Verification of the laws of luminescence of solids for manganese complexes of benzyl-trimethylammonium and 2-chloropyridinium

A formula at low temperature for the function G($\text{1}\text{λ}$) = I_λλ⁶ has been derived in terms of configuration curve theory and checked on luminescence spectra near 77 K. The vibrational quantum in the excited state has been calculated from the decrease of G($\text{1}\text{λ}{}_{\mathrm{M}}$), where λ_M is the wavelength of the maxima of G at low temperature, as a function of temperature.     

Nature of the transition in nonlinear spin-S Ising models (half-integer spin)

We consider the spin-S Hamiltonian $\text{H}\text{=-JΣ}{}_{\mathrm{〈i,j〉}}\text{Q}{}_{\mathrm{S}}\text{(S}{}_{\mathrm{i}}\text{)Q}{}_{\mathrm{S}}\text{(S}{}_{\mathrm{j}}\text{)?λΣ}{}_{\mathrm{i}}\text{Q}{}_{\mathrm{S}}\text{(S}{}_{\mathrm{i}}\text{)}$ where Q_S(y) is a polynomial in y of degree 2S whose eigenvalues are ±1 and rigorously show that except for a multiplicative constant, the partition functions for all half-integer values of S are identical.     

Electron-hole interaction in the presence of excitons

We calculate the effective electron-hole interaction V_re in the presence of an exciton gas, which reads in real space:

$\text{V}{}_{\mathrm{re}}\text{(r)=}\text{?e}{}^2\text{r}\text{{1+}\text{∑}\text{i=1}\text{4}\text{(?1)}{}^{\mathrm{i}}\text{C}{}_{\mathrm{i}}\text{exp}\text{(?Z}{}_{\mathrm{i}}\text{r}\text{a}\text{}}$

The parameters C_i and Z_i are given explicitly for GaAs. For this material, we show the binding energy of the exciton is weakly modified so long as $\text{8πR}{}_0\text{?}{}_{\mathrm{ex}}\text{a}{}_0{}^3\text{kT?1}$. (R₀, exciton Rydberg, a₀ exciyon radius, ?_ex exciton density, T temperature).     

Monte Carlo study on dynamical behaviour of spins and spin clusters in the 2D ± J Ising spin-glass

To investigate dynamical (time-dependent) behavior of spins and spin clusters in the two-dimensional ± J Ising spin-glass, we have evaluated the relaxation time τ_i of individual spins by the Monte Carlo simulation. An interesting finding is that, at least in the temperature range $\text{T ? 0.8J}$, most of τ_i are described by $\text{τ}{}_{\mathrm{i}}\text{∝}\text{exp}\text{{}\text{E}{}_{\mathrm{i}}\text{(T ? T}{}_0\text{}}$ with T₀?0.5J (E_i being a constant), which suggests that the system undergoes a glass transition obeying Fulcher's law.     

Dual model for dislocation and disclination melting

We show that defect melting involving dislocations and disclinations is dually equivalent to an extension of an XY model with an energy of the type Σ_{i, j}{[cos(?_iu_j + ?_ju_i) + ? cos ?_iω_j] }, where $\text{ω}{}_{\mathrm{t}}\text{=}\text{1}\text{2}\text{?}{}_{\mathrm{tjk}}\text{?}{}_{\mathrm{j}}\text{u}{}_{\mathrm{k}}$ is the local rotation field. The. model clarifies the proper choice of defect core energies arising from nonlinear elasticity. These permit the pile-up of dislocations to disclinations which is essential for the first order of the melting transition.     

Nonorthogonality corrections in the method of correlated basis functions

A set of normalized linearly independent basis functions φ₁, φ₂, …, φ_j, … generates matrix representatives $\text{H}$ and $\text{N}$ of the Hamiltonian operator and the identity. An orthonormal basis $\text{φ}{}_1$, $\text{φ}{}_2$, …, $\text{φ}{}_{\mathrm{j}}$, … generated by a Löwdin transformation is characterized by the distance in Hilbert space between $\text{φ}{}_{\mathrm{j}}$ and φ_j. The choice of positive definite $\text{N}$${}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ minimizes these distances and maximizes the diagonal elements of $\text{N}$${}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$. Again for positive definite $\text{N}$${}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and a finite basis, 1 ? j ? p, the analysis yields a general theorem on Trace $\text{N}$${}^{\mathrm{<mtext>?n</mtext><mtext>2</mtext>}}$ (? p for all positive and negative integral values of n except n = ?1 and ? p for n = ?1).Sufficient conditions are determined which permit the application of the binomial theorem to the evaluation of the transform of $\text{H}$. Approximate formulas for the energy eigenvalues through third order in nondiagonal matrix elements are presented in a compact form containing characteristic nonorthogonality corrections depending on the exterior or interior location of the matrix element in the perturbation formulas.     

