Raman scattering from the molecular charge transfer crystal anthracene-PMDA

The Raman spectrum of the mixed stack charge transfer (CT) crystal anthracene-PMDA, has been measured in the wavelength region near the lowest CT transition at 5458 Å. Six low frequency modes are observed below 140 cm^?1, the mode at 130 cm^?1 showing strong resonance enhancement. These modes are assigned as librational motion of the anthracene and PMDA molecules by rigid body analysis of X-ray structural data.     

Forbidden band width and effective charge in crystal lattice of ZnS

The optical and thermal widths of the forbidden band are determined by the absorption spectrum and temperature dependence of the conductivity respectively. The difference between them is determined also by the spectral sensitivity of different phosphors to optical stimulation. The effective charge of an ion in ZnS is determined in several ways by using the value of this difference, the refractive index, dielectric constant and frequencies in the Raman spectrum and the spectrum of infra-red absorption of ZnS. It was found to be equal to approximately half of the electron charge.     

Collective excitations in exciton crystal

Crystal phase of indirect excitons formed by spatially separated electrons and holes in coupled quantum wells is analyzed. The collective mode spectrum of the exciton crystal at zero and nonzero agnetic fields is found. The spectrum consists of two optical and two acoustical modes (transverse and longitudinal in each case). We also study changes of the dipole crystal collective excitations at the transition exciton crystal-electron-hole plasma.     

Observation of a donor exciton band in silicon

Far-infrared transmission measurements on P-doped Si at donor concentrations below the metal-insulator transition show absorption bands from donor pairs. We identify the lowest energy band as charge transfer excitations from a donor to its neigbhor, forming excitons (D⁺D^-) in the Mott-Hubbard gap. The results suggest that charge transfer states in complexes dominate the low-energy optical excitations as the insulator approaches the Mott density.     

Anomalous polaron phenomena in the inward region of the exciton band

If the excitons have an intermediate radius and interact strongly with lattice deformations, the band being wide enough, then the exciton dispersion branch has a break in the central region of the band. The break is caused by the anomalous multiphonon scattering of excitons related to their trapping to local states.     

Vibronic Frenkel exciton in a soft-mode crystal

The pair electron-hole Jahn-Teller effect, which is realized on degenerate states of a vibronic Frenkel exciton (VFE) in soft-mode crystals, is considered. It is shown that the vibronic effect in a VFE can be significantly enhanced in crystals having soft lattice modes. The occurrence of strong local order-disorder fluctuations in this situation is predicted. The manifestations of VFEs localized at impurities in soft matrices (Cr³⁺ in SrTiO₃, Fe⁵⁺ in KTaO₃, and Mn⁵⁺ in TbVO₄ and TbPO₄) are considered. The possibility of fluctuation effects related to VFEs in nominally pure soft-mode crystals (SrTiO₃ and BaTiO₃) is discussed.     

Triplet exciton energy and the magnitude of the charge-transfer interaction inside dimers in the Alkali-TCNQ salts

The optical absorption spectra of several crystalline anion radiacal salts have been analyzed recently within the frame of the model Hamiltonian of electrons and intramolecular excitons and vibrations in the limit of strong interaction of the excitonic and vibrational motions with the unpaired electrons. In the present work the magnitude of the intermolecular charge transfer interaction inside dimers in the Alkali TCNQ salts is deduced from the knowledge of the experimental triplet exciton energy and the constants characterizing the electronic, excitonic and vibrational properties of TCNQ molecules. Perturbation calculation is used to derive a formula for the triplet exciton energy.     

Competition between charge-transfer exciton dissociation and direct photocarrier generation in molecular donor-acceptor compounds

The interfacial charge-separation and photovoltaic characteristics of a molecular donor-acceptor charge-transfer compound were examined. Measurements of laser beam-induced currents on the single crystals allowed selective detection of hole and electron photocurrents through the metal-semiconductor interfaces. This method also reveals the exceptionally long diffusion length of 20 μm in the crystal. The transition from charge-transfer exciton dissociation to direct photocarrier generation is discussed on the basis of the photon-energy-dependent diffusion length and photon-to-current conversion spectrum.     

Phase transition and triplet exciton mobility in anthracene—tetracyanobenzene charge-transfer single crystals

Triplet-Excitons in a mixed 1 : 1 anthracene—tetracyanobenzene single crystal are established by ESR-spectrocopy. These excitons (lifetime 0.5 msec) are characterized by a hopping frequency of v = 1.3 × 10⁶ K at 300K. The temperature dependence of the ESR line shape indicates a phase transition of the crystal at T_t = 205K. Above and below the phase transition the exciton mobility is nearly temperature independent.     

Electromagnetically induced exciton mobility in a photonic band gap

It is suggested that an exciton in the engineered vacuum of a photonic-band-gap-quantum-well heterostructure exhibits electromagnetically induced anomalous quantum dynamics. The exciton is dressed by coherent emission and reabsorption of virtual photons near the photonic band edge and captured in momentum space, lowering its energy by 1-10 meV and lowering its effective mass by 4-5 orders of magnitude. The photonic band gap simultaneously enables strong coupling to confined optical modes and long exciton lifetime.     

