General model for the functional dependence of defect concentration on oxygen potential in mixed conducting oxides

To understand and engineer applications for mixed conducting oxides, it is desirable to have explicit, analytical expressions for the functional dependence of defect concentration and transport properties on the partial pressure of the external gas phase. To fulfill this need, general expressions are derived for the functional dependence of defect concentration on the oxygen partial pressure () for the mixed ionic electronic conductors. The model presented in this paper differs from expressions obtained using the popular Brouwer approach because they are continuous across multiple Brouwer regions.

Ion exchange equilibrium between cation exchange membranes and aqueous solutions of K+/Na+, K+/Ca2+, and Na+/Ca2+

Equilibrium between synthetic ion exchangers and solutions of cations has been the subject of this investigation. Competitive ion exchange reactions were studied for two cation exchange membranes (CMX and CRP) involving K⁺, Na⁺, and Ca²⁺ ions. The ionic strength of the equilibrating solutions was maintained constant, but the molar fraction varied; all experiments were conduced with nitrate as nonexchanging anions at 25 °C. Adsorption isotherm for the three binaries systems: K⁺/Na⁺, K⁺/Ca²⁺, and Na⁺/Ca²⁺ were studied. The obtained results show that potassium was the most strongly sorbed and the selectivity order for CMX and CRP membranes is K⁺>Ca²⁺>Na⁺ at 0.1 M, under the experimental conditions. Selectivity coefficients , , and for the three binaries and for the two membranes were determined at an ionic strength of 0.1 M and at a constant temperature of 25 °C. We remark that all the selectivity coefficient values are quite different from the unit. Ternary equilibrium was taken for the Ca²⁺/K⁺/Na⁺ system. It was found that binary selectivity data could be successfully used to predict the ternary ion exchange equilibrium.     

An Infinite Genus Mapping Class Group and Stable Cohomology

We exhibit a finitely generated group whose rational homology is isomorphic to the rational stable homology of the mapping class group. It is defined as a mapping class group associated to a surface of infinite genus, and contains all the pure mapping class groups of compact surfaces of genus g with n boundary components, for any g ≥ 0 and n > 0. We construct a representation of into the restricted symplectic group of the real Hilbert space generated by the homology classes of non-separating circles on , which generalizes the classical symplectic representation of the mapping class groups. Moreover, we show that the first universal Chern class in is the pull-back of the Pressley-Segal class on the restricted linear group via the inclusion . L. F. was partially supported by the ANR Repsurf:ANR-06-BLAN-0311.     

Quantisation of Twistor Theory by Cocycle Twist

We present the main ingredients of twistor theory leading up to and including the Penrose-Ward transform in a coordinate algebra form which we can then ‘quantise’ by means of a functorial cocycle twist. The quantum algebras for the conformal group, twistor space , compactified Minkowski space and the twistor correspondence space are obtained along with their canonical quantum differential calculi, both in a local form and in a global *-algebra formulation which even in the classical commutative case provides a useful alternative to the formulation in terms of projective varieties. We outline how the Penrose-Ward transform then quantises. As an example, we show that the pull-back of the tautological bundle on pulls back to the basic instanton on and that this observation quantises to obtain the Connes-Landi instanton on θ-deformed S ⁴ as the pull-back of the tautological bundle on our θ-deformed . We likewise quantise the fibration and use it to construct the bundle on θ-deformed that maps over under the transform to the θ-deformed instanton. The work was mainly completed while S.M. was visiting July-December 2006 at the Isaac Newton Institute, Cambridge, which both authors thank for support.     

An Algebra of Deformation Quantization for Star-Exponentials on Complex Symplectic Manifolds

The cotangent bundle T ^* X to a complex manifold X is classically endowed with the sheaf of k-algebras of deformation quantization, where k := is a subfield of . Here, we construct a new sheaf of k-algebras which contains as a subalgebra and an extra central parameter t. We give the symbol calculus for this algebra and prove that quantized symplectic transformations operate on it. If P is any section of order zero of , we show that is well defined in .     