Influence of self-fields on the Vlasov equilibrium and stability properties of relativistic electron beam-plasma systems

The influence of self-fields on the equilibrium and stability properties of relativistic beam-plasma systems is studied within the framework of the Vlasov-Maxwell equations. The analysis is carried out in linear geometry, where the relativistic electron beam propagates through a background plasma (assumed nonrelativistic) along a uniform guide field $\text{B}{}_0\text{e}\text{?}{}_{\mathrm{z}}$, It is assumed that $\text{ν}\text{γ}{}_0\text{? 1}$ for the beam electrons (ν is Budker's parameter, and γ₀mc² is the electron energy), but no a priori assumption is made that the beam density is small (or large) in comparison with the plasma density, or that conditions of charge neutrality or current neutrality prevail in equilibrium. It is shown that the equilibrium self-electric and self-magnetic fields, $\text{E}{}_{\mathrm{r}}{}^{\mathrm{s}}\text{(r)}\text{e}\text{?}{}_{\mathrm{r}}$ and $\text{B}{}_{\mathrm{\theta }}{}^{\mathrm{s}}\text{(r)}\text{e}\text{?}{}_{\mathrm{\theta }}$, can have a large effect on equilibrium and stability behavior. Equilibrium properties are calculated for beam (j = b) and plasma (j = e, i) distribution functions of the form f_b⁰(H, P_θ, P_z) = F(H ? ω_rbP_θ) × δ(P_z ? P₀)(j = b), and $\text{f}{}_{\mathrm{j}}{}^0\text{(H, P}{}_{\mathrm{\theta }}\text{, P}{}_{\mathrm{z}}\text{) = f}{}_{\mathrm{j}}{}^0\text{(H ? ω}{}_{\mathrm{rj}}\text{P}{}_{\mathrm{\theta }}\text{? V}{}_{\mathrm{j}}\text{P}{}_{\mathrm{z}}\text{?}\text{m}{}_{\mathrm{i}}\text{V}{}_{\mathrm{j}}{}^2\text{2}\text{)}$ (j = e, i), where H is the energy, P_θ is the canonical angular momentum, P_z is the axial canonical momentum, and ω_rj (the angular velocity of mean rotation for j = b, e, i), V_j (the mean axial velocity for j = e, i), and P₀ are constants. The linearized Vlasov-Maxwell equations are then used to investigate stability properties in circumstances where the equilibrium densities of the various components (j = b, e, i) are approximately constant. The corresponding electrostatic dispersion relation and ordinary-mode electromagnetic dispersion relation are derived (including self-field effects) for body-wave perturbations localized to the beam interior (r <R_b). These dispersion relations are analyzed in the limit of a cold beam and cold plasma background, to illustrate the basic effect that lack of charge neutrality and/or current neutrality can have on the two-stream and filamentation instabilities. It is shown that relative rotation (induced by self-fields) between the various components (j = b, e, i) can (a) result in modified two-stream instability for propagation nearly perpendicular to $\text{B}{}_0\text{e}\text{?}{}_{\mathrm{z}}$, and (b) significantly extend the band of unstable k_z-values for axial two-stream instability. Moreover, in circumstances where the beam-plasma system is charge-neutralized but not current-neutralized, it is shown that the azimuthal self-magnetic field $\text{B}{}_{\mathrm{\theta }}{}^{\mathrm{s}}\text{(r)}\text{e}\text{?}{}_{\mathrm{\theta }}$ has a stabilizing influence on the filamentation instability for ordinary-mode propagation perpendicular to $\text{B}{}_0\text{e}\text{?}{}_{\mathrm{z}}$.     

