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1.
The experimental isothermal P– x data at T=313.15 K for the two ternary systems (isopropyl ether+ n-heptane+1-hexene) and (1-hexene+ n-heptane+benzene) are reported. Data reduction by Barker’s method provides correlation for GE. The Wohl expansion, also Wilson, NRTL and UNIQUAC models have been applied successfully to the ternary systems. The experimental data, in this work are not available in the literature. 相似文献
2.
Vapor Liquid Equilibria in mixtures of dimethyl ether, methyl chloride and methanol were investigated in a static equilibrium apparatus for temperatures 250 K < T <350 K and pressures up to 1 MPa. Temperature, pressure and the composition of the liquid and the vapor phase were determined.The consistency of the binary experimental data was checked and parameters of several g E-models were fitted. The binary parameters were used to predict the ternary VLE and the calculated results were compared with the experimental data. 相似文献
3.
Experimental isothermal P– x data at T=313.15 K for seven binary systems (1,1-dimethylethyl methyl ether (MTBE)+2,2,4-trimethylpentane); (1,1-dimethylethyl methyl ether (MTBE)+toluene); (toluene+2,2,4-trimethylpentane); (toluene+1-hexene); (toluene+cyclohexane); (2,2,4-trimethylpentane+1-hexene) and (2,2,4-trimethylpentane+cyclohexane) are reported. Data reduction by Barker’s method provides correlations for GE using the Margules equation, Wilson, NRTL and UNIQUAC models, which have been applied successfully. We have compared the behaviour in the vapour–liquid equilibrium of the aromatic compounds benzene and toluene and the paraffins heptane and 2,2,4-trimethylpentane. And finally we have modelled a gasoline of five components using the Wilson model, and we have compared the influence of three different ethers used as oxygenated additives in gasolines. 相似文献
4.
Isothermal vapour–liquid equilibrium data are reported for binary mixtures of propan-2-one with 1,1,2,2-tetrachloroethane (I) and 1,4-dichlorobutane (II) within the 298.15–313.15 K temperature range. Total vapour pressures were measured by a static method, the mixtures beeing prepared by weight and degased directly into the working cell. The experimental data were correlated by Barker's method and different expressions for excess Gibbs energy were tested. The results indicate negative deviation from ideality for mixture (I), while mixture (II) behaves almost ideally, with slightly positive deviations. 相似文献
5.
Experimental isothermal P– x data at 313.15 K for the ternary system ( tert-amylmethyl ether (TAME)+ n-heptane+methanol) and for one of the unmeasured constituent binary systems, ( tert-amylmethyl ether (TAME)+methanol) are reported. Data reduction by Barker's method provides correlations for gE using the Margules equation for the binary systems and the Wohl expansion for the ternary system. Wilson, NRTL and UNIQUAC models have been applied successfully to both the binary and the ternary systems. The presence of azeotropes in the ternary system and constituent binaries are studied as well as the presence of immiscible zones. 相似文献
6.
Liquid–liquid equilibrium (LLE) data were determined for two binary systems { di-isopropyl ether (DIPE) + 1-ethyl-3-methylimidazolium-ethylsulfate (EMISE)} and {DIPE + 1-butyl-3-methylimidazolium-tetrafluoroborate([Bmim][BF 4])}at temperatures between 293.15 K and 313.15 K. LLE data for six ternary systems {DIPE + water + EMISE} and {DIPE + water + [Bmim][BF 4]} at 293.15 K, 303.15 K, and 313.15 K were also reported. Experiments were carried out at atmospheric pressure using stirred and thermo-regulated cells. The experimental data were correlated with the well-known NRTL and UNIQUAC activity coefficient models. In addition, distribution coefficients and selectivities of the ionic liquids EMISE and [Bmim][BF 4] for water in the DIPE phase were measured. 相似文献
7.
Zeck, S. and Knapp, H., 1986. Vapor-liquid and vapor-liquid-liquid phase equilibria for binary and ternary systems of nitrogen, ethane and methanol; experiment and data reduction. Fluid Phase Equilibria, 25: 302–322.VLE and VLLE are investigated for three binary and one ternary system containing N 2, C 2H 6 and CH 3OH in a high-pressure phase equilibrium apparatus with vapor recirculation at temperatures 240 < T < 298 K and pressures 4 < p < 75 bar. Two liquid phases are observed in the systems C 2H 6CH 3OH and N 2CH 3OH. Experimental results are reported and compared with available correlations. 相似文献
8.
