Effect of surface catalytic activity on nonequilibrium heat transfer in a subsonic jet of dissociated nitrogen

The present paper investigates experimentally and numerically the effect of the heterogeneous recombination of atoms on the heat transfer of models in a subsonic jet of dissociated nitrogen for the conditions of an experiment in the VGU-2 plasma generator and determines the effective probabilities of the heterogeneous recombination of nitrogen atoms for a number of materials at high temperatures.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 166–172, May–June, 1985.     

Diffusion separation of chemical elements on a catalytic surface

An asymptotic expansion of the solution, for large Schmidt numbers, of the system of equations of a chemically nonequilibrium multicomponent boundary layer on the catalytic surface of a blunt body [1] is used to obtain expressions for the diffusion fluxes of the reaction products and chemical elements and the heat flux as functions of the gradients of the reaction product concentrations, chemical element concentrations and enthalpy across the boundary layer. It is shown that when the body is exposed to a supersonic air flow, the diffusion separation of the chemical element oxygen depends importantly on the atom concentration at the outer edge of the boundary layer and the nature of the homogeneous and heterogeneous catalytic reactions. If the surface promotes the rapid recombination of oxygen atoms and is chemically neutral with respect to nitrogen atoms, then an excess of the chemical element oxygen is formed on the body. Otherwise we get an enhanced concentration of the element nitrogen. As distinct from the case of an ideally catalytic wall [2–4], on a surface possessing the property of catalytic selectivity the diffusion separation of chemical elements takes place even when only atoms are present at the outer edge of the boundary layer. On a chemically neutral surface diffusion separation may be caused by homogeneous recombination reactions between oxygen and nitrogen atoms if their rate constants are essentially different.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 115–121, July–August, 1988.     

Increased heat transfer to a titanium surface with oxygen injection into the nonequilibrium boundary layer

The results of an experimental and numerical investigation of the heat transfer between a subsonic jet of dissociated nitrogen and a titanium surface, through which molecular oxygen is blown into the jet, are presented. It is established that in the nonequilibrium boundary layer regime the dependence of the heat flux on the injected oxygen flow rate is nonmonotonic. At a certain flow rate the heat transfer to the titanium surface reaches a maximum that considerably exceeds (by 20%) the heat transfer to an impermeable wall. The observed increase in heat transfer in the presence of injection is attributed to the interaction of the gas-phase exchange reactions and the recombination of atoms on the titanium surface, which has sharply different catalytic properties with respect to the recombination of nitrogen and oxygen atoms.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 4, pp. 148–155, July–August, 1991.     

Methods and Results of an Experimental Determination of the Catalytic Activity of Materials at High Temperatures

Methods of experimental determination of the rate constants of heterogeneous catalytic recombination of nitrogen and oxygen atoms in dissociated subsonic nitrogen and air flows generated by a high-frequency inductive plasmatron are discussed. Together with the values of the probability of heterogeneous recombination used in the literature, the rate constant of the elementary process of nitrogen atomic recombination is determined in accordance with the Langmuir-Hinshelwood mechanism.     

Investigation of the Influence of Different Heterogeneous Recombination Mechanisms on the Heat Fluxes to a Catalytic Surface in Dissociated Carbon Dioxide

A kinetic model of heterogeneous recombination in dissociated carbon dioxide on high-temperature heat-shield coatings is developed; the model takes into account the nonequilibrium adsorption-desorption reactions of oxygen atoms and their recombination in the Eley-Rideal and Langmuir-Hinshelwood reactions. On the basis of a comparison of the calculated heat fluxes in dissociated carbon dioxide with those measured in the VGU-3 plasma generator of the Institute for Problems in Mechanics of the Russian Academy of Sciences (IPM RAS) and the available literature data, the parameters of the catalysis model are chosen for the glassy coating of the Buran orbiter tile heat shield based on the SiO₂–B₂O₃–SiB₄ system. The effects of heterogeneous recombination proceeding in accordance with the Langmuir-Hinshelwood mechanism, as well as the processes involving carbon atoms and those involving physically adsorbed oxygen atoms, on the heat fluxes to the glassy coating are analyzed on the surface temperature range from 300 to 2000 K.     

