共查询到20条相似文献，搜索用时 46 毫秒
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通过X射线应力测试和有限元分析相结合的方法,研究了金刚石层厚度对聚晶金刚石复合片（PDC）残余应力的影响,并根据实验测试结果推导出了PDC表面中心与边缘的应力随金刚石层厚度变化的关系式。随着金刚石层厚度由0.5 mm增加到2.0 mm,PDC表面中心的压应力从1 800 MPa下降至700 MPa左右,而边缘部分的应力逐渐由压应力转为拉应力。金刚石层加厚虽然对边缘部分的最大拉应力影响不大,但使PDC边缘拉应力区宽度由0.76 mm增加到了2.85 mm。金刚石层厚度的增加还使得PDC边缘界面附近y方向的最大拉应力和位于界面边缘处的最大剪应力显著加大,这是金刚石层较厚的PDC界面容易产生裂纹的主要原因。 相似文献
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本文利用低温力学测试系统研究了电化学沉积纳米晶Ni在不同温度和宽应变速率条件下的压缩行为. 借助应变速率敏感指数、激活体积、扫描电子显微镜及高分辨透射电子显微镜方法, 对纳米晶Ni的压缩塑性变形机理进行了表征. 研究表明, 在较低温度条件下, 纳米晶Ni的塑性变形主要是由晶界位错协调变形主导, 晶界本征位错引出后无阻碍的在晶粒内无位错区运动, 直至在相对晶界发生类似切割林位错行为. 并且, 在协调塑性变形时引出位错的残留位错能够增加应变相容性和减小应力集中; 在室温条件下, 纳米晶Ni的塑性变形机理主要是晶界-位错协调变形与晶粒滑移/旋转共同主导. 利用晶界位错协调变形机理和残留位错运动与温度及缺陷的相关性揭示了纳米晶Ni在不同温度、不同应变速率条件下力学压缩性能差异的内在原因. 相似文献
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The time-of-flight neutron diffraction technique and the elastoplastic self-consistent model were used to study the behaviour of single and multi-phase materials. Critical resolved shear stresses and hardening parameters in austenitic and austenitic–ferritic steels were found by analysing the evolution of the lattice strains measured during tensile tests. Special attention was paid to the changes of the grain stresses occurring due to transition from elastic to plastic deformation. Using a new method of data analysis, the variation of the stress localisation tensor as a function of macrostress was measured. The experimental results were successfully compared with model predictions for both phases of the duplex steel and also for the austenitic sample. 相似文献
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Ryo Matsumoto Zhufeng Hou Shintaro Adachi Masanori Nagao Sayaka Yamamoto Peng Song 《高压研究》2020,40(1):22-34
ABSTRACTData-driven exploration for pressure-induced superconductors was performed based on the high-throughput first-principles screening of electronic band structures. In the screening conditions, we focused on the characteristics including a narrow band gap, flat band feature, and possibility of metallization under high pressure. The 27 promising compounds were screened out from the database of Atomwork for the candidates of new pressure-induced superconductors. Among the candidates, we actually synthesized three compounds in a single crystal, and all candidates exhibited the pressure-induced superconductivity. For the in-situ electrical transport measurements, we developed a novel configuration of diamond anvil cell with boron-doped diamond electrodes and an undoped diamond insulating layer. The discovered new pressure-induced superconductors via the data-driven approach and the developed diamond anvil cell were summarized in this paper. 相似文献
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采用X射线衍射（XRD）分析、扫描电子显微镜（SEM）和能谱分析（EDX）等方法,对在压力5.6 GPa、温度1 460 ℃条件下,加热时间分别为2、3、4、6、8、10 min的聚晶金刚石复合片（PDC）样品进行了分析。结果表明：PDC的烧结经历了金刚石的石墨化过程,而且在烧结过程中金刚石层表面的XRD图谱出现了WC衍射峰,强度由弱到强,再由强到弱,直至消失;进一步的研究发现,PDC中助烧结剂Co的晶格常数因C和W原子的固溶会变大,并随PDC加热时间的延长出现一个峰值;从硬质合金基体扩散到金刚石层的Co由于扩散通道各异、所受阻力不同,使得其分布不均匀。 相似文献
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P. G. Kopylov A. M. Lotonov I. A. Apolonskaya A. N. Obraztsov 《Moscow University Physics Bulletin》2009,64(2):161-165
The results of the experimental study of the conductivity of a polycrystalline diamond film by dielectric spectroscopy are presented. A diamond film about 200 μm thick was grown by microwave plasma-assisted chemical vapor deposition for 180 h. Two pronounced local peaks in the frequency dependence of the conductivity were observed. The relevant frequencies were temperature-dependent. These data permit us to hypothesize that the hopping mechanism of conductivity occurs in the polycrystalline diamond film. Two types of electrically active centers with different activation energies and relaxation times are involved in the conductivity. 相似文献