Torelli Theorem for the Deligne–Hitchin Moduli Space

Fix integers g ≥ 3 and r ≥ 2, with r ≥ 3 if g = 3. Given a compact connected Riemann surface X of genus g, let denote the corresponding Deligne–Hitchin moduli space. We prove that the complex analytic space determines (up to an isomorphism) the unordered pair , where is the Riemann surface defined by the opposite almost complex structure on X.     

Complete Einstein Metrics are Geodesically Rigid

We prove that every complete Einstein (Riemannian or pseudo-Riemannian) metric g of nonconstant curvature is geodesically rigid: if any other complete metric has the same (unparametrized) geodesics with g, then the Levi-Civita connections of g and coincide.     

Ion Mobility Measurements and Ion Chemical Reaction Studies at Heavy Elements in a Buffer Gas Cell

Drift time measurements of ions in a buffer gas cell filled with argon have been performed from which changes of the ion mobility and ionic radii for various heavy elements and their compounds were determined. The ionic radius of americium shrinks by (3.1 1.3)% with respect to that of plutonium, and an increase of the radius by (28 2)% of plutonium oxide with respect to plutonium was found. Ion chemical reactions of erbium ions were studied online in an argon buffer gas cell to which the reaction gases oxygen (O) and methane (CH) were added. The erbium ions were implanted into the buffer gas cell with an energy of 50 MeV. The online measured reaction constant = (3.2 0.4) 10 cm/(molecule s) for the reaction Er + O ErO + O agrees with a reference measurement = (3.6 0.4) 10 cm/(molecule s), performed with a Fourier-Transform-Mass-Spectrometer.     

Non-relativistic Limit of a Dirac Polaron in Relativistic Quantum Electrodynamics

A quantum system of a Dirac particle interacting with the quantum radiation field is considered in the case where no external potentials exist. Then the total momentum of the system is conserved and the total Hamiltonian is unitarily equivalent to the direct integral of a family of self-adjoint operators acting in the Hilbert space , where is the Hilbert space of the quantum radiation field. The fiber operator is called the Hamiltonian of the Dirac polaron with total momentum . The main result of this paper is concerned with the non-relativistic (scaling) limit of . It is proven that the non-relativistic limit of yields a self-adjoint extension of a Hamiltonian of a polaron with spin 1/2 in non-relativistic quantum electrodynamics.     

Preparation and characterization of nanocrystalline ZnO particles from a hydrothermal process

Rod-like ZnO nanoparticles were prepared by the hydrolysis of zinc acetate under heating in diethylene glycol (DEG). Structural characterization of the synthesized powders was investigated by XRD, FT-IR, electron paramagnetic resonance (EPR) and transmission electron microscopy (TEM). The size of the particles increased as the amount of H₂O added increased in the nano size range. The average crystallite size calculated from the XRD patterns varied from 6 to 64 nm corresponding to the amount of H₂O added. The ZnO nanopartilces possess the wurtzite type crystallographic structure. It was found that these ZnO nanoparticles had singly ionized oxygen vacancy defect () and superoxide ions from the EPR investigations. A strong near UV emission of the ZnO nanoparticles at about 380 nm was observed and its intensity decreased as the amount of H₂O increased. This emission of ZnO nanoparticles is found to be particles size dependent due to the confinement effect. A green emission at about 540 nm due to the recombination of electrons trapped at singly ionized oxygen vacancies defect () appeared when the amount of H₂O increased. The intensity of the green emission increases as the concentration of increases.     

