Evolution under thermal annealing of Mn-doped iron disilicides obtained by ball milling

Phase formation in the Mn doped $\upbeta $ -FeSi₂ system (Fe_1???x Mn _x Si₂, with 0.00 ≤?x?≤ 0.24) was studied using X-ray diffraction and Mössbauer spectroscopy. Samples were prepared by the simultaneous mill of pure Si, Mn and Fe under Ar atmosphere followed by an annealing at 1,123 K during 4 h at 1 × 10^???7 Torr. After milling, an admixture of $\upbeta $ -FeSi₂, $\upalpha $ -FeSi₂ and $\upvarepsilon $ -FeSi phases was present while $\upalpha $ -FeSi₂ disappeared after annealing, resulting $\upbeta $ -FeSi₂ the main phase. Depending on Mn concentration, small amounts of $\upvarepsilon $ -FeSi and Si segregation were also observed. A preferential substitution of Fe atoms by Mn ones in the Fe_II site of the $\upbeta $ -FeSi₂ regular lattice was inferred from the Mössbauer results.     

Dopants incorporation in ZnO mechanical milled powders sensed by positrons

The unique meteorite bencubbinite Isheyevo CH/CB which was recently found in Bashkortostan, Russia was studied using Mössbauer spectroscopy with high velocity resolution. Mössbauer hyperfine parameters of metal in Isheyevo CH/CB external and internal regions demonstrated the presence of three phases such as martensite $\upalpha _{2}$ -Fe(Ni,Co), kamacite $\upalpha $ -Fe(Ni,Co) and disordered taenite $\upgamma $ -Fe(Ni,Co).     

Mössbauer spectroscopy in the investigation of new mineral–related materials

New materials based on the composition of the mineral schafarzikite, FeSb $_{2}\textit {O}_{4}$ , have been synthesised. $^{57}$ Fe- and $^{121}$ Sb- Mössbauer spectroscopy shows that iron is present as Fe $^{2+}$ and that antimony is present as Sb $^{3+}$ . The presence of Pb $^{2+}$ on the antimony sites in materials of composition FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ induces partial oxidation of Fe $^{2+}_{}$ to Fe $^{3+}$ . The quasi-one-dimensional magnetic structure of schafarzikite is retained in FeSb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ and gives rise to weakly coupled non-magnetic Fe $^{2+}$ ions coexisting with Fe $^{3+}$ ions in a magnetically ordered state. A similar model can be applied to account for the spectra recorded from the compound Co $_{0.5}$ Fe $_{0.5}$ Sb $_{1.5}$ Pb $_{0.5}\textit {O}_{4}$ .     

Influence of temperature on the electric,dielectric and AC conductivity properties of nano-crystalline zinc substituted cobalt ferrite synthesized by solution combustion technique

Cobalt–zinc nanoferrites with formulae Co $_{1-x}$ Zn $_{x}$ Fe $_{2}$ O $_{4}$ , where x = 0.0, 0.1, 0.2 and 0.3, have been synthesized by solution combustion technique. The variation of DC resistivity with temperature shows the semiconducting behavior of all nanoferrites. The dielectric properties such as dielectric constant ( $\varepsilon $ ’) and dielectric loss tangent (tan $\delta )$ are investigated as a function of temperature and frequency. Dielectric constant and loss tangent are found to be increasing with an increase in temperature while with an increase in frequency both, $\varepsilon $ ’ and tan $\delta $ , are found to be decreasing. The dielectric properties have been explained on the basis of space charge polarization according to Maxwell–Wagner’s two-layer model and the hopping of charge between Fe $^{2+}$ and Fe $^{3+}$ . Further, a very high value of dielectric constant and a low value of tan $\delta $ are the prime achievements of the present work. The AC electrical conductivity ( $\sigma _\mathrm{AC})$ is studied as a function of temperature as well as frequency and $\sigma _\mathrm{AC}$ is observed to be increasing with the increase in temperature and frequency.     

