Two-frequency correlation of photon echo signals in a medium excited by a few-cycle pulses

Two-frequency correlation between the profiles of signals of the primary and long-lived (stimulated) photon echos in a three-level medium excited by combined sequences of resonance quasimonochromatic (encoding) signals and femtosecond pulses consisting of a few optical oscillations (down to one) is predicted. It is shown that the profiles of echo responses of both frequencies correlate with each other and with the profiles of encoding pulses, copy them, and induce mirror rotations, as well as scaling transformations in time in dependence on the methods of forming exciting sequences.     

Selective detection of echoEPR signals due to naturally substituted13C radicals in a single crystal of ammonium tartrate

Echo-detected electron paramagnetic resonance (echoEPR) profiles for irradiated deuterated ammonium tartrate single crystals depend strongly on the delays between pulses of the echo sequence. This is mainly due to instantaneous and spectral diffusion that plays a crucial role in determining the decay of the echo at every field position: the dephasing rate 1/7_M depends on the number of spins excited by the pulses and on the total number of interacting spins. A rigorous simulation of the echoEPR profiles at different delays requires the evaluation of the modulation pattern (ESEEM) and of the dephasing processes at every field position. From the simulations, information on the microscopic radical concentration, and on the electron-electron flip-flop rates of the single radical species can be obtained. Natural isotope¹³C substitution generates low-concentration radicals with relaxation properties different from the equivalent¹²C-substitued radicals. The different behavior is discussed.     

The influence of the skin effect on gamma detected pulsed NMRON signals

The influence of the skin effect on single and triple (spin echo) gamma detected pulsed NMRON signals is calculated using a density matrix approach within a pure Zeeman manifold. For single pulse NMRON the turn angle dependences of the signals for uniform and exponential profiles of the resonant nuclei are presented for a typical inhomogeneous broadening applicable to intermediate mass impurities in ferromagnetic hosts. For triple pulse NMRON the baseline and principal spin echo amplitudes for equal resonant rf pulses are presented for the same inhomogeneous broadening. It is found that the skin effect leads to the form of pulsed NMRON signals that are in accord with experiment.     

Stimulated spin echo upon excitation with pseudorandom pulses

Different regimes of excitation of a stimulated spin echo by pseudorandom pulses and short coherent delta-shaped pulses are considered. Radio pulses phase-shifted by a 127-element M sequence are used as pseudorandom signals. The shape of the complex envelope of the stimulated echo is simulated in linear and nonlinear regimes with respect to the phase-shifted pulses. It is demonstrated that the excitation pulses can be described by correlation functions. Appropriate conditions are determined under which the amplitude of the stimulated echo can be greater than the amplitude corresponding to the classical algorithm used for exciting a stimulated echo by three delta-shaped pulses. The results obtained can be used for analyzing the formation of a stimulated photon echo.     

Selective refocusing pulses in magic-angle spinning NMR: characterization and applications to multi-dimensional protein spectroscopy

Band-selective pulses are frequently used in multi-dimensional NMR in solution, but have been used relatively less often in solid-state NMR applications because of the complications imposed by magic-angle spinning. In this work, we examine the frequency profiles and the refocusing efficiency of several commonly employed selective general rotation pi pulses through experiments and numerical simulations. We demonstrate that highly efficient refocusing of transverse magnetization can be achieved, with experiments that agree well with numerical simulations. We also show that the rotational echo is shifted by a half rotor period if a selective pulse is applied over an integer number of rotor periods. Appropriately synchronizing indirect evolution periods with selective pulses ensures proper phasing of cross peaks in 2D spectra. The improved performance of selective pulses in multi-dimensional protein spectroscopy is demonstrated on the 56-residue beta1 immunoglobulin binding domain of protein G (GB1).     

Forward masking as a mechanism of automatic gain control in odontocete biosonar: a psychophysical study

In a false killer whale Pseudorca crassidens, echo perception thresholds were measured using a go/no-go psychophysical paradigm and one-up-one-down staircase procedure. Computer controlled echoes were electronically synthesized pulses that were played back through a transducer and triggered by whale emitted biosonar pulses. The echo amplitudes were proportional to biosonar pulse amplitudes; echo levels were specified in terms of the attenuation of the echo sound pressure level near the animal's head relative to the source level of the biosonar pulses. With increasing echo delay, the thresholds (echo attenuation factor) decreased from -49.3 dB at 2 ms to -79.5 dB at 16 ms, with a regression slope of -9.5 dB per delay doubling (-31.5 dB per delay decade). At the longer delays, the threshold remained nearly constant around -80.4 dB. Levels of emitted pulses slightly increased with delay prolongation (threshold decrease), with a regression slope of 3.2 dB per delay doubling (10.7 dB per delay decade). The echo threshold dependence on delay is interpreted as a release from forward masking by the preceding emitted pulse. This release may compensate for the echo level decrease with distance, thus keeping the echo sensation level for the animal near constant within a certain distance range.     

