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1.
Four new and five known norditerpenoid alkaloids were isolated from the processed tubers of Aconitum carmichaeli. The new alkaloids are 14-O-cinnamoylneoline (3), 14-O-anisoylneoline (4) 14-O-veratroylneoline (5), and lipo-14-O-anisoylbikhaconine (8). The known alkaloids are neoline (1), 14-O-acetylneoline (2), foresaconitine (6), crassicauline A (7), and lipohypaconitine (9). Alkaloids 2, 6, and 7 were isolated from this plant for the first time. The structures of the new alkaloids were established by spectroscopic and chemical methods. 相似文献
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3.
Five new C18-diterpenoid alkaloids, anthriscifolcines A (1), B (2), C (3), D (4), and E (5), together with a known C19-diterpenoid alkaloid delcorine (6), were isolated from the whole herb of Delphinium anthriscifolium var. savatieri. The structures of these new alkaloids were established on the basis of spectral data (1D- and 2D-NMR, HR-ESI-MS). 相似文献
4.
Two new alkaloids, sessilifolines A ( 1 ) and B ( 2a ), were isolated from the stems of Stemona sessilifolia, together with three known alkaloids, tuberstemonine ( 3 ), sessilifoliamide A ( 4 ), and stemoninoamide ( 5 ). Their structures were established by mass‐spectrometric and spectroscopic methods, especially 2D‐NMR techniques. 相似文献
5.
Four new alkaloids, didehydrotuberostemonine A ( 1 ), stemoninone ( 2 ), tuberostemospiroline ( 3 ), and tuberostemonine L ( 4 ), together with seven known alkaloids, were isolated from the roots of Stemona tuberosa. Their structures were elucidated on the basis of spectroscopic analysis. The known alkaloids were identified as 2‐oxostenine ( 5 ), tuberostemonine ( 6 ), sessilifoliamide H ( 7 ), tuberostemonone ( 8 ), didehydrotuberostemonine ( 9 ), bisdehydrostemoninine ( 10 ), and tuberostemoamide ( 11 ). 相似文献
6.
Feng‐Zheng Chen Qiao‐Hong Chen Xiao‐Yu Liu Feng‐Peng Wang 《Helvetica chimica acta》2011,94(5):853-858
Three new C20‐diterpenoid alkaloids, along with twenty‐two known alkaloids, were isolated from the whole herbs of Delphinium tatsienense. The new alkaloids include a vakognavine‐type C20‐diterpenoid alkaloid, designated as tatsienenseine A ( 1 ), and two hetisine‐type C20‐diterpenoid alkaloids, designated as tatsienenseines B ( 2 ) and C ( 3 ). Their structures were elucidated by IR, HR‐ESI‐MS, 1D‐ and 2D‐NMR analyses. 相似文献
7.
Yang Qing He Xiao Mei Wei Yi Li Han Li Ming Gao 《中国化学快报》2007,18(5):545-547
Chemical investigation on the ethanol extract from the whole plants of Delphinium chrysotrichum resulted in the isolation of two new diterpene alkaloids named delphatisine A (1) and delphatisine B (2), respectively. The structures of the new compounds were deduced on the basis of their spectral data (IR, HREIMS, EIMS, 1D, 2D-NMR). This is the first report on the isolation of diterpenoid alkaloids from the D. chrysotrichum. 相似文献
8.
Mukhtar MR Hadi AH Rondeau D Richomme P Litaudon M Mustafa MR Awang K 《Natural product research》2008,22(11):921-926
The phytochemical study of the bark of Malaysian Phoebe scortechinii (Lauraceae) has resulted in the isolation and identification of two new proaporphine alkaloids; (+)-scortechiniine A (1) and (+)-scortechiniine B (2) together with two known proaporphines; (-)-hexahydromecambrine A (3), (-)-norhexahydromecambrine A (4), and one aporphine; norboldine (5). Structural elucidations of these alkaloids were performed using spectroscopic methods especially 1D and 2D (1)H and (13)C NMR. 相似文献
9.
Two new isoquinoline alkaloids, 2,10-dimethoxy-3,11-dihydroxy-5,6-dihydroprotoberberine (1) and 1,9-dihydroxy-2,11 -dimethoxy-4,5-dihydro-7-oxoaporphine (2), together with thirteen known alkaloids, were isolated from the ethanolic extracts of the stem and leaves of Miliusa cuneata (Graib). Their structures were elucidated predominantly by spectral evidence. 相似文献
10.
Nafiah MA Mukhtar MR Omar H Ahmad K Morita H Litaudon M Awang K Hadi AH 《Molecules (Basel, Switzerland)》2011,16(4):3402-3409
A phytochemical study of the bark of Alseodaphne perakensis has yielded three aporphine alkaloids: the new compound N-cyanomethylnorboldine (1), and the two known alkaloids N-methyllaurotetanine (2) and norboldine (3). The isolation was achieved by chromatographic techniques and the structural elucidation was performed via spectral methods, notably 1D- and 2D-NMR, UV, IR, and HRFABMS. The vasorelaxation activity of compound 1 has been studied. 相似文献
11.