Structure of some FeII − III hydroxysalt green rusts (carbonate, oxalate, methanoate) from Mössbauer spectroscopy

The abundances of Fe^II and Fe^III environments within green rusts one, GR1s, that intercalate carbonate, oxalate and methanoate (formate) anions are found from Mössbauer spectra for compositions corresponding to [Fe $^{\rm II}_{6}$ Fe $^{\rm III}_{2}$ (OH)₁₆]^2?+??[CO $_{3}^{2-}$ ?5H₂O]^2???, [Fe $^{\rm II}_{4}$ Fe $^{\rm III}_{2}$ (OH)₁₂]^2?+??[CO $_{3}^{2-}$ ?3H₂O]^2???, [Fe $^{\rm II}_{6}$ Fe $^{\rm III}_{2}$ (OH)₁₆]^2?+??[C₂O $_{4}^{2-}$ ?4H₂O]^2??? and [Fe $^{\rm II}_{5}$ Fe $^{\rm III}_{2}$ (OH)₁₄]^2?+??[2HCOO^????3H₂O]^2???. These formulae correspond to orders α, β and γ where cation distances are (2 × a ₀), ( $\surd 3$ × a ₀) or a mixture of both leading to (7 × a ₀), where ratio x = {[Fe^III]/[Fe_total]} = 1/4, 1/3 and 2/7, respectively. Anion distributions within interlayers are also devised and long-range orders determined accordingly.     

Fe-doped SnO 2 nanopowders obtained by sol–gel and mechanochemical alloying with and without thermal treatment

The present work is aimed to compare the physical properties of $\mbox{Sn}_{1-x} \mbox{Fe}_x \mbox{O}_{2-\delta } $ (x?=?0, and 0.05) nanopowders obtained by sol–gel method, mechanochemical alloying, and mechanochemical alloying followed by thermal treatment. The X-ray diffraction of $\mbox{Sn}_{1-x} \mbox{Fe}_x \mbox{O}_{2-\delta } $ samples prepared by sol–gel showed peaks due to the cassiterite phase of SnO₂ and thier Mössbauer spectra showed ferromagnetic and paramagnetic signals. The samples obtained by the milling process of SnO₂ mixed with $\upalpha $ -Fe showed Bragg peaks due to SnO₂ (rutile) with a line broadening caused by the reduction of grain sizes and the presence of microstrains. Mössbauer spectra for these samples revealed the presence of Fe^3?+? as well as unreacted $\upalpha $ -Fe. In the case of mechanochemical alloying with thermal treatment, the incorporation of Fe^3?+? in the SnO₂ structure with the presence of impurities was observed.     

Formation and crystallization kinetics of Nd–Fe–B-based bulk amorphous alloy

In order to improve the glass-forming ability (GFA) of Nd–Fe–B ternary alloys to obtain fully amorphous bulk Nd–Fe–B-based alloy, the effects of Mo and Y doping on GFA of the alloys were investigated. It was found that the substitution of Mo for Fe and Y for Nd enhanced the GFA of the Nd–Y–Fe–Mo–B alloys. It was also revealed that the GFA of the samples was optimized by 4 at.% Mo doping and increased with the Y content. The fully amorphous structures were all formed in the Nd $_{6-{x}}$ Y $_{{x}}$ Fe $_{68}$ Mo $_{4}$ B $_{22}$ (x $=$ 1–5) alloy rods with 1.5 mm-diameter. After subsequent crystallization, the devitrified Nd $_{3}$ Y $_{3}$ Fe $_{68}$ Mo $_{4}$ B $_{22}$ alloy rod exhibited a uniform distribution of grains with a coercivity of 364.1 kA/m. The crystallization behavior of Nd $_{3}$ Y $_{3}$ Fe $_{68}$ Mo $_{4}$ B $_{22}$ BMG was investigated in isothermal situation. The Avrami exponent n determined by JAM plot is lower than 2.5, implying that the crystallization is mainly governed by a growth of particles with decreasing nucleation rate.     

