Transient-mode excitation, terahertz generation and wavelength shifting in a photonic band gap

Dynamic responses of photonic crystal microcavities in nonlinear media are analyzed via both a finite-difference code and coupled-mode theory in the time domain. Optical frequency generation in both second- and third-order nonlinear materials is demonstrated based on the transient evolution of cavity modes. Terahertz waves can be generated in quadratically nonlinear crystals by optical rectification, whereas state generation inside the band gap can be linked to a Rabi-like splitting in cubic media. An all-optical ultra-fast wavelength shifter is proposed.     

Raman spectroscopic and structural studies of heat-treated graphites for lithium-ion batteries

Standard graphite TIMREX® SLX 50 was oxidised at 500–800 °C under air atmosphere in a muffle and a rotary furnace. Scanning Electron Microscopy (SEM), Raman spectroscopy, and X-Ray Powder Diffraction (XRD) were used to study the changes in surface morphology and crystallinity. The results show a slight increase of the L_a value and a decrease of the rhombohedral fraction with increased heat-treatment temperature (HTT). XRD measurements show no significant change in L_a values within the bulk of graphite samples. Above 700 °C SEM images of graphite reveals holes and cavities, whereas heat-treatment temperatures below 700 °C do not significantly affect graphite materials parameters.     

不同激发波长下单壁碳纳米管与多壁碳纳米管的拉曼光谱比较

对不同激发波长下单壁和多壁碳纳米管的激光拉曼光谱进行了比较。发现单壁碳纳米管D峰强度和G峰强度的比值(ID/IG)几乎不随激发光子能量的改变而变化,多壁碳纳米管ID/IG值随着激发光子能量的增加以斜率0 3/eV减小。并对此现象进行了初步的分析。此外,还发现在1064nm激发波长下,单壁和多壁碳纳米管2500-3500cm-1之间拉曼峰的相对强度随着入射激光功率的增加而增加。     

Multi parameter optimization of Raman Fiber Amplifier using genetic algorithm for S band dense wavelength division multiplexed system

A simple genetic algorithm is implemented to perform multi parameter optimization of Raman Fiber Amplifier for 100 channel S band dense wavelength division multiplexed system at 25 GHz interval. A cost effective system using single Raman pump is investigated aiming at maximum average gain. The single counter propagating pump is optimized to frequency of 211.528 THz and 652.93 mW power level with optimum Raman fiber length of 44.064 Km. There is evidence to show that the optimum solution presents a small gain variation (less than 3 dB) over an effective bandwidth covering 197–199.475 THz. The optimized configuration enabled an adequate system performance in terms of acceptable Q-factor (19.52 dB) and BER (1.46 × 10⁻²¹).     

Raman spectroscopy with LED excitation source

We propose and experimentally demonstrate a novel instrument arrangement, which allows for the collection of Raman spectra with a broadband light source. This is achieved by spatially dispersing the optical spectrum in the focal plane and confocally reimaging the Raman signal, which originates from different locations, onto the entrance slit of an imaging spectrometer. Using this approach and broadband radiation derived from a commercially available LED, we acquired high signal‐to‐noise spectra with a spectral resolution limited by the spectral resolution of a spectrometer. Copyright © 2013 John Wiley & Sons, Ltd.     

Theory of the evolution of 2D band in the Raman spectra of monolayer and bilayer graphene with laser excitation energy

A double‐resonance process gives rise to the 2D band in the Raman spectra of monolayer and bilayer graphene. Based on the electronic and vibrational dispersion energies of graphene, the wavenumbers of the 2D band were calculated under different laser excitation energies (from 1.0 to 4.4 eV). Calculated results are in good agreement with experimental data and reproduce the experimental dispersion slope of the 2D band very well. The calculated wavenumbers of the 2D band do not show a linear dependence on the laser excitation energies. Moreover, it is explained that the lowest wavenumber peak of the 2D band of the bilayer graphene, which is composed of four components, has the largest slope with laser excitation energy. Copyright © 2009 John Wiley & Sons, Ltd.     

Coherent anti‐Stokes Raman scattering in Raman lasers and Raman wavelength converters

In this paper recent research progress on the use of Coherent Anti‐Stokes Raman Scattering (CARS) in Raman lasers and Raman wavelength converters is reviewed. The latest insights in the physical nature and behavior of CARS are addressed, and the recent performance breakthroughs in CARS‐based Raman wavelength conversion are discussed. Based on the new findings regarding the behavior of CARS, a physical explanation for apparent inconsistencies in various experimental observations of Raman wavelength conversion is provided. To conclude it is shown that these recent insights also pave the way to the development of a novel CARS‐based mechanism for reducing the heat dissipation in Raman lasers.     

