Transport of reactive solutes in unsteady annular flow subject to wall reactions

The present paper concerns with the dispersion process in steady and oscillatory flows through an annular pipe in presence of reversible and irreversible reactions at the wall. Method of homogenization, a multiple-scale method of averaging, is adopted for deriving the effective transport equations. The main objective is to look into the effect of aspect ratio of the annular pipe on the dispersion coefficient due to the combined effect of axial convection and radial diffusion in steady and oscillatory flows along the annulus, subject to the kinetic reversible phase exchange and irreversible absorption at the outer wall. Results demonstrate that upto a certain critical value of aspect ratio, dispersion coefficient increases with increase of aspect ratio when the wall is retentive, though the wall inertness may lead to decrease of dispersion coefficient with increase of aspect ratio. The results would be useful to the medical practitioners working in the domain of catheterized artery.     

Variational-Lagrangian irreversible thermodynamics of initially-stressed solids with thermomolecular diffusion and chemical reactions

A general principle of virtual dissipation in irreversible thermodynamics is applied to a solid under initial stress with small non-isothermal incremental deformations and coupled thermomolecular diffusion and chemical reactions. Dynamical field and Lagrangian equations are obtained directly by variational procedures. In addition, the treatment embodies new fundamental concepts and methods in the thermodynamics of open systems and thermochemistry. The new concept of ‘thermobaric potential’ is briefly outlined. The theory is also applicable to porous solids with ‘diffusionlike’ behaviour of pore-fluid mixtures. General validity of viscoelastic correspondence for chemical or other relaxation processes with internal coordinates is indicated in acoustic propagation and seismic problems.     

Reactive Euler equations of discrete models with reversible reactions

Received November 25, 1998     

Dispersion of particles in wall-bounded particle-laden turbulent flows with high wall permeability

A series of numerical simulations were performed to investigate the distribution and deposition properties of particles in turbulent flows bounded by permeable walls using the Large Eddy Simulation (LES) with a Lagrangian trajectory approach. The wall permeation speeds were taken from 10⁻⁴ to 10⁻² of the bulk velocity. The directions of the permeation speed were the same at both walls, and they were inward on one wall but outward on the other wall to reserve the fluid mass. Particles with Stokes number (respecting viscous time scale) around 0.1, 1 and 10 were released in the fully developed turbulent channel flow. The particle–particle interaction and the retroaction from particles to the fluid were neglected. The fluid-phase turbulence statistical properties and particle's transport characteristics by vortexes were then analyzed in details. If the wall permeation exists, the turbulence intensities will be depressed close to the outward permeable wall but increased near the inward permeable wall. Not influenced by the wall permeation, the suspended particles with St⁺ ∼O(1) tend to accumulate in the less vortical zones away from the wall, while those particles in the flow regions near the outward permeable wall will distribute disregarding of the vorticity. The turbulence structures near the outward permeable wall are found to exert promotional effects on the particle deposition rate, but such effects are different for particles with various Stokes number. A distribution tendency of streamwise streaks for the deposited particles is also found on the wall imposed by the high outward permeation speed and the clustering deposition pattern is more obvious with increasing particle Stokes number.     

Modulation of reactive oxygen species to enhance sonodynamic therapy

Reactive oxygen species (ROS), involving in many biological reactions, play an important role in disease treatment. Among the various ROS-based therapeutic modalities, sonodynamic therapy (SDT) stands out with its unique advantages. In turn, the SDT efficacy is mainly dependent on the ROS levels in the disease microenvironment. Therefore, in recent years, researchers have extensively investigated SDT with high ROS generation capacity. In this review, we focus on effective strategies to improve the therapeutic efficiency of SDT by modulating ROS, overview the basic mechanisms of ROS generation by sonosensitizers, highlight the rational design of sonosensitizers, and summarize strategies to improve the SDT efficacy by modulating disease microenvironment. In addition, multiple ROS synergistic treatment modalities and the prospect of SDT are discussed. We believe that the understanding and exploration of SDT enhancement strategies will facilitate the clinical translation of SDT.     

Extended irreversible thermodynamics and its relation with other continuum approaches

We present an introduction to extended irreversible thermodynamics (EIT) as applied to polymer solutions in the presence of shear flow and of diffusion flux. We discuss with special attention the definition of chemical potential in non-equilibrium situations and its use in the analysis of shear-induced phase transitions. In the second part, we compare EIT with other contemporary continuum approaches: theories with internal variables, the GENERIC approach, and the matrix model. All these theories share an emphasis on the relations between dynamics and thermodynamics at a deeper level than in the classical theory, but each of them has some peculiar advantage in the analysis of some specific aspects of physical problems.     