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Rajarshi ChakrabortySuresh C. Sharma 《Physica B: Condensed Matter》2011,406(22):4170-4174
We studied the structure of diamond nanoparticles grown by chemical vapor deposition. SEM images show that the material contains cubic, hexagonal, and possibly icosahedral structures ranging in size from 10 to 200 nm. Raman spectroscopy shows bands, which are characteristic of crystalline diamond, E2g mode of hexagonal diamond, a-C, and graphite. 相似文献
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Petr P. Sharin Sofia P. Yakovleva Susanna N. Makharova Maria I. Vasilieva Vasilii I. Popov 《Composite Interfaces》2019,26(1):53-65
The structural-phase state of the contact zone and the factors that influence on the strength of diamond retention in the diamond carbide composites were determined. Composites were obtained by the new hybrid technology that eliminates the reheating of the metalized coating. The elaborated technology combines the thermal diffusion metallization of a diamond and the sintering by the scheme of self-dosed impregnation in a one-stage technological cycle. By the methods of electron microscopy, X-ray diffraction analysis, and Raman spectroscopy the structural and phase characteristics of the interphase boundary were investigated. The improvement of chemical and mechanical adhesion between the diamond and carbide matrix was obtained. It was shown that the specific productivity of the samples with a metalized diamond component is 39% higher than those without metallization. 相似文献
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AbstractThe purpose of this paper is to provide new experimental data for high-strength VT 22 titanium α + β-type alloy under impact-oscillatory loading and dynamic non-equilibrium process. Based on the performed experimental studies, it was found that overall plastic deformation of this alloy can be increased by a factor 2.75 compared with its initial state without significant loss of strength. To achieve this goal, a new methodology to study the impact behaviour of materials under non-equilibrium process has been used. Physical research revealed that significant microstructural refinement of the alloy is observed after such type of loading, as the result of which the fine grains are formed with subgrain refinement which takes place within the basis of alloy. 相似文献
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A brief survey of the current theories of formation of diamonds in nature leads to the hypothesis which suggests the possibility
of natural diamonds having formed metastably—a hypothesis which has not been enjoying much experimental support in its favour.
The authors present briefly some aspects of the investigations which have resulted in demonstrating a new process whereby
the dissolution and metastable autoepitaxial (re)crystallization of diamond occurs at atmospheric pressure. A comparison of
certain reported growth characteristics of natural (terrestrial) and synthetic (high pressure, solvent-catalyst) diamonds
with those of the metastable diamond overgrowths reveal many striking similarities. These results therefore serve as evidence
to support the metastable origin hypothesis. 相似文献
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高压力学研究在材料学领域和地学领域掀起了交叉科学研究的热潮,为高难度材料制备、材料力学性能改善、地震波各向异性成因及地球内部动力学过程研究等科学问题提供了解决方案。针对高压力学领域的研究方法,介绍了金刚石对顶砧结合X射线径向衍射法、旋转型金刚石对顶砧施加剪切应变法、高压扭转型压机施加剪切应变法、D-DIA型大腔体压机形变法和冲击压缩产生塑性形变法及其研究进展,展示了压应力与剪切力的耦合作用在调控材料的结构、性能及宏观力学行为方面的独特效应,揭示了高压力学研究的价值与应用潜力。
相似文献14.
