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1.
Alkali atoms were scattered with hyperthermal energies from a clean and an oxygen covered (θ ≈ 0.5 ML) W(110) surface. The trapping probability of K and Na atoms on oxygen covered W(110) has been measured as a function of incoming energy (0–30 eV) and incident angle. A considerable enhancement of trapping on the oxygen covered surface compared to a clean surface was observed. At energies above 25 eV there are still K and Na atoms being trapped by the oxygen covered surface. From the temperature dependence of the mean residence time τ of the initially trapped atoms the pre-exponential factor τ0 and the desorption energy Q were derived using the relation: τ = τ0exp(QkTs). On clean W(110) we obtained for Li: τ0 = (8 ± 84) × 10?14sec, Q = (2.78 ± 0.09) eV; for Na: τ0 = (9 ± 3) × 10?14 sec, Q = (2.55 ± 0.04) eV; and for K: τ0 = (4 ± 1) × 10?13 sec, Q = (2.05 ± 0.02) eV. Oxygen covered W(110) gave for Na: τ0 = (7 ±3) × 10?15 sec, Q = (2.88 ± 0.05) eV; and for K: τ0 = (1.3 ± 0.90.6) × 10?14sec, Q = (2.48 ±0.05) eV. The adsorption on clean W(110) has the features of a supermobile two-dimentional gas; on the oxygen covered W(110) adsorbed atoms have the partition function of a one-dimen-sional gas. The binding of the adatoms to the surface has a highly ionic character in the systems of the present experiment. An estimate is given for the screening length of the non-perfect conductor W(110):ks?1≈ 0.5 Å.  相似文献   

2.
The vibration-rotation transitions for v = 1 ← 0 of NO (2Π12) have been studied by using the technique of laser magnetic resonance spectroscopy. Five magnetic resonance lines are observed with three CO laser lines in the range from 1859 to 1886 cm?1. From these, three zero-field transition frequencies, v = 1 ← 0; R(32), P(72), and P(92) are obtained with an accuracy of ±0.0007 cm?1. The molecular constants which have been determined by borrowing centrifugal constants from a previous infrared work are B021 = 1.72004 ± 0.00006 cm?1, B121 = 1.70212 ± 0.00010 cm?1, and G(v = 1) ? G(v = 0) (for 2Π12) = 1875.8470 ± 0.0007 cm?1.  相似文献   

3.
The ratio between the cross sections for the reactions π? p→ χ?0n and π?pη→2γ n has been measured to be (2.4 ± 0.9) × 10?2, (2.1 ± 0.6) × 10?2 and (2.8 ± 1.3) × 10?2 at 3.8,6,8 and 12 GeV/c incident momentum respectively.At the same momenta the cross section for πt- p → neutrals is (1.48 ± 0.09) mb, (0.86 ± 0.05) mb, (0.64 ± 0.04) mb and (0.42±0.03) mb.  相似文献   

4.
A millimeter-wave spectrometer having a sensitivity of 4 × 10?10 cm?1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure JJ, K = 0 ← 3 transitions in PH3 and JJ, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD3. The B0 and C0 spectral constants (in MHz) are: for PH3, B0 = 133 480.15 ± 0.12 and C0 = 117 488.85 ± 0.16; for PD3, B0 = 69 471.10 ± 0.03 and C0 = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH3, r0 (A?) = 1.4200 and α0(o) = 93.345; for PD3, r0 (A?) = 1.4176 and α0(o) = 93.359. The corresponding zero-point-average values were calculated to be: for PH3, rz (A?) = 1.42699 ± 0.0002 and αz(o) = 93.2287; for PD3, rz (A?) = 1.42265 ± 0.0001 and αz(o) = 93.2567 ± 0.004. For both species, the equilibrium values are re (A?) = 1.41159 ± 0.0006 and αe(o) = 93.328 ± 0.02.  相似文献   

