测定核间距的不对称2D NOESY方法2.Cis-Pt(NH3)2(Guo)2Cl2的不对称2D NOESY实验研究

应用不对称2DNOESHY实验方法研究了顺铂配合物Cis-Pt (NH₃)₂(Guo)₂Cl₂的水溶液中的构象,表明鸟苷同铂配合后其糖环构象发生明显的变化。     

Fairness-aware resource allocation for D2D-enabled IoT in NOMA-based cellular networks with mutual successive interference cancellation

Device-to-device (D2D) communications and non-orthogonal multiple access (NOMA) are promising technologies to meet the growing demand for IoT-connected devices. However, they bring about new challenges including the co-channel interference, that can limit the performance improvement. To manage the co-channel interference, we address the problem of joint power allocation and sub-channel assignment for D2D-enabled IoT devices (IoTDs) underlaying a NOMA-based cellular network, in which the successive interference cancellation (SIC) decoding is enabled at the level of IoTDs and cellular user equipment (CUE)to increase the number of connected devices and the capacity. This problem is modeled as a mixed-integer nonconvex optimization problem which includes the concept of fairness with respect to the data rates of IoTDs. To solve the problem, a semi-distributed algorithm is developed, which is of polynomial time complexity. The proposed algorithm leverages the successive convex approximation and a heuristic approach. Evaluation results demonstrate the efficiency of the proposed scheme with respect to the sum rate, fairness, access rate and computational complexity.     

N2（A）及N（2D）对IF（X）的传能研究

在微波放电系统中,对NH_3-F-F_2-CF_3I体系进行研究,结果表明,向IF(X)传能的诸多媒介中,N_2(A)及N(~2D)起着主要作用,并且这一结论在经微波激发后的N_2与CF_3I的直接反应中得到了进一步证实。     

基于二维彩色靶标的结构光三维测量系统快速标定方法

系统标定是基于结构光投影的主动式光学三维面形测量的关键技术之一,同时也是一项复杂和耗时的工作。提出了一种基于RGB彩色模型的系统快速标定新方法。利用一个彩色的二维平面靶标和由投影仪投影的彩色标记特征图像实现了摄像机和投影仪的同时快速标定,对靶标的每个标定姿态位置只需要拍摄一幅图像即可得到该位置的特征参数。与传统方法相比,标定过程简单快捷,所需的数据量较少。利用该方法对一个结构光三维测量系统进行了现场标定,并测量了一个平面和一个半圆柱物体,实验结果中点到拟合平面的最大距离为0.8039mm,平均误差为0.1693mm。利用该系统恢复半圆柱物体的面形与传统标定方法的测量结果符合得很好。实验表明,由该方法获得的结果准确可用,且标定速度快。     

CdSe infiltrated TiO2 based omnidirectional photonic crystals for visible light control

Control of light emission by engineering the electromagnetic vacuum is important in photonics for fundamental understanding as well as in applications. Omnidirectional photonic crystals such as logpile photonic crystals provide a very interesting system to study such phenomena. Here, we describe the first steps towards achieving systematic and reproducible control of light using titanium dioxide (TiO₂) logpile photonic crystals (PC) with incorporated cadmium chalcogenide (CdSe) quantum dots (QDs) (λ  600 nm) to potentially modify QD photoluminescence (PL). We present a technique for coating a monolayer of the QDs on the PC rods based on 3-mercaptopropyltrimethoxysilanol linkage and measured the resulting PL response. Comparison of the PL spectra to a finite difference time domain model shows the need for further localization of QDs and fabrication of additional PC unit cells to observe PL modification.     

A12O3X2（X=H，D，T）的电子振动近似方法

用密度泛函理论在B3LYP／6．311＋＋g（d,P）基组水平上对A12O3X2（X=H,D,T）分子的可能较低能量构型进行了几何优化．结果表明该分子的基态电子态和对称性为A12O3X2（X=H,D,T）（1A’）G,计算了氢同位素分子及A12O3X2（X=H,D,T）的电子能量E、定容热容Cv和熵S．用电子振动近似方法计算了固体A12O3的氢化热力学函数△H0,△S0,△G0,以及平衡压力与温度的关系．当A1203吸附氢（氘,氚）形成固体时,反应的氢氘氚排代效应的顺序为氚排代氘,氘排代氢,与钛等金属与氢及其同位素反应的氢氘氚排代效应的顺序相反．总体来说,这种排代效应都非常弱．随着温度的增加,这系列反应的氢氘氚排代效应趋于消失．     

Al2O3X(X=H,D, T)的电子振动近似理论方法研究

用密度泛函理论(DFT)方法在6-311++G(d,p)水平上对Al₂O₃X(X=H, D, T)分子较低能量的几何构型进行了优化. 计算结果表明该分子有两个可能基态, 即Al₂O₃X(X=H,D,T)(²A′)C_s和Al₂O₃X 关键词： 2O₃X(X=H;D;T)分子团簇')" href="#">Al₂O₃X(X=H;D;T)分子团簇 热力学函数 氢同位素效应 吉布斯自由能改变