Quantum billiards in multidimensional models with branes

A gravitational $D$ -dimensional model with $l$ scalar fields and several forms is considered. When a cosmological-type diagonal metric is chosen, an electromagnetic composite brane ansatz is adopted and certain restrictions on the branes are imposed; the conformally covariant Wheeler–DeWitt (WDW) equation for the model is studied. Under certain restrictions asymptotic solutions to WDW equation are found in the limit of the formation of the billiard walls which reduce the problem to the so-called quantum billiard on the $(D+ l -2)$ -dimensional Lobachevsky space. Two examples of quantum billiards are considered. The first one deals with $9$ -dimensional quantum billiard for $D = 11$ model with $330$ four-forms which mimic space-like $M2$ - and $M5$ -branes of $D=11$ supergravity. The second one deals with the $9$ -dimensional quantum billiard for $D =10$ gravitational model with one scalar field, $210$ four-forms and $120$ three-forms which mimic space-like $D2$ -, $D4$ -, $FS1$ - and $NS5$ -branes in $D = 10$ $II A$ supergravity. It is shown that in both examples wave functions vanish in the limit of the formation of the billiard walls (i.e. we get a quantum resolution of the singularity for $11D$ model) but magnetic branes could not be neglected in calculations of quantum asymptotic solutions while they are irrelevant for classical oscillating behavior when all $120$ electric branes are present.     

Study of Alpha Decay Chains of Superheavy Nuclei and Magic Number Beyond Z = 82 and N = 126

We study various $\alpha $ -decay chains on the basis of the preformed cluster decay model. Our work targets the superheavy elements, which are expected to show extra stability at shell closure. Our computations identify the following combinations of proton and neutron numbers as the most stable nuclei: $Z=112$ , $N=161, 163$ ; $Z=114$ , $N=171, 178, 179$ ; and $Z=124$ , $N=194$ . We also investigate the alternative of heavy cluster emissions in the decay chain of ³⁰¹120, instead of $\alpha $ decay. Our study of cluster radioactivity shows that the half-life for ¹⁰Be decay in ²⁸⁹114 is larger, indicating enhanced stability at $Z=114$ , $N=175$ . Similar calculations concerning the emission of $\ ^{14}{\rm C}$ and $\ ^{34}{\rm Si}$ from ³⁰¹120 find the more stable combinations $Z=114$ , $N=173$ , and $Z=106$ , $N=161$ , respectively. From the same parent, ³⁰¹120, the emission of a $\ ^{49-51}{\rm Ca}$ cluster yielding a $Z=100$ , $N=152$ daughter is the most probable.     

Analysis of the vertexes \Xi_{Q}^{*}′QV , \Sigma_{Q}^{*} \Sigma_{Q}^{}V and radiative decays \Xi_{Q}^{*} \rightarrow ′Q \gamma , \Sigma_{Q}^{*} \rightarrow \Sigma_{Q}^{} \gamma

In this article, we study the vertexes $ \Xi_{Q}^{*}$ ′_Q V and $ \Sigma_{Q}^{*}$ $ \Sigma_{Q}^{}$ V with the light-cone QCD sum rules, then assume the vector meson dominance of the intermediate $ \phi$ (1020) , $ \rho$ (770) and $ \omega$ (782) , and calculate the radiative decays $ \Xi_{Q}^{*}$ $ \rightarrow$ ′_Q $ \gamma$ and $ \Sigma_{Q}^{*}$ $ \rightarrow$ $ \Sigma_{Q}^{}$ $ \gamma$ .     

An Algebraic Construction of Boundary Quantum Field Theory

We build up local, time translation covariant Boundary Quantum Field Theory nets of von Neumann algebras ${\mathcal A_V}$ on the Minkowski half-plane M ₊ starting with a local conformal net ${\mathcal A}$ of von Neumann algebras on ${\mathbb R}$ and an element V of a unitary semigroup ${\mathcal E(\mathcal A)}$ associated with ${\mathcal A}$ . The case V?=?1 reduces to the net ${\mathcal A_+}$ considered by Rehren and one of the authors; if the vacuum character of ${\mathcal A}$ is summable, ${\mathcal A_V}$ is locally isomorphic to ${\mathcal A_+}$ . We discuss the structure of the semigroup ${\mathcal E(\mathcal A)}$ . By using a one-particle version of Borchers theorem and standard subspace analysis, we provide an abstract analog of the Beurling-Lax theorem that allows us to describe, in particular, all unitaries on the one-particle Hilbert space whose second quantization promotion belongs to ${\mathcal E(\mathcal A^{(0)})}$ with ${\mathcal A^{(0)}}$ the U(1)-current net. Each such unitary is attached to a scattering function or, more generally, to a symmetric inner function. We then obtain families of models via any Buchholz-Mack-Todorov extension of ${\mathcal A^{(0)}}$ . A further family of models comes from the Ising model.     

