表面活性剂减阻水溶液突扩流的阻力特性

为揭示胶束水溶液突扩流的减阻特性,实验研究了质量分数为1×10-4, 2 ×10-4的十六烷基三甲基溴化铵水溶液通过管径比为1:1.52的突扩的流动阻力行为. 实验结果表明,在直管段最大减阻率都可达到70%的两给定质量分数的胶束水溶液,其突扩局部阻力系数,在较低雷诺数区域,较牛顿流体仅有10%~20%程度的降低,呈现局部低减阻特性;在较高雷诺数区域远大于牛顿流体,尤其当突扩进口流快失去减阻能力时,甚至接近牛顿流体的1.5倍,呈现明显的局部增阻行为. 胶束水溶液减阻流,在突扩下游再次形成充分发展流所需的下游长度,远大于牛顿流体的7.8倍下游管径(45倍突扩台阶高度),流入突扩前完全失去减阻能力的质量分数为2×10-4的胶束水溶液流,所需的突扩下游长度达到最大,约合158倍下游管径(920倍突扩台阶高度). 通过胶束水溶液流变特性的实验分析认为,减阻水溶液突扩流的阻力行为与它的胶束网联结构的形成及松弛的时间特性密切相关.      

On pipe diameter effects in surfactant drag-reducing pipe flows

Remarkable power saving in a fluid transport system is possible if the surfactant drag reduction technology is used. Application of surfactant drag reduction to district heating and cooling systems has been investigated in the past. The establishment of the scale-up law in drag-reducing pipe flows is one of the most important problems in this application. Main purpose of this study is aimed to develop a reliable scale-up law in surfactant drag-reducing flows. As the basic data of surfactant solutions, both non-Newtonian viscosity and viscoelasticity were experimentally determined. A turbulent eddy diffusivity model based on the Maxwell model was employed to estimate the drag reduction of surfactant solutions. The predictions by the turbulence model developed in this study with proper rheological characteristics of surfactant solutions has resulted in a reliable estimation of the pipe diameter effect in surfactant drag-reducing flows over the pipe diameter range from 11 to 150mm. Received: 30 June 1997 Accepted: 29 December 1997     

Flow patterns and heat transfer in vertical upward air–water flow with surfactant

Flow patterns, the pressure drag reduction and the heat transfer in a vertical upward air–water flow with the surfactant having negligible environmental impact were studied experimentally in a tube of 2.5 cm in diameter. Visual observations showed that gas bubbles in the air–water solution with surfactant are smaller in size but much larger in number than in pure air–water mixture, at the all flow regimes. The transition lines in the flow regime map for the solution of air–water mixture with surfactant of the 300 ppm concentration are mainly consistent with the experimental data obtained in clear air–water mixture. An additive of surfactant to two-phase flow reduces the total pressure drop and decrease heat transfer, especially in the churn flow regime.     

添加剂湍流减阻流动与换热研究综述

添加剂湍流减阻是指在液体的管道湍流中添加少量的高分子聚合物或某种表面活性剂从而使湍流阻力大大降低的现象.从其被发现至今,经过近半个世纪的研究(实验研究、理论分析、数值模拟和实际系统的应用研究),尽管对这一现象及其实际应用价值已有了较为深入的认识,但仍有许多方面尚有欠缺,例如对湍流减阻的机理仍然在探索中.本文归纳评述了高分子聚合物或表面活性剂添加剂湍流减阻流动与换热现象的研究现状,从湍流减阻剂的特性、减阻剂的湍流减阻机理、湍流减阻发生时的换热机理、减阻流动速度场分布和换热控制等几个方面综述了添加剂湍流减阻流动与换热特性,并综述了湍流减阻剂在实际工业系统中的应用情况,在对添加剂湍流减阻机理、有湍流减阻发生时的对流换热机理等的理解方面进行了新的总结.      

Experimental study on the effects of shear induced structure in a drag-reducing surfactant solution flow

In this paper, The drag reduction characteristics of surfactant solutions have been experimentally studied, as well as, the shear viscosities of turbulent drag-reducing surfactant solution have been measured as a function of concentration, shear rate and temperature by using AG-G2 (TA Instruments, New Castle, USA) rheometer. In comparison the rheological property with the macroscopic behavior of the solutions in turbulent channel flow, a deeper insight into the mechanisms of drag-reducing surfactant solution has been obtained. For no shear induced structure of surfactant solutions they just show features shear thinning, but the drag reduction is very significant phenomenon. Surfactant solution of the shear induced structure is not a surfactant fluid drag reduction of the necessary elements.     

