Low-gamma shift asymmetrical double-side blue-phase liquid crystal display

ABSTRACT

A single-domain blue-phase liquid crystal display (BPLCD), which has asymmetrical double-side electrode structure, is proposed to reduce gamma shift. Firstly, the electro-optical curve and gamma shift of the proposed BPLCD are discussed under the comparison with conventional in-plane switching (IPS) BPLCD. And then, its gamma shift is investigated under various conditions. Compared with the conventional IPS-BPLCD, the operating voltage can be reduced by ~31%, and the transmittance is increased by ~6%. The indistinguishable gamma shift can be obtained under various electrodes’ sizes, when the cell gap is appropriate. The results also indicate that if the electrodes’ height and Kerr constant of BPLC increase, the operating voltage can be further reduced (only 9.6 V in this work), and the gamma shift almost do not change. Moreover, a certain misalignment between the top and bottom glasses are permitted, which is good for reducing the fabrication difficulty. In terms of viewing angle, the proposed BPLCD has an average contrast ratio of ~5000:1, and the gamma shifts at full viewing angles are all indistinguishable.     

Polarisation-independent blue-phase liquid crystal microlens array with different dielectric layer

A fast response (sub-milliseconds) and polarisation-independent blue-phase liquid crystal (BPLC) microlens array with periodical double layer electrodes using different dielectric layers is proposed. The bottom double layer electrodes are coated with transparent and different dielectric layers to generate linearly varying electric potential from the centre to the edge, while the top planar electrode iridium tin oxide (ITO) electrode has a constant potential. As a result, gradient vertical electric fields are generated, and a gradient refractive index profile is obtained. When the applied voltage is changed, the focal length of the BPLC microlens array can be tuned from ∞ to 12.05 mm while keep a low operating voltage (~35V_rms). Besides, the driving mode (simplification driving) and fabrication process (using printing method or mold-pressing method) of the BPLC microlens array is very simple. The simulation results show that the BPLC microlens array is insensitive to the polarisation of incident light while keeping parabolic-like phase profile.     

A blue-phase liquid crystal lens array based on dual square ring-patterned electrodes

We propose a blue-phase liquid crystal (BPLC) lens array based on dual square ring-patterned electrodes. A high dielectric constant layer is used to smoothen out the horizontal electric field and reduce the operating voltage. By creating a potential difference between the dual square ring-patterned electrodes, gradient electric fields are generated and lens-like phase profile is obtained. Besides, the focal length of the BPLC lens is adjustable with voltage changes and all simulation results indicate that the BPLC lens array is polarisation-insensitive.     

The effects of silica nanoparticles on blue-phase liquid crystals

We investigate the effects of hydrophobic silica nanoparticles (SNs) on blue-phase liquid crystals (BPLCs). The optical microscope and reflection spectra observation reveal that a tiny hydrophobic SN dopant stabilises the BPLC phase, and widens the temperature range of the BP I phase. Furthermore, the doped dilute SNs can fine-tune their positions to relax the formation stress of the BPLC lattices, and slightly increase the platelet sizes of the BPLCs. The doped SNs also decrease the driving voltage and response time of the BPLC cell, because the added SNs decrease the elastic constant of the LC host and the relaxation time constant of the BPLC mixture.     

High-diffraction-efficiency Fresnel lens based on annealed blue-phase liquid crystal–polymer composite

We demonstrated a relatively simple and effective method to fabricate a periodically isolated polymer wall of blue-phase liquid crystal Fresnel lens (BPLCFL) by employing a single-masking process of the ultraviolet (UV) irradiation, leading to excellent photopolymerisation-induced phase separation between blue -phase liquid crystal (BPLC) molecules and UV-curable monomers. Nevertheless, some uncured monomers would inherently reside in the BPLC-rich area and slightly inhibit the BPLC molecules realigned under the external electric field. To enhance the optical properties of the polymer-wall BPLCFL considerably, a novel technique for fabricating a pure BPLC zone is proposed that successfully expels the residual monomers from the BPLC volume using a thermal annealing process. Experimental results show that the maximum diffraction efficiency reaches ~36%, which approaches the theoretical limit of ~41%. Consequently, the annealing technique to purify phase-separated composite films has a strong potential to construct the BPLCFL in light of polarisation-free applications.     

A polarisation-free blue phase liquid crystal lens with enhanced tunable focal length range

A polarisation-free blue phase liquid crystal (BPLC) lens with enhanced tunable focal length range is proposed. A matched conventional glass lens is introduced on a BPLC lens to increase the range of the tunable focal length. The focal length of the BPLC lens can be switched from positive to negative, the negative lens-like phase profile can be neutralised by the conventional glass lens to get an infinity focal length and the positive lens-like phase profile can be enhanced by the conventional glass lens to get a shorter focal length. The minimum focal length can be decreased to almost half of that after the proposed method is adopted in our simulation. Moreover, the proposed BPLC lens exhibits a good polarisation-free feature and the optical effect is relatively good.     