Etude des proprietes thermodynamiques d'un groupement tetranucleaire: Application au compose Na3RuO4

The exact eigenvalues spectrum of the spin hamiltonian $\text{H}\text{= ?2}\text{∑}\text{(i, j)}\text{J}{}_{\mathrm{ij}}\text{S}\text{?}{}_{\mathrm{i}}\text{S}\text{?}{}_{\mathrm{j}}$ have been calculated for a tetranuclear cluster formed by four spins 3/2 at the vertices of a lozenge. Two isotrope exchange interactions J₁ and J₂ are able to explain the thermodynamic properties (magnetic susceptibility, entropy, specific heat). A ground state transition from singlet to triplet state occurs when the $\text{J}{}_2\text{J}{}_1$ ratio reaches the value $\text{4}\text{3}$. The magnetic susceptibility data of Na₃RuO₄ fit well with the theoretical values proposed for $\text{J}{}_1\text{K}\text{= (?19,5 K)}$ and J₂/k (?22,5 K).     

Note on conservation laws based upon traceless energy-momentum tensors in flat space-time

In this note we prove the following theorem. If in a flat space-time with metric g_ij(x) treferred to general coordinates xⁱ a vector ξⁱ(x) satisfies (Tⁱ_jξ^j)_;i=0 (semicolon denotes covariant differentiation) for all energy-momentum tensors of the set $\text{{}\text{T}{}^{\mathrm{ij}}\text{T}{}^{\mathrm{i}}{}_{\mathrm{j;i}}\text{=0;g}{}_{\mathrm{ij}}\text{T}{}^{\mathrm{ij}}\text{=0}$; T^ij = T^ji; T^iju_iu_j > 0 (where u_i is a time-like vector)}, then the vector ξⁱ defines a conformal motion. This theorem, which may be considered as a converse (in flat space-time) to a well-known result of Trautman, is a generalization of a result obtained by J. T. ?opuszański and J. Szczucka-Soko?owska [Reports on Mathematical Physics 11 (1977), 153] in which they assumed the vector ξⁱ was a polynomial in Minkowski coordinates.     

Light composite fermions in a dynamical subquark model of pregauge interactions

The masses of composite leptons and quarks are discussed in a “dynamical subquark model of pregauge interactions”. In this model, the leptons and quarks are made of a spinor and scalar subquark with equal mass, M, and the gauge bosons and Higgs scalar of the SU(3)_c×SU(2)_L×U(1)_Y model are made of a subquark-antisubquark pair. The SU(2)_L×U(1)_Y symmetry is spontaneously broken by the composite Higgs scalar and the (scalar) subquark mass parameter is in turn bounded as $\text{M > 5.4}\text{TeV}\text{(=2π(}\text{2}\text{G}{}_{\mathrm{<mtext>F</mtext>}}{}^{\mathrm{?1}}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{where}\text{G}{}_{\mathrm{<mtext>F</mtext>}}$ is the Fermi coupling constant). The spontaneously generated mass of a lepton or quark, m_i⁽ⁿ⁾ (i = 1, 2; n = 1 ～ N_g), is calculated to be: $\text{m}{}_{\mathrm{i}}{}^{\mathrm{(n)}}\text{= r}{}_{\mathrm{i}}{}^{\mathrm{(n)}}\text{= r}{}_{\mathrm{i}}{}^{\mathrm{(n)}}\text{× (4+3N}{}_{\mathrm{<mtext>g</mtext>}}\text{)α}{}_{\mathrm{<mtext>e.m.</mtext>}}\text{(}\text{2}\text{G}{}_{\mathrm{<mtext>F</mtext>}}{}^{\mathrm{?1}}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{/3}\text{6}\text{(=0.35r}{}_{\mathrm{i}}{}^{\mathrm{(n)}}\text{(4+3N}{}_{\mathrm{<mtext>g</mtext>}}\text{)}\text{GeV}\text{),}\text{where}\text{r}{}_{\mathrm{i}}{}^{\mathrm{(n)}}$ are the parameters satisfying that 0 ? r_i⁽ⁿ⁾ ? 1 and Σ (r_i⁽ⁿ⁾)² = 1;N_g is the total number of generations of the leptons and quarks; α_e.m. is the fine structure constant. The appearance of light composite fermions is related to a specific mechanism of generating global chiral symmetries of the leptons and quarks. Global symmetries of scalar subquarks yield chiral symmetries of the leptons and quarks. Our model turns out to satisfy 't Hooft's anomaly conditions on massless composite fermions.     