Rheological characteristics of trimethylolethane hydrate slurry treated with drag-reducing surfactants

Rheological characteristics of trimethylolethane (TME) clathrate–hydrate slurry treated with drag-reducing surfactants were investigated. Friction coefficients and apparent viscosities were measured when the concentration of TME and its hydrate fraction treated with and without drag-reducing surfactants were changed in several steps. From the results, it is found that the surfactant addition causes effective drag reduction in a pipe flow when the hydrate fraction becomes high, while effective drag reduction disappears in the cases of low hydrate fraction. The results of viscosity measurements indicate that the TME molecules disturb the formation of shear-induced structures (SIS) causing drag reduction phenomena. To investigate this interaction between TME and surfactant micelles, the effect of TME concentration on viscosity and relaxation time of solutions was discussed. From this, it was found out that there exists a critical concentration of TME on the formation of SIS and that it becomes larger as shear rate increases. Thus, we conclude that this interaction between TME and micellar structures causes less drag reduction for the cases of low hydrate fraction, while the drag reduction appears in cases of high hydrate fraction because TME concentration in liquid phase becomes small.     

矩形槽道内表面活性剂减阻流体场特性

采用粒子图像测速仪对矩形槽道内表面活性减阻流体在流动方向(x方向)与壁 面垂直方向(y方向)所在平面的流场进行了测量,分析了速度、涡量、速度脉 动相关量在流场内的瞬态分布,以及对500幅相同工况的流场进行了统计平均. 结 果显示: 与牛顿流体相比, 表面活性剂减阻流体接近于层流流动,横向速度脉动被大幅 减弱,导致湍流输运减弱,雷诺应力远远小于水. 减阻流体流向速度脉动呈条带 特征,沿流动方向发展,反映了减阻流体不同于水的湍流输运特征.     

Experiments in Turbulent Pipe Flow with Polymer Additives at Maximum Drag Reduction

In this paper we report on (two-component) LDV experiments in a fully developed turbulent pipe flow with a drag-reducing polymer (partially hydrolyzed polyacrylamide) dissolved in water. The Reynolds number based on the mean velocity, the pipe diameter and the local viscosity at the wall is approximately 10000. We have used polymer solutions with three different concentrations which have been chosen such that maximum drag reduction occurs. The amount of drag reduction found is 60–70%. Our experimental results are compared with results obtained with water and with a very dilute solution which exhibits only a small amount of drag reduction. We have focused on the observation of turbulence statistics (mean velocities and turbulence intensities) and on the various contributions to the total shear stress. The latter consists of a turbulent, a solvent (viscous) and a polymeric part. The polymers are found to contribute significantly to the total stress. With respect to the mean velocity profile we find a thickening of the buffer layer and an increase in the slope of the logarithmic profile. With respect to the turbulence statistics we find for the streamwise velocity fluctuations an increase of the root mean square at low polymer concentration but a return to values comparable to those for water at higher concentrations. The root mean square of the normal velocity fluctuations shows a strong decrease. Also the Reynolds (turbulent) shear stress and the correlation coefficient between the stream wise and the normal components are drastically reduced over the entire pipe diameter. In all cases the Reynolds stress stays definitely non-zero at maximum drag reduction. The consequence of the drop of the Reynolds stress is a large polymer stress, which can be 60% of the total stress. The kinetic-energy balance of the mean flow shows a large transfer of energy directly to the polymers instead of the route by turbulence. The kinetic energy of the turbulence suggests a possibly negative polymeric dissipation of turbulent energy. This revised version was published online in July 2006 with corrections to the Cover Date.     

Analysis of an organized turbulent structure using a pattern recognition technique in a drag-reducing surfactant solution flow

This work presents the investigation for an organized turbulent structure in a drag-reducing flow of dilute surfactant solution by utilizing a particle image velocimetry system to perform the pattern recognition technique on a trajectory in four quadrants of streamwise and wall-normal velocity fluctuations. The pattern recognition is added to a new algorithm in order to directly capture the spatial rotation motion. The Reynolds number based on the channel height and bulk mean velocity was set to 1.5 × 10⁴. Surfactant solution with a weight concentration of 150 ppm was employed and the drag reduction rate was 65%. In the drag-reducing flow, we observe increased frequencies of occurrence of the flow events that correspond to a meandering motion in the wall-normal direction of the high-and low-speed regions. Three findings from investigation of the ensemble-averaged Reynolds shear stress and vortex structure are as follows: (i) the Reynolds shear stress in the large fluctuation range occurs in the narrow region; (ii) Size, strength, arrangement and inclination in the spatial vortex structure in the drag-reducing flow differ from those of the water; and (iii) all trajectory contributions for the wall friction coefficient decrease. Finally, we interpreted that the viscoelasticity characterizing the viscoelastic stress and relaxation time in rheological properties of the flow changes specific elementary vortex for the drag-reducing flow, and the trajectories of each flow pattern change drastically.     

