共查询到20条相似文献,搜索用时 15 毫秒
1.
J.M. Weber I.I. Fabrikant E. Leber M.-W. Ruf H. Hotop 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,11(2):247-256
Using laser photoelectron attachment to methyl iodide clusters in a differentially-pumped seeded supersonic helium beam and
mass spectrometric ion detection, we have measured the rate coefficients for formation of (q = 0-2) ions over the electron energy range 0-100 meV with an effective energy width of about 2.5 meV. Whereas a prominent
vibrational Feshbach resonance just below the onset for the C-I stretch vibration ( ) is observed for dissociative attachment to monomers (yielding I- ions), only weak and broad structure, shifted to lower energies, is detected for formation of ions and essentially no structure is left in the attachment spectrum for . These observations are interpreted by model R-matrix calculations which successfully describe the DA cross-section for the monomer and qualitatively recover the trend
observed for cluster ion formation. For the clusters, the effects of increased electron-target long-range interaction and
of solvation as well as coupling to soft vibrational modes lead to strong broadening and shifting of the vibrational Feshbach
resonance and, ultimately, to its disappearance.
Received 29 November 1999 and Received in final form 14 January 2000 相似文献
2.
Y. Ren R. Moro V. V. Kresin 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,43(1-3):109-112
Individual amino acid molecules embedded in helium
nanodroplets fragment extensively when the beam is ionized by electron
bombardment. However, we find that when glycine and tryptophan are picked up
right after, or right before, a small amount of water, the mass spectra
become significantly altered. For glycine, the detected ions consist almost
entirely of intact protonated amino acids, with or without a few water
molecules attached. In other words, the presence of water exerts a striking
“buffering” effect on the ionization-induced fragmentation. For tryptophan
the effect is weaker but also present. In both cases, the hydroxyl group
lost upon ionization overwhelmingly comes from the water partner (in strong
contrast to the situation observed when amino acids are picked up by neat
water clusters). A complementary experiment involving DCl molecules
co-embedded with water shows that in this case Cl and/or DCl invariably
leave the droplet upon ionization. The observed patterns may be steered by
the analytes' dipole moments or by solvation effects. 相似文献
3.
O. Keller C. Mang M. Nikola G. Schulz 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,4(3):309-319
Emission spectra following electron impact on molecules of the homologous series of fluoromethanes CHxF4-x with x=0-4 have been investigated from the near infrared at 700 nm to the ultraviolet VUV-spectral region at 100 nm. Earlier experimental
data for the visible and ultraviolet spectral region were revised and evaluated again on the basis of reliable new data for
the dynamic viscosity of the molecules. The measurement of absolute and relative cross-sections were systematically extended
into the VUV region from 100 nm to 200 nm. The examination of atomic lines as well as molecular band systems in the VUV gives
further insight into the dissociation mechanism and shows that many excited levels even of atomic and molecular species cannot
be populated directly, but only by transitions from higher-lying energy levels. Simple steric effects can be distinguished
from more complex transition phenomena.
Received: 25 February 1998 / Revised: 29 May 1998 and 18 June 1998 / Accepted: 23
June 1998 相似文献
4.
M. Keil T. Kolling K. Bergmann W. Meyer 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,7(1):55-64
The process of dissociative attachment (DA) of low-energy electrons ) to vibrationally excited sodium dimer molecules is studied with high electron energy resolution () in a supersonic molecular beam. A novel photoelectron source, based on two-step photoionization of the sodium atoms in the
beam, may deliver a current of up to 1 nA and has been used with a current of typically 0.2 nA in this experiment. The energy
dependence of the rate of sodium anion formation is determined by ion detection based on a time-of-flight analysis. The molecules
are selectively excited to levels using the technique of coherent population transfer by delayed pulses (STIRAP). The comparison of the experimental data with
recent resonance model calculations based on improved potential curves reveals generally good agreement for levels v
”>12. For some distinct differences between theoretical and experimental results persist.
