Dynamical enhanced electron emission and discharges at contaminated surfaces

Broad-area electrodes show electron emission already at electric field strengthsF≈10⁷ V/m. This enhanced field emission (EFE) occurs only for contaminated surfaces. EFE is accompanied by photon emission and gas desorption yielding finally discharges. EFE is caused by dust and contaminants initiating the following effects:

an electron is stochastically emitted in a trigger zone

the electron gains energyΔE?eΔxF ^*

which excites electronic states

which relax by the emission of electrons, photons, and atoms

where the positive charges left behind enhanceF ^*=βF (β?1) initiating so an electron avalanche, i.e., a high conductivity channel. Because of charge migration and neutralization, this avalanche has a life time. This pulsating EFE is accompanied by light emission and gas desorption yielding finally a gas cloud and a discharge.

The pulsating, self-sustained EFE has the same root as:

the enhanced secondary emission found first by Malter

the conductivity switching exhibited by thin (≈ 1 μm) layers of semiconductors or insulators

the normal cathode fall and

the firing-wave instability in neurodynamics.

     

Symmetrieeigenschaften achtkomponentiger Spinorfelder im Gitterraum

Starting from the four component Dirac equation for free particles without mass W.Heisenberg und W.Pauli have shown that the interaction term is uniquely defined, if one requires that all symmetries of free particles are preserved. Here we obtain similar results if we start from the eight component Dirac equation for free particles without mass:

1. The symmetry group of the eight component Dirac equation for free particles without mass has 16 parameters. It is isomorph to the direct product of the SU 4 and a one-parametric group: SU 4× (1).
2. The interaction operator is uniquely defined if one requires to preserve as many symmetries as possible of those given in (1).
3. But some of the symmetries in (1) are necessarily broken, in particular that of SU 3. The symmetry of the interaction operator is given by SO 4× (1)× (1).

These results mean:

1. The Heisenberg theory is uniquely defined, only if one assumes that the free particle part of the equation is well known.
2. The theory can be changed without modifying the fundamental idea ofHeisenberg andPauli to deduce an uniquely defined interaction operator if one starts with a modified free particle part.
3. A special kind of modification of the free particle part leads essentially to the SU 4-symmetry including that of SU 3, which is necessarily broken by the interaction term.
4. The question arises if this break of the SU 3-symmetry has something to do with the real break. This question is not yet touched in this paper.

     

New interferometric method for determining the refractive index of thin dielectric film,its thickness,the phase shift,and the order of interference

A new interferometric method is proposed, using white light fringes of equal chromatic order to determine simultaneously the following paramcters:

1. The refractive index of a thin dielectric film, and hence its dispersion.
2. The film thickness.
3. The correct value of the order of interference.
4. The phase shift occuring due to reflection at the dielectric/metal interface. In the present work, doubly silvered zinc sulphide (ZnS) thin dielectric film was used as an example in applying the proposed method.

     

Existence of phase transitions for quantum lattice systems

We prove that the following lattice systems:

1. anisotropic Heisenberg model,
2. Ising model with transverse magnetic field,
3. quantum lattice gas with hard cores extending over nearest neighbours,

exhibit phase transitions if the temperature is sufficiently low and the transverse (or kinetic) part of the interaction sufficiently small.     

The possibility of using a semiconductor thermal probe to investigate the power flow distribution in waveguides

Conclusions

1. The temperature profile of an absorbing film for a given microwave power flux distribution has been considered.
2. The conditions under which agreement is found between the temperature relief and the flux distribution has been clarified.
3. An experimental investigation has been carried out of the temperature profile in a matched film for the TE₁₀ mode.
4. The possibility of using a semiconductor thermal probe to investigate the microwave power flux distribution has been demonstrated.