One-dimensional model for simulating blue-phase liquid crystal display

We proposed a one-dimensional model for simulating some performances of blue-phase liquid crystal (BPLC) and polymer-stabilised blue-phase liquid crystal (PSBPLCD). The one-dimensional model treats liquid crystal arrangement of BPLC as cholesteric liquid crystal with high and uniform tilt angle to simulate the Bragg reflection of BPLC. The simulated results agree quite well with the experimental results. The elastic and dynamical equations are formed to calculate the effective elastic parameters and the response times of PSBPLCD. The effective elastic parameter is a constant for low electric field and decreases with the increasing of electric field. The varied effective elastic parameter means the varied restoring force of liquid crystal under the electric field. The dynamical equations are proposed to calculate response times, and the response mechanism of BPLCD is discussed by researching the difference between the decay times from equation and experiment. The sub-millisecond response time results from the weak anchoring of polymer network or the increasing of rotational viscosity of PSBPLC with high-concentration monomer, and the reason of 10 µs response time is the strong anchoring and small amount of chiral dopant and monomer.     

Blue-phase liquid crystal display with insulating protrusion

In order to lower the saturation voltage and enhance the transmittance of in-plane switching blue-phase liquid crystal display (IPS-BPLCD), IPS-BPLCD with insulating protrusion is proposed. The single-protrusion (only set on the top of pixel electrode) and double-protrusion (set on the top of pixel and common electrodes) structures are investigated in this work. The potential distribution changes when the protrusion is used. There is a thicker transverse electric field in BPLC range, because the stronger electric field at the edges of the electrodes is decentralised into BPLC range. As a result, the saturation voltage is reduced from 36.3 V to 28.9 V when the double-protrusion structure is used, and transmittance is increased by ~20%. The contrast ratio is larger than 1000:1 in 60° viewing cone using a half-wave biaxial film. Both single-protrusion and double-protrusion structures have the uniform gamma curves at large oblique viewing angles. Moreover, the off-axis image distortion index is 0.1590 at 60º polar angle when zigzag electrodes are used.     

A hysteresis-free polymer-stabilised blue-phase liquid crystal

We report a polymer-stabilised blue-phase liquid crystal (BPLC) in an in-plane-switching (IPS) cell with negligible hysteresis and good stability. Long ultraviolet (UV) wavelength and top-side (no IPS electrode) exposure create uniform polymer network, which in turn helps to suppress hysteresis. The effect of photoinitiator is also investigated. Although a BPLC precursor without photoinitiator requires a higher UV dosage to stabilise the polymer network, it is favourable for keeping high resistivity and reducing image sticking.     

A multifunctional blue phase liquid crystal lens based on multi-electrode structure

A blue phase liquid crystal (BPLC) lens with multifunction using multi-electrode structure and a dielectric layer with high dielectric constant is proposed. The refractive index of the BPLC can be changed flexibly in different regions. Some functional or technical requirements such as switch between positive and negative lenses can be achieved. The lens reveals a good parabolic refractive index distribution and focus adjustment capacity simultaneously. The applied voltage on the electrodes is regular and computable. To decrease the applied voltage of the proposed lens with a large diameter, a drive-type adopted Fresnel lens is introduced.     

Switchable polarisation-independent blue phase liquid crystal Fresnel lens based on phase-separated composite films

A simple method for fabricating a polarisation independent blue-phase liquid crystal Fresnel lens (BPLCFL) is demonstrated by utilising the photo-polymerisation-induced phase separation. The BPLC/polymer binary Fresnel zones is obtained well by periodic UV illumination with phase separation of the BPLC molecules and UV-curable pre-polymer mixture. The diffraction efficiency can be controlled when applying a uniform electric field which modulates the phase difference between even and odd Fresnel zones. Experimental results show that the maximum diffraction efficiency reaches 24.3%, which is close to the measured diffraction efficiency of the used Fresnel zone-plate mask of 25%. We also characterise the tunable lens performance at different applied voltages.     

PbS nanoparticles stabilised blue phase liquid crystals

A kind of blue phase liquid crystal (BPLC), consisting of nematic liquid crystal, E7, and chiral dopants, CB15 and R1011, was investigated by doping PbS nanoparticles. The blue phase temperature range was extended from 3^oC to 4.6°C by doping PbS nanoparticles with diameters around 9.6 nm. A kind of porous texture was observed both in the forming process of PbS nanoparticles doped BPLCs as well as in the BPLCs (with/without PbS nanoparticles) under assisting electric field. The porous texture may indicate that the liquid crystals molecule should be reoriented during the formation process of PbS nanoparticles doped BPLCs.     

Inducing monodomain blue phase liquid crystals by long-lasting voltage application during temperature variation

We demonstrate a new successful technique for inducing a monodomain in blue phase (BP) liquid crystals (BPLCs). By application of an AC voltage during the cooling or heating of the material into the BP temperature range, a fairly homogeneous BP area was obtained, compared to the case without voltage. We determined that applying a voltage of 3.3 V/µm was very effective in terms of obtaining a monodomain: for four of the seven different applied cooling/heating rates an area ratio of more than 99% was obtained for one particular BP orientation. This study describes a successful and replicable technique to make a BPLC monodomain, which is important for the development of BPLCs and other applications.     

