НИЗКОЧАСТОТНЫЕ КОЛЕ БАНИЯ ПРЯМОУГОЛЬНЫХ ПЛАСТИНОК ADP

- — . , - NH₄H₂PO₄,- ADP. ; - .     

Calculation of the dispersion of the third-order optical nonlinearity in C60 films

Using wave functions determined from ground-state local-density calculations, we have calculated the wave-dispersed free response of the optical nonlinear polarizability ⁽³⁾(–3;,,), for the C₆₀ molecule and ⁽³⁾(–3;,,) i.e. Third-Harmonic Generation (THG) for films using a sum-over-states approach. The influence of screening was determined by applying an external static electric field in separate selfconsistent calculations to evaluate induced dipole moments which was used to determine the static linear and nonlinear polarizabilities. The polarizabilities calculated in the static limit were used to determine an effective screening parameter which was, in turn, used together with an RPA approach to calculate screened wave-dispersed, third-order nonlinear optical properties such as ⁽³⁾(–3;,,) and ⁽³⁾(–3;,,). Comparing evaluated polarizabilities with experimental values we found that the non-resonant free polarizability compares well in absolute magnitude with experimental results. Inclusion of screening results in a polarizability about two orders of magnitude below the experimental values.Paper presented at the 129th WE-Heraeus-Seminar on Surface Studies by Nonlinear Laser Spectroscopies, Kassel, Germany, May 30 to June 1, 1994     

Stability and fragmentation processes of highly charged sodium clusters

Highly charged sodium clusters produced in collisions between neutral clusters and multiply charged ions are formed within a large range of temperatures and fissilities, and identified by means of a high-resolution reflectron-type time-of-flight mass spectrometer ( m/m 14000). The limit of stability of these charged clusters is experimentally investigated, and the time-of-flight spectra are compared with theoretical spectra based on Monte-Carlo simulations. The results indicate that the maximum fissility (X) of stable clusters is approaching the Rayleigh limit (X = 1) for larger clusters sizes. It is mainly limited by the initial neutral cluster temperature ( T 100 K) and the energy transfer in the ionizing collision. In addition, the comparison between the measured and simulated spectra suggests for high cluster charges a multi-fragmentation process, in which most of charge is emitted, creating low charged residual cluster ions.     

Study of (Al2O3)n(Ox) clusters with n = 16 and x = 0, 1, 2 from first principles calculations

The ionic and electronic structure of (Al₂O₃)_n(O_x) clusters with n 16 and x = 0, 1, 2 is studied by means of first principles density functional calculations, norm-conserving pseudopotentials and a numerical atomic basis set. The equilibrium geometries have been determined by total energy minimization, starting with several initial geometries for each cluster size. The trends obtained for the atomic arrangements (structural isomers, coordination numbers, disordered versus ordered structures, etc.) and the electronic properties (binding energies, Homo-Lumo gap and dipole moments) are discussed. For most of the oxidized clusters studied here we find that the Homo-Lumo gap and the magnitude of dipole moment of isomeric species can vary drastically.     

Photoemission spectra of deuterated silicon clusters: experiment and theory

We compare experimentally measured and ab initio computed photoelectron spectra of negatively charged deuterated silicon clusters ( , 4m10, 0n2) produced in a plasma environment. Based on this comparison, we discuss the kinetics and thermodynamics of the cluster formation and the effect of deuterium on the geometrical and electronic structure of the clusters.     

The quantum theory of multipole radiation in a dielectric

The potentials of an electromagnetic field of multipoles in a dielectric, which is realized by a dielectric sphere having a perfectly conducting surface, are derived. The diagonal values of the energy for thez component of the angular momentum and the square of the angular momentum of the field are determined and also the ratio between thez component of the angular momentum and the energy and the ratio between the square of the angular momentum and the square of the energy. It is shown that the total angular momentum can be divided in the usual way into orbital and spin parts but that these parts cannot be interpreted as the orbital and spin angular momentum because their eigenvalues cannot be the eigenvalues of any operator of infinitesimal rotation. In the commutation rules of a multipole field the vector character of the field is to a certain extent suppressed and the spin of the photon in a state with a certain value of the energy, parityz component of the angular momentum and the square of the angular momentum is not defined.