     

Small-angle X-ray scattering on spinodal,nucleotic or coarsening processes in two-phase systems containing spherical,fibrillar or lamellar inhomogeneities

We study the effects of some of the most important and typical structural changes in two-phase systems on selected structural parameters obtained from small-angle x-ray scattering (SAXS) measurements. To limit the present study, it was assumed that the Phase, 1, embedded in the matrix

1. is monodispersed and homogeneous,
2. possesses one of the three most extreme shapes (spherical, fibrillar or lamellar) and
3. changes its behaviour

1. through type change (spinodal or nucleotic or coarsening), without changing the shape,
2. through a change of the shape only, or
3. through a) (type change) and b) (shape change) simultaneously.

To find the type of change for three basically different shapes of Phase 1 and to calculate its intensity (amount of the change) the following three SAXS parameters must be compared before and after the treatment of the system:

1. chord lengthl ₁ (and/or radius of gyrationR),
2. volume partw ₁ of the Phase 1, and
3. relative inner surfaceS _v of the system.

It is shown by this comparison that by the pure type change in the case of

1. spinodal change, all three SAXRS parameters are increasing or decreasing simultaneously and proportional to a power of the intensity of the change,
2. nucleotic change,l ₁ (and/orR) is unchanged, the other two (w ₁ andS _v ) are increasing or decreasing simultaneously and directly proportional to the intensity,
3. coarsening change,w ₁ is unchanged and anincreasing ofl ₁ is always accompanied by adecreasing ofS _v and vice versa.

In addition to this type change, the cases of mere changes of the shape (“shape change”) and finally of simultaneous type and/or shape change are studied. For the case of pure shape change the alteration of the dimensions (chord lengthl ₁ and/or radius of gyrationR) must be followed. The limitations of the analyses of the simultaneous type and/or shape change are discussed in detail.     

Nanoparticle and Nanoporous Carbon Adsorbents for Removal of Trace Organic Contaminants from Water

Removal of a wide range of trace organic contaminants from water to concentrations below USEPA Maximum Contaminant Levels (MCL) remains an important goal for the water industry. Design of advanced carbon based adsorption systems represents a unique approach to solving these problems. A number of successful examples are cited in this paper and are briefly summarized in the following section.

1. Removal of foulants such as humic acid using nanoparticle carbon blacks and chemically activated nanoporous fibers;
2. Removal of trace organic contaminants such as benzene, toluene, ethylbenzene and p-xylene (BTEX) to levels below USEPA MCL using nanoporous carbon fibers;
3. Removal of trace chemical warfare simulants such as diisopropylmethyl phosponate and chloroethylethylsulfide using enlarged nanoporous carbon fibers;
4. Removal of trace chlorinated solvents such as trichloroethylene (TCE) and chloroform using tailored nanoporous carbon fibers;
5. Removal of the trace herbicide, atrazine, to below USEPA MCL level using nanoporous chemically activated fibers.

In this paper the enormous improvement of the above systems over commercially available products in static and dynamic adsorption evaluation is described.     

Absence of singular continuous spectrum for certain self-adjoint operators

We give a sufficient condition for a self-adjoint operator to have the following properties in a neighborhood of a pointE of its spectrum:

1. its point spectrum is finite;
2. its singular continuous spectrum is empty;
3. its resolvent satisfies a class of a priori estimates.

     

Infrared and conductivity studies on blends of PMMA/PEO based polymer electrolytes

Poly(methylmetacrylate)/poly(ethylene oxide) (PMMA/PEO) based polymer electrolytes were synthesized using the solution cast technique. Four systems of PMMA/PEO blends based polymer electrolytes films were investigated:

1. PMMA/PEO system,
2. PMMA/PEO + ethylene carbonate (EC) system,
3. PMMA/PEO + lithium hexafluorophosphate (LiPF₆) system and
4. PMMA/PEO + EC + LiPF₆ system.

The polymer electrolytes films were characterized by Impedance Spectroscopy and Fourier Transform Infrared Spectroscopy (FTIR). The FTIR spectra show the complexation occurring between the polymers, plasticizer and lithium salt. The FTIR results give further insight in the conductivity enhancement of PMMA/PEO blends based polymer electrolytes.     

