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采用激光束反射偏转法测量了用溶胶-凝胶法在Si(11)基片上制备的TiO2-SiO2复合薄膜的曲率半径。由此计算出薄膜的热应力,应力和本征应力。研究了工艺过程与薄膜应力的关系,其应力随热处理温度的增加而由张应力转变为压应力;当热处理温度较低时,随膜厚的增加,其应力增大,而最终导致膜的开裂,薄膜的最大不开裂厚度随热处理温度和TiO2含量的增加而增加。 相似文献
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研究了TiO2纳米棒的制备和形成机理及其在光催化降解活性艳红中的应用。采用超声法,以TiCl4为原料,制备了纳米TiO2。SEM结果显示所制备的TiO2为棒状结构,直径30 nm左右,长约200 nm。比表面积为60.500 7 m2/g。XRD显示其为金红石型晶体,700℃烧结后结晶程度增强,形貌保持不变,比表面积降到37.963 2 m2/g。超声法制备的TiO2纳米棒700℃烧结后应用于光催化降解活性艳红时,降解率高达98.94%,表现出优于P25的催化活性。 相似文献
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纳米TiO2光催化杀灭大肠杆菌的超微结构研究 总被引:4,自引:0,他引:4
在近紫外光的照射下,纳米TiO2具有较强的光催化灭茵效果。用透射电子显微镜较完整地研究纳米TiO2光催化杀灭大肠杆菌的超微结构变化。结果表明,纳米TiO2可直接或间接作用于大肠杆菌;光催化过程中产生的氢氧自由基等活性氧类物质可导致大肠杆菌的外壁和质膜严重破损、断裂;胞浆流出;细胞质凝聚;类核区解体和丝状染色质消失。本研究为探讨纳米TiO2光催化灭茵机理提供了直观的证据。 相似文献
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铁氮共掺杂制备TiO_2及其蓝光下的光催化性能 总被引:2,自引:0,他引:2
用硝酸铁和盐酸羟胺分别作Fe源和N源,在TiO2溶胶中同时引入Fe和N,一步合成得到Fe、N共掺杂的纳米TiO2粉末。用XRD等技术研究了焙烧温度和N源量对其晶相结构的影响,并用低功率蓝光LED作光源测试其光催化性能。结果表明,400℃焙烧的Fe、N共掺杂TiO2粉末具有最好的催化性能,2h内对若丹明B的降解率达68.0%。增加N源量,有利于Fe在TiO2晶格中扩散,减小晶粒度;Fe、N共掺杂对TiO2的催化性能具有协同作用,其催化能力明显优于单掺杂样品;降解机理可能与紫外光源有所不同。 相似文献
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溶胶半导化工艺制备(Sr,Pb)TiO3系热敏电阻材料 总被引:1,自引:0,他引:1
用溶胶-凝胶法制取了钇(Y)掺杂剂溶胶。利用Y溶胶添加剂对钛酸锶铅V型正温度系数材料进行了半导化。为便于比较,制备了具有不同含量Y溶胶添加剂及Y2O3固相氧化物的(Sr0.5,Pb0.5)TiO3样品。实验结果表明,Y溶胶作为半导化添加剂优于Y2O3固相氧化物,它能改善(Sr,Pb)TiO3系陶瓷的各项性能。通过Y溶胶添加剂所制备的(Sr0.5,Pb0.5)TiO3样品的最小电阻率为2.90×102Ω·cm,其Y溶胶引入量r(Y)为0.45%。 相似文献
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PZT铁电薄膜的掺杂改性 总被引:5,自引:0,他引:5
用溶胶-凝胶方法制备了掺高价离子钇及过量Pb的PZT铁电薄膜。探讨了添加剂对PZT铁电薄膜的结构和电特性的影响。实验表明,过量r(Pb)6%或掺高价离子r(Y)3%能较大地改善PZT铁电薄膜的电性能。 相似文献
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(Pb,La)TiO3铁电薄膜的制备及热释电性能研究 总被引:1,自引:1,他引:1
讨论了PLT15铁电薄膜的溶胶-凝胶制备技术,及PLT薄膜的结构和电性能研究。结果表明,在Si基片上成功地生长出钙钛矿型结构多晶铁电薄膜,在(111)Pt/Ti/SiO2/Si上外延生长出(111)PLT15铁电薄膜。溶胶-凝胶制备的PLT15铁电薄膜具有优良的热释电性能,其热释电系数p为5.25×10-8Ccm-2K-1,电压响应率优值FV达到0.78×10-10Ccm/J,探测率优值Fm为1.13×10-8Ccm/J,适于制备热释电红外探测器 相似文献
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Kondrateva A. Enns Ya. Kazakin A. Kleimanov R. Morozov I. Karaseov P. Mishin M. 《Semiconductors》2020,54(14):1885-1888
Semiconductors - In this work, a versatile method to increase the optical response of oxide nanostructures is described. Thin TiO2 films with buried gold nanoparticles (TiO2-AuNP) were synthesized... 相似文献
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控制铅挥发制备钛酸锶铅半导体陶瓷 总被引:2,自引:0,他引:2
在 Y 掺杂的钛酸锶铅中,分别添加过量 PbO、SiO_2、ZrO_2制备之半导体陶瓷样品,在居里点(约 120℃)以上具有强的 PTC 效应,升阻比接近 5 个数量级。其中,SiO_2或 ZrO_2增强了居里点以下的 NTC 效应,降阻比可达 1个数量级;而少量 PbO 则降低了陶瓷的室温电阻率和 NTC 效应。通过热处理可以使热敏特性由 PTC 型向 NTC-PTC复合型转变,表明 NTC 效应与铅含量变化密切相关,控制铅挥发能获得不同热敏特性的钛酸锶铅半导体陶瓷。 相似文献
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TiO_2纳米粉体的制备工艺研究进展 总被引:14,自引:0,他引:14
综述了制备TiO2纳米粉体的各种方法,评述了金属醇盐水解法、水热晶化法、溶胶-凝胶法、均匀沉淀法和液相一步合成法制备工艺及特点,并指出液相一步合成法是在常压低温条件下,在液相中就可制得TiO2纳米粉体的工艺简单、适宜大规模工业化生产的最具潜力的一种制备工艺。 相似文献
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Gang Liu Jian Pan Lichang Yin John TS Irvine Feng Li Jun Tan Philip Wormald Hui‐Ming Cheng 《Advanced functional materials》2012,22(15):3233-3238