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In conclusion the author thanks Dr. . Muziká for directing the work, F. Samek for valuable remarks and discussion and J. Kvasnica for help in preparing the paper for publication and for adding a number of remarks.     

A contribution to the theory of the triple crystal diffractometer

The first part of the paper gives a general equation for triple-crystal arrangement with perfect crystals on the assumption that the third crystal is rotated. It is shown that in the case of perfect crystals the shape of the reflection curve is practically independent of the vertical divergence. The case of mosaic crystals is also solved and the possibility of rotation by other than the third crystal is considered. A method is proposed for investigating the imperfection of a crystal which is different from methods used up to now. The paper is supplemented by some experimental results.

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The optical constants of single crystals of hexagonal selenium

The optical constants of single crystals of hexagonal selenium in the region of the intrinsic absorption edge in polarized light were investigated. The absorption edge for light polarized normal to the optical axis of the crystal is displaced towards longer wavelengths. The absorption maximum of hexagonal selenium for a wavelength of 0·6 is interpreted as the maximum corresponding to interaction between neighbouring chains and in connection with this the position of the absorption edge of different modifications of selenium is discussed.

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In conclusion the author wishes to thank Dr. E. Klier and R. Kuel for valuable discussions and advice. He thanks laboratory assistants J. Ontl and O. Kundrátová for help in the work.     

Струи паров материал ов электродов нри кратковременном электрическом разря де с Большой силой тока

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The vapour jets of electrode material of a short-time high-intensity electric discharge

The velocity of vapours from electrodes and the values of the electric gradient of the channel were measured. An explanation is given of the dependence of the discharge rate of the vapours on the electrode material and the thermal origin of the jets is confirmed. The validity of the results is shown for the case of a different experimental arrangement, or the formation of other types of discharges on electrodes.

     

Nonlinear resonances and phase transitions of two-ion Coulomb clusters in a Paul trap: Calculations without laser cooling

The mechanism responsible for transitions of laser-cooled trapped ions from an ordered crystal state to an irregular cloud state has been discussed controversially. A numeric and analytic study of the relative motion of two trapped ions without laser cooling is performed and compared with the results of previous simulations involving the laser. It turns out that the system without laser, in spite of its simplicity, already exhibits a non-monotonic dependence of crystal stability on trap parameters, which is linked to the presence of low-order nonlinear resonances.     

Новый тип рентгеновс кого спектрографа

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МОДЕЛИРОВАНИЕ ЭЛЕКТ РОННО-ОПТИЧЕСКИХ СИС ТЕМ С ОСЕВОЙ СИММЕТРИЕЙ П РИ ПОМОЩИ СЕТИ СОПРОТИВЛЕНИЙ

The paper explains the theory of modelling electrostatic fields by a resistance network. The conditions, which the resistance network must satisfy, are derived and the question of modelling electrodes of different shapes is solved. The finished network and the results obtained on it when modelling a jet for a linear h-f accelerator of electrons are described. Particular attention is paid to the influence of a space charge, the modelling of which is an advantage of this method.

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Приготовление оченъ чистого железа и опре деление его чистоты по некото рым физическим свойс твам

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The use of the repulsive potential in the quantum theory of solids

A new method is proposed for calculating the energy in certain special points of the Brillouin zone. The wave functions of valence and conduction electrons are given in the form of the linear combination of plane waves and the orthogonality condition of these functions to the wave functions of lower states is replaced by the repulsive potential. The practical application of this very simple method is illustrated on the energy spectrum of silicon in the centre of the Brillouin zone. It is proved that the results are comparable with some other methods, e. g. the orthogonalized plane-wave method.

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The basic thesis of this paper, together with concrete calculation of the energy spectrum of diamond, was delivered at the Czechoslovak-Polish conference in Sopoty in November 1956.

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In conclusion the autor would like to thank K. Trnková for carrying out the numerical calculations.     

