Elastische und unelastische Streuung von Elektronen an Gasen

The theoretical differential cross section for the elastic scattering and for the excitation of optical transitions in helium by electron impact has been refined in Born approximation by use of the two parameter Eckart eigenfunction for the ground state and for the excited states. The angular distributions of 25 kev electrons scattered elastically and inelastically by helium were measured in the angular range 2·3·10^?4≦?≦4·10^?2. The intensity distribution of the elastically scattered electrons is in accordance with the theoretical curve for?>7·10^?3 and is disturbed at smaller angles by the primary beam. Normalization of the experimental values to the theoretical elastic differential cross section leads to agreement between the experimental differential cross section for the excitation of the 2¹ P and 3¹ P state and the scattering formulae given in this paper. There are small systematic deviations (<20%) for the 2¹ P differential cross section in the angular range 3·10^?3<?<1·10^?2 only. The oscillator strength of these two transitions has been determined from the scattering measurements:f ₂₁=0·312±0·04 andf ₃₁=0·0898±0·006.     

OnE0 transitions in the decay of152Eu m (9.3 h)

The conversion electron spectrum of the decay of¹⁵²Eu ^m (9.3 h) has been specially investigated forE0 transitions with the aid of a magnetic spectrometer and coincidence techniques. Besides the knownE0 transitions of 685 keV in¹⁵²Sm and 615 keV in¹⁵²Gd two further pureE0 transitions of 432 keV and 1048 keV have been observed. It is shown that theseE0 transitions are identical with those observed previously in the decay of¹⁵²Tb. NoE0 transitions could be found from a 0⁺ state of 1083 keV in¹⁵²Sm. The measured intensities together with the gamma spectrum measured by Barretteet al. give a consistent decay scheme of¹⁵²Eu ^m . Furthermore the half-life of the 0⁺ level at 615 keV in¹⁵²Gd was measured using the method of “delayed coincidences”. The result was (0.2≦t _1/2≦2.1)×10^?10 s. From this theE0 transition probability for the level was derived as (0.3≦W _K (E0)≦3.7)× 10⁹ s^?1 and theρ-value as 0.10≦¦ρ¦≦0.36. The results are discussed within the framework of the collective model.     

Diffusion of titanium in slightly reduced rutile

The self-diffusion of ⁴⁴Ti in slightly reduced rutile. TiO_2?δ, was measured along the c axis over the temperature range of 1000–1100°C between 0.2 and 1 × 10^?18atm. oxygen pressure. These measurements enabled the determination of the defect structure of TiO_2-δ for 0.02 ?gd ? 0.001. For oxygen pressures between 1 × 10^?13 and 1 × 10^?16atm. at 1058.4°C random tetravalent titanium atoms are the predominant defects evident from self-diffusion. The enthalpy of motion was determined as ΔH_m = 57.03 ± 4.9% kcal/mole. From the activation energy at 1.69 × 10^?16atm., the enthalpy of formation for tetravalent titanium interstitials was determined as ΔH_f = 276 ± 15.6% kcal/mole.For oxygen pressures less than 1 × 10^?16atm. at 1058.4°C, the tracer diffusion coefficient shows a continuous decline as the oxygen pressure is lowered. Comparisons with thermogravimetric studies and consideration of the similarity in structure between nonstoichiometric point defect phases and the first homologous series phase indicate that the order-disorder transition retains a considerable degree of short range order below the critical concentration in the form of Wadsley defects.     