Received: 21 November 1998 / Received in final form: 7 April 1999 相似文献
5.
S. Keller 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,13(1):51-59
Triple differential cross-sections (TDCS) for (
e
,2
e
) processes on C60 have been calculated in the plane wave Born and distorted wave Born approximations using a jellium shell model to describe
the target valence states. The peculiarities of these TDCS are demonstrated by comparison with results for atomic hydrogen.
Ionisation into a resonant state leads to dramatic modifications of the TDCS. This effect could also be observed in a surface
(
e
,2
e
) experiment in specular geometry using a thin film of physisorbed C60.
Received 14 April 2000 and Received in final form 27 July 2000 相似文献
6.
J. Sun G. Yu Y. Jiang S. Zhang 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,4(1):83-88
The additivity rule is employed to obtain the total (elastic+inelastic) cross-sections for positron scattering from molecules
including a number of diatomic, polyatomic molecules (H2, N2, HCl, CO2, NH3, SF6, CH4, C2H4 and C3H8) over an incident energy range of 10-1000 eV. The total cross-sections (TCS) of the constituent atoms of molecules are obtained
by employing a complex optical model potential (composed of static, polarization and absorption potential). The present results
are compared with experimental data and other theoretical calculations, good agreement is obtained in intermediate- and high-energy
region.
Received: 11 November 1997 / Revised: 23 March 1998 / Accepted: 16 June 1998 相似文献
7.
V. Kasperovich K. Wong G. Tikhonov V.V. Kresin 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,16(1):99-102
An analysis of integral cross sections for slow electron collisions with neutral sodium clusters and nanoparticles reveals
that, in addition to an effective negative ion formation channel, there exists a strong inelastic threshold-type process which
appears above a collision energy of 1-1.3 eV. We show that it can be plausibly associated with the onset of direct electron-induced
cluster fragmentation. This result highlights the importance of understanding the dynamics of electron-vibrational energy
transfer in nanoclusters, including the relative probability of direct vs. statistical energy transfer.
Received 24 November 2000 相似文献
8.
R. Thissen P. Lablanquie R.I. Hall M. Ukai K. Ito 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,4(3):335-342
Photoionization of rare gas clusters in the innervalence shell region has been investigated using threshold photoelectron
and photoion spectrometers and synchrotron radiation. Two classes of states are found to play an important role: (A) valence
states, correlated to dissociation limits involving an ion with a hole in its innervalence ns shell, (B) Rydberg states correlated to dissociation limits involving an ion with a hole in its outervalence np shell plus an excited neutral atom. In dimers, class A states are “bright”, that is, accessible by photoionization, and serve
as an entrance step to form the class B “dark” states; this character fades as the size of the cluster increases. In the dimer,
the “Mulliken” valence state is found to present a shallow potential well housing a few vibrational levels; it is predissociated by the
class B Rydberg states. During the predissociation a remarkable energy transfer process is observed from the excited ion that
loses its innershell electron to its neutral partner.
Received: 10 February 1998 / Revised: 17 July 1998 / Accepted: 31 July 1998 相似文献
9.
K. Hashimoto M. Okamoto K. Takayanagi 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,2(1):75-78
The stability of neutral, singly and multiply ionized silicon clusters, (N
= 2-7, M
= 0, , , ), has been investigated using an ab initio density functional method. We show that the fragmentation effect significantly affects the structure of mass-spectra of multiply
ionized silicon clusters. For clusters, the clusters with a large fragmentation energy are found to correspond to the high peaks at N = 4 and 6 in mass-spectra. For clusters, a peak at N = 5 in mass-spectra has been predicted to be especially high.
Received: 9 June 1997 / Revised: 8 January 1998 / Accepted: 25 February 1998 相似文献
10.
