Effect of ultrasound on adsorption of Geniposide on polymeric resin

The effects of pulse ultrasound with different pulse parameter on the adsorption isotherm and kinetics of Geniposide on Resin 1300 were studied. And the mass transfer model describing the adsorption process was constructed. Amount of Geniposide adsorbed on Resin 1300 in the presence of ultrasound is lower than that in the absence of ultrasound. At our experimental conditions, the adsorption equilibrium constant decreases with increasing ultrasonic intensity and pulse duty ratio, and with decreasing pulse period. In addition, pulse ultrasound can enhance both liquid film diffusion and intraparticle diffusion, and the intensification of liquid film diffusion with pulse ultrasound is stronger than that of intraparticle diffusion. The intraparticle diffusion coefficient D(e)/R2 increases with increasing ultrasonic intensity and pulse duty ratio, and with decreasing pulse period.     

Static foam destruction: role of ultrasound

High intensity ultrasonic vibrations were used for destabilizing the static foam structure. Ultrasonic horn as a source of ultrasonic vibration was used for the destruction of the foam. The effect of the ratio of the horn to the column diameter on the drainage and collapse rate of foam has been analyzed. Further, an empirical correlation for the initial foam collapse rate in the presence of ultrasonic horn has been developed in terms of the initial liquid hold-up, surface tension of the surfactant solution and the ratio of horn diameter to the column diameter. Efficiency of the ultrasonic horn is related to the position of the tip of the horn. Periodic supply of ultrasonic vibrations was found to be a more viable option than the continuous supply in terms of saving in energy and operating cost for defoaming using ultrasound.     

Effect of ultrasound on desorption kinetics of phenol from polymeric resin

This work mainly involves the study of desorption kinetics of phenol from polymeric resins under the influence of an ultrasound field. A new phase equilibrium-kinetics model (PEKM), for estimation of diffusion coefficient was proposed, kinetic experiments of phenol desorption on NKA-II resin in the presence and the absence of ultrasound were separately conducted, and diffusion coefficients of phenol within an adsorbent particle were estimated by means of proposed PEKM. Results showed that the use of ultrasound could enhance the diffusion of phenol within the resin. The diffusion coefficient of phenol in the resin in an ultrasonic field increased by an order of magnitude in comparison with the diffusion coefficient in the absence of ultrasound. The more intense the ultrasonic field the larger was the diffusion coefficient.     

超声波在树脂再生中的应用

本文阐述了超声波用于树脂再生的最新技术，超声脱附以及它的原理一超声场聚能效应。该方法和传统的化学方法相比较：不仅具有操作简单，化学药品消耗少，排污量少等优点。而且还能增加树脂的脱附速率，减少脱附时间，增加解吸平衡物的浓度。本文综述了在这一领域的最近研究进展，各种不同频率和功率对树脂再生效果的影响，为该领域的研究工作提供参考。     

Measurement of microstructural changes promoted by ultrasound application on plant materials with different porosity

This research investigated the effects of ultrasound application (192 ± 6 W/L) on the microstructure of vegetables/fruits with different porosities, cell sizes and patterns (eggplants, beetroots, and apples), submitted to an immersion treatment in different liquids: distilled water, citric acid (1% w/v), and the vegetable/fruit juice, at 25 °C during 5 min. The ultrasound application did not significantly (p > 0.05) affect the size of the cells of the most porous material (eggplant) compared to the samples immersed without ultrasound assistance. The apple samples (with a middle-high porosity and the largest cells) were the most affected by ultrasound application. The median cell areas of samples treated with ultrasound in water and apple juice were 26 and 20% larger than those of samples treated without ultrasound, mainly because of cell wall disruption which caused the cells to merge into bigger clusters, but no effect was observed with the citric acid. Ultrasound application significantly (p < 0.05) increased the median cell area of the less porous raw matter (beetroot) only when the treatment was carried out in the vegetable juice (cells were 26% larger after treatment assisted with ultrasound than without it). Thus, the effects of ultrasound differ in materials with initially different characteristics.     