Determination of the constants of electrochemical reactions and the ion mobility coefficients in weakly conducting liquids from an analysis of the current—voltage characteristics

The problem is considered of the passage of a direct current through a solution of a weak electrolyte in a two-dimensional cell. Allowance is made for the electrochemical reactions of dissociation and reconbination which take place in the electrolyte when the rate of dissociation of the molecules is regarded as dependent on the electric field intensity [1–3]. For electrolytes whose recombination coefficient is of the order of magnitude of the Langevin coefficient, theoretical current—voltage characteristics are given for the limiting cases of large and small values of the characteristic times for the ion concentrations to be changed by electrochemical reactions and the transport of ions by the electric field. A method of determining the dissociation rate, the recombination coefficient, and the ion mobility coefficients is proposed on the basis of comparison of the theoretical and experimental current—voltage characteristics.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6. pp. 113–120, November–December, 1984.     

Propagation of a shear crack in a randomly heterogeneous body

Propagation of a crack in a randomly heterogeneous body exposed to longitudinal shear is considered (in a Born approximation). It is proved that the stress means at the crack tip have singularities on the order of (r)^–1/2. The effective coefficient of stress intensity is introduced. It is known that the propagation of a crack in a homogeneous body is of a local nature, i.e., energy consumption in the growth of the crack is completely determined by the coefficient of stress intensity, which is a local characteristic. The equivalence of the force and energy approaches is mathematically expressed by the Irwin equation [1]. An analog of the Irwin equation is obtained for the case of a randomly heterogeneous body.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 1, pp. 145–148, January–February, 1976.     

Model of the physico-chemical kinetics behind the front of a very intense shock wave in air

A model of the physico-chemical kinetics of the reactions taking place behind the front of an intense shock wave propagating in air with a speed of 9–14 km/s is proposed. The problem of describing the chemical reactions, namely, molecular dissociation and exchange reactions involving vibrationally excited molecules in the absence of vibrational equilibrium, is solved. The vital role of the vibrational excitation delay in the dissociation of oxygen and nitrogen is established. The rate of the exchange reaction between nitrogen molecules and oxygen atoms in the shock wave depends only slightly on the vibrational excitation level. It is demonstrated that the rate constants for thermally nonequilibrium dissociation reactions can be represented within the framework of the one-temperature approximation at constant vibrational temperatures of the dissociating species satisfying quasi-stationary conditions.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 2, pp. 169–182, March–April, 1995.     

Recombination of electrons in a plasma expanding into a vacuum

As noted in a paper by one of the authors [1], when a hot ionized gas expands into a vacuum, at a certain moment ionization equilibrium must necessarily break down. Shortly after this point, which may be found by the method indicated in [1], ionizing events become very rare and only recombination occurs in the gas. In [1] photorecombination and triple collisions with the capture of an electro to the ground level of the atom were considered. Here the recombination did not proceed to the end: on expanding to infinity and cooling to zero the gas remained partially ionized.Papers have recently appeared [2–7] in which the significant role of triple collisions with the capture of electrons to upper atomic levels is noted. The recombination process has a cascade character at low temperatures and densities which are not excessively small. At first, the electron is captured by one of the upper atomic levels in a triple collision with an ion and another electron. Subsequently, as a result of electron collisions of the second kind, and later also as a result of radiative transitions, the bound electron descends through the energy levels to the atomic ground state. The recombination coefficient for such a process depends much more strongly on the electron temperature T than for a triple collision with capture directly by the ground level (as T^–9/2 as opposed to T^–1), and at low temperatures cascade recombination proceeds much more quickly than capture to the ground level. Since this casts doubt upon the conclusions of [1] regarding the residual ionization when a plasma expands into a vacuum, we were led to re-examine the question, which, as will be clear from what follows, is not considerably more complicated.     