F. Zappa S. Denifl I. Mähr J. Lecointre F. Rondino Olof Echt T. D. Märk P. Scheier 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,43(1-3):117-120
Embedding molecules in helium clusters has become a
powerful technique for the preparation of cold targets for spectroscopy
experiments, as well as for the assembly of complex, fragile molecular
species. We have recently developed a helium cluster source and a pick-up cell
to produce neutral beams of doped helium droplets, to be used as targets in
studies on electron collisions with molecules of biological relevance. In
the present work we present the results of a series of experiments on
electron-impact ionization of helium clusters doped with thymine and
1-methylthymine, where several interesting phenomena were observed, i.e.,
(i) electron impact ionization of molecular clusters inside the helium
droplets leads predominantly to protonated clusters; (ii) the appearance
energies are close to the ionization threshold of the helium atom but
ionization efficiency curves in addition extend down by several eV; (iii)
ionized molecular clusters can undergo metastable decay via the loss of one
neutral monomer. 相似文献
11.
S.M.S. da Costa M.H.F. Bettega 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,3(1):67-71
We report elastic integral, momentum transfer and differential cross sections for electron scattering by N2O for energies up to 50 eV. These results were obtained at the static-exchange approximation with the Schwinger Multichannel
Method with Pseudopotentials [M.H.F. Bettega, L.G. Ferreira and M.A.P. Lima, Phys. Rev. A 47, 1111 (1993)]. In general our results show good agreement with experimental data and with other theoretical results but some
discrepancies are found. We have also found a shape resonance around 4 eV in agreement with previous calculations using the R-matrix Method of Sarpal et al. [J. Phys. B 29, 857 (1996)]. On the other hand, the existence of a resonance at about 13 eV, clearly seen by the Schwinger Variational Iterative Method [Michelin et al., J. Phys. B 29, 2115 (1996)], can not be confirmed by our calculations. At this energy, our cross sections show a broad bump with no clear resonant behavior given by the eigenphase sum.
Received: 13 November 1997 / Revised: 13 March 1998 / Accepted: 9 April 1998 相似文献
12.
J. B. Boffard M. F. Gehrke M. E. Lagus L. W. Anderson C. C. Lin 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,8(2):193-198
This paper describes a method for reducing the influence of cascades on the measurement of electron excitation cross sections
using the optical method and a fast beam atomic target. By using a fast beam of target atoms one can reduce the influence
of cascades on a measurement, and estimate the cascade contribution to the excitation signal.
Received 19 April 1999 and Received in final form 10 August 1999 相似文献
13.
14.
Calculation of dielectronic recombination cross sections and rate coefficients for heliumlike carbon
J.-G. Wang T.-Q. Chang Y.-Z. Qu 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,2(3):231-235
A simplified relativistic configuration interaction method is used to calculate the dielectronic recombination cross sections
and rate coefficients for heliumlike carbon. In this method, the infinite resonant doubly excited states can be treated conveniently
in the frame of Quantum Defect Theory. Our calculated cross sections are in agreements with the experimental measurements
except for the 1s2lnl'(n=6,7) resonances. The total energy-integrated cross sections and rate coefficients over all dielectronic resonances are in
agreements with the experimental measurements within percent.
Received: 7 July 1997 / Revised: 7 October 1997 / Accepted: 8 December 1997 相似文献
15.
R. Cheikh J. Hanssen B. Joulakian 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1998,2(3):203-208
The fivefold differential cross section (5DCS) of the ionisation by electron impact of atomic sodium is determined theoretically
for its fundamental 3s(2
S) state and the excited 3p(2
P) and 3d(2
D) states by a procedure which employs in the transition matrix element of the first order Born approximation, the correlated
double continuum (3C) wave function. This permits us to determine the statistical M-state population and the orientation and alignment tensors in (e,2e) detection. It is also shown that, the use of Gamow correlation term, in the independent particle (2C) model, reproduces,
only in some situations, the shape of the angular distribution of the 5DCS obtained by the (3C) wave function.