Pneumatic foam generation in the presence of a high-intensity ultrasound field

Designer foams find applications in a wide range of industries. Foam quality is mostly determined by its complex cellular structure which defines its texture, rheology and stability. In addition to formulation design, the formation process is crucial to the development of a foam with an optimum structure. There is, therefore, a need for techniques that can assist in the generation of controlled foam structures. The work described in this paper demonstrates the potential of using high-intensity ultrasound to control foam structure during production. Foam generated in the presence of ultrasound usually exhibits a narrower bubble size distribution, i.e. a more uniform texture. Such enhanced homogeneity in texture is desirable to reduce the presence of aesthetically unattractive large cavities, and to reduce the destabilising effects of foam coarsening. In addition, a smaller mean bubble size and a slower rate of foam collapse usually result when ultrasound is applied. The work shows the effects on foams stabilised with different surfactants.     

Effects of porosity on the measured fracture energy of brittle materials

Although it is known that growing cracks will interact with pores, it is unclear whether the magnitude of this effect is sufficient to influence the fracture energy. To study this, experiments have been carried out where cracks have been grown through simple distributions of pores in poly(methyl methacrylate). These show that the applied force required to grow the crack between two pores can be greater than that required to grow the crack in the pore-free material. Direct observation during crack growth shows that this increase in applied force is associated with the crack front becoming curved. Based on these observations, the effect of equiaxed pores on the fracture energy of brittle materials has been quantitatively described. The analysis predicts how the relative fracture energy should be influenced by the pore volume fraction, and that it should be independent of the size of the pores or the fracture energy of the matrix. These predictions give good agreement with experimental measurements in different ceramic materials, in which the microstructure of the matrix surrounding the pores does not change with pore volume fraction.     

The influence of porosity on ultrasound attenuation in carbon fiber reinforced plastic composites using the laser-ultrasound spectroscopy

Wideband acoustic spectroscopy with a laser ultrasound source for quantitative analysis of the effect of porosity on the attenuation coefficient of longitudinal acoustic waves in carbon fiber reinforced plastic (CFRP) composite materials was experimentally implemented. The samples under study had different bulk-porosity levels (up to 10%), which were determined using X-ray computer tomography. A resonance ultrasound attenuation peak associated with the one-dimensional periodicity of the layered composite structure was observed for all samples. The absolute value of the resonance-peak maximum and its width depend on the local concentration of microscopic isolated pores and extended delaminations in the sample structure. The obtained empirical relationships between these parameters of the frequency dependence of the ultrasound attenuation coefficient and the type of inhomogeneities and their volume concentration can be used for rapid evaluation of the structural quality of CFRP composites.     

Effects of high intensity ultrasound on inorganic solids

Ultrasonic irradiation dramatically affects the reactivity of a variety of inorganic solids. We have found, for example, large increases in the rates of intercalation of a wide range of compounds into various layered inorganic solids (such as ZrS2, V2O5, TaS2 and MoO3. High intensity ultrasound also enhances the heterogeneous catalysis of alkene hydrogenation by Ni powders. Scanning electron microscopy reveals that ultrasound has multiple effects on the morphology and surface characteristics of inorganic solids, creating substantial surface damage, increasing surface areas significantly and causing increased particle aggregation.     

Effects of ultrasound energy on degradation of cellulose material

The rationale for selection of waste cellulose source and method for its degradation, such as ultrasound, aeration and coupled energy, is examined. Consideration is given to the availability of waste material for the conservation of global resources, pollution effects from energy forms and efficiency of energy transfer. Availability of the sources and possible ways of converting them to fuels, processes involved in its production and the possible effects on the environment are discussed. Manufactured cellulose and waste paper are used as the source for these experiments and the rationale behind their use in the environment is analysed. An ultrasound reactor that operates at 80 W and 38 kHz was used in breaking down the samples to produce glucose and other chemical species. One of the routes being explored is the further conversion of these molecules into fuel (alcohol).     