Nachwirkungsmechanismen in Ferriten

In ferrites a large number of after-effects are found, with time constants between nano-seconds and years. In this review the after-effects due to ion-and electron motion will be treated. One finds:

1. single-ion effects in combination with lattice deformations, e.g. Mn³⁺;
2. ion effects caused by mobile vacancies, e.g. Co²⁺;
3. effects due to electron transfer:
4. Co²⁺?Co³⁺
5. Me²⁺?Fe³⁺, in combination with Me⁴⁺ and vacancies.
6. Me⁴⁺?Fe²⁺, with Me=Si, Ti (photomagnetic effect).

The electron transfer is found to be related to electrical effects. In analogy to the photoelectric effect, one has found that illumination produces changes in magnetic properties. Generally speaking, one has in ferrites as many problems with donors and acceptors as in other semiconductors. Information from magnetic measurements helps to elucidate their nature.     

Unbounded derivations ofC*-algebras II

It is demonstrated that a closed symmetric derivation δ of aC?-algebra \(\mathfrak{A}\) generates a strongly continuous one-parameter group of automorphisms of aC?-algebra \(\mathfrak{A}\) if and only if, it satisfies one of the following three conditions

1. (αδ+1)(D(δ))= \(\mathfrak{A}\) , α∈?\{0}.
2. δ possesses a dense set of analytic elements.
3. δ possesses a dense set of geometric elements.

Together with one of the following two conditions

1. ∥(αδ+1)(A)∥≧∥A∥, α∈IR,A∈D(δ).
2. If α∈IR andA∈D(δ) then (αδ+1)(A)≧0 impliesA≧0.

Other characterizations are given in terms of invariant states and the invariance ofD(δ) under the square root operation of positive elements.     

Two-dimensional quantum field theories containing a massless scalar field

The following new findings are briefly reported:

1. A consistent quantum theory can be formulated for a free massless scalar field in two-dimensional spacetime.
2. Satisfactory operator solutions in terms of asymptotic fields can be constructed in the Thirring and Schwinger models.
3. Gauge invariance is spontaneously broken in the Thirring model as well as in the Schwinger model.

     

Magnetostriction measurement by means of strain modulated ferromagnetic resonance (SMFMR)

A novel method for measuring magnetostriction constants is presented. A strain, periodic in time, applied to the sample, causes a modulation of the ferromagnetic resonance line position. The height of the signal obtained after phase-sensitive detection is proportional to the strain modulation depth. The appropriate magnetostriction constant λ is obtained by comparing the height of the SMFMR signal with that of the FMR line, as recorded by means of magnetic field modulation. Features of the new technique are:

1. high sensitivity: λ_min? 10_?9 forM=100 Oe and linewidth ΔH _d=1 Oe;
2. λ's belonging to distinct precession modes are separately determined;
3. applicable to thin layers for which strain gauge techniques cannot be used;
4. wide temperature range: 1.2 K<T<300 K;
5. uniform stress.

An illustrative example (YIG layer on GGG substrate) is given.     

Probing of the Higgs-fermion coupling atγγ-colliders

Three possibilities to observe the Higgs-top interation at future γγ-colliders are discussed:

1. associated Higgs production via the \(\gamma \gamma \to t\bar tH\) reaction,
2. Higgs obliged radiative correction to the \(\gamma \gamma \to t\bar t\) channel,
3. Higgs resonance production via γγ→H→ZZ.

The results obtained show windows of the Higgs mass where the Yukawa interaction of the Higgs with the top quark can be studied at γγ-colliders.     

Magnetic field and doppler velocity correlation in quiescent solar prominences

Analyzing statistically the magnetic and Doppler velocity data for 85 quiescent prominences observed in 1983–1987 by Nikolsky's magnetograph, we came to the following preliminary conclusions:

The average longitudinal magnetic field of the prominence determines the dynamic velocity of the latter: the stronger magnetic fields correspond to the higher Doppler velocities.