Asymptotic Behavior for a Version of Directed Percolation on the Triangular Lattice

We consider a version of directed bond percolation on the triangular lattice such that vertical edges are directed upward with probability $y$ , diagonal edges are directed from lower-left to upper-right or lower-right to upper-left with probability $d$ , and horizontal edges are directed rightward with probabilities $x$ and one in alternate rows. Let $\tau (M,N)$ be the probability that there is at least one connected-directed path of occupied edges from $(0,0)$ to $(M,N)$ . For each $x \in [0,1]$ , $y \in [0,1)$ , $d \in [0,1)$ but $(1-y)(1-d) \ne 1$ and aspect ratio $\alpha =M/N$ fixed for the triangular lattice with diagonal edges from lower-left to upper-right, we show that there is an $\alpha _c = (d-y-dy)/[2(d+y-dy)] + [1-(1-d)^2(1-y)^2x]/[2(d+y-dy)^2]$ such that as $N \rightarrow \infty $ , $\tau (M,N)$ is $1$ , $0$ and $1/2$ for $\alpha > \alpha _c$ , $\alpha < \alpha _c$ and $\alpha =\alpha _c$ , respectively. A corresponding result is obtained for the triangular lattice with diagonal edges from lower-right to upper-left. We also investigate the rate of convergence of $\tau (M,N)$ and the asymptotic behavior of $\tau (M_N^-,N)$ and $\tau (M_N^+ ,N)$ where $M_N^-/N\uparrow \alpha _c$ and $M_N^+/N\downarrow \alpha _c$ as $N\uparrow \infty $ .     

Analysis of the {3\over 2}^{+} heavy and doubly heavy baryon states with QCD sum rules

In this article, we study the ${3\over 2}^{+}$ heavy and doubly heavy baryon states $\varXi^{*}_{cc}$ , $\varOmega^{*}_{cc}$ , $\varXi^{*}_{bb}$ , $\varOmega^{*}_{bb}$ , $\varSigma_{c}^{*}$ , $\varXi_{c}^{*}$ , $\varOmega_{c}^{*}$ , $\varSigma_{b}^{*}$ , $\varXi_{b}^{*}$ and $\varOmega_{b}^{*}$ by subtracting the contributions from the corresponding ${3\over 2}^{-}$ heavy and doubly heavy baryon states with the QCD sum rules, and we make reasonable predictions for their masses.     

Influence of assortativity and degree-preserving rewiring on the spectra of networks

Newman’s measure for (dis)assortativity, the linear degree correlation coefficient $\rho _{D}$ , is reformulated in terms of the total number N _k of walks in the graph with k hops. This reformulation allows us to derive a new formula from which a degree-preserving rewiring algorithm is deduced, that, in each rewiring step, either increases or decreases $\rho _{D}$ conform our desired objective. Spectral metrics (eigenvalues of graph-related matrices), especially, the largest eigenvalue $\lambda _{1}$ of the adjacency matrix and the algebraic connectivity $\mu _{N-1}$ (second-smallest eigenvalue of the Laplacian) are powerful characterizers of dynamic processes on networks such as virus spreading and synchronization processes. We present various lower bounds for the largest eigenvalue $\lambda _{1}$ of the adjacency matrix and we show, apart from some classes of graphs such as regular graphs or bipartite graphs, that the lower bounds for $\lambda _{1}$ increase with $\rho _{D}$ . A new upper bound for the algebraic connectivity $\mu _{N-1}$ decreases with $\rho _{D}$ . Applying the degree-preserving rewiring algorithm to various real-world networks illustrates that (a) assortative degree-preserving rewiring increases $\lambda _{1}$ , but decreases $\mu _{N-1}$ , even leading to disconnectivity of the networks in many disjoint clusters and that (b) disassortative degree-preserving rewiring decreases $\lambda _{1}$ , but increases the algebraic connectivity, at least in the initial rewirings.     