Variational irreversible thermodynamics of physical-chemical solids with finite deformation

A new thermodynamics of open thermochemical systems and a variational principle of virtual dissipation are applied to the finite deformation of a solid coupled to thermomolecular diffusion and chemical reactions. A variational derivation is obtained of the field differential equations as well as Lagrangian equations with generalized coordinates. New formulas for the affinity and a new definition of the chemical potential are presented. An outline is given of an unusually large field of applications, such as active transport in biological systems, finite element methods, plastic properties as analogous to chemical reactions, phase changes and recrystalization, porous solids, heredity and initially stressed solids. A new and unified insight is thus provided in highly diversified problems.     

Conjugated heat and mass transfer between a reactive solid and a gas in the presence of nonequilibrium chemical reactions

An investigation of a multicomponent boundary layer taking account of nonequilibrium chemical reactions has been made in a number of publications [1–3]; here, the temperature of the solid was assumed to be known or was determined from the condition of the conservation of energy at the interface between the gas and the solid, taking account of the solution of the equation of thermal conductivity in the solid phase. At the same time, heating of the material of a coating is an unavoidable step in any mechanism of thermokinetic decomposition and, in view of this, it is necessary to take account of the lag of the heat-transfer process inside the solid. Therefore, it is necessary to solve the equation of the energy balance in the solid phase simultaneously with the system of the equations of the boundary layer, i.e., the conjugate problem. The present article discusses the problem of flow around a solid in the vicinity of a frontal critical point, taking account of the dependence of the processes taking place in the solid body on the time, in the presence of two heterogeneous and one homogeneous reactions. The distributions of the velocity, the temperature, and the concentrations in the boundary layer are obtained, as well as the mass rate of entrainment of the material at different moments of time. The time of the change between kinetic and diffusion conditions of the course of the heterogeneous chemical reactions (the ignition time) is determined. It is established that, in the presence of a homogeneous chemical reaction, the mass rate of entrainment is less than with a frozen flow.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 121–128, March–April, 1974.     

Experimental study of massive wall systems with fins attached on the heated wall and with glazing

 Natural convection, radiation and conduction heat transfer in passive solar massive wall systems with fins attached to the heated surface and with glazing is experimentally studied. The system was 0.78 m high, 0.40 m wide and 0.10 m thick concrete wall with a glazing placed at 0.0265 m from the surface. It had 0.025 m long, 0.004 m thick horizontal fins made as an integral part of the massive wall and placed at 0.01 m intervals. A heat source was used to impose a constant heat flux which could be varied from about 200–800 W/m². Temperatures at various points and heat flux by convection at the back were measured. Using various assumptions, the systems was also analyzed theoretically. The results show that about 40% of the heat flux imposed on the finned surface goes through the system and is dissipated at the back. Received on 7 September 2000     

Thermodynamics of irreversible processes and the lyapuncv-function method

A connection is established between the production of entropy in irreversible processes and the Lyapunov function of the corresponding system of equations. Thermodynamic limitations are formulated on the functions that enter in the kinetic equations. The results are illustrated with relaxation processes in viscoelastic media.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, No. 4, pp. 99–107, July–August, 1972.     

Soret and Dufour effects on mixed convection unsteady MHD boundary layer flow over stretching sheet in porous medium with chemically reactive species

This paper studies the thermal-diffusion and diffusion thermo-effects in the hydro-magnetic unsteady flow by a mixed convection boundary layer past an imperme- able vertical stretching sheet in a porous medium in the presence of chemical reaction. The velocity of t~he stretching surface, the surface temperature, and the concentration are assumed to vary linearly with the distance along the surface. The governing partial differential equations are transformed into self-similar unsteady equations using similarity transformations .and solved numerically by the Runge-Kutta fourth order scheme in as- sociation with the shooting method for the whole transient domain from the initial state to the final steady state flow. Numerical results for the velocity, the temperature, the concentration, the skin friction, and the Nusselt and Sherwood numbers are shown graph- ically for various flow parameters. The results reveal that there is a smooth transition of flow from unsteady state to the final steady state. A special case of our results is in good agreement with an earlier published work.     

Transient analysis of diffusive chemical reactive species for couple stress fluid flow over vertical cylinder

The unsteady natural convective couple stress fluid flow over a semi-infinite vertical cylinder is analyzed for the homogeneous first-order chemical reaction effect. The couple stress fluid flow model introduces the length dependent effect based on the material constant and dynamic viscosity. Also, it introduces the biharmonic operator in the Navier-Stokes equations, which is absent in the case of Newtonian fluids. The solution to the time-dependent non-linear and coupled governing equations is carried out with an unconditionally stable Crank-Nicolson type of numerical schemes. Numerical results for the transient flow variables, the average wall shear stress, the Nusselt number, and the Sherwood number are shown graphically for both generative and destructive reactions. The time to reach the temporal maximum increases as the reaction constant K increases. The average values of the wall shear stress and the heat transfer rate decrease as K increases, while increase with the increase in the Sherwood number.     