Experimental investigation of excitation of argon metastables by an electron swarm in argon nitrogen gas mixtures

Excitation of argon metastable levels (4³ P ₂+4³ P ₀) in a nonselfsustained discharge in Ar(≧99%)+N₂(≦1%) gas mixtures has been investigated by measuring N₂ second positive group which is the result of excitation transfer from Ar metastables to N₂ molecules. The method is based on the assumption, experimentally verified, that addition of small quantities of N₂ do not change markedly the probability of Ar excitation. The obtained excitation coefficients for production of Ar ^m in theE/N range (20–70)×10^?21Vm² are (3.5–13)×10^?22m² with an estimated uncertainty of ±50%. Simultaneously, excitation coefficients for direct excitation of nitrogenC-state by swarm electrons in Ar-N₂ mixtures have been obtained. A comparison of nitrogen spectra excited by electrons and by argon metastables showed significant differences in relative population of vibrational and rotational levels of the N₂(C ³ Π _U state in these two cases.     

Low mass-scale parity restoration in expanded gauge theories

It is shown that schemes of grand unification withSU(2n)⁴ gauge symmetry permit the embedding of the left-right symmetricSU(2) _L ×SU(2) _R ×U(1)×SU(3) ^c intermediate symmetry at relativelylow energies [between 250 GeV and a few TeV] as well as allows light unification mass-scales (≦10⁵ TeV) ifn≧3 for values of the weak angle Sin² θ _W and the strong coupling α _S in the ranges 0.20≦Sin² θ _W ≦0.25, 0.10≦α _S ≦0.15.     

Supertransferred hyperfine structure in EPR of V4+ ion in Ca3In2Ge3O12 garnet

Interaction of an unpaired electron of the tetrahedral V⁴⁺ ion in Ca₃In₂Ge₃O₁₂ garnet with the four nearest In nuclei gives rise to clearly resolved structure of EPR spectra. We report the observation and analysis of these spectra at three frequencies and at temperature 77 K. The temperature dependence between liquid helium and the room temperatures was also studied. Parameters of the spin Hamiltonian are g_∥=1·8735; g_⊥=1·9825; ∣ ¦A∥|=150·4×10^?4cm^?1; ¦ A_⊥¦ = 36·7 × 10^?4 cm^?1. The supertransferred hyperfine interaction was found to be isotropic, absolute value of the corresponding parameter a is 22·1 × 10^?4 cm^?1.     

Nuclear magnetic relaxation by self-diffusion in solid lithium:T 1-frequency dependence

We report on measurements of the⁷Li nuclear spin relaxation timeT ₁ in solid lithium as a function of temperature (?170°C≦T≦+180°C) and Larmor frequency (450kHz≦v _Li≦31.5 MHz). Using a relaxation model developed by Wolf and Cavelius and combining it with Seeger's diffusion formalism, the diffusion parameters for mono-and divacancy migration were evaluated by a least squares fit to the newly obtainedT ₁ data as well as to previousT _1? measurements. The result for the self-diffusion coefficientD ^SD is given byD ^SD=D ₁₀·exp(?Q ₁/RT)·[1+D ₂₁·exp(?Q ₂₁/RT)], withD ₁₀=0.038 cm²s^?1,Q ₁=12.0 kcal mol^?1,D ₂₁=250,Q ₂₁=4 kcal mol^?1 andR=1.98₅·10^?3 kcal mol^?1 degree^?1. Due to the flexibility of Seeger's formula, which contrasts with the standard Arrhenius interpretation of diffusion, discrepancies between earlier high- and low-frequency NMR investigations were eliminated. Furthermore, an excellent agreement with available results from tracer experiments was achieved by taking into account the theoretical predictions of the isotope effect and the vacancy correlation factor.     

Estimation ofv μ→v τ oscillation parameters in the E-564 hybrid experiment

The limits on the parameters of thev _μ→v _τ oscillations are obtained in the E-564 hybrid experiment: Δm ²≦4.5 eV² and sin²(2θ)≦6.0·10^?2 (90% CL). A possibility of direct observation of τ-lepton decays in the nuclear emulsion vertex detector allowed the sensitivity of this experiment to the parameters of the oscillations to be increased.     