Investigation of turbulence structures in a drag-reduced turbulent channel flow with surfactant additive by stereoscopic particle image velocimetry

In the present study, we employed stereoscopic particle image velocimetry (PIV) to investigate the characteristics of turbulence structures in a drag-reduced turbulent channel flow with addition of surfactant. The tested drag-reducing fluid was a CTAC/NaSal/Water (CTAC: cetyltrimethyl ammonium chloride; NaSal: sodium salicylate) system at 25°C. The weight concentration of CTAC was 30 ppm. Stereoscopic PIV measurement was performed for a water flow (Re=1.1×10⁴) and a CTAC solution flow (Re=1.5×10⁴ with 54% drag reduction) in both the streamwise–spanwise and wall-normal-spanwise planes, respectively. The three-dimensionality of hairpin vortex structures in the near-wall region for wall-bounded turbulent flow was reproduced by conditionally averaging the stereoscopic two-dimensional-three-component velocity fields. A series of wall-normal vortex cores were found to align with the near-wall low-speed streaks with opposite vorticity signals at both sides of the streaks and with the vorticity decreased on average by about one order of magnitude in CTAC solution flow compared with water flow; the spanwise spacing between the near-wall low-speed streaks in the solution flow is increased by about 46%. The streamwise vorticity of the vortex cores appearing in the wall-normal-spanwise plane was also decreased by the use of drag-reducing surfactant additives.     

Visual study of bursting using infrared technique

The turbulent flow of water and high drag-reducing surfactant solution in a flume was studied experimentally. We used a new method of burst frequency detection based on visual observation of the thermal spots on the free fluid surface. An analysis and comparison with results of previous investigations is presented in this study, with a special emphasis on the connection between the bursting frequency in drag-reducing solutions and onset of drag reduction. The effect of burst damping is discussed.     

矩形槽道内表面活性剂减阻流体流场特性

采用粒子图像测速仪对矩形槽道内表面活性减阻流体在流动方向(x方向)与壁面垂直方向(y方向)所在平面的流场进行了测量,分析了速度、涡量、速度脉动相关量在流场内的瞬态分布,以及对500幅相同工况的流场进行了统计平均. 结果显示: 与牛顿流体相比, 表面活性剂减阻流体接近于层流流动,横向速度脉动被大幅减弱,导致湍流输运减弱,雷诺应力远远小于水. 减阻流体流向速度脉动呈条带特征,沿流动方向发展,反映了减阻流体不同于水的湍流输运特征.      

Viscoelasticity of a surfactant and its drag-reducing ability

There is considerable interest in the use of viscoelastic cationic surfactant-counterion mixtures in district heating and cooling systems to reduce pressure losses. A recent field test in a secondary system near Prague showed a 30+% reduction in pumping energy requirements.We have studied a number of commercial surfactants and we report here results of rheological, drag reduction and turbulence measurements on Arquad 18–50 (octadecyl trimethyl ammonium chloride (AR 18)) with an excess of sodium salicylate (NA). The concentration studied was 1.6 mM AR 18 and 4.0 mM NA which is about one third the concentration for excellent drag reduction in this surfactant's effective temperature range 30–90°C.Viscosity, , vs. shear rate,D, first normal stress difference,N ₁, vs. shear rate, drag reduction (as pressure drop,i=P/1) vs. average velocity,U _ave, in a 39.4 mm tube for AR 18, and turbulence intensity data for three drag reducing surfactants are reported.Of particular interest are the generally low turbulence intensities in all three directions which correspond to reduced heat, mass and momentum transfer rates compared to water, and the existence of large normal stress differences at 20°C for AR 18, a temperature at which no drag reduction occurs with this surfactant, indicating that normal stress effects do not correlate directly with drag reduction.The effect of time of pumping on increasing drag reduction demonstrates that this factor overwhelms the expected increase in drag reduction as temperature is raised from 18–19°C to 40.5°C.     