Low-voltage blue-phase liquid crystal display with diamond-shape electrodes

We propose a new electrode configuration, called diamond-shape in-plane switching, to lower the operation voltage of polymer-stabilised blue-phase liquid crystal (BPLC) displays (BPLCDs). The electrode structure is modified from conventional protruded IPS, where the strip protrusion is changed to diamond shape. By optimising the electrode gap and diamond length, we are able to obtain peak transmittance over 75% at 15 V. It enables single thin-film transistor (TFT) driving, and more importantly, this is based on an industrially proven BPLC material. That means good long-term stability, adequate TFT charging time for high-resolution displays and sub-millisecond response time and acceptable voltage-holding ratio for field sequential displays can be achieved simultaneously. Our device design helps accelerate the emergence of the long-awaited BPLCDs.     

Analysis of focal length of blue-phase liquid crystal (BPLC) cylindrical lens for the light of the various incident angles and polarisations

Horizontally non-uniform electric field along the vertical direction inside blue-phase liquid crystal (BPLC) layer induces the Gradient index (GRIN) lens effect. Dependence of lens performance on the incident angle and polarisation is investigated by calculating the spatial phase distribution and the direction of wave front for lights passing through the BPLC layer. The calculated trajectories of light rays show that the focal distance for e-wave is less affected by the incidence angle than the focal distance of the o-wave. This can be attributed to the fact that steepness of spatial distribution of the effective refractive index for e-wave decreases for the larger incident angles.     

Cobalt π-cations in carbocyclic ring constructions

In a combination of cobalt-mediated cationic and free radical chemistry, treatment of the allyl silane substituted β-hydroxycobaloxime 13 with pTSA led predominantly to the trans-disubstituted cyclopentane 14, which on irradiation with TEMPO produced 15. In a similar manner, the cobaloxime 18 was cyclised to 19 in the presence of pTSA which, on irradiation with a sunlamp then underwent radical mediated cyclisation to the substituted indane 20.     

Über Reaktionen mit Betain, 13. Mitt.: Darstellung von trihalogenacetyl-methyliden und ihrer Salze aus Betainen

Reaction of the betaine1 and pyridinebetaine8 with trifluoroacetic anhydride yields the salts4a or9a and the yellow ylide5, respectively. In an analogous manner8 reacts with trichloroacetic anhydride to give11a. In a competitive reaction the trifluoroacetates6 and10 are also formed. Pyridinebetaine hydrochloride reacts similarily with trichloroacetic anhydride.

12. Mitt.:Wittmann H., Sobhi D., Petio F. A., Z. Naturf.31 b, 850 (1976).     

Two Efficient Syntheses of Protected 4‐Deoxy‐D‐lyxo‐hexose (4‐Desoxy‐D‐mannose)

The formation of four differently protected 4‐deoxy‐D‐lyxo‐hexose derivatives 7, 8, 12, and 14 is described. In the first procedure, a nucleophilic displacement of the allylic mesylate 4 by hydride was combined with a highly stereoselective osmylation of olefin 6 to afford diol 7. In the second radical procedure, tributyl tin hydride was substituted by the cheap and environmentally friendly hypophosphorous acid as a hydrogen donor in the reduction of xanthate 13 to 4‐deoxy lyxo‐hexose 14.     

Synthesis of new boswellic acid derivatives as potential antiproliferative agents

Abstract

In the current investigation, a series of heterocyclic derivatives of boswellic acids were prepared along with new monomers of 3-O-acetyl-11-keto-β-boswellic acid (AKBA, 1) 11-keto-β-boswellic acid (KBA, 2) and several new bis-AKBA and KBA homodimers and AKBA-KBA heterodimers. The effects of these compounds on the proliferation of different human cancer cell lines, viz., FaDu (pharynx carcinoma), A2780 (ovarian carcinoma), HT29 (colon adenocarcinoma), and A375 (malignant melanoma), have been evaluated. Thus, KBA homodimer 21 effectively inhibited the growth of FaDu, A2780, HT29, and A375 cells with EC₅₀ values below 9?μM. In addition, compounds 7, 8, 11, 12, 15, 16, and 17 also exhibited cytotoxic effects for A2780, HT29, and A375 cancer cells. In particular, the pyrazine analog 8 was highly cytotoxic for A375 cancer cells with an EC₅₀ value of 2.1?μM.     

Protein tyrosine phosphatase 1B inhibitors from a marine-derived fungal strain aspergillus sp. SF-5929

Abstract

In the course of our continuing investigation of bioactive secondary metabolites from marine-derived fungal strains, a racemate of a novel diphenolic derivative named (±)-tylopilusin D (1) along with ten previously known secondary metabolites (2–11) were isolated from a marine-derived fungal strain Aspergillus sp. SF-5929. Their structures were elucidated mainly by analysis of NMR and MS data. In addition, the inhibitory effects of the isolated compounds against protein tyrosine phosphatase 1B (PTP1B) activity were evaluated, and compounds 1, 2, and 5–7 inhibited PTP1B activity with IC₅₀ values ranging from 3.3 to 8.1?µM. Kinetics studies suggested that compounds 1, 2, and 5 had noncompetitive inhibitory effects against PTP1B.