SU(7) Electroweak unification

Electroweak unification is obtained in anSU(7) model at a mass scale 3×10¹⁰≦M≦3×10¹⁶ GeV's, with left-right symmetric subgroups and sin² θ _w (M)=3/8. BelowM, the model reduces toSU(3) _L ×SU(3) _R , the flavor sector of the “trinification theory” of Glashow et al., or of theE ₆ grand unified theory. This model predicts a natural massless neutrino, and fractionally charged leptons with masses in theM regime.     

Transport and magnetic properties of multiwall carbon nanotubes before and after bromination

Bulk samples of oriented carbon nanotubes were prepared by electric arc evaporation of graphite in a helium environment. The temperature dependence of the conductivity σ(T), as well as the temperature and field dependences of the magnetic susceptibility χ(T, B) and magnetoresistance ρ(B, T), was measured for both the pristine and brominated samples. The pristine samples exhibit an anisotropy in the conductivity σ_∥(T)/σ_⊥>50, which disappears in the brominated samples. The χ(T, B) data were used to estimate the carrier concentration n ₀ in the samples: n _0ini ～3×10¹⁰ cm^?2 for the pristine sample, and n _0Br～10¹¹ cm^\t—2 for the brominated sample. Estimation of the total carrier concentration n=n _e+n _p from the data on ρ(B, T) yields n _ini=4×10¹⁷ cm^?3 (or 1.3×10¹⁰ cm^?2) and n _Br=2×10¹⁸ cm^?3 (or 6.7×10¹⁰ cm^?2). These estimates are in good agreement with one another and indicate an approximately fourfold increase in carrier concentration in samples after bromination.     

High-precision evaluation of the magnetic moment of the helion

NMR spectra of samples containing a mixture of hydrogen deuteride HD with pressure of about 80 atm and helium-3 with partial pressure of about 1 atm are analyzed. The ratio of the resonance frequencies of the nuclei, F(³He)/F(H₂), is determined to be 0.761786594(2), which is equal to the magnetic moment of the helion (bound in a helium atom) in the units of the magnetic moment of a proton (bound in molecular hydrogen). The uncertainty of two digits in the last place corresponds to a relative error of ??[F(³He)/F(H₂)] = 2.6 × 10^?9. The use of the known calculated data on the shielding of nuclei in the helium-3 atom (??(³He) = 59924(2) × 10^?9) and on the shielding of protons in hydrogen (??(H₂) = 26288(2) × 10^?9) yields a value of ??(³He)/?? _p = ?0.761812217(3) for the free magnetic moment of the helion in the units of the proton magnetic moment.     

Chemi-ionization and spin exchange upon collisions of metastable helium atoms with potassium atoms in the ground state

The spin exchange and chemi-ionization cross sections have been calculated for the metastable helium atom-potassium atom system in the ground state. The data on the spin exchange cross section in the system He(2³ S ₁)-K(4² S _1/2) have been obtained for the first time. The cross sections were calculated for the collision energies ranging from 2 × 10^?4 to 60 × 10^?4 au The chemi-ionization cross sections obtained have been compared with the data in the literature.     

Accurate lifetime measurements for the noble gases by the electron beam alignment technique

Rotational rainbow scattering has been measured in the systems K- and Rb-CO₂ at collision energies 0.17≦E≦0.56 eV and CMS angles 110°≦?≦170°. The ellipsoidal hard shell anisotropy of the normal (repulsive) potentials is evaluated to be (c?a)=0.67Å in K?CO₂, (c?a)=0.63Å in Rb?CO₂, averaged over a slight energy dependence. Below an apparent activation thresholdE _a?0.23 eV, nearly equal in both systems, the scattering largely conforms to that of diatomic molecules, indicating linear, rigid rotor type behaviour as the dominant collisional response of triatomic CO₂. AboveE _a characteristic, eventually drastic distortions set in. They are probably caused by intermediary charge transfer which activates a complex, coupled vibrational, rotational motion inM ⁺-CO ₂ ^? , altering the outcome of the collisions altogether. The simple model of a partially absorptive, hard shell is used to find that some gross features of the distortions are consistent with distinct properties of the acceptingelectronic orbital 6a ₁ in CO ₂ ^? .     