Global-local HROM for non-linear thermal problems with irreversible changes of material states

Highly concentrated moving nonlinearities are extremely difficult to solve numerically. The Selective Laser Melting Additive Manufacturing process is a problem of this kind. A material global-local scheme is proposed, which consists in describing the neighbourhood of the heat source by a moving local domain while the material phase fractions are represented in a global domain. The equations of the non-linear thermal problem are defined on the local domain only, assuming that the local domain is large enough to capture the most important variations of the temperature field. Additionally, a Hyper-Reduced-Order Model (HROM) is proposed for the local domain problem. The performance is studied by solving a SLM problem taken from the literature.     

On the diffusion of a chemically reactive species in a convective flow past a vertical plate

A numerical solution of the first-order homogeneous chemical reaction in an unsteady free convective flow past a semi-infinite vertical plate is studied. The dimensionless governing equations are solved by an efficient, more accurate, unconditionally stable, and rapidly converging implicit finite-difference scheme. The effect of various parameters, such as the Prandtl number, Schmidt number, buoyancy ratio parameter, and chemical reaction parameter on flow velocity and temperature is determined. The velocity profiles are in excellent agreement with available results in the literature. The local and average values of skin friction and Nusselt and Sherwood numbers are calculated. The effects of the chemical reaction parameters on these values are discussed for both generative and destructive reactions. Owing to the presence of the first-order chemical reaction, the velocity is found to increase in the generative reaction and to decrease in the destructive reaction.     

Contribution to efficiency of irreversible passive energy pumping with a strong nonlinear attachment

The present study deals with nonlinear energy pumping which consists in passive irreversible transfer of energy from a linear structure to a nonlinear one. Various results (theoretical, numerical, and experimental) about energy pumping based on recent works are given. Thus, the phenomenon is studied for different excitations: transient and periodical. Moreover, advantages of such a system are carried out in particular efficiency of this phenomenon. That is why the robustness and comparison with classical tuned mass damper are analyzed. An application is considered with physical experiment using a reduced scale building.     

Dispersion and Dispersivity Tensors in Saturated Porous Media with Uniaxial Symmetry

The coefficient of dispersion, D _ij , and the dispersivity, a _ijkl , appear in the expression for the flux of a solute in saturated flow through porous media. We present a detailed analysis of these tensors in an axially symmetric porous medium, e.g., a stratified porous medium, with alternating layers, and show that in such a medium, the dispersivity is governed by six independent moduli. We present also the constraints that have to be satisfied by these moduli. We also show that at least two independent experiments are required in order to obtain the values of these coefficients for any three-dimensional porous medium domain.     

Dispersion of a filtration stream in media with random inhomogeneities

The transport of a dynamically neutral impurity by a stream into a porous medium with random inhomogeneities is considered. In contrast to [1, 2], in which a Markov random-walk process of the impurity particles was postulated substantially (taking a hypothesis about Markov random walk processes contradicts to a definite degree the representation of particle motion along a streamline, finiteness of the velocity, and smoothness of the trajectory), the complete system of equations for the filtration concentration and velocities is investigated here by a perturbation method, which results in a non-local equation for the mean concentrations after taking the average. It is shown that the local equation (parabolic or hyperbolic) is the limit case in the scheme considered. The effect of a regular drift of saturation, analogous to the effect of directed transport in the theory of inhomogeneous turbulent diffusion [3], is established. One-dimensional, plane, and three-dimensional flows are considered. The fundamental relationships contain moments of the random velocity field. The relationship between these moments and the characteristics of the random permeability and porosity fields has been established in [1, 2].     

Laminar flow and mass transfer in channels with a porous bottom wall and with fins attached to the top wall

 The steady incompressible, viscous, two- dimensional flow of a solution in a channel was considered. The bottom wall was porous and the fins were attached to the top wall. Employing control volume approach, a computer program based on SIMPLE algorithm was developed. Computations were carried out to investigate the effects of the inlet Reynolds number, the fin length, the suction Reynolds number and the slip coefficient on the flow structure and the concentration distribution. It was observed that the thickness of concentration boundary layer increases in the flow direction. The concentration on the porous wall and the concentration boundary layer thickness decrease with increasing fin length, the slip coefficient and the inlet Reynolds number. These results show that fins attached to the upper wall of the channel can be utilized to reduce the concentration polarization and hence improve the effectiveness of the separation process. Received on 24 February 1999