Renormalized Traces and Cocycles on the Algebra of S 1-Pseudo-differential Operators

Using renormalized (or weighted) traces of classical pseudo-differential operators and calculus on formal symbols. We exhibit three cocycles on the Lie algebra of classical pseudo-differential operators $Cl(S^1,\mathbb{C}^n)Using renormalized (or weighted) traces of classical pseudo-differential operators and calculus on formal symbols. We exhibit three cocycles on the Lie algebra of classical pseudo-differential operators acting on . We first show that the Schwinger functional associated to the Dirac operator is a cocycle on , and not only on a restricted algebra Then, we investigate two bilinear functionals and , which satisfies We show that and are two cocycles in , and and have the same nonvanishing cohomology class. We finaly calculate on classical pseudo-differential operators of order 1 and on differential operators of order 1, in terms of partial symbols. By this last computation, we recover the Virasoro cocyle and the K?hler form of the loop group. Mathematics Subject Classification (1991). 47G30, 47N50     

Group Orbits and Regular Partitions of Poisson Manifolds

We study a large class of Poisson manifolds, derived from Manin triples, for which we construct explicit partitions into regular Poisson submanifolds by intersecting certain group orbits. Examples include all varieties of Lagrangian subalgebras of reductive quadratic Lie algebras with Poisson structures defined by Lagrangian splittings of . In the special case of , where is a complex semi-simple Lie algebra, we explicitly compute the ranks of the Poisson structures on defined by arbitrary Lagrangian splittings of . Such Lagrangian splittings have been classified by P. Delorme, and they contain the Belavin–Drinfeld splittings as special cases.     

(Co)cyclic (Co)homology of Bialgebroids: An Approach via (Co)monads

For a (co)monad T _l on a category , an object X in , and a functor , there is a (co)simplex in . The aim of this paper is to find criteria for para-(co)cyclicity of Z ^*. Our construction is built on a distributive law of T _l with a second (co)monad T _r on , a natural transformation , and a morphism in . The (symmetrical) relations i and w need to satisfy are categorical versions of Kaygun’s axioms of a transposition map. Motivation comes from the observation that a (co)ring T over an algebra R determines a distributive law of two (co)monads and on the category of R-bimodules. The functor Π can be chosen such that is the cyclic R-module tensor product. A natural transformation is given by the flip map and a morphism is constructed whenever T is a (co)module algebra or coring of an R-bialgebroid. The notion of a stable anti-Yetter-Drinfel’d module over certain bialgebroids, the so-called  ×  _R -Hopf algebras, is introduced. In the particular example when T is a module coring of a  ×  _R -Hopf algebra and X is a stable anti-Yetter-Drinfel’d -module, the para-cyclic object Z _* is shown to project to a cyclic structure on . For a -Galois extension , a stable anti-Yetter-Drinfel’d -module T _S is constructed, such that the cyclic objects and are isomorphic. This extends a theorem by Jara and Ştefan for Hopf Galois extensions. As an application, we compute Hochschild and cyclic homologies of a groupoid with coefficients in a stable anti-Yetter-Drinfel’d module, by tracing it back to the group case. In particular, we obtain explicit expressions for (coinciding relative and ordinary) Hochschild and cyclic homologies of a groupoid. The latter extends results of Burghelea on cyclic homology of groups.     

Zero Modes’ Fusion Ring and Braid Group Representations for the Extended Chiral <Emphasis Type="Italic">su</Emphasis>(2) WZNW Model

A zero modes’ Fock space is constructed for the extended chiral WZNW model. It gives room to a realization of the fusion ring of representations of the restricted quantum universal enveloping algebra at an even root of unity, and of its infinite dimensional extension by the Lusztig operators We provide a streamlined derivation of the characteristic equation for the Casimir invariant from the defining relations of A central result is the characterization of the Grothendieck ring of both and in Theorem 3.1. The properties of the fusion ring in are related to the braiding properties of correlation functions of primary fields of the conformal current algebra model.      