Determination of iodide in urine based on chemiluminescence system of cerium (IV)–tween 40–iodide

In acidic medium, the oxidation reaction of cerium (IV) with iodide can produce strong chemiluminescence (CL) in the presence of surfactant tween 40 as an enhancer. On this basis, a flow injection method with CL detection was established for the determination of iodide. The method is simple, rapid and effective to determine iodide in the range of 8.0×10^?8–5.0×10^?5 mol/L with a determination limit of 5.0×10^?8 mol/L. The relative standard deviation is 2.7% for the determination of 5.0×10^?6 mol/L iodide (n=11). The method has been applied to determine the content of iodide in urine with satisfactory results. Furthermore, it is suggested that the light emission from cerium (IV)–tween 40 reaction is probably because of the formation of singlet oxygen ¹O₂^? and the emitter is excited oxygen molecular pairs O₂(¹Δ_g)O₂(¹∑_g^?).     

Drift mobility measurements in melt-grown baryum titanate

Drift mobility measurements in melt-grown BaTiO₃ single crystal have been performed using the Spear method. The mobility of (3 ± 1) × 10^?3 cm²V^?1 sec^?1 at room temperature is found to be thermally activated, with an activation energy of 0.15 ± 0.04 eV. Two interpretations are investigated to explain these results: trapping effects due to oxygen vacancies or small polaron hopping.     

The anomalous magnetic moment of positive and negative muons

The anomalous g-factor a ≡ (g?2)/2 has been measured for muons of both charges in the Muon Storage Ring at CERN. The two results, a_μ⁺ = 1165910(12) × 10^?9 and a_μ^? = 1165936(12) × 10^?9, are in good agreement with each other, and combine to give a mean a_μ = 1165922(9) × 10^?9, which is very close to the most recent theoretical prediction 1165921(10) × 10^?9. For the experimental results, the total statistical and systematic error is given. The measurements thus confirm the remarkable QED calculation plus hadronic contribution, and serve as a precise verification of the CPT theorem for muons.     

Absolute intensity measurements of the CO2 bands 401III←000 and 411III←010

The absolute intensities of the transitions 401_III←000 and 411_III←010 of CO₂ have been measured from spectra obtained under high resolution. Both the vibration-rotation line intensities and the integrated band intensities are reported. The rotationless transition moment of 401_III←000 is deduced and a vibration-rotation interaction factor F(m) = 1+(4.92×10^?4)m+(4.4×10^?7)m² is determined. The values obtained are: S_Band(401_III←000) = (25.54±0.22)×10^?5 cm^?2atm_{(293 K)}^?1, |R₀₀₀^401_III| = (1.87±0.02)×10^?4D, and S_Band(411_III←010) = (1.83±0.13)×10^?5 cm^?2atm_{(293 K)}^?1.     

Reversal of sign of the Hall coefficient in n-InSb in the magnetic freeze out regime

Change in sign of the Hall coefficient has been observed in n-InSb with carrier concentrations ranging from 2 × 10¹⁴ cm^?3 to 6 × 10¹⁴ cm^?3, which occurs at liquid helium temperatures and magnetic fields above 30 kG. The influence of the compensation ratio, temperature, and geometry has been investigated.     

Nuclear magnetic resonance of intermetallic compounds Gd2Ni17−xAlx

²⁷Al Knight shifts vs temperature and magnetic susceptibility for the intermetallic compounds Gd₂Ni_17?xAl_x (x = 17; 16.2; 16; 15) are presented. The results are discussed in terms of the uniform polarization model fo the conduction electrons by the 4f and 3d spins localized on the Gd and Ni ions. The phenomenological exchange constants J_sf and J_sd range between ?1.80×10^?3 and 1.19×10^?3 eV and ?0.63×10^?3 and ?0.52×10^?3 eV, respectively.