Charmonium rescattering effects in \psi(2S) \rightarrow \gamma \eta_{c}^{} decay

Charmonium rescattering effects in the M1 transition of $ \psi$ (2S) $ \rightarrow$ $ \gamma$ $ \eta_{c}^{}$ are investigated by modeling a $ \chi_{{cJ}}^{}$ or J/ $ \psi$ rescattering into a $ \eta_{c}^{}$ final state. The absorptive and dispersive part of the transition amplitudes for the rescattering loops of $ \eta$ $ \psi$ ( $ \gamma^{{\ast}}_{}$ ) and $ \gamma$ $ \chi$ ( $ \psi$ ) are separately evaluated. The numerical results show that the contribution from the $ \gamma$ $ \chi$ ( $ \psi$ ) rescattering process is negligible. Compared with the virtual D $ \bar{{D}}$ (D ^*) rescattering processes, the $ \eta$ $ \psi$ ( $ \gamma^{{\ast}}_{}$ ) process may be regarded as the next-leading order of the hadronic loop mechanism, which only offers the partial decay width of ～ 0.045 keV to the $ \psi$ (2S) $ \rightarrow$ $ \gamma$ $ \eta_{c}^{}$ .     

Quinazoline-2,4(1H,3H)-diones inhibit the growth of multiple human tumor cell lines

Quinazoline-2,4( $1H,3H$ )-diones exhibit a wealth of biological activities including antitumor proliferation. We established an improved method for the synthesis of quinazoline-2,4( $1H,3H$ )-dione derivatives with three points of molecular diversity. Data indicate that compounds 60 (average $\text{ logGI}_{50} \!=\! -6.1$ ), 65 (average $\text{ logGI}_{50} \!=\! -6.13$ ), 69 (average $\text{ logGI}_{50} \!=\! -6.44$ ), 72 (average $\text{ logGI}_{50} \!=\! -6.39$ ), and 86 (average $\text{ logGI}_{50} = -6.45$ ) significantly inhibited the in vitro growth of 60 human tumor cell lines tested. Structure–activity relationship analyses indicate that chlorophenethylureido is the necessary substituent at the $\text{ D}_{3}$ diversity point (7-position of quinazoline-2,4( $1H,3H$ )-dione), in particular, $o$ -chlorophenethylurea (69) achieved optimal activity. $o$ - or $m$ -Chlorophenethyl substitutions (69 and 72) at the $\text{ D}_{2}$ diversity point (3-position of quinazo line-2,4( $1H,3H$ )-dione) gave the most potent compounds. Methoxyl and 4-methylpiperazin-1-yl substitution at the $\text{ D}_{1}$ diversity point (6-position of quinazoline-2,4( $1H,3H$ )-dione skeleton) may yield better activity than other groups. The quinazoline-2,4( $1H,3H$ )-dione scaffold can be effectively replaced by 2 $H$ -benzo[b][1,4]thiazin-3(4 $H$ )-one.     

Mössbauer study of magnetism in FeII − III (oxy-)hydroxycarbonate green rusts; ferrimagnetism of FeII − III hydroxycarbonate

Fe^II???III hydroxycarbonate Fe $^{\rm II}_{4}$ Fe $^{\rm III}_{2}$ (OH)₁₂CO₃, green rust GR(CO $_{3}^{2-})$ , reveals a ferrimagnetic behaviour. Moments that lie within two-dimensional cation layers are parallel for same species and antiparallel between Fe^II and Fe^III. Respective ordering temperatures are 5.2 and 7 K. A sextet with distribution from 350 to 580 kOe for Fe^III and an octet reflecting a mixture of states with field of 130 kOe and quadrupole splitting of ?3.0 mm s^???1 for Fe^II are observed at 1.4 K. Ferric oxyhydroxycarbonate Fe $^{\rm III}_{6}$ O₁₂H₈CO₃ is ferromagnetic and displays at 4 K a sextet with field between 400 and 500 kOe (maximum at 480 kOe) and transition at 80 K. GR(CO $_{3}^{2-})$ deprotonation gives magnetic domains with compositions at x?=?1/3, 2/3 and 1 due to long range order.     