Influence of bubble size on micro-bubble drag reduction

Micro-bubble drag reduction experiments were conducted in a turbulent water channel flow. Compressed nitrogen was used to force flow through a slot injector located in the plate beneath the boundary layer of the tunnel test section. Gas and bubbly mixtures were injected into a turbulent boundary layer (TBL), and the resulting friction drag was measured downstream of the injector. Injection into tap water, a surfactant solution (Triton X-100, 20 ppm), and a salt-water solution (35 ppt) yielded bubbles of average diameter 476, 322 and 254 μm, respectively. In addition, lipid stabilized gas bubbles (44 μm) were injected into the boundary layer. Thus, bubbles with d ⁺ values of 200 to 18 were injected. The results indicate that the measured drag reduction by micro-bubbles in a TBL is related strongly to the injected gas volumetric flow rate and the static pressure in the boundary layer, but is essentially independent of the size of the micro-bubbles over the size range tested.     

Flow and heat transfer characteristics of drag reducing surfactant solution in a helically coiled pipe

The reduction characteristic of turbulent drag and heat transfer of drag reduction surfactant solution flowing in a helically coiled pipe were experimentally investigated. The drag reduction surfactant used in the present study was the amine oxide type nonionic surfactant of oleyldihydroxyethylamineoxide (ODEAO, C₂₂H₄₅NO₃=371). The zwitterion surfactant of cetyldimethylaminoaciticacidbetaine (CDMB, C₂₀H₄₁NO₂=327) was added by 10% to the ODEAO solution in order to avoid the chemical degradation of ODEAO by ionic impurities in a test tape water. The experiments of flow drag and heat transfer reduction were carried out in the helically coiled pipe of coil to pipe diameter ratio of 37.5 and the helically coiled pipe length to pipe diameter of 1180.5 (pipe diameter of 14.4 mm) at various concentrations, temperatures and flow velocities of the ODEAO surfactant solution. The ODEAO solution showed a non-Newtonian behavior at high concentration of the ODEAO. From the experimental results, it was observed that the friction factor of the ODEAO surfactant solution flowing through the coiled pipe was decreased to a great extent in comparison with water as a Newtonian fluid in the turbulent flow region. Heat transfer measurements for water and the ODEAO solution were performed in both laminar and turbulent flow regions under the uniform heat flux boundary condition. The heat transfer coefficients for the ODEAO solution flow were the same as water flow in the laminar region. On the other hand, heat transfer reduction of the ODEAO solution flow was remarkedly reduced as compared with that of the water flow in the turbulent flow region.     

On two distinct types of drag-reducing fluids,diameter scaling,and turbulent profiles

Two distinct scaling procedures were found to predict the diameter effect for different types of drag-reducing fluids. The first one, which correlates the relative drag reduction (DR) with flow bulk velocity (V), appears applicable to fluids that comply with the 3-layers velocity profile model. This model has been applied to many polymer solutions; but the drag reduction versus V scaling procedure was successfully tested here for some surfactant solutions as well. This feature, together with our temperature profile measurements, suggest that these surfactant solutions may also show this type of 3-layers velocity profiles (3L-type fluids).The second scaling procedure is based on a correlation of τ_w versus V, which is found to be applicable to some surfactant solutions but appears to be applicable to some polymer solutions as well. The distinction between the two procedures is therefore not simply one between polymer and surfactants. It was also seen that the τ_w versus V correlation applies to fluids which show a stronger diameter effect than those scaling with the other procedure. Moreover, for fluids that scale according to the τ_w versus V procedure, the drag-reducing effects extend throughout the whole pipe cross section even at conditions close to the onset of drag reduction, in contrast to the behavior of 3L fluids. This was shown by our measurements of temperature profiles which exhibit a fan-type pattern for the τ_w versus V fluids (F-type), unlike the 3-layers profile for the fluids well correlated by drag reduction versus V. Finally, mechanically-degraded polymer solutions appeared to behave in a manner intermediate between the 3L and F fluids.Furthermore, we also showed that a given fluid in a given pipe may transition from a Type A drag reduction at low Reynolds number to a Type B at high Reynolds number, the two types apparently being more representative of different levels of fluid/flow interactions than of fundamentally different phenomena of drag reduction. After transition to the non-asymptotic Type B regime, our results suggest that, without degradation, the friction becomes independent of pipe diameter and that the drag reduction level becomes also approximately independent of the Reynolds number, in a strong analogy to Newtonian flow.     

Turbulent pipe flow of a drag-reducing rigid “rod-like” polymer solution

Fully developed turbulent pipe flow of an aqueous solution of a rigid “rod-like” polymer, scleroglucan, at concentrations of 0.005% (w/w) and 0.01% (w/w) has been investigated experimentally. Fanning friction factors were determined from pressure-drop measurements for the Newtonian solvent (water) and the polymer solutions and so levels of drag reduction for the latter. Mean axial velocity u and complete Reynolds normal stress data, i.e. u′, v′ and w′, were measured by means of a laser Doppler anemometer at three different Reynolds numbers for each fluid. The measurements indicate that the effectiveness of scleroglucan as a drag-reducing agent is only mildly dependent on Reynolds number. The turbulence structure essentially resembles that of flexible polymer solutions which also lead to low levels of drag reduction.     