Investigation of non-steady-state centeally symmetric filtration of a liquid in closed heterogeneous media

This paper is the final stage in a study of the properties of the non-steady-state filtration of a homogeneous liquid towards a central well with a hemispherical end face in heterogeneous media with a dual porosity, consisting of hemispherical regions set one inside the other with different values of the medium parameters [1, 2]. Exact solutions are found for the problems of the decrease in seam pressure as a function of time and distance, as well as of the time change in output of a well with a hemispherical end face operating at a fixed flow rate, or at a fixed end face pressure, respectively, in closed heterogeneous media. The effect of the magnitudes of the heterogeneous media parameters on the change in their production process indicators is established on the basis of numerical calculations.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 3, pp. 98–104, May–June, 1976.     

Flow of a dual-temperature plasma in the channel of a disk-magnetohydrodynamic generator,taking account of nonequilibrium ionization and recombination reactions

The establishment of a supersonic one-dimensional flow of a dual-temperature, partially ionized plasma is investigated in the channel of a disk-MHD generator, taking account of nonequilibrium ionization and recombination reactions. A detailed formulation of the problem is given in [1]; flows are considered in the absence of ionization and recombination reactions and in the case of equilibrium reactions.Moscow. Translated from Izvestiya Akademii Nauk SSSR. Mekhanika Zhidkosti i Gaza, No. 6, pp. 135–142, November–December, 1972.     

Formulas for the heat and diffusion fluxes to a catalytic surface in a chemically nonequilibrium multicomponent boundary layer

On the basis of an asymptotic expansion of the solution of the equations of a multicomponent chemically nonequilibrium boundary layer for large Schmidt numbers, formulas are obtained for the heat flux and the diffusion fluxes of the reaction products and chemical elements on a surface with arbitrary catalytic activity. The results are compared with well-known analytic and numerical solutions. The comparison reveals the high accuracy of the formulas proposed. The results of calculating the diffusional separation of the mixture due to the selectivity of the catalytic properties of the surface with respect to recombination of oxygen and nitrogen atoms are presented. Values of the reduction of the convective heat fluxes due to the catalytic properties of the surface are obtained over a wide range of conditions in the free stream.Moscow. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 2, pp. 171–176, March–April, 1996.     

Definition and calculation of effective ambipolar diffusion coefficients for a laminar multicomponent ionized boundary layer

Effective diffusion coefficients substantially facilitate solution of detailed problems for multicomponent boundary layers with frozen-in reactions in the flow and heterogeneous reactions at the wall; they provide physically lucid correlation formulas and final equations for the convective heat flow to the undamaged solid as well as for the mass loss rate or effective erosion enthalpy if the walls are subject to thermochemical attack [1–5].Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 4, pp. 60–72, July–August, 1970.     

Ignition of hydrogen in a turbulent boundary layer on a plate

The ignition of hydrogen blown into a turbulent supersonic boundary layer on a flat plate is investigated numerically. It is assumed that the mixture consists of six chemically active components H, O, OH, H₂O, O₂, H₂ and inert nitrogen N₂. The boundary layer is divided into outer and inner regions, for which different expressions for the coefficients of turbulent transport are used. The influence of pulsations on the rates of the chemical reactions, and also the back reaction of the chemical processes on the mechanism of turbulent transfer are not taken into account. The surface of the plate is assumed to be absolutely catalytic with respect to the recombination reactions of the H and O atoms. The influence of the blowing intensity, the Mach number in the outer flow, and the pressure on the ignition delay is analyzed. The possibility of effective porous cooling of the surface when there is combustion in the boundary layer is demonstrated.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 33–40, November–December, 1979.I thank V. G. Gromov and V. A. Levin for their interest in the work.     

Flow of a supersonic low-density jet of nitrogen and nitrogen-hydrogen mixture over a blunt body

This paper gives the results of electron-beam measurements of the rotational temperature of nitrogen and its concentration in front of a spherically blunt cylinder situated on the axis of a supersonic rarefied jet of nitrogen and nitrogen-hydrogen mixture.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 6, pp. 50–55, November–December, 1972.     