Large N approach to Kaon decays and mixing 28 years later: \Delta I=1/2 rule, \hat{B}_K,and \Delta M_K

We review and update our results for $K\rightarrow \pi \pi $ decays and $K^0$ – $\bar{K}^0$ mixing obtained by us in the 1980s within an analytic approximate approach based on the dual representation of QCD as a theory of weakly interacting mesons for large $N$ , where $N$ is the number of colors. In our analytic approach the Standard Model dynamics behind the enhancement of $\hbox {Re}A_0$ and suppression of $\hbox {Re}A_2$ , the so-called $\Delta I=1/2$ rule for $K\rightarrow \pi \pi $ decays, has a simple structure: the usual octet enhancement through the long but slow quark–gluon renormalization group evolution down to the scales $\mathcal{O}(1\, {\hbox { GeV}})$ is continued as a short but fast meson evolution down to zero momentum scales at which the factorization of hadronic matrix elements is at work. The inclusion of lowest-lying vector meson contributions in addition to the pseudoscalar ones and of Wilson coefficients in a momentum scheme improves significantly the matching between quark–gluon and meson evolutions. In particular, the anomalous dimension matrix governing the meson evolution exhibits the structure of the known anomalous dimension matrix in the quark–gluon evolution. While this physical picture did not yet emerge from lattice simulations, the recent results on $\hbox {Re}A_2$ and $\hbox {Re}A_0$ from the RBC-UKQCD collaboration give support for its correctness. In particular, the signs of the two main contractions found numerically by these authors follow uniquely from our analytic approach. Though the current–current operators dominate the $\Delta I=1/2$ rule, working with matching scales $\mathcal{O}(1 \, {\hbox { GeV}})$ we find that the presence of QCD-penguin operator $Q_6$ is required to obtain satisfactory result for $\hbox {Re}A_0$ . At NLO in $1/N$ we obtain $R=\hbox {Re}A_0/\hbox {Re}A_2= 16.0\pm 1.5$ which amounts to an order of magnitude enhancement over the strict large $N$ limit value $\sqrt{2}$ . We also update our results for the parameter $\hat{B}_K$ , finding $\hat{B}_K=0.73\pm 0.02$ . The smallness of $1/N$ corrections to the large $N$ value $\hat{B}_K=3/4$ results within our approach from an approximate cancelation between pseudoscalar and vector meson one-loop contributions. We also summarize the status of $\Delta M_K$ in this approach.     

An Averaging Theorem for FPU in the Thermodynamic Limit

Consider an FPU chain composed of $N\gg 1$ particles, and endow the phase space with the Gibbs measure corresponding to a small temperature $\beta ^{-1}$ . Given a fixed $K$ , we construct $K$ packets of normal modes whose energies are adiabatic invariants (i.e., are approximately constant for times of order $\beta ^{1-a}$ , $a>0$ ) for initial data in a set of large measure. Furthermore, the time autocorrelation function of the energy of each packet does not decay significantly for times of order $\beta $ . The restrictions on the shape of the packets are very mild. All estimates are uniform in the number $N$ of particles and thus hold in the thermodynamic limit $N\rightarrow \infty $ , $\beta >0$ .     

Determination of the Dalitz plot parameter \alpha for the decay \eta → 3 \pi^{0}_{} with the Crystal Ball at MAMI-B

A precise measurement of the Dalitz plot parameter, $ \alpha$ , for the $ \eta$ → 3 $ \pi^{0}_{}$ decay is presented. The experiment was performed with the Crystal Ball and TAPS large-acceptance photon detectors at the tagged photon beam facility of the MAMI-B electron accelerator in Mainz. High statistics of 1.8 · 10⁶ $ \eta$ → 3 $ \pi^{0}_{}$ events were obtained, giving the result $ \alpha$ = - 0.032±0.002_stat±0.002_syst .