A static high pressure equilibrium facility has been used to obtain P − x − y measurements for the methanol—acetone binary for the three isotherms 372.8, 397.7 and 422.6 K. These measurements show that maximum pressure azeotropic behaviour exists at each of these temperatures. The data obtained have been correlated satisfactorily using the three suffix Margules equation. A comparison has been made between the information resulting from this study and the high pressure data of Griswold and Wong. Parameters of the three suffix Margules equation have been correlated with temperature over the range 285–425 K using additional vapor—liquid equilibrium and excess enthalpy data available in the literature. These correlations have been used to predict isobaric behavior. Auxiliary expressions have been developed which relate azeotropic pressure and composition to temperature. 相似文献
9.
Vapor–liquid equilibrium (VLE) data are reported for the binary mixtures formed by octane and the branched ether 1,1-dimethylpropyl methyl ether ( tert-amyl methyl ether or TAME). A Gibbs–van Ness type apparatus was used to obtain total vapor pressure measurements as a function of composition at 298.15, 308.15, 318.15 and 328.15 K. The system shows positive deviations from Raoult’s law. These VLE data are analyzed together with data previously reported for octane+TAME mixtures: VLE data at 323.15 and 423.15 K, excess enthalpy ( HmE) data at 298.15 and 313.15 K and excess volume ( VmE) data at 298.15 K. The UNIQUAC model, the lattice–fluid (LF) model, and the Flory theory are used to simultaneously correlate VLE and HmE data. The two latter models are then used to predict VmE data. The original UNIFAC group contribution model and the modified UNIFAC (Dortmund model) are used to predict VLE data. 相似文献
10.
Zeck, S. and Knapp, H., 1986. Vapor—liquid and vapor—liquid—liquid phase equilibria of binary and ternary systems of nitrogen, ethene and methanol: experiment and data evaluation. Fluid Phase Equilibria, 26: 37–58.VLE and VLLE of three binary and one ternary system containing the components N 2, C 2H 4 and CH 3OH are investigated in a high-pressure phase equilibrium apparatus with vapor recirculation at temperatures 240 < T < 298 K and pressures 4 < p < 100 bar. Immiscibilities in the liquid phase are observed in the binary system C 2H 4CH 3OH with a lower critical end point and in the ternary system N 2C 2H 4CH 3OH.The experimental results are reported and compared with the results of other investigators and of available correlations. 相似文献
11.
Isobaric vapor–liquid equilibria data at 101.3?kPa were reported for the binary mixtures ethyl tert butyl ether (ETBE)?+?( p-xylene, m-xylene and ethylbenzene). VLE experimental data were tested for thermodynamic consistency by means of a modified Dechema test and was demonstrated to be consistent. The activity coefficients were correlated with the Margules, van Laar, UNIQUAC, NRTL, and Wilson equations. The Analytical Solution Of Groups (ASOG) model also was applied for prediction. 相似文献
12.
Isobaric vapor–liquid equilibria (VLE) have been obtained for the systems trichloroethylene+1-pentanol, trichloroethylene+2-methyl-1-butanol and trichloroethylene+3-methyl-1-butanol at 100 kPa using a dynamic still. The experimental error in temperature is ±0.1 K, in pressure ±0.1 kPa, and in the liquid and vapor mole fraction ±0.001. The three systems satisfy the point-to-point thermodynamic consistency test. All the systems show positive deviations from ideality. The data have been correlated with the Margules, van Laar, Wilson, NRTL and UNIQUAC equations. 相似文献
13.
The excess molar volume of the ternary mixture [2-propanol?+?ethyl acetate?+?n-hexane], and its binary constituents; [2-propanol?+?ethyl acetate], [2-propanol?+?n-hexane] and [ethyl acetate?+?n-hexane] were evaluated by the mixtures density measurements over the whole concentration range at three temperatures 298.15, 308.15 and 313.15?K. The excess molar volumes data were fitted to the Redlich–Kister (RK) type equation and the parameters of this equation have been calculated and presented for the studied mixtures. 相似文献
14.
Experimental data of vapour–liquid equilibrium (VLE) for the binary systems tetrahydrofuran, or tetrahydropyran, or 2-methyl-tetrahydrofuran, or 2,5-dimethyl-tetrahydrofuran with bromocyclohexane have been measured in isobaric conditions at two pressures, 40.0 and 101.3?kPa. The equipment used was a dynamic recirculating still. The consistency of the measured VLE data has been tested with the Van Ness’ point-to-point method. The activity coefficients have been correlated with the mole fraction through Wilson, NRTL and UNIQUAC equations. 相似文献
15.