Determination of pore space shape and size in porous systems using NMR diffusometry. Beyond the short gradient pulse approximation

The influence of finite length gradient pulses on NMR diffusion experiments on liquids confined to diffuse between two parallel planes is investigated. It is experimentally verified that the pore size decreases when determined using finite gradient pulses if the results are analyzed within the short gradient pulse approximation. The results are analyzed using the matrix formulation. The observed minima in the echo decay profiles are considerably less sharp than theoretical analysis would indicate and we suggest that this is due to the presence of a distribution of pore sizes in the sample. In addition, effects due to the presence of background gradients are discussed. It is argued that effects due to the finite length gradient pulses are relatively minor and in realistic applications the effects due to inhomogeneities in pore sizes and effects due to background gradients will constitute more serious problems in pore size determinations by means of NMR diffusometry.     

脉冲激光测距回波信号时间选通处理技术

为了降低高重频脉冲激光测距回波信号的误识别率,提高测距性能,对高重频脉冲激光测距回波信号调理技术进行深入研究。采用FPGA作为主控芯片,产生激光调制脉冲,并根据被测距离3.33 μs～33.33 μs时间选通方波信号,驱动开关芯片产生与量程关联的时间波门,有效滤除脉冲回波中的干扰脉冲,该方法改进了常规脉冲激光测距信号处理系统的自动增益控制环节。测试实验结果表明:在脉冲回波信号60 dB的动态范围内,可有效滤除回波信号中引入的干扰脉冲,极大地降低了干扰脉冲误识别造成粗大误差的可能性。该方法可推广应用于脉冲激光测距信号处理系统,使系统测距精度提高12.6%。     

Femtosecond photon echo in dye-doped polymer films at room temperature

The signals of primary and stimulated femtosecond photon echo in polymer films doped with dye (phthalocyanine) molecules have been experimentally investigated at room temperature. A femtosecond echo spectrometer for these echo experiments is described. The decay curves of echo signals with increasing time intervals between excitation femtosecond pulses are obtained and blue shifts of the spectra of femtosecond echo signals with respect to the spectrum of excitation pulses are revealed. The possibilities of using the studied doped polymer films as recording media for high-temperature echo processors and coolants in optical refrigerators are analyzed.     

Excitation of photon echo by noise pulses

The excitation of photon echo by noise pulses that are formed by modulation of the carrying frequency with Gauss noise is modeled. The modeling is based on optical Bloch equations the solution of which for noise pulse realizations is constructed by their stepwise approximation. In terms of the formalism of state transfer matrices, the two- and three-pulse excitation modes are analyzed. The complex envelopes of the primary and stimulated echo responses are determined. In the linear (low-level-signal) mode, the shape of the two-pulse echo corresponds to that of the time delayed and inverted noise pulse. The boundary of the linear mode, upon exceeding of which distortions of the shape of the noise pulse become noticeable, is determined. The shape of the stimulated (three-pulse) echo in the linear mode corresponds to that of the autocorrelation function of the noise pulse realization. Upon passage beyond the boundary of the linear mode, the shape of the three-pulse echo corresponds either to the cross-correlation function of distorted noise pulses (with different intensities) or to the autocorrelation function of distorted pulses (with the same intensities). The modeled photon echo excitation modes can be used in photon echo processors to process signals in the light range.     

Coherent population control and three-pulse photon echoes: Their dependence on phase of excitation pulse

We discuss analytically here coherent population control and photon echoes of two-level atoms excited by two excitation pulses of different characteristics: (i) the excitation pulses with the same carrier-envelope phases and (ii) the excitation pulses, which are obtained by intensity-modulation of a continuous-wave laser beam and are free from incidental phase- and frequency-modulation. A perturbative calculation, which includes the effect of relaxations during pulse excitations shows that both the coherently controlled population and the echo field show considerably different behaviors depending on the characteristics of the excitation pulses. We also find that the peak position of the echo field can be controlled by adjusting the pulse widths of the excitation pulses.     

Stimulated photon echo under excitation by incoherent and coherent pulses

Excitation of stimulated photon echo by two incoherent pulses obtained from one source and one coherent pulse is considered. The dependence of the average amplitude of stimulated echo on the parameters of noise pulses is determined. The results can be used for analysis of the corresponding algorithm of excitation of stimulated spin echo, as well as in calculations of characteristics of the signal processors based on the phenomena of photon and spin echoes.     

Primary acoustic echo during excitation of a paramagnetic crystal by picosecond elastic video pulses

The primary acoustic echo formed during excitation of a paramagnetic crystal with effective spin S=1 by two transverse picosecond elastic video pulses is investigated theoretically. Both exciting video pulses are applied perpendicular to the external magnetic field. It is shown that the primary acoustic echo in the general case consists of six longitudinal and transverse signals at the frequencies of the transitions within a Zeeman triplet. The optimal parameters of the exciting video pulses for the appearance of different echo signals are determined. Fiz. Tverd. Tela (St. Petersburg) 41, 623–628 (April 1999)     

Photon echo excited in multilevel quantum media by ultimately short pulses

The photon echo excitated in a multilevel quantum medium by two or more ultimately short pulses with duration down to one period of optical oscillations is studied theoretically. It is shown that the number of echo responses formed in the system depends on the number of quantum levels covered by the spectrum of the exciting pulses and strongly increases with this number. General equations for the spatio-temporal characteristics of the multipulse echo signals are obtained.     