5.
The E-B (0g+-0u+) band system of Br2 has been investigated at Doppler-limited resolution using polarization labeling spectroscopy. Merged E state data for the three naturally occurring isotopes in the range vE = 0–16, expressed in terms of the constants for 79Br2, are (in cm?1) Y0,0 = 49 777.962(54), Y1,0 = 150.834(22), Y2,0 = ?0.4182(28), Y3,0 = 6.6(11) × 10?4, Y0,1 = 4.1876(28) × 10?2, Y1,1 = ?1.607(16) × 10?4, and Y0,2 = 1.39(39) × 10?8. The bond distance is re = 3.194 A?, and the diabatic dissociation energy to Br+(3P2) + Br?(1S0) is 34 700 cm?1.  相似文献   

6.
The mean lifetimes of the Λ and Ξ0 hyperons have been measured in a short neutral beam at the CERN Proton Synchrotron. Λ and Ξ0 decays have been identified by measuring their decay products in a magnetic spectrometer and in a lead glass hodoscope. The experimental results, based on 53 000 Λ decays and 6300 Ξ0 decays are
τΛ = (2.69 ± 0.03)×10?10s, τΞ0 = (2.77 ± 0.16) ×10?10s?(τΛ ? 2.69 × 10?10s).
From the result for τΞ0 together with existing data on τΞ? we obtain a violation of the ΔI = 12 rule in non-leptonic Ξ decays.  相似文献   

7.
Molecular constants of the first E 0+ ion-pair state of IBr vapor have been determined using polarization-labeling spectroscopy applied to the sequential transitions E 0+B′ 0+X 0+, while the second f 0+ ion-pair state is reported and characterized for the first time. A least-squares, simultaneous analysis of data for the I79Br and I81Br isotopes gives the following constants (in cm?1) for I79Br:
E state: Te = 39487.32(12), ωe = 119.518(21), ωeξe = 0.2109(12)
,
ωeye = ? 2.34(22) × 10?4, Be = 2.9701(14) × 10?2
,
αe = 5.43(59) × 10?5, and γe = ? 6.8(16) × 10?7
.
F state: Te = 45382.58(17), ωe = 128.805(66), ωeξe = 0.3630(69)
,
ωeye = ? 9.7(22) × 10?4, Be = 3.0073(30) × 10?2, and αe = 8.52(48) × 10?5
. Preliminary data for the first Ω = 1 ion-pair state, accessed in the sequence 1(3P2) ← A(Ω = 1) ← X 0+, indicate that Te is ?30 cm?1 higher in energy than that of the E state.  相似文献   

8.
The Raman active fundamentals ν1(A1g), ν2(Eg), ν5(F2g), and the overtone 2ν6 of SF6 have been investigated with a higher resolution and the band origins were estimated to be: ν1 = 774.53 cm?1, ν2 = 643.35 cm?1, ν5 = 523.5 cm?1, and 2ν6 = 693.8 cm?1. Raman and infrared data have been combined for estimation of several anharmonicity constants. The ν6 fundamental frequency is calculated as 347.0 cm?1. From the analysis of the ν2 Raman band, the following rotational constants of both the ground and upper states have been calculated:
B0 = 0.09111 ± 0.00005cm?1; D0 = (0.16±0.08)10?7cm?1
;
B2 = 0.09116 ± 0.00005cm?1; D2 = (0.18±0.04)10?7cm?1
.  相似文献   

9.
The wavenumbers of the vibration rotation band lines of 14N16O are reported for the 2Π12-2Π12, 2Π12-2Π12 and 2Π12-2Π12 subbands of the 1-0 transition in the infrared. The full set of spectroscopic constants for this band has been determined by direct approach using the analysis of Zare, Schmeltekopf, Harrop, and Albritton. In addition to the band origin ν0 and the B, D, H constants for the lower and upper vibrational levels, the following spin-orbit coupling constants have been derived: A?0 = 123.02772 ± 0.00011 and A?1 = 122.78248 ± 0.00011 (in cm?1). Apparent centrifugal corrections to these constants have been determined and the values obtained for them are A?D0 = (0.347573 ± 0.00051) × 10?3 and A?D1 = (0.337135 ± 0.00050) × 10?3cm?1. Λ-Type doubling constants evaluated by using both grating and tunable laser data are also reported.  相似文献   