Effects of square micro-pillar array porosity on the liquid motion of near surface layer

The influence rules of square micro-pillar array porosity on the liquid motion characteristics of the near-surface layer are investigated by quartz crystal microbalance(QCM).QCM is a powerful and promising technique in studying the interfacial behavior,which exhibits great advantages in investigating the effects of surface microstructure,roughness,and array.In our experiments,three different arrays with the same height of about 280 nm and center distance of 200 μm,but different diameters of about 78 μm,139 μm,and 179 μm are investigated.The results indicate that when the surface array has a large porosity,its influence on the liquid motion of the near surface layer is slight,thus resulting in a small increase of half-bandwidth variation due to the additional friction energy dissipation.When the surface array has a small porosity,the array tends to make the liquid film trapped in the array oscillating with the substrate,then there may be a layer of liquid film behaving like rigid film,and it also will make the liquid motion near the array layer more complicated.Thus for the#3 surface with a small porosity,both the absolute values of frequency shift |△f_3| and half-bandwidth variation △Γ_3 increase obviously.The experimental results show good consistence with the theoretical model of Daikhin and Urbakh.This study sheds light on understanding the influence mechanism of surface array porosity on the liquid motion of near-surface layer.     

Effects related to spacetime foam in particle physics

It is found that the existence of spacetime foam leads to a situation in which the number of fundamental quantum bosonic fields is a variable quantity. The general aspects of an exact theory that allows for a variable number of fields are discussed, and the simplest observable effects generated by the foam are estimated. It is shown that in the absence of processes related to variations in the topology of space, the concept of an effective field can be reintroduced and standard field theory can be restored. However, in the complete theory the ground state is characterized by a nonvanishing particle number density. From the effective-field standpoint, such particles are “dark.” It is assumed that they comprise dark matter of the universe. The properties of this dark matter are discussed, and so is the possibility of measuring the quantum fluctuation in the field potentials. Zh. éksp. Teor. Fiz. 115, 1921–1934 (June 1999)     

Effects of ultrasound on the enzymatic degradation of pectin

Ultrasound-assisted enzymatic maceration (UAEM) has gained considerable interest in the fruit juice industry, owing to its potential to increase juice yield and content of polyphenols while simultaneously saving time and energy. In this study, the effects of UAEM (ultrasonic probe, 20 kHz, 21 W*cm⁻² and 33 W*cm⁻²) on pectin degradation in a continuous circulation system were investigated over 60 and 90 min. Main pectinolytic enzymes activities of (polygalacturonase, pectin lyase and pectin methylesterase) of a commercial enzyme preparation were examined for individual synergistic effects with US. Pectin hydrolysis by UAEM differed significantly compared to treatment with ultrasound or enzymes alone regarding the profile of degradation products compared to treatment with ultrasound or enzymes alone. Ultrasound fragmented pectin to less branched oligomers of medium molecular weight (Mp approx. 150 kDa), which were further degraded by pectinolytic activities. The low molecular weight fraction (<30 kDa), which is known to be beneficial for juice-quality by adding nutritional value and stabilizing polyphenols, was enriched in small oligomers of homogalacturonan-derived, rhamnogalacturonan I-derived, and rhamnogalacturonan II-derived residues. Synergistic effects of ultrasound application enhanced the effective activities of polygalacturonase and pectin lyase and even prolonged their performance over 90 min, whereas the effective activity of pectin methylesterase was not affected. Final marker concentrations determined by each enzyme assay revealed a considerable higher total process output after UAEM treatment at reduced temperature (30 °C) comparable to the output after conventional batch maceration at 50 °C. The obtained results demonstrate the high potential of UAEM to produce high-quality juice by controlling pectin degradation while reducing process temperature and equally highlight the matrix and enzyme specific effects of a simultaneous US treatment.     