A longitudinal magnetic field less than 25 G allows the material to move with arbitrary velocity within the limits of several kilometers per second. A magnetic field higher than 25 G suppresses such movements.

The horizontal length of the flux tube exceeds its vertical part by 1.5 orders of magnitude (the upper limit).

There is an angle of 10°between the horizontal component of the velocity vector in quiescent prominences and the long axis of the filament.

The maximum velocity in quiescent prominences is about 7 km/s.

     

Detection of highly ionizing particles: Nonlinear near-surface phenomena in silicon radiation detectors

As far as the detection system is concerned, experimens on synthesis and study of the properties of superheavy nuclei is one of the most difficult tasks. In fact, these experiments can be considered extreme in many senses:

• —extremely low (fractions of a picobarn-picobarns) formation cross sections of the products under investigation
• —extremely high heavy ion beam intensities for example, ～1.1–1.5 pμA^{1 48}Ca
• —high radioactivity of actinide targets, which are used in the experiments aimed at the synthesis of super-heavy nuclei
• —very long duration of the experiment (as long as a year)
• —extremely low yield of the products under investigation (sometimes less than 1 per month)
• —very high sensitivity of the detection system
• —radical suppression of the background products (method of “active correlations”).

The two last points are the subject of the present paper, as well as the subject of two of my reviews published before. It is evident that without knowledge of the nature of the internal processes in semiconductor detectors it is virtually impossible to provide clear detection of ultra rare signals. In the present paper, the author reports on the investigation of near-surface phenomena in silicon radiation detectors, first of all bearing in mind the theoretical-methodological aspect of these phenomena. Non-equilibrium electron-hole recombination, pulse height defect formation, charge multiplication, and formation of “hot” electron system, are considered. With just these phenomena one can observe nonlinearity of energy-charge-amplitude conversion for heavy ion (recoil nucleus) registered by a silicon detector. Practical applications are also considered. One of them is a deeply modified method of “active correlations”. Projection of applying the method in the experiments with the modernized cyclotron (DC-280 FLNR project) is projected as well as possible applications in the heavy-ion-induced complete fusion nuclear reactions.     

Rigid Body Motion in Special Relativity

We study the acceleration and collisions of rigid bodies in special relativity. After a brief historical review, we give a physical definition of the term ‘rigid body’ in relativistic straight line motion. We show that the definition of ‘rigid body’ in relativity differs from the usual classical definition, so there is no difficulty in dealing with rigid bodies in relativistic motion. We then describe

1. The motion of a rigid body undergoing constant acceleration to a given velocity.
2. The acceleration of a rigid body due to an applied impulse.
3. Collisions between rigid bodies.

     

Stereological substructure analysis in hot-deformed metals from TEM-images

In the present paper three possible methods of stereological evaluation of particle arrangements are discussed:

determination of mean particle diameters by means of the so-called Poisson-Voronoi mosaics,

evaluation of the spatial particle-diameter distribution using the interception-length method of Spektor and

determination of the spatial distribution of grain or subgrain diameters on the basis of an intercept-area method of Saltykov.

Practical application of the procedures is demonstrated by results which were obtained from hot-deformation of several material under different hot-working conditions. It can be shown that stereological interpretation of TEM images renders refined conclusions concerning the mechanisms of structure changes occurring in hot-deformation.     

Three applications toSO(4) invariant systems of a theorem of L. Michel relating extremal points to invariance properties

We consider a theorem due to Michel [1] which relates the invariance properties in peculiar directions in a linear space on which we represent a Lie groupG to the extremal points of an arbitrary smoothG-invariant function. The group we are interested in isSO(4) and we apply the mathematical results to the following problems:

1. mixed linear Stark Zeeman effect in a hydrogen atom,
2. perturbation of a finite Robertson-Walker metric,
3. gas evolutions preserving angular momentum and vorticity.