A Negative Mass Theorem for the 2-Torus

Let M be a closed surface. For a metric g on M, denote the area element by dA and the Laplace-Beltrami operator by Δ = Δ _g . We define the Robin mass m(p) at the point to be the value of the Green function G(p, q) at q = p after the logarithmic singularity has been subtracted off, and we define trace . This regularized trace can also be obtained by regularization of the spectral zeta function and is hence a spectral invariant which heuristically measures the total wavelength of the surface.We define the Δ-mass of (M, g) to equal , where is the Laplacian on the round sphere of area A. This scale invariant quantity is a non-trivial analog for closed surfaces of the ADM mass for higher dimensional asymptotically flat manifolds.In this paper we show that in each conformal class for the 2-torus, there exists a metric with negative Δ-mass. From this it follows that the minimum of the Δ-mass on is negative and attained by some metric . For this minimizing metric g, one gets a sharp logarithmic Hardy-Littlewood-Sobolev inequality and an Onofri-type inequality.We remark that if the flat metric in is sufficiently long and thin then the minimizing metric g is non-flat. The proof of our result depends on analyzing the ordinary differential equation which is equivalent to h′′ = 1 − 1/h. The solutions are periodic and we need to establish quite delicate, asymptotically sharp inequalities relating the period to the maximum value. The author was supported by the National Science Foundation #DMS-0302647.     

A Uniform Quantum Version of the Cherry Theorem

Consider in the operator family . P ₀ is the quantum harmonic oscillator with diophantine frequency vector ω, F ₀ a bounded pseudodifferential operator with symbol decreasing to zero at infinity in phase space, and . Then there exist independent of and an open set such that if and , the quantum normal form near P ₀ converges uniformly with respect to . This yields an exact quantization formula for the eigenvalues, and for the classical Cherry theorem on convergence of Birkhoff’s normal form for complex frequencies is recovered. Partially supported by PAPIIT-UNAM IN106106-2.     

Quenched Averages for Self-Avoiding Walks and Polygons on Deterministic Fractals

We study rooted self avoiding polygons and self avoiding walks on deterministic fractal lattices of finite ramification index. Different sites on such lattices are not equivalent, and the number of rooted open walks W _n (S), and rooted self-avoiding polygons P _n (S) of n steps depend on the root S. We use exact recursion equations on the fractal to determine the generating functions for P _n (S), and W _n(S) for an arbitrary point S on the lattice. These are used to compute the averages ,, and over different positions of S. We find that the connectivity constant μ, and the radius of gyration exponent are the same for the annealed and quenched averages. However, , and , where the exponents and , take values different from the annealed case. These are expressed as the Lyapunov exponents of random product of finite-dimensional matrices. For the 3-simplex lattice, our numerical estimation gives and , to be compared with the known annealed values and .     

Measures on Banach Manifolds and Supersymmetric Quantum Field Theory

We show how to construct measures on Banach manifolds associated to supersymmetric quantum field theories. These measures are mathematically well-defined objects inspired by the formal path integrals appearing in the physics literature on quantum field theory. We give three concrete examples of our construction. The first example is a family of measures on a space of functions on the two-torus, parametrized by a polynomial P (the Wess-Zumino-Landau-Ginzburg model). The second is a family of measures on a space of maps from to a Lie group (the Wess-Zumino-Novikov-Witten model). Finally we study a family of measures on the product of a space of connections on the trivial principal bundle with structure group G on a three-dimensional manifold M with a space of -valued three-forms on M. We show that these measures are positive, and that the measures are Borel probability measures. As an application we show that formulas arising from expectations in the measures reproduce formulas discovered by Frenkel and Zhu in the theory of vertex operator algebras. We conjecture that a similar computation for the measures , where M is a homology three-sphere, will yield the Casson invariant of M. Dedicated to the memory of Raoul Bott Supported in part by NSF grant DMS 04/05670.     

The <Emphasis Type="Italic">N</Emphasis> = 1 Triplet Vertex Operator Superalgebras

We introduce a newfamily of C ₂-cofinite N = 1 vertex operator superalgebras , m ≥ 1, which are natural super analogs of the triplet vertex algebra family , p ≥ 2, important in logarithmic conformal field theory. We classify irreducible -modules and discuss logarithmic modules. We also compute bosonic and fermionic formulas of irreducible characters. Finally, we contemplate possible connections between the category of -modules and the category of modules for the quantum group , , by focusing primarily on properties of characters and the Zhu’s algebra . This paper is a continuation of our paper Adv. Math. 217, no.6, 2664–2699 (2008). The second author was partially supported by NSF grant DMS-0802962.