NiO: correlated band structure of a charge-transfer insulator

The band structure of the prototypical charge-transfer insulator NiO is computed by using a combination of an ab initio band structure method and the dynamical mean-field theory with a quantum Monte-Carlo impurity solver. Employing a Hamiltonian which includes both Ni d and O p orbitals we find excellent agreement with the energy bands determined from angle-resolved photoemission spectroscopy. This brings an important progress in a long-standing problem of solid-state theory. Most notably we obtain the low-energy Zhang-Rice bands with strongly k-dependent orbital character discussed previously in the context of low-energy model theories.     

Experimental validation of band gaps and localization in a one-dimensional diatomic phononic crystal

The propagation of compressional ultrasonic pulses through a finite one-dimensional chain of various unit cells is investigated experimentally. The chain, initially compressed by an axially applied constant force, is excited by a periodic force, which acts in line with axis of bead chain. The experimental measurements giving the eigenfrequencies of the specimen are based on a Fourier analysis of the transmitted acoustic pulse. The results are compared with the numerical calculations and it is shown that the two approaches are well correlated. A phononic band structure is observed and under certain conditions, depending on the parity of the number and on the masses of the beads in the chain, it is shown that localized modes propagating in the forbidden band are exhibited. Much attention is devoted to the existence of these localized modes according to the mass ratio between two adjacent beads constituting the unit cell.     

Experimental energy band dispersions for a TiN(100) crystal

The energy band dispersions of TiN along the Γ-X symmetry line have been determined using a TiN(100) crystal and the angle-resolved photoemission technique combined with tunable synchrotron radiation. Using the direct transition model with a free-electron like final state, the dispersions are mapped out by varying the photon energy. The results are compared to an APW energy band calculation.     

Magnetooptical absorption of a molecular crystal in the exciton frequency range

Nonlinear absorption of a molecular crystal in an external magnetic field is considered. The exciton absorption shape functions under polarized laser radiation and a weak magnetic field, as well as the mechanisms responsible for the formation of a hysteresis loop in the dependence of the output light intensity on the applied magnetic field, were studied for the particular case of benzene. It was established that, for the magnetooptical response of the molecular crystal under study, the formation of bistable loops is inverse in character, which makes it possible to monitor and control the behavior of bistable elements in optical logics systems with an external magnetic field at a fixed illumination frequency.     

The vibrational exciton spectrum of p-nitrotoluene crystal film

The exciton absorption spectrum of p-nitrotoluene crystal film has been investigated by polarized IR radiation at low temperature. The Raman scattering in the crystalline and the solution state has been studied as an aid in the interpretation of the crystal spectrum. The observed exciton splittings are small and could be measured with certainty for only a few vibrations. The interpretation of the low temperature spectrum conforms to the crystal structure determined at room temperature by Barve and Pant.     

Experimental determination of the band structure of photonic crystals of colloidal silica spheres

A photonic band structure of colloidal crystals of silica spheres is analytically determined by a band model with three fitting parameters: the sphere size, the effective refractive index, and the band-gap. Optical properties of the crystals annealed at various temperatures were characterized by a procedure similar to X-ray diffraction technique, and the width of photonic band-gap measured from the transmission spectra experimentally servers as an additional check on the validation of the model. The photonic band structures defined by the band-gap, the refractive index, and the Brillouin zone are obviously superior to the use of the Bragg's expression involving simple zone folding.     

Valence band parameters and free exciton reduced mass of zinc telluride derived from free exciton magnetoreflectance

Reflectance spectra were measured on ZnTe in magnetic fields up to 18 T for B ? [100] and B ? [110]. The experiments yield renormalized valence band parameters $\text{γ}{}^1{}_2\text{= 0.83 ± 0.08}$ and $\text{γ}{}^1{}_3\text{= 1.30 ± 0.12}$, corresponding to bare parameters γ₂ = 0.95 ± 0.09 and γ₃ = 1.48 ± 0.14. From the free exciton Rydberg energy $\text{R}{}^1{}_0\text{= 12.8}\text{meV}$ we derive a reduced exciton polaron mass m₀ 0.080 ± 0.005 and a bare reduced mass m₀ 0.074 ± 0.005, corresponding to $\text{γ}{}^1{}_1\text{= 3.9 ± 0.7}$ and γ₁ = 4.4 ± 0.7 for an electron effective polaron mass $\text{m}{}^1{}_{\mathrm{e}}\text{= 0.116 m}{}_0$. We further calculate the exciton diamagnetic shift rate according to existing low-field theories modified by a variational calculation taking into account polaron effects and valid up to γ ? 1. The difference between experiment and theory is 10% and the agreement is considered satisfactory.     

Experimental determination of the constants of absolute volume deformation potentials at band edges in semiconductors

A method is proposed for determining the constants of absolute volume deformation potentials at edges of the conduction and valence bands in semiconductors. This method is based on (i) the volume-concentration effect, (ii) the concept that the energy of deep-lying strongly localized impurity centers does not depend on the hydrostatic pressure, and (iii) the use of experimental data on the electrical resistivity and Hall coefficient. For Ge, GaAs, InAs, and InSb semiconductors, the constants of absolute volume deformation potentials at edges of the conduction and valence bands are determined from our results and data available in the literature.