The estimation of solid–liquid phase equilibrium is important for the design, development, and operation of many industrial processes because of application in many manufacturing fields such as cosmetic, pharmaceutic, and biotechnology industries. In this work, we measured solid–liquid phase equilibrium of six fatty acid binary mixtures using the DSC technique and developed thermodynamic approaches for binary fatty acid mixtures to estimate melting temperatures as a function of mole fraction in solid–liquid phase equilibrium. Derivation of NRTL and UNIQUAC activity models was developed to predict melting temperatures and latent heat to achieve eutectic points of undecylic acid, pentadecylic acid, margaric acid, and stearic acid six pairwise binary mixtures. The fatty acids eutectic mixtures are appropriate for heat water systems, phase clothes, concrete, and other similar applications. The results showed low deviations from experimental data measured in this study. 相似文献
16.
Isothermal vapor–liquid equilibrium (VLE) data for the propane+1,1,1,2,3,3,3-heptafluoropropane (R227ea) binary system were measured at 293.16, 303.14, 313.14, 333.15, 343.16 and 353.18 K and pressures up to 3.5 MPa. The experimental method, used in this work, is of the static-analytic type. It takes advantage of two pneumatic capillary samplers (Rolsi™, Armines’ patent) developed in the Cenerg/TEP laboratory. The peculiarity of R227ea–propane binary system is to present azeotropic behavior at each studied temperature.The six sets of isothermal P, x, y data are represented with the Soave–Redlich–Kwong (SRK) equation of state (EoS) and several mixing rules involving the NRTL model. 相似文献
17.
Excess molar volumes, VmE, at 298.15 K and atmospheric pressure over the entire composition range for binary mixtures of 2-butanone with di- n-butyl ether and 2-pentanone and 3-pentanone with di- n-butyl ether and 2,5-dioxahexane, 2-heptanone and 4-heptanone with di- n-butyl ether, 2,5-dioxahexane and 3,6,9-trioxaundecane are reported from densities measured with a vibrating-tube densimeter. All the excess volumes present strong contractions when compared to those of n-alkanone+ n-alkane systems.Molar excess enthalpies HmE and VmE of the considered mixtures vary similarly. This may be attributed to interactional effects which prevail over structural effects.Flory’s theory has been applied to the systems under study. As expected, results for HmE are better when the difference in polarity of the components of the mixture decreases. VmE is often poorly represented. 相似文献
18.
Isothermal vapor–liquid equilibria at 333.15 K and 353.15 K for four binary mixtures of benzene + nonane, toluene + o-xylene, m-xylene + sulfolane and o-xylene + sulfolane have been obtained at pressures ranged from 0 to 101.3 kPa over the whole composition range. The Wilson, NRTL and UNIQUAC activity coefficient models have been employed to correlate experimental pressures and liquid mole fractions. The non-ideal behavior of the vapor phase has been considered by using the Peng–Robinson equation of state in calculating the vapor mole fraction. Liquid and vapor densities of these solutions were measured by using two vibrating tube densitometers. The excess molar volumes of the liquid phase were also determined. The P– x– y phase behavior indicates that mixtures of m-xylene + sulfolane, o-xylene + sulfolane and benzene + nonane present large positive deviations from the ideal solution and belong to endothermic mixings because their excess Gibbs energies are positive. 相似文献
19.
Liquid–liquid equilibrium (LLE) data for three binary alcohol + n-alkane (C 10–C 16) systems—methanol + decane, ethanol + tetradecane, and ethanol + hexadecane—were measured using a laser scattering technique. The experimentally determined cloud points were satisfactorily correlated by three local composition models (NRTL, Tsuboka–Katayama’s modification of the Wilson equation, and the modified complete local composition model suggested by Nagata and Tamura). Prediction of vapor–liquid equilibria by means of these models with parameters obtained from the LLE data was also tested. 相似文献
20.
Vapor–liquid equilibrium data for the difluoromethane (R32) + pentafluoroethane (R125) + propane (R290) ternary mixture were measured at 5 isotherms between 263.15 K and 323.15 K. The measurement was carried out using a circulation-type apparatus recently developed, which was validated with binary mixtures. With binary interaction parameters obtained for the three corresponding binary mixtures, VLE modeling and prediction were performed for the ternary mixture using the Peng–Robinson equation of state with the classical mixing rules and MHV1 mixing rules. Hou's group contribution model for VLE of new refrigerant mixtures was further tested with the experimental data for the ternary system. The predicted pressure and vapor phase composition were compared with experimental ones. 相似文献
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