共查询到20条相似文献,搜索用时 62 毫秒
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截至2021年底,中国的汽车保有量超过3亿辆,其中汽油车占比90%以上,是中国最重要的汽车类型。为了应对汽油车尾气中的氮氧化物(NOx)、碳氢化合物(HC)和一氧化碳(CO)等典型污染物,“三效催化剂”这一具有里程碑意义的汽油车尾气后处理技术被开发、应用并不断完善。新近流行的汽油缸内直喷(GDI)技术会导致显著的颗粒污染物(PM)排放,由此又催生了汽油车颗粒物过滤器(GPF)技术。上述技术的实施或多或少都需要依赖中国战略资源——稀土的参与。本文首先对各类汽油车尾气净化技术的发展进行了回顾,之后重点分析了(以CeO2为主的)稀土材料在三效催化剂储氧材料、催化剂载体/贵金属稳定剂和汽油车颗粒物过滤器中的具体应用方式和效果。可以看出,随着新型稀土材料的开发和技术迭代,现代汽油车尾气净化技术正在变得越来越高效、越来越便宜。最后,本文对汽油车尾气净化用稀土材料的发展趋势进行了展望,分析了相关产业未来升级的重点和难点所在。 相似文献
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过滤净化用多孔金属材料的开发应用与进展 总被引:7,自引:0,他引:7
综述了过滤净化用多孔金属材料的最新开发应用进展与市场状况, 对我国目前过滤净化用多孔金属材料的研发应用及市场等各方面存在的现象进行了初步分析, 并对这一领域的发展前景进行了展望. 相似文献
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研究了乙烷和丙烷在催化膜反应器中的氧化脱氢反应.所用的膜材料为La2Ni0.9V0.1O4+δ和Ba0.5Sr0.5Co0.8Fe0.2O3-δ.为了平衡氧气通量和额外的均匀气相反应,实验选择在中温段进行(550或者650℃).实验结果表明膜的氧渗透通量和膜表面上主要激活烷烃的活性位在获得高的烷烃转化率过程中起决定性作用.乙烷和丙烷的氧化脱氢实验数据均符合Mars-van Krevelen机理,其中烷烃和膜表面的晶格氧反应产生相应的烯烃.同时证明了气相和膜表面的氧浓度是决定烯烃选择性的关键. 相似文献
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简要介绍了稀土元素的电子结构特点,并以稀土永磁体、稀土单离子磁体、稀土磁共振造影剂和稀土分子量子比特等主题为例,介绍了部分稀土元素在和磁性质相关的生产和研究中的应用。 相似文献
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Kalinnikov V. T. Makarov D. V. Tikhomirova E. L. Elizarova I. R. Kuznetsov V. Ya. 《Russian Journal of Applied Chemistry》2002,75(11):1760-1764
Thermal gravimetric, X-ray phase, IR spectroscopic, and chemical analyses were applied to study the reaction of yttrium and neodymium oxides with NH4HF2. 相似文献
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稀土氧化物超微粉的催化酯化行为 总被引:6,自引:0,他引:6
制备了5种稀土氧化物超微粉并考察了它们的催化酯化的活性,发现超微粉的催化活性均高于普通稀土氧化物,Y_2O_3超微粉催化酯化产物的酸值接近0.1,有应用前景。 相似文献
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Russian Journal of General Chemistry - This review presents geochemical and medical-ecological information on the content, distribution, and accumulation of rare-earth elements in soils of... 相似文献
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稀土元素测定方法的研究进展 总被引:1,自引:0,他引:1
综述了稀土元素测定方法(包括电感耦合等离子体质谱法、电感耦合等离子体原子发射光谱法、原子吸收光谱法、荧光光度法、紫外-可见分光光度法、高效液相色谱法、电化学方法、常规化学分析法和在线联用技术等)的研究进展(引用文献37篇)。 相似文献
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采用改进的溶胶-凝胶法合成出了几种含铈稀土复合氧化物催化剂,运用XRD,IR等不同测试手段对复合氧化物催化剂进行了表征,测试了甲烷催化燃烧活性.XRD分析结果表明:经1200 ℃焙烧3 h后4种催化剂中Ba-Ce-O,Sr-Ce-O主要以单一相钙钛矿结构BaCeO3和SrCeO3的形式存在,La-Ce-O体系催化剂呈现面心立方晶体结构特征衍射峰,与立方结构CeO2的衍射峰相似,只是峰的位置偏向低角度;Mg-Ce-O主要以简单氧化物CeO2的相存在,在甲烷催化燃烧反应中La-Ce-O显示出了良好的催化活性,T10为510 ℃,T90为670 ℃;主相为SrCeO3的Sr-Ce-O体系催化剂的甲烷催化活性最差,T10为570 ℃,T90为743 ℃. 相似文献
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G. F. Krysenko D. G. Epov M. A. Medkov P. V. Sitnik V. A. Avramenko 《Russian Journal of Applied Chemistry》2018,91(10):1665-1670
Distribution and existence forms of rare-earth elements in decomposition of the loparite concentrate with ammonium hydrofluoride were studied. It was found that, in the course of the aqueous leaching of the fluorinated concentrate, rare-earth elements fully remain in the insoluble residue as complex salts of general formula NaLnF4. The process of pyrohydrolysis of the insoluble residue was examined. It was shown that varying the process conditions always results in that a NaLnF4-containing product is obtained. It was found that rare-earth elements can be extracted from the insoluble residue and separated from calcium and thorium, and the conditions for this extraction were determined. 相似文献