Understanding and manipulating the two half‐reactions of photoinduced electron reduction and hole oxidation are key to designing and constructing efficient photocatalysts. Here, how the spatial distribution of the heteroatom modulates photocatalytic reduction (hydrogen evolution) and oxidation (oxygen evolution) reaction preferences is investigated by moving boron from the core to the shell of an anatase TiO2 microsphere along [001] via thermal diffusion control. The preference towards photocatalytic hydrogen and oxygen producing reactions from splitting water can be switched by creating a shell with an interstitial Bσ+ (σ ≤ 3) gradient in the TiO2 microsphere. This switching stems from the downward shift of electronic band edges of the shell by a band bending effect that originates from the extra electrons coming from the interstitial Bσ+. These results create new opportunities for designing and constructing efficient photocatalysts by spatial heteroatom engineering. 相似文献
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In this work, the anatase and rutile TiO2 of single crystal structure are prepared by a facile hydrolysis method. The obtained samples are studied via various characterizations, and compared with different commercial TiO2 (P25, ST-21, ST-31), which have mixed structures, to investigate the photocatalytic performance from water splitting. The experimental results show that the photocatalytic activity of samples depends on the surface properties and particle sizes. Moreover, compared with the TiO2 of single crystal structure, P25 and ST-21 mixed crystal structures show superior photocatalytic hydrogen production from water splitting. According to experimental results, the possible photocatalytic mechanism of TiO2 with mixed crystal structure is proposed. 相似文献
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Harvesting Lost Photons: Plasmon and Upconversion Enhanced Broadband Photocatalytic Activity in Core@Shell Microspheres Based on Lanthanide‐Doped NaYF4, TiO2, and Au 下载免费PDF全文
Zhenhe Xu Marta Quintanilla Fiorenzo Vetrone Alexander O. Govorov Mohamed Chaker Dongling Ma 《Advanced functional materials》2015,25(20):2950-2960
Efficiently harvesting solar energy for photocatalysis remains very challenging. Rational design of architectures by combining nanocomponents of radically different properties, for example, plasmonic, upconversion, and photocatalytic properties, offers a promising route to improve solar energy utilization. Herein, the synthesis of novel, plasmonic Au nanoparticle decorated NaYF4:Yb3+, Er3+, Tm3+‐core@porous‐TiO2‐shell microspheres is reported. They exhibit high surface area, good stability, broadband absorption from ultraviolet to near infrared, and excellent photocatalytic activity, significantly better than the benchmark P25 TiO2. The enhanced activity is attributed to synergistic effects from nanocomponents arranged into the nanostructured architecture in such a way that favors the efficient charge/energy transfer among nanocomponents and largely reduced charge recombination. Optical and energy‐transfer properties are modeled theoretically to support our interpretations of catalytic mechanisms. In addition to yielding novel materials and interesting properties, the current work provides physical insights that can contribute to the future development of plasmon‐enhanced broadband catalysts. 相似文献