An investigation of possible mechanisms of heterogeneous drag reduction in pipe and channel flows

When concentrated polymer solutions are injected into the core-region of a turbulent pipe or channel flow, the injected polymer solution forms a thread which preserves its identity far beyond the injection point. The resulting drag reduction is called heterogeneous drag reduction.This study presents experimental results on the mechanism of this type of drag reduction. The experiments were carried out to find out whether this drag reduction is caused by small amounts of polymer removed from the thread and dissolved in the near-wall region of the flow or by an interaction of the polymer thread with the turbulence. The friction behavior of this type of drag reduction was measured for different concentrations in pipes of different cross-sections, but of identical hydraulic diameter. The parameters of the injection, i.e. injector geometry as well as the ratio of the injection to the bulk velocity, were varied. In one set of experiments the polymer thread was sucked out through an orifice and the friction behavior in the pipe was determined downstream of the orifice. In another experiment, near-wall fluid was led into a bypass in order to measure its drag reducing properties. Furthermore, the influence of a water injection into the near-wall region on the drag reduction was studied.The results provide a strong evidence that heterogeneous drag reduction is in part caused by small amount of dissolved polymer in the near-wall region as well as by an interaction of the polymer thread with the turbulence.Nomenclature a channel height - b channel width - c _p concentration of the injected polymer solution - c _R effective polymer concentration averaged over the cross-section - d pipe or hydraulic diameter - d _i injector diameter - DR drag reduction - f friction factor - l downstream distance from injector - L length of a pipe segment - P polymer type - p differential pressure - Re Reynolds number - U bulk velocity - u ^* ratio of injection to bulk velocity - y ⁺ dimensionless wall distance - v kinematic viscosity - density of the fluid - _w wall shear stress     

Surfactant systems for drag reduction: Physico-chemical properties and rheological behaviour

The first part of the work presents an overview of the physical chemistry of surfactants which in aqueous solutions reduce the frictional loss in turbulent pipe flow. It is shown that these surfactants form rodlike micelles above a characteristic concentraionc _t. The experimental evidence for rodlike micelles are reviewed and the prerequisites that the surfactant system must fulfill in order to form rodlike micelles are given. It is demonstrated by electrical conductivity measurements that the critical concentration for the formation of spherical micelles shows little temperature dependence, whereasc _t increases very rapidly with temperature. The length of the rodlike micelles, as determined by electric birefringence, decreases with rising temperature and increases with rising surfactant concentration. The dynamic processes in these micellar systems at rest and the influence of additives such as electrolytes and short chain alcohols are discussed.In the second part, the rheological behaviour of these surfactant solutions under laminar and turbulent flow conditions are investigated. Viscosity measurements in laminar pipe and Couette flow show the build-up of a shear induced viscoelastic state, SIS, from normal Newtonian fluid flow. A complete alignment of the rodlike micelles in the flow direction in the SIS was verified by flow birefringence. In turbulent pipe flow, drag reduction occurs in these surfactant systems as soon as rodlike micelles are present in the solution. The extent and type of drag reduction, i.e. the shape of the friction factor versus Reynolds number curve, depends directly on the size, number and surface charge of the rodlike micelles. The friction factor curve of each surfactant investigated changes in the same characteristic way as a function of temperature. For each surfactant, independent of concentration, an upper absolute temperature limit,T _L, for drag reduction exists which is caused by the micellar dynamics.T _L is influenced by the hydrophobic chain length and the counter-ion of the surfactant system. A first attempt is made to explain the drag reduction of surfactants by combining the results of these rheological measurements with the physico-chemical properties of the micellar systems.     

Drag reduction in aqueous cationic soap solutions

The pipe flow drag-reducing properties of mixtures of alkyltrimethylammonium halides with 1-naphthol in aqueous solution have been investigated. The effects of solution concentration, soap-naphthol ratio, soap molecular weight and solution temperature upon drag reduction and swirl decay time are reported. The critical wall shear stresses above which the drag-reducing properties cease correlate well with swirl decay time. At low soap concentrations greater than equimolar proportions of 1-naphthol with the soap are required for maximum drag reduction. The drag-reducing properties of these solutions are greatest at and around the Krafft point of the pure soap. A phenomenon similar to onset for polymer solution drag reduction is reported for these soap solutions.