Muktar MR Osman N Awang K Hazni H Qureshi AK Hadi AH Zaima K Morita H Litaudon M 《Molecules (Basel, Switzerland)》2011,17(1):267-274
A new indole alkaloid; neonaucline (1), along with six known compounds-Cadamine (2), naucledine (3), harmane, benzamide, cinnamide and blumenol A-were isolated from the leaves of Ochreinauclea maingayii (Rubiaceae). In addition to that of compound 1, (13)C-NMR data of cadamine (2) and naucledine (3) were also reported. Structural elucidations of these alkaloids were performed using spectroscopic methods especially 1D- and 2D-NMR, IR, UV and LCMS-IT-TOF. The excellent vasorelaxant activity on isolated rat aorta was observed for the alkaloids 1-3 after injection of each sample at 1 × 10(-5) M. 相似文献
12.
Choudhary MI Ismail M Ali Z Shaari K Lajis NH Atta-ur-Rahman 《Natural product communications》2010,5(11):1747-1750
Phytochemical investigations of the stems of Tinospora crispa led to the isolation of one new aporphine alkaloid, N-formylasimilobine 2-O-beta-D-glucopyranoside (1), along with six known alkaloids, N-formylasimilobine 2-O-beta-D-glucopyranosyl-(1 --> 2)-beta-D-glucopyranoside (2) (tinoscorside A), N-formylanonaine (3), N-formyldehydroanonaine (4), N-formylnomuciferine (5), N-demethyl-N-formyldehydronornuciferine (6), magnoflorine (7), paprazine (8), N-trans-feruloyltyramine (9), and cytidine (10). The structure of new compound 1 was deduced on the basis of spectroscopic data. 相似文献
13.
直缘乌头中新的C19—二萜生物碱的结构研究 总被引:2,自引:0,他引:2
从直缘乌头(Aconitum transsectum Diels.)根中分离得到4个新的乌头碱型 C_(19)-二萜生物碱。由光谱法(IR, ~1H NMR, ~(13)C NMR, 2D-NMR, MS)确定其 结构为:8-O-乙基滇乌碱(8-O-ethylyunaconitine) (1)、去氮乙基查斯曼宁(N- deethyl chasmanine)(2)、直缘乌碱丁(transconitine D)(3)和直缘乌碱戊( transconitine E)(4)。 相似文献
14.
Two new bisbenzylisoquinoline alkaloids, alpha, alpha'-dioxo-7'-O-demethylstebisimine (1) and 7'-O-demethylstebisimine (2), along with 14 known alkaloids, were isolated from the roots of Cocculus laurifolius. These alkaloids were characterized mainly by spectroscopic methods. 相似文献
15.
A new C(19)-diterpenoid alkaloid, ouvrardiantine (1) and two new C(20)-diterpenoid alkaloids, ouvrardiandines A (2) and B (3) were isolated from the root of Aconitum ouvrardianum HAND.-MAZZ. The structure of the new alkaloids was established on the basis of spectral data (1D- and 2D-NMR, HR-MS). 相似文献
16.
Atta-Ur-Rahman Atia-Tul-Wahab Nawaz SA Choudhary IM 《Chemical & pharmaceutical bulletin》2004,52(7):802-806
Phytochemical investigation on Cocculus pendulus (J. R. & G. FORST.) resulted in the isolation of two new and three known bisbenzylisoquinoline alkaloids. The structures of the new alkaloids, kurramine-2'-beta-N-oxide (1) and kurramine-2'-alpha-N-oxide (2), were elucidated with the help of spectroscopic techniques. The cholinesterase inhibitory activities of these bisbenzylisoquinoline alkaloids are reported here for the first time. 相似文献
17.
Qiang Zhang Ying‐Tong Di Hai‐Yang Liu Ning‐Chuan Kong Suo Gao Chun‐Shun Li Yu Zhang Shun‐Lin Li Xiao‐Jiang Hao 《Helvetica chimica acta》2008,91(5):914-919
Two new yuzurine alkaloids, daphnoldines A ( 1 ) and B ( 2 ), possessing a rare four‐ring system, were isolated from the fruits of Daphniphyllum oldhami. Their structures were established on the basis of extensive spectroscopic analyses. Daphnoldine A ( 1 ) is the first example of Daphniphyllum alkaloids bearing a hydroxymethyl group at C(14). 相似文献
18.
Two C(18)-diterpenoid alkaloids, puberunine (1) and puberudine (2), together with four other new alkaloids, including the first examples having β-oriented substitution at C-3 and a rare chloro-substituent were isolated from Aconitum barbatum var. puberulum. Their structures were elucidated by spectroscopic methods. Puberunine and puberudine, which possess a unique rearranged E ring and an opened A ring, respectively, represent new subtypes of the C(18)-diterpenoid alkaloids. A plausible biosynthetic pathway of 1 and 2 was proposed. 相似文献
19.
Corinne Sguineau Pascal Richomme Jean Bruneton Jacques Pusset 《Helvetica chimica acta》1992,75(7):2283-2288
The leaves of a New Caledonian celastraceae, Pleurostylia opposita (WALL .) MERRILL -METCALF , have yielded three new spermidine alkaloids, 7-hydroxypleurostyline ( 1 ), 7-hydroxycelacinnine ( 2 ), and 7′-hydroxy-7′,8′-dihydropleurostyline ( 3 ), as minor basic constituents, together with three related alkaloids pleurostyline ( 4 ), celacinnine ( 5 ), and celallocinine ( 6 ). 相似文献
20.
Further investigation of the roots of Delphinium giraldii DIELS led to the isolation of three new C(19)-diterpenoid alkaloids, giraldines G (1), H (2), and I (3). The structures of 1-3 were established based on spectroscopic evidence. 相似文献