On the theory of localized spin and phonon excitations in amorphous ferromagnets

Within the framework of a perturbation theory and a quasicrystalline approximation we have solved the linearized equation of motion for the circular spin component S⁺_j = S^x_j + iS^y_j in a one-dimensional amorphous ferromagnet with periodic external excitation of the spin S⁺₀ at site j = 0. It is shown that localized spin modes of the simple form $\text{«S}{}^{\mathrm{+}}{}_{\mathrm{j}}\text{a}\text{?}\text{= S}{}^{\mathrm{+}}\text{(q0) exp[iq}{}_0\text{· R}{}_{\mathrm{j}}\text{- iω(q0) t] exp (-gk?R}{}_{\mathrm{j}}\text{?)}$ with fall-off-length κ^-1 are solutions of the ensemble-averaged equation of motion. On the other hand, we have a damping of extended spin waves according to exp(-Γt). A simple relation is derived between the fall-off-length κ^-1 of localized spin modes and the damping factor Γ of extended spin waves. Analogous results hold for phonons in amorphous materials.     

The external field problem for QCD

In lattice gauge theory, many computations such as the strong coupling expansions, mean field theory, or the few plaquette models require the evaluation of the one-link integral in the presence of an arbitrary N × N complex matrix source (J). For SU(N) gauge theories, we express our general solution to the external field problem as an integral over the maximal abelian subgroup [U(1)]^N?1

where S₀ = 2Σ_kz_k cos(φ_k ? θ), z_j are eigenvalues of √JJ⁺, e^2iNθ=detJ/detJ⁺, and G is an appropriate jacobian determinant. Our explicit solution follows from differential Schwinger-Dyson equations cast in a separable form by using fermionic variables, and the special cases of N = 2, 3 and ∞ agree with earlier derivations.     

On the boundedness of the eigenvalue spectrum of phonon collision operator

Anharmonicity in lattice potential leads to boundedness of the eigenvalue Spectrum of the phonon collision operator. Considering the deviation, ψ_q, in the distribution function of the phonons $\text{N}{}_{\mathrm{q}}\text{, N}{}_{\mathrm{q}}\text{=}\text{N}\text{?}{}_{\mathrm{q}}\text{+}\text{N}\text{?}{}_{\mathrm{q\psi q}}\text{(}\text{N}\text{?}\text{+ 1)}$. bar denoting equilibrium value, as an odd function of the phonon wave vector q it has been possible to obtain a lower bound, μ, on the eigenvalue spectrum of the phonon collision operator P. This satisfies the inequelity relation 0?μ?p_i?λ, where p_i are the eigenvalue of P, and λ is an upper bound on it (as given by Benin). The occurence of μ ensures for the possibility of obtaining a sequence of upper bounds on the lattice thermal transport coefficient.     

Conditions for static balance for the post-Newtonian two-body problem with electric charge in general relativity

The usual condition for static balance, for two bodies with masses and charges m_i and e_i (i = 1, 2), is $\text{e}{}_{\mathrm{i}}\text{=±G}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{m}{}_{\mathrm{i}}$. From a post-Newtonian analysis of the two-body problem, an alternate condition for static balance $\text{e}{}_{\mathrm{i}}\text{=±(Gm}{}_1\text{m}{}_2\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ has been found. We do not know if this condition is exact beyond the post-Newtonian approximation.     

Transverse spin correlation function of the one-dimensional spin-12 XY model

The transverse spin pair correlation function p^x_n=<S^x_mS^x_m+n>=<S^x_mS^x_m+n> is calculated exactly in the thermodynamic limit of the system described by the one-dimensional, isotropic, spin-$\text{1}\text{2}$, XY Hamiltonian

$\text{H=?2J}\text{∑}\text{l=1}\text{N}\text{(S}{}^{\mathrm{x}}{}_{\mathrm{l}}\text{S}{}^{\mathrm{x}}{}_{\mathrm{l+1}}\text{+S}{}^{\mathrm{y}}{}_{\mathrm{l}}\text{S}{}^{\mathrm{y}}{}_{\mathrm{l+1}}\text{)}$

. It is found that at absolute zero temperature (T = 0), the correlation function ρ^x_n for n ≥ 0 is given by

$\text{ρ}{}^{\mathrm{x}}{}_{\mathrm{2p}}\text{=}\text{1}\text{4}\text{2}\text{π}{}^{\mathrm{2p}}\text{Π}\text{j=1}\text{p?1}\text{4j}{}^2\text{4j}{}^2\text{?1}{}^{\mathrm{2p?2j}}\text{if}\text{n=2p}$