Compensation of refocusing inefficiency with synchronized inversion sweep (CRISIS) in multiplicity-edited HSQC

Use of adiabatic pulses in broadband inversion and decoupling is well known. Replacement of the rectangular pi pulses in the INEPT and rev-INEPT parts of the HSQC and gHSQC experiments with adiabatic pulses substantially improves the sensitivity of these experiments. However, modulation of cross peak intensity in multiplicity-edited HSQC or gHSQC experiments can be quite severe. These modulations arise during the multiplicity-editing periods due to the inefficient refocusing of the spin-echo caused by the mismatch of the echo delay with the one-bond coupling constant. These modulations (which we call echo modulations) are field strength (and hence spectral width) independent. Use of adiabatic pulses with the inversion sweep synchronized to the 1H-13C coupling constant range typically observed in a 13C spectrum will provide substantial improvement in sensitivity. The inversion profile problems associated with rectangular pi pulses can be moderately compensated by composite pulse schemes and these schemes could prove to be reasonable alternatives to adiabatic pulses. However, the adiabatic sweep provides a unique method to compensate the echo modulations for multiplicity-edited experiments. The origin and the compensation of refocusing inefficiency with synchronized inversion sweep (CRISIS) method to minimize these modulations is described.     

The nuclear spin-echo signals under combined action of magnetic field and RF pulses

The effect of a pulse magnetic field on formation of the single-pulse echo signal in some magnetic materials has been studied. The signals of nuclear-spin echo formed by the combined action of radio frequency and magnetic pulses have been observed. The duration of the magnetic pulse was only limited by the length of the radio frequency pulse. The echo signal formed by the two magnetic pulses, the edges of a long magnetic pulse, and other situations that allowed us to reproduce the analogue of multipulse action, were observed as well.     

螺纹边界法对圆柱超声缓冲杆尾随脉冲干扰的抑制*

对于高温管道壁厚的超声波在线监测,需要超声波探头与缓冲杆搭配使用,以降低探头的接触温度。超声波在圆柱形缓冲杆的边界会发生波型转换,在缓冲杆的第一次和第二次底面回波之间产生等间隔的尾随脉冲干扰,影响管道内壁回波的识别与提取。该文创新性地采用螺纹边界法改变缓冲杆的边界特征以抑制尾随脉冲干扰,经实验验证螺纹边界法对尾随脉冲干扰有较好的抑制效果;不同螺纹螺距的实验对比表明,对于直径为20 mm的钢材料圆柱缓冲杆,在1 mm、2 mm和3 mm三种螺距中,螺距为2 mm的螺纹边界对5 MHz超声波的尾随脉冲干扰的抑制效果最强。     

结合脉冲梯度场(PFG)的选择性形状脉冲的相位特性研究

从转动矩阵理论与实验两方面研究了结合脉冲梯度场的选择性形状脉冲的相位特性,结果表明:单梯度自旋回波(SPFGSE)和双梯度自旋回波(DPFGSE)对于对称和反对称的形状脉冲,都能很好地克服其相位畸变;而双梯度自旋回波(DPFGSE)对于非对称的形状脉冲也能克服其相位畸变;双选择性单梯度自旋回波无法克服形状脉冲的相位畸变.     

Raman echo induced by ultimately short pulses under conditions of strong nonresonant pumping

On the basis of quantum-mechanical approach, a theoretical study of the primary Raman photon echo was carried out under conditions of excitation of a medium by pulses with a duration on the order of one period of electromagnetic oscillations (ultimately short pulses) and by strong quasi-monochromatic nonresonant pumping. It is shown that the intensities of the pumps determine to a considerable extent the time of formation of the echo signal, its duration, the direction of emission, and the power and that the use of ultimately short pulses promotes the substantial simplification of the schemes of prospective experiments. The possibilities of echo generation at the Stokes and anti-Stokes frequencies in the regimes of two-, one-, and zero-pulse excitations are revealed. In the last case, the Raman-active transitions are excited by two pumps with different intensities.     

The Spatial Dependence of Spin-Echo Signals

The signals in NMR spin echoes which are refocused by 90° pulses are spatially modulated. The spatial modulation is not normally observed in images or profiles obtained using Hahn or stimulated echoes, but may cause errors if the sample structure varies on the distance scale of the modulation. Localized spectra measured using stimulated echoes will also show errors under these conditions. Simple Fourier-transform arguments show that conditions which allow the modulation to become visible in an image or profile have the effect of introducing a second echo into the time-domain acquisition window. Phase cycling may be used to remove the spatial dependence of