10.
The bending vibration bands ν4 and ν5 of HCCI were studied. From the observed rotational structure the rotational constant B0 and the centrifugal distortion constant D0 were obtained. The results were B0 = 0.105968(7) cm?1 and D0 = 1.96(7) × 10?8 cm?1 from ν4 and B0 = 0.105948(8) cm?1 and D0 = 1.96(11) × 10?8 cm?1 from ν5. The structure of the hot bands 2ν5(Δ) ← ν5(Π) and 3ν5(φ) ← 2ν5(Δ) was also resolved and hence the values α5 = ?3.033(8) × 10?4 cm?1 and q5 = 9.3(3) × 10?5 cm?1 could be derived. The other most intense hot bands following ν5 could be explained in terms of the Fermi diads ν350 and ν3 + ν5±15±1. Of the numerous hot bands accompanying ν4, only those between different excited states of ν4 could be assigned. Then estimates for α4 and q4 were also obtained. In addition, several vibrational constants were derived.  相似文献   

11.
A stroboscopic technique for the observation of quadrupole hyperfine interactions of isomeric nuclear states has been successfully developed. The inherent precision and resolution of this technique have been demonstrated by measuring the quadrupole hyperfine frequency for 69Ge(92+1, τ = 4.0μ) in Zn metal at several temperatures; ω0 = [19.67 ± 0.06] × 106s?1 (at 623 ± 3 K).  相似文献   

12.
The resonant 2-photon E(O+g) ← B(O+g) ← X(O+g) transition of I2 vapor has been studied by polarization spectroscopy, leading to a rotational analysis of the ν = 0–15 vibrational levels of the E state. The principal constants determined are Be = 19.9738(42) × 10-3, αe = 5.602(84) × 10-5, γe = 1.02(41) × 10-7, DeJ = 3.040(74) × 10-9cm-1, and re = 3.6470(5) A?.  相似文献   

13.
Medium resolution infrared grating spectra of gaseous ketene, H2CCO were recorded between 1000 and 400 cm?1, both at instrument temperature (40°C) and with cooling (?40°C). Interferometric Fourier spectra were also measured at ?70°C with resolution 0.22 cm?1 between 450 and 330 cm?1. The K structure of the fundamentals ν5, ν6, ν8, and ν9 was assigned. These fundamentals are coupled by a-axis Coriolis interactions. These couplings were analysed on the symmetric top basis for setting up the perturbation matrix and by utilizing the K-dependent Coriolis shifts of levels. A preliminary analysis of the Coriolis intensity anomalies was also undertaken.Band center values from combination differences are ν50 = 587.30 (27) and ν60 = 528.36 (39) cm?1. Synthetic spectra indicate the band origins of ν8 and ν9 to be close to 977.8 and 439.0 cm?1, respectively. Estimates of Coriolis coupling constants obtained from synthetic spectra are ζ58a = + 0.33 (5), ζ68a = + 0.714 (20), ζ59a = ? 0.774 (20), and ζ69a = ? 0.30 (2). Approximate ratios of unperturbed vibrational transition moments obtained from spectral simulations are M80:±iM50:±iM60:M90 ≈ +2:?9:+10:+0.5.  相似文献   

14.
A forward dispersion relation cannot be applied to charged particle scattering amplitudes unless the influence of the Coulomb interaction is explicitly considered. Earlier studies have shown how Coulomb effects can be taken into account when direct (s-channel or bound-state) poles are investigated. In this paper we extend the Coulomb modification to include I = 0 exchange (u-channel) processes as well. We then apply a forward dispersion relation to empirical d + α, p + d and n + d elastic scattering amplitudes which contain both direct and exchange poles with and without Coulomb effects. We obtain detailed and model-independent information on the following vertices: 6Li-α-d (S- and D-state) 4He-d-d, 3He-d-p, 3H-d-n and d-p-n. From the coupling constants we calculate the asymptotic normalization (spectroscopic factors) C21 of the corresponding cluster wave functions, which become: C20(6Li, αd) = 4.62 ± 0.23, C22(6Li, αd) = (1 ± 6) × 10?4, C20(α, dd) < 2, C20(3He, dp) = 3.5 ± 0.4, C20(3H, dn) = 2.6 ± 0.3 and C20(d, np) = 1.66 ± 0.1.  相似文献   