Raman lasing and cascaded coherent anti-Stokes Raman scattering of a two-phonon Raman band

Raman lasing of a two-phonon Raman band in the anti-Stokes side is demonstrated. Two femtosecond light pulses with identical wavelengths are irradiated onto a SrTiO3 crystal in a cross-beam configuration. Under low excitation power, several wave-mixing signals with identical wavelengths are emitted. When the power exceeds a critical value, cascaded coherent anti-Stokes Raman scattering (CARS) signals are emitted, the frequency step of which is coincident with that of the strongest two-phonon Raman band of 2TO2.     

Effects of laser excitation wavelength and optical mode on Raman spectra of human fresh colon,pancreas, and prostate tissues

Early cancer detection is the central and most important factor for allowing successful treatment and resultant positive long‐term patient outcomes. Recently, optical techniques have been applied to this purpose, although each has inherent limitations. In particular, Raman spectroscopy applied in the pathological diagnosis of cancerous tissues has received increasing attention, with the merit of being highly sensitive to the biochemical alterations in tissue compositions and applicable in vivo. Nevertheless, its application has been impeded by the high background intensity, which masks the Raman signal of biological molecules. In this work, the influence of laser excitation wavelength (785 vs. 830 nm) and optical mode (single mode vs. multimode) on the background intensity of fresh human tissues was studied. Based on the results, laser with 830 nm excitation demonstrated better background reduction than that with 785 nm excitation for the same optical mode, but the Raman signal intensity was conversely reduced, and the signal‐to‐noise ratio (SNR) not improved. In contrast, by comparing single‐mode and multimode 785 nm excitations, it was shown that the single‐mode laser with its smaller beam waist and beam propagation factor had better background reduction ability and an improvement of the SNRs. It is speculated that this decrease in background intensity comes from the effect of the optical mode on the Mie scattering from the biological tissue. High‐quality spectra based on a careful selection of both laser excitation wavelength and optical mode will benefit Raman measurements in further research focusing on spectral interpretation and histopathological correlation ultimately aimed toward intraoperative applications. Copyright © 2014 John Wiley & Sons, Ltd.     

Extremely wide band Rayleigh resonant reflector with sharp angular spectra in near infrared wavelength band

In this paper, we propose an extremely broadband Rayleigh resonant reflector with sharp angular spectra operating in near infrared wavelength band, this device consisting of a single germanium resonant grating layer is designed and analyzed by using with the rigorous vector diffraction theory. At the Rayleigh angle, the first diffracted order can be appear from evanescent to a propagating one, thus, a very sharp angular spectrum characteristics can be presented in the device. Based on the guided mode resonant effect, high index material such as silicon and germanium can be designed as wide band reflector, beam splitter and polarizer in near infrared wavelength region. Through connecting Rayleigh phenomena and guided mode resonant effect, we can design a new kind of optical devices with versatile characteristics such as sharp angular spectra and extremely wide reflection band. In this paper, we present a Rayleigh resonant reflector with extremely high reflection (R > 99.5%) for TE polarization light over ∼600 nm wavelength range and sharp angular spectral distribution. In addition, it is shown from our calculations that the high-index nano-layer located adjacent to the substrate is seen to critically affect the resulting spectra of Rayleigh resonant reflector.     

Pulse surface wave generator of millimeter band wavelength

Theoretical and experimental studies of high-power, relativistic surface-wave microwave Cherenkov generators are briefly considered. Some simulation and experiment results included, the experimentation being made in mm-wave region.     

Calculation of resonance Raman excitation profiles

The present work describes a novel mathematical scheme for the evaluation of multi-dimensional time domain integrals that arise in the calculation of resonance Raman excitation profiles and the optical absorption spectra when the electronic transitions take place between displaced, distorted, and rotated harmonic potential energy surfaces. A recipe is provided for formulating the time domain integrals in terms of a tractable summation of products involving hermite polynomials. Expressions for the special cases (displaced and/or distorted oscillators) are written in terms of mathematical special functions which are computationally easier to deal with. Relations with the so-called transform theory are discussed. Resonance Raman excitation profiles and the optical absorption spectrum for a 7-mode system are calculated as an illustration of our expressions.     

Dye laser excitation of the fluorosulfate radical: Origin band excitation

Discrete visible fluorescence is observed from excitation of the fluorosulfate radical by means of a dye laser. The frequency of the dye laser is chosen to coincide with each of the two components of the origin band observed at 19 383 and 19 354 cm^?1. Ground-state fundamentals are assigned for the radical and evidence is provided to suggest that the ground state of the radical may not have C_3v symmetry.     