The critical point indices of ferroelectric and ferromagnetic phase transitions

Magnetic transitions are described by the critical indices0,1/3,4/3 while some ferroelectric transitions appear to give0,R~1/2,1. It is pointed out that these two sets of values for the critical indices are allowed by the scaling laws and stability conditions near the phase transitions.The authors thank Prof. R. S. Krishnan for his encouragement and Mr. B. Viswanathan for some discussions. The financial assistance from DAE and CSIR is also acknowledged.     

The distribution of neutron density in the vicinity of a partly inserted black rod in two-group approximation

The neutron density in the vicinity of a black cylindrical rod partly inserted in a bare reactor is calculated and illustrated by a numerical example. The starting point is a two-group diffusion theory approximation. While the dependence of the effect of the rod on the insertion depth can be calculated simply by means of perturbation theory, the question of the neutron density estimate in the vicinity of the rod is considerably more difficult and in some considerations the estimate of the neutron density caused by the presence of the rod is indispensable. The method makes it possible to determine the reactivity value of the rod in dependence on the insertion depth and especially the neutron density deformation in the vicinity of the rod.

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In conclusion the author thanks J. Svato for help in carrying out the numerical calculations.     

On the photo-electroluminescence of ZnS-Cu

The influence of weak ultra-violet irradiation on the brightness waves of electroluminescence is investigated for two types of ZnS-Cuphosphors. The observed effects (increase in brightness in the primary peak and its phase shift, the disappearance of the secondary peak) are explained on the basis of present-day conceptions on electroluminescence.

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ZnS-Cu

ZnS-Cu. ( , ) .

     

Atomic versus ionized states in many-particle systems and the spectra of reduced density matrices: A model study

We study the spectrum of appropriate reduced density matrices for a model consisting of one quantum particle (electron) in a classical fluid (of protons) at thermal equilibrium. The quantum and classical particles interact by a shortrange, attractive potential such that the quantum particle can form atomic bound states with a single classical particle. We consider two models for the classical component: an ideal gas and the cell model of a fluid. We find that when the system is at low density the spectrum of the electron-proton pair density matrix has, in addition to a continuous part, a discrete part that is associated with atomic bound states. In the high-density limit the discrete eigenvalues disappear in the case of the cell model, indicating the existence of pressure ionization or a Mott effect according to a general criterion for characterizing bound and ionized electron-proton pairs in a plasma proposed recently by M. Girardeau. For the ideal gas model, on the other hand, eigenvalues remain even at high density.     

A contribution to direct processes in the Co59(p,n) reaction forE p ∼ 6·5 MeV

Nuclear emulsions were used to study the energy spectrum and forward-backward asymmetry of neutrons from the Co⁵⁹(p,n) reaction forE _p 6·5 MeV. It was found that the decay of the compound nucleus makes a maximum contribution of 50% to the reaction yield. Energies of some excited states of the Ni⁵⁹ nucleus were also determined.

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Co⁵⁹(p,n) E _p 6,5 MeV

- Co⁵⁹(p,n) E _p 6,5 MeV. , 50%. , Ni⁵⁹.

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The authors would like to thank all those who helped in this work, particularly all members of the cyclotron group of the Nuclear Research Institute of the Czechoslovak Academy of Sciences, who so willingly helped with the irradiation, and H. Koutová from the Faculty of Technical and Nuclear Physics, who carefully measured the emulsions. Our thanks are also due to R. Krejová from the Faculty of Technical and Nuclear Physics for developing the emulsions and J. Kopecký from the Nuclear Research Institute for providing the cobalt target.     

Automatic measurement of the complex permittivity at millimeter wavelengths

A measuring system including an oversized cavity resonator operating in the TE₀₁ mode for the determination of the complex permittivity - j of low-loss liquids at frequencies of about 36 GHz is described. While is obtained by wavelength measurements in the filled and the empty resonator, is determined from the variation of the Q factor of the filled resonator with the length of the dielectric sample. The Q factors of values of about 2·10⁴ to 10⁵ can be measured automatically by means of a desk calculator which controls the frequency and collects the digitized values of the detector output voltage. By means of the calculator, the Q factors of the resonator are determined by fitting analytical (Lorentzian) resonance curves to the measurement data. and the Q factor for zero sample length are calculated according to Göttmann's methods.