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Optimal conditions for the complexation of La, Nd, Sm, Tb, Dy, Gd, Ho, Er, and Yb ions with Arsenazo III were found, and molar absorptivities of the complexes were calculated. Chromaticity characteristics of the complexes were determined. The coefficients of calibration plot equations and molar coefficients of chromaticity functions were calculated for the concentration range 10–50 g of rare-earth element per 25 mL of solution. It was demonstrated that the use of the most sensitive chromaticity functions increases the sensitivity of the reaction by 1.5–2 orders of magnitude compared to the photometric method. 相似文献
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Olga N. KazhevaNataliya D. Kushch Oleg A. Dyachenko Enric Canadell 《Journal of solid state chemistry》2002,168(2):457-463
The new molecular conductors with some rare-earth metal-complex anions (ET)5[M(NCS)6NO3]·C2H5OH (M=Dy (1), Y (2), Ho (3)) and (TMTSF)3[Y(NO3)5]·2C6H5Cl (4) as well as a new low-temperature modification of tetra-n-buthylammonium dysprosium(III) complex, (Bu4N)3[Dy(NCS)4(NO3)2] (5) used for the preparation of salt 1 were synthesized and studied by X-ray crystallography at 295 and 110 K. Salts 1-3 have a layered crystal structure with a new packing type of the radical cation layers, called an ω-type. Electronic structure calculations for the compounds 1-3 showed that the paired ET molecules have a positive charge +1 and the single ET molecules are neutral. The directions of the TMTSF stacks in the neighboring organic layers of 4 are practically perpendicular so that salt 4 can be regarded as a precursor of 2D conductors formed by mutually perpendicular directions of conductivity. 相似文献
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The temperature regions for separate crystallization of rare-earth element (REE) oxides of the cerium group in the presence of CaCO3 have been determined using X-ray diffraction, differential thermogravimetric analysis, inductively coupled plasma mass spectroscopy, and X-ray fluorescence. The possibility to separate REE oxides from CaCO3 in H2SO4 solutions after heat treatment (450–600°C) has been studied. The solid phase of the precipitate is represented by slightly soluble calcium sulfate, whereas the REE oxides pass into the liquid phase in the form of highly soluble sulfates. After heat treatment of the test mixture of REE oxalates and calcium oxalate at a temperature higher than 750°C, calcium compounds pass into 1–2% HNO3 liquid phase in the form of nitrates, whereas lanthanide oxides remain in the insoluble phase of REE oxide solid solution having CeO2 structure. 相似文献