A Fourier transform Raman spectrometer with visible laser excitation

We present the development and performance of a Fourier transformation (FT)‐based Raman spectrometer working with visible laser (532 nm) excitation. It is generally thought that FT‐Raman spectrometers are not viable in the visible range where shot noise limits the detector performance and therein they are outperformed by grating based, dispersive ones. We show that contrary to this common belief, the recent advances of high‐performance interference filters makes the FT‐Raman design a valid alternative to dispersive Raman spectrometers for samples which do not luminesce. We critically compare the performance of our spectrometer to two dispersive ones: a home‐built single channel and a state‐of‐the‐art charge coupled device‐based instruments. We demonstrate a similar or even better sensitivity than the charge coupled device‐based dispersive spectrometer particularly when the laser power density is considered. The instrument possesses all the known advantages of the FT principle of spectral accuracy, high throughput, and economic design. We also discuss the general considerations, which helps the community reassess the utility of the different Raman spectrometer designs. Copyright © 2015 John Wiley & Sons, Ltd.     

Raman band intensities of tellurite glasses

Raman spectra of TeO2-based glasses doped with WO3, ZnO, GeO2, TiO2, MoO3, and Sb2O3 are measured. The intensity of bands in the Raman spectra of MoO3-TeO2 and MoO3-WO3-TeO2 glasses is shown to be 80-95 times higher than that for silica glass. It is shown that these glasses can be considered as one of the most promising materials for Raman fiber amplifiers.     

Integrated all-optical nonlinear device for re- configurable add/drop and wavelength shifting of WDM signals

A novel configuration is proposed for an all-optical device performing two key functionalities in a communication network based on wavelength-division-multiplexing (WDM): reconfigurable add/drop and wavelength shifting of single channels. The device is based on guided second-order nonlinear interactions, such as sum-frequency generation and difference-frequency generation, between the WDM channels and a suitable pump beam. A directional coupler and two parallel waveguides allow the spatial separation between the main WDM signal and the dropped or wavelength-shifted channel for a subsequent routing in the desired path. A first numerical simulation provided a cross-talk level in the dropped channel lower than -41 dB and a wavelength-shifting range of more than 40 nm. Received: 18 May 2001 / Published online: 30 October 2001     

Temperature and excitation wavelength dependencies of 3-pentanone absorption and fluorescence for PLIF applications

The temperature and excitation wavelength dependencies of 3-pentanone absorption and fluorescence were studied in support of planar laser-induced fluorescence (PLIF) imaging of temperature and mixture fraction in flows of practical interest. The temperature dependencies (300–875 K) of absorption and fluorescence were measured for gaseous 3-pentanoneat atmospheric pressure in a nitrogen bath gas using 248, 266, and 308 nm excitation. The results indicate that the fluorescence signal per unit mole fraction using 248 nm excitation is highly temperature-sensitive below 600 K, while the signal from 308 nm excitation is not temperature sensitive below 500 K. For quantitative measurements over a broad range of temperatures, one must choose excitation schemes carefully to balance the trade-off between measurement sensitivity and the amount of signal at the expected conditions. As an example of such a choice and to show the capabilities of ketone PLIF techniques, we include temperature and mixture fraction images of a 300–650 K heated air jet using near-simultaneous 308 and 266 nm excitation. Received: 29 May 2002 / Revised version: 5 November 2002 / Published online: 26 February 2003 RID="*" ID="*"Corresponding author. Fax: +1-650/723-1748, E-mail: jkoch@stanford.edu RID="**" ID="**"E-mail: hanson@me.stanford.edu     

Extremely large birefringence and shifting of zero dispersion wavelength of photonic crystal fibers

Three different types of photonic crystal fibers have been investigated which promise very large birefringence. The first type fiber is band gap guiding, the second index guiding, while the third type is index guiding with high refractive index circular and elliptical regions in the innermost ring. The birefringence, group velocity dispersion, modal effective index and mode field area of these fibers have been numerically estimated by employing finite difference time domain method. When elliptical regions are introduced in the first and second rings with the combination of small circular regions, each of these proposed fibers exhibits large birefringence with shifted zero dispersion point. Among these three different types of fibers, the band gap guiding photonic crystal fiber promises the largest birefringence (～5.45×10^?2) reported so far. The value of the birefringence and group velocity dispersion of these fibers can be controlled by controlling the hole pitch. Largest birefringence is achieved with a specific value of hole pitch.     

Multichannel Raman polarizer with suppressed relative intensity noise for wavelength division multiplexing transmission lines

We propose a method of suppressing the relative intensity noise caused by polarization-dependent gain that is inherent to Raman polarizers (RPs). This method involves bit-synchronously scrambling the state of polarization of a pulse (bit) before the pulse enters the RP. The proposed solution works for RPs operating in a depleted regime and is compatible with multichannel configurations.