The extraordinary properties of diamond make it the number-one choice for anvils in high pressure experiments involving anvil cells. In much of the literature on the properties of diamond the only cleavage mentioned is {111}. However, experience has shown that diamond anvils made with their [001] axis oriented in line with the principal stress axis of the anvil or at a small angle to it often failed with flat faces having {110} orientations; a cleavage plane is reported in some publications. Analysis of the anisotropy of strength and Poisson ratio in diamond has shown that such orientations do, indeed, favor initial failure on {110} cleavage planes. This analysis, in conjunction with stereographic projections of the {111} and {110} cleavage planes, suggests that a 27° tilt of the [001] axis with respect to the linear stress axis by rotation around the [100] or [010] axis should provide significantly greater resistance to failure by cleaving. 相似文献
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讨论了PDC材料烧结过程中钴在金刚石层中的固相扩散、钴液熔渗、两次钴高浓度峰的波浪式迁移过程中的运动规律及其作用机制,并根据实验观测的数据进行了有关计算。结果表明：在5.8 GPa、1 300 ℃条件下,钴的扩散系数D1.610-7 cm2/s,是一般常压及相同温度条件下钴固相扩散系数（310-10 cm2/s）和相同压力条件下钴的液相扩散系数（510-5 cm2/s）的中间值;对于粒度W10 m的金刚石烧结体系,钴液熔渗作用时间非常短暂,略大于0.5 s,而对于W1 m的超细金刚石烧结体系而言,钴熔渗作用时间为28 s,比粒度W10 m的金刚石烧结要长得多;两次钴高浓度峰的迁移速度分别约为50 m/s和100 m/s。 相似文献
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正交试验法优化金刚石复合片合成工艺 总被引：1，自引：0，他引：1
通过正交试验法,以磨耗比、电阻、完整性、硬度为指标,设计了金刚石复合片的合成工艺。正交试验可以减少合成工艺试验次数,优化合成工艺。试验结果表明,较合理的烧结工艺为：合成压力5.5 GPa,升温速度为200 ℃/min,保温时间16 min,冷却时间14 min,烧结温度1 350 ℃。从压力、温度和时间等因素的影响方面讨论了金刚石复合片的性能。认为：适当地提高温度有利于提高磨耗比及硬度;延长加热时间有利于性能均匀性的提高;延长冷却时间可减少残余热应力。 相似文献
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纳米尺度金属Ag以其独特的导电和导热性,广泛应用于微电子、光电子学、催化等领域,特别是在纳米微电极和纳米器件方面的应用.本文采用分子动力学方法模拟了不同晶粒尺寸下多晶银纳米线的拉伸变形行为,详细分析了晶粒尺寸对多晶银纳米线弹性模量、屈服强度、塑性变形机理的影响.发现当晶粒尺寸小于13.49 nm时,多晶Ag纳米线呈现软化现象,出现反Hall-Petch关系,此时的塑性变形机理主要以晶界滑移、晶粒转动为主,变形后期形成五重孪晶;当晶粒尺寸大于13.49 nm时,塑性变形以位错滑移为主,变形后期产生大量的孪晶组织. 相似文献
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Theory predicts that deformation that occurs by emission of strain bursts falls into two regimes, one in which the burst emission remains a stochastic process as strain increases, and another in which the emission of bursts settles into a deterministic process for large strains. The stochastic regime occurs when the burst emission rate decreases with strain, and in this case, large statistical scatter persists in the stress–strain response on repeated measurements. The deterministic regime occurs when the emission rate increases with strain, and the scatter in the corresponding stress–stress behaviour diminishes at large strains. The strength at the same strain in the stochastic regime is also higher than in the deterministic regime. Factors that affect the burst emission rate include the number of sources as well as the stress dependence of the efficiency of the sources. 相似文献
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This research employs two approaches to characterise the apparent structure observed in localised strain maps constructed from surface topography data acquired from AA5754-O sheet stock that was deformed in three in-plane stretching modes. The first uses a conventional two-point autocorrelation function (ACF), while the second uses the combination of the eigenvalue spectrum associated with each map and information theory. The results from the ACF analysis are inconclusive, implying that this technique lacks the sensitivity necessary to quantify the relationships between multi-point clustering and strain localisation. The information theory-based approach reveals that the relative spectral entropy increases monotonically, attains a maximum and then decreases sharply to the failure strain. This behaviour occurs in all three strain modes and results from two competing processes: one where the formation of structure is favourable and one where it is not. The crossover point is a clear indicator of the onset of critical strain localisation and, therefore, can be regarded as a precursor to failure because once the dominant process shifts, additional strain results in the precipitate formation of a critical strain localisation event. 相似文献
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在５．８ＧＰａ和１４８０℃条件下,首次用Ｂ４Ｃ作碳源,通过触媒合金（Ｎｉ７０Ｍｎ２５ＣＯ５及Ｆｅ５５Ｎｉ２９ＣＯ１６）的作用,合成出粒度为２０～２５μｍ,含硼量高于１ｗｔ％的黑色金刚石,晶体中存在大量针形体。最近艹勾清泉教授提出了这种金刚石形成的原子分子过程模型。用模型预言可能形成具有某些优异特性的针形硼皮及硼氮皮金刚石 相似文献