15.
A red-degraded band head, normally badly overlapped by the gamma system, A3Φ - X′ 3Δ, of zirconium oxide, appears in emission spectra of zirconium arcs and in absorption spectra of S-type stars and of frozen rare gas matrices containing zirconium. The emission band has been examined at high-resolution with the aid of separated zirconium isotopes. Identification of the band as 0-0 of a 1Π - X 1Σ+ system of zirconium oxide is confirmed by rotational analysis where the following constants (cm?1) are obtained for 90Zr16O:
B0′(R,P) = 0.40142 D0′(R,P) = 3.51 × 10?7
B0′(Q) = 0.40166 D0′(Q) =3.52 × 10?7
B0″ = 0.42263 D0″ =3.19 × 10?7
ν0 = 15383.81s
The Λ-type doubling in the 1Π state and the question of whether X 1Σ+ or X′ 3Δ is the true ground state of ZrO are discussed.  相似文献   

16.
The 6? and 7? isomeric states in 66Ga and 68Ga at 1440.9 and 1229.6 keV, respectively, have been populated with the (13C, 2np) and (15N, n2p) reactions on natural Fe. The half-lives of these states have been measured to be T12(6?, 66Ga) = 57.3 ± 1.2 ns and T12(7?, 68Ga) = 64 ± 2 ns. Using previous data on the hyperfine field of Ga in Fe, the g-factors of these states have been determined by means of the TDPAD method. The results are g(6?, 66Ga) = 0.129 ± 0.003 and g(7?, 68Ga) = 0.105 ± 0.003. These values are in very good agreement with the independent particle model if one assumes the f52, νg92}6?,7? and p32, νg92}6? configurations and uses the empirical proton and neutron g-factors from odd-A neighboring nuclei instead of the Schmidt values. The large disagreements with experiment when Schmidt values are used show that core polarization effects are important in these nuclei.  相似文献   

17.
Collisions between two excited atoms leading to an increase in the excitation energy of the particles have been under investigation. All measurements were made in the afterglow of gas-discharge plasma. The cross sections of the following reactions have been determined: Hg(63P012) + Hg(63P012) → Hg7 + Hg(61S0), Hem (21,3S) + Xem(3P0,2) → (Xe+)1 + He0 + e. The cross section of the first reaction for different transitions lies in the region (2?35) × 10?15 cm2 and the cross section of the second, in (0.2?2.4) × 10?16 cm2. Possible systematic errors and the role of cascade transitions are discussed. Cross sections of the Penning reaction Hem + Xe0 → He0 + Xe+ + e have also been measured. The result is σ (23S) = (1.4 ± 0.2) × 10?15 cm2, σ (21S) = (1.2 ± 0.3) × 10?15 cm2.  相似文献   

18.
The isotopes 118Cs(T12 = 16 s) and 120 Cs (58 s) were found to have unresolved, bell-shaped α-particle spectra extending from 7 to 10 MeV and from 6 to 9 MeV, respectively. The branching ratios are (2.4 ± 0.4) × 10?5 and (2.0 ± 0.4) × 10?7. The experiment confirms 120Cs to be a delayed-proton emitter with a proton branch of (7±3) × 10?8.  相似文献   

19.
For e+ energy > 0.3 GeV and 10 GeV < visible energy < 100 GeV we find that: (i) ? = (vμ + Ne → μ?e+)/(vμ + Ne → μ?) = (0.41 ± 0.15)%; (ii) 1.2 ± 0.5 neutral strange particles are produced per μ?e+ event; (iii) the lifetime of possible positron-parent particles is < 3 × 10?10 s (90% C.L.); (iv) the cross section for direct e+ production via the neutral current is < 0.2 times that via the charged current (90% C.L.); (v) the cross section for producing heavy leptons, L+, decaying into e+ … is < 0.7 × 10?3 times that for μ?production, implying M(L+) > 10 GeV.  相似文献   

20.
Using a target prepared by on-line isotope separation, thermal neutron capture in 84Rb (Iπ = 2?) has been shown to induce proton emission to the ground state (0+) and first excited state (2+) of 84Kr. The branching ratio was measured as Γp(0+)Γp(2+) = 4.7 ± 0.7, favouring a 32? assignment of the capturing state without excluding 52?, and the (nth, p) cross section as 12 ± 2 b. The energy available for the process was determined to be 3.45 ± 0.01 MeV, in agreement with other mass data in the region.  相似文献   

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