baseline of around 7150 km which is roughly the magic baseline, e.g., ICAL@INO, and (b) a 50 kton Totally Active Scintillator Detector at a distance of 730 km, e.g., at Gran Sasso. We choose ⁸B and ⁸Li source ions with a boost factor γ of 650 for the magic baseline while for the closer detector we consider ¹⁸Ne and ⁶He ions with a range of Lorentz boosts. We find that the locations of the two detectors complement each other leading to an exceptional high sensitivity. With γ=650 for ⁸B/⁸Li and γ=575 for ¹⁸Ne/⁶He and total luminosity corresponding to 5×(1.1×10¹⁸) and 5×(2.9×10¹⁸) useful ion decays in neutrino and antineutrino modes respectively, we find that the two-detector set-up can probe maximal CP violation and establish the neutrino mass ordering if sin²2θ₁₃ is 1.4×10⁻⁴ and 2.7×10⁻⁴, respectively, or more. The sensitivity reach for sin²2θ₁₃ itself is 5.5×10⁻⁴. With a factor of 10 higher luminosity, the corresponding sin²2θ₁₃ reach of this set-up would be 1.8×10⁻⁵, 4.6×10⁻⁵ and 5.3×10⁻⁵ respectively for the above three performance indicators. CP violation can be discovered for 64% of the possible δ_CP values for sin²2θ₁₃10⁻³ (8×10⁻⁵), for the standard luminosity (10 times enhanced luminosity). Comparable physics performance can be achieved in a set-up where data from CERN to INO@ICAL is combined with that from CERN to the Boulby mine in United Kingdom, a baseline of 1050 km.     

Development of surface-textured hydrogenated ZnO:Al thin-films for μc-Si solar cells

This study addresses the optimization of rf magnetron-sputtered hydrogenated ZnO:Al (HAZO) films as front contacts in microcrystalline silicon solar cells. The front contact of a solar cell has to be highly conductive and highly transparent to visible and infrared radiation. Furthermore, it has to scatter the incident light efficiently in order for the light to be effectively trapped in the underlying silicon layers. In this research, HAZO films were rf-magnetron-sputtered on glass substrates from a ceramic (98 wt% ZnO, 2 wt% Al₂O₃) target. Various compositions of AZO films on glass substrates were prepared by changing the H₂/(Ar + H₂) ratio of the sputtering gas. The resulting smooth films exhibited high transparencies (T  85% for visible light including all reflection losses) and excellent electrical properties (ρ = 2.7 × 10⁻⁴ Ω · cm). Depending on their structural properties, these films developed different surface textures upon post-deposition etching using diluted hydrochloric acid. The light-scattering properties of these films could be controlled simply by varying the etching time. Moreover, the electrical properties of the films were not affected by the etching process. Therefore, within certain limits, it is possible to optimize the electro-optical and light-scattering properties separately. The microcrystalline silicon (μc-Si:H)-based p–i–n solar cells prepared using these new texture-etched AZO:H substrates showed high quantum efficiencies in the long wavelength range, thereby demonstrating effective light trapping. Using the optimum AZO:H thin-film textured surface, we achieved a p–i–n μc-Si solar cell efficiency of 7.78%.     

Interrelation between electronic structure and interatomic distances for compounds

The heat capacity was studied for LaMn₂Si₂, La_0.75Y_0.25Mn₂Si₂, La_0.7Y_0.3Mn₂Si₂, YMn₂Si₂ and LaFe₂Si₂ isostructural intermetallic compounds in the temperature range 1.8–360 K. The electronic, magnetic and lattice contributions to the heat capacity of the compounds were determined and analyzed. The interrelation was found between values of the electronic contribution to the heat capacity (density of states at the Fermi level) and crystal lattice parameters of R(Mn,Fe,Ni)₂Si₂ compounds. The electronic contribution and the density of states at Fermi level increase with increasing lattice parameters of the compounds. The change of interlayer Mn–Mn exchange interactions with change of Y concentration in La_1-xY_xMn₂Si₂ compounds is not accompanied by considerable changes in the electronic contribution to the heat capacity and density of states at the Fermi level. The performed analysis of the magnetic contribution shows that no essential differences exist between the behavior of the heat capacity of the compounds with d_Mn–Mnd_c and with d_Mn–Mn<d_c upon various types of the magnetic phase transitions.     

Far-field properties and beam quality of vectorial Hermite–Laguerre–Gaussian beams beyond the paraxial approximation

The far-field properties and beam quality of vectorial nonparaxial Hermite–Laguerre–Gaussian (HLG) beams are studied in detail, where, instead of the second-order-moments-based M² factor, the extended power in the bucket (PIB) and βparameter are used to characterize the beam quality in the far field and the intensity in the formulae is replaced by the z component of the time-averaged Poynting vector S_z. It is found that the S_z PIB and βparameter of vectorial nonparaxial HLG beams depend on the mode indices n, m, αparameter and waist-width-to-wavelength ratio w₀/λ and the PIB and βparameter are additionally dependent on the bucket's size taken.     

The extraction of total cross section from

We report on the first measurement of the differential cross section of -meson photoproduction for the d(γ,pK⁺K⁻)n exclusive reaction channel. The experiment was performed using a tagged-photon beam and the CEBAF Large Acceptance Spectrometer (CLAS) at Jefferson Lab. A combined analysis using data from the d(γ,pK⁺K⁻)n channel and those from a previous publication on coherent production on the deuteron has been carried out to extract the −N total cross section, σ_N. The extracted −N total cross section favors a value above 20 mb. This value is larger than the value extracted using vector-meson dominance models for photoproduction on the proton.     

Dielectric/piezoelectric properties and temperature dependence of domain structure evolution in lead free single crystal

(K_0.5Na_0.5)NbO₃ (KNN) single crystals were grown using a high temperature flux method. The dielectric permittivity was measured as a function of temperature for [001]-oriented KNN single crystals. The ferroelectric phase transition temperatures, including the rhombohedral–orthorhombic T_R−O, orthorhombic–tetragonal T_O−T and tetragonal–cubic T_C were found to be located at −149  C, 205 C and 393 C, respectively. The domain structure evolution with an increasing temperature in [001]-oriented KNN single crystal was observed using polarized light microscopy (PLM), where three distinguished changes of the domain structures were found to occur at −150  C, 213 C and 400 C, corresponding to the three phase transition temperatures.     

Proca Effect in Reissner–Nordstrom de Sitter Metric

Reissner–Nordstrom de Sitter spacetime with photon rest mass is studied. An iteration method is used to get the metric of this spacetime. In the case of μ → 0, the solution will return to the common Reissner–Nordstrom de Sitter spacetime.