,

$\text{ρ}{}^{\mathrm{x}}{}_{\mathrm{2p+1}}\text{=±}\text{1}\text{4}\text{2}\text{π}{}^{\mathrm{2p+1}}\text{Π}\text{j=1}\text{p}\text{4j}{}^2\text{4j}{}^2\text{?1}{}^{\mathrm{2p+2j}}\text{if}\text{n=2p+1}$

, where the plus sign applies when J is positive and the minus sign applies when J is negative. From these the asymptotic behavior as n → ∞ of |?^x_n| at T = 0 is derived to be $\text{|ρ}{}^{\mathrm{x}}{}_{\mathrm{n}}\text{| ～}\text{a}\text{n}$ with a = 0.147088?. For finite temperatures, ρ^x_n is calculated numerically. By using the results for ?^x_n, the transverse inverse correlation length and the wavenumber dependent transverse spin pair correlation function are also calculated exactly.     

On the rotational contributions to the dipole-moment derivatives

In order to get dipole-moment derivatives, $\text{?}\text{u}\text{?}\text{?S}{}_{\mathrm{j}}$ that are free from rotational contributions, we used Crawford's method applied to a new type of reference molecule. The agreement with earlier calculated rotational correction terms is good, the applicability of the new reference molecule is wider. The rotational contributions to the $\text{?}\text{u}\text{?}\text{?S}{}_{\mathrm{j}}$-quantities are presented for a number of C_2v- and C_3v-type molecules.     

Activation energy of field emission flicker noise power due to adsorbed potassium on tungsten

The temperature dependence of the field emission flicker noise spectral density functions has been investigated for potassium adsorbed on tungsten (112) planes by a probe hole technique. By integration of the spectral density functions $\text{W(?) = B}{}_{\mathrm{i}}\text{?}{}^{\mathrm{?ge}}\text{i}$ the noise power $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ for different frequency intervals Δ? is obtained. From the exponential temperature dependence of $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ noise power “activation energies” q_Δ? are determined. Plots of these energies versus coverage show a similar “oscillating” behaviour as recently found for $\text{W(?}{}_{\mathrm{j}}\text{)}$ or which indicates phase transitions of the adsorbed potassium submonolayers. The noise activation energies are discussed in terms of existing models and a comparison is made between the experimental q values and surface diffusion energies E_d as determined by conventional methods.     

The effect of a non-minimally coupled scalar field upon classical thermodynamics

It is known that a scalar field that is non-minimally coupled to the geometry implies a varying gravitational “constant” G_eff, and hence a violation of the continuity equations, $\text{T}\text{?}{}^{\mathrm{ik}}{}_{\mathrm{;k}}\text{≠ 0}$, where $\text{T}\text{?}{}_{\mathrm{ij}}$ is the uncorrected energy-momentum tensor. This in turn upsets classical thermodynamics. 3he simplest resolution of this difficulty is to multiply all energetic quantities by $\text{G}{}_{\mathrm{<mtext>eff</mtext>}}\text{G}{}_{\mathrm{<mtext>N</mtext>}}$, where G_N is the newtonian gravitational constant. This modified thermodynamics is applied to the scalar-field version of the cosmological model of Zee, for which it is shown to cause restoration of the symmetry above some critical temperature T_c close to the Planck temperature. We also illustrate how the second law of thermodynamics is always obeyed, correcting a recent discussion by Davies.     

Exact approach to equilibrium for the glauber model of a one-dimensional Ising system with random ±J bonds

The (discrete-time) Glauber model is considered for a one-dimensional system of spins s_j = ±1 with nearest-neighbor Ising interaction $\text{H}\text{= -Σ}{}_{\mathrm{j}}\text{J}{}_{\mathrm{j}}\text{s}{}_{\mathrm{j}}\text{s}{}_{\mathrm{j+1}}$. The J_j = ±J are treated as random variables with an arbitrary joint probability p(J). The exact time-dependent average 〈s_j〉_t is determined, and from it the “quenched” average $\text{〈〈s}{}_{\mathrm{j}}\text{〉}{}_{\mathrm{t}}\text{〉}{}_{\mathrm{<mtext>av</mtext>}}\text{=Σ}{}_{\mathrm{<mtext>J</mtext>}}\text{p}\text{(}\text{J}\text{)〈s}{}_{\mathrm{j}}\text{〉}{}_{\mathrm{t}}$ is explicitly found.