Ultrasonic-assisted Dunlop method for natural rubber latex foam production: Effects of irradiation time on morphology and physico-mechanical properties of the foam

An ultrasonic-assisted technique was first introduced for the production of natural rubber latex foam (NRLF). The flexible elastomeric foam was formed by a liquid–solid state transformation in an aqueous media. The aim of the current research was to provide a novel strategy for fabricating NRLF using ultrasonication and the Dunlop method, as well as to simultaneously utilize irradiation events to achieve the desired foam properties. NRLFs were exposed to ultrasonication at 25 kHz at the beginning of the gelling process. The effects of irradiation times of 0, 1, 3, 5 and 7 min on the morphology, foaming behaviors, physical properties and mechanical performance of NRLFs were investigated. The results revealed that using ultrasonic irradiation, unfoamed regions and a bimodal structure, which seem to be microstructural defects in conventional NRLF, could be completely eliminated. However, excessive irradiation times of 5 min and longer appeared to affect the physico-mechanical properties of the foams in terms of transient cavitation and the unfavorable physicochemical effects of ultrasonic vibrations. As a result, the optimal ultrasonic irradiation time was found to be 3 min. Using this irradiation duration, a foam with the suitable microcellular structure achieved the most desirable properties, such as its expansion ratio (7-fold increase), foam porosity (85.7%), compression recoverability (98.7%), and tensile strength (307.3 kPa). Moreover, the foam still maintained its characteristic soft nature (hardness less than 100 N) with an indentation hardness of 71.9 N. Therefore, ultrasonic treatment introduced to the conventional Dunlop method is a potentially feasible technique since it improves the morphology and the physico-mechanical properties of NRLFs.     

Effects of ultrasound on adsorption-desorption of p-chlorophenol on granular activated carbon

The aim of this work is the evaluation of the effects of ultrasound on p-chlorophenol adsorption-desorption on granular activated carbon. Adsorption equilibrium experiments and batch kinetics studies were carried out in the presence and the absence of ultrasound at 21 kHz. Results indicate that the adsorption of p-chlorophenol determined in the presence of ultrasound is lower than the adsorption observed in the absence of ultrasound. Desorption of p-chlorophenol from activated carbon with and without the application of ultrasound was studied. The desorption rates were favoured by increased ultrasound intensity. This rise is more noticeable as temperature increases. The addition of ethanol or NaOH to the system causes an enhancement of the amount of p-chlorophenol desorbed, especially in the presence of ultrasound. A synergetic enhancement of the desorption rate was observed when ultrasonic irradiation was coupled with ethanol chemical regeneration.     

Effects of ultrasound on the catalytic activity of matrix-bound glucoamylase

The effect of ultrasonic waves on the activity of glucoamylase bound to a porous polystyrene matrix is investigated in this Paper. The immobilized enzyme was sonated in a flow cuvette at frequencies between 1 and 11 MHz and sound intensities up to 5 kW m-2. The effect was measured as a function of the type and concentration of the substrate, carrier particle size, flow rate of the substrate solution and ultrasonic frequency. The activity increase is discussed in terms of a possible ultrasonic mechanism.     

Effects of ultrasound on the synthesis of silicalite-1 nanocrystals

Application of power ultrasound, offers potential in the degree of control over the preparation and properties of nanocrystalline zeolites, which have become increasingly important due to their diverse emerging applications. Synthesis of silicalite-1 nanocrystals from a clear solution was carried out at 348 K in the absence and presence of ultrasound of 300 and 600 W, in an attempt to investigate the effects of sonication, in this respect. Variation of the particle size and particle size distribution was followed with respect to time using a laser light scattering device with a detector set to collect back-scattered light at an angle of 173°. Product yield was determined and the crystallinity was analyzed by X-ray diffraction for selected samples collected during the syntheses. Nucleation, particle growth and crystallization rates all increased as a result of the application of ultrasound and highly crystalline silicalite-1 of smaller average particle diameter could be obtained at shorter synthesis times. The particle size distributions of the product populations, however, remained similar for similar average particle sizes. The rate of increase in yield was also speeded up in the presence of ultrasound, while the final product yield was not affected. Increasing the power of ultrasound, from 300 to 600 W, increased the particle growth rate and the crystalline domain size, and decreased both the final particle diameter and the time required for the particle growth to reach completion, while its effect on nucleation was unclear.