Conjugated heat and mass transfer between a reactive solid and a gas in the presence of nonequilibrium chemical reactions

An investigation of a multicomponent boundary layer taking account of nonequilibrium chemical reactions has been made in a number of publications [1–3]; here, the temperature of the solid was assumed to be known or was determined from the condition of the conservation of energy at the interface between the gas and the solid, taking account of the solution of the equation of thermal conductivity in the solid phase. At the same time, heating of the material of a coating is an unavoidable step in any mechanism of thermokinetic decomposition and, in view of this, it is necessary to take account of the lag of the heat-transfer process inside the solid. Therefore, it is necessary to solve the equation of the energy balance in the solid phase simultaneously with the system of the equations of the boundary layer, i.e., the conjugate problem. The present article discusses the problem of flow around a solid in the vicinity of a frontal critical point, taking account of the dependence of the processes taking place in the solid body on the time, in the presence of two heterogeneous and one homogeneous reactions. The distributions of the velocity, the temperature, and the concentrations in the boundary layer are obtained, as well as the mass rate of entrainment of the material at different moments of time. The time of the change between kinetic and diffusion conditions of the course of the heterogeneous chemical reactions (the ignition time) is determined. It is established that, in the presence of a homogeneous chemical reaction, the mass rate of entrainment is less than with a frozen flow.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 121–128, March–April, 1974.     

Three-dimensional chemically nonequilibrium viscous shock layer on a catalytic surface with allowance for associated heat transfer

A three-dimensional flow of dissociating air past blunt bodies is investigated in the framework of the thin viscous shock layer theory. Multicomponent diffusion and homogeneous chemical reactions, including dissociation, recombination, and exchange reactions, are taken into account. The generalized Rankine-Kugoniot conditions are specified on the shock wave and the conditions which take into account the heterogeneous catalytic reactions, on the surface of the body. The viscous shock layer equations are solved together with the heat equations inside the coating, which is carbon with a deposited thin film of SiO₂, or quartz. The case of a thermally insulated surface is also considered. The problem for the case of the motion of a body along the re-entry trajectory into Earth's atmosphere is investigated numerically. The temperature of the surface and the heat flux toward it are given as a dependence on the height (tine) of the flight for different cases of the specification of the catalytic reactions. It is shown that the difference between the heat fluxes towards the thermally insulated surface and the fluxes toward the heat-conducting surface in the neighborhood of the stagnation point is of the order of 6–12% for all the cases considered. This makes it possible to decouple the solution of the problem of heat conduction in the body.Translated fron Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 140–146, November–December, 1985.deceased     

Investigation of a dense,chemically reacting plasma by the high-frequency probe potential modulation method

A method is proposed for investigating a chemically reacting plasma by means of an electric probe whose potential is modulated by a high-frequency sinusoidal voltage. The method is based on the use of a numerical solution of the problem of an electric probe introduced under negative potential into a steady-state low-temperature plasma formed in a mixture of chemically reacting molecular gases. The conditions under which the charged particle concentration in the region undisturbed by the probe is constant as a result of equilibrium between the ionization and recombination rates are examined.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 114–119, November–December, 1987.     

Catalytic properties of a copper transducer for determining flow parameters in a high-frequency induction plasmatron

The rate coefficients of the elementary stages of the complete system of heterogeneous catalytic recombination of dissociated oxygen on a copper oxide surface are determined on the basis of quantum-mechanics calculations within the framework of cluster models. The coefficients are used to calculate the dependence of the effective coefficient of heterogeneous catalytic recombination of oxygen atoms on the temperature and the partial pressure on a wide range of surface conditions. It is established that it can considerably vary depending on these conditions.     

Numerical study of the structure of a finely disperse unsteady two-phase jet

The structure of an unsteady two-phase jet is numerically studied within the framework of the model of a heterogeneous medium with nonequilibrium velocities and temperatures with allowance for particle collisions and intergranular pressure.Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 46, No. 2, pp. 91–97, March–April, 2005.