Received: 17 November 1997 / Received in final form: 16 March 1998 / Accepted: 21 March 1998 相似文献
16.
J.-G. Wang T.-Q. Chang C.-Z. Dong T. Kato 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,5(2):167-171
A simplified relativistic configuration interaction method is used to study the dielectronic satellite transition processes.
In this method, the infinite resonant doubly excited states can be calculated, and furthermore, the whole high-n dielectronic satellite transition processes can be treated conveniently by interpolation (rather than extrapolation) in the
frame of Quantum Defect Theory. As an example, we calculate the contributions from high-n dielectronic satellites to the resonance line in helium-like iron, and the results are in good agreement with the experimental measurements.
Received: 16 April 1998 / Revised: 8 September 1998 / Accepted: 14 September
1998 相似文献
17.
K.N. Joshipura M. Vinodkumar B.K. Antony N.J. Mason 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,23(1):81-90
Total ionization cross-sections of electron impact are calculated for the molecular targets CHx, CFx, SiHx, SiFx (x = 1-4) and CCl4 at incident energies 20-3 000 eV. The calculation is based on Complex Scattering Potential approach, as developed by us recently.
This leads to total inelastic cross-sections, from which the total ionization cross-sections are extracted by reasonable physical arguments. Extensive comparisons are made here with the previous theoretical
and experimental data. The present results are satisfactory except for the CFx and SiFx (x = 1-3) radicals, for which the experimental data are lower than most of the theories by more than 50%.
Received 23 May 2002 / Received in final form 24 October 2002 Published online 21 January 2003
RID="a"
ID="a"e-mail: knjoshipura@yahoo.com 相似文献
18.
M. Gupta K. L. Baluja 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,41(3):475-483
Electron-H2S collision process is studied using the R-matrix method. Nine low-lying states of H2S molecule are considered in the R-matrix formalism to obtain elastic integral, differential, momentum transfer and excitation cross sections for this scattering
system. We have represented our target states using configuration interaction (CI) wavefunctions. We obtained adequate representation
of vertical spectrum of the target states included in the scattering calculations. The cross sections are compared with the
experiment and other theoretical results. We have obtained good agreement for elastic and momentum transfer cross sections
with experiment for entire energy range considered. The differential cross sections are in excellent agreement with experiment
in the range 3–15 eV. A prominent feature of this calculation is the detection of a shape resonance in 2B2 symmetry which decays via dissociative electron attachment (DEA). Born correction is applied for the elastic and dipole allowed
transition to account for higher partial waves excluded in the R-matrix calculation. The electron energy range is 0.025–15 eV. 相似文献
19.
J. Mahoney V. Tarnovsky K. H. Becker 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,46(2):289-293
We measured absolute partial cross sections for the formation of all singly
charged positive ions produced by electron impact on SiCl2 and SiCl
from threshold to 200 eV using the fast-neutral-beam technique. Some of the
cross section curves exhibit an unusual energy dependence with a pronounced
low-energy maximum at an energy around 30 eV, which may be indicative of the
presence of indirect ionization channels. Dissociative ionization channels
are dominant for both species. The experimentally determined total single
ionization cross sections for both species agree very well with calculated
cross sections using the Deutsch-M?rk (DM) formalism. A brief summary of
the ionization cross sections determined for all four SiClx (x=1–4)
species is given highlighting similarities and differences. 相似文献
20.
J.M. Weber E. Leber M.-W. Ruf H. Hotop 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》1999,7(4):587-594
Using a high resolution laser photoelectron attachment method, we have studied the formation of (H
2
O)
q
- (q = 2, 6, 7, 11, 15) cluster ions in collisions of slow free electrons (E = 1-80 meV) and Rydberg electrons (n = 12-300) with water clusters. Resonances at zero energy have been observed, the shapes of which are strongly dependent on
cluster size. The results are discussed in terms of the formation of metastable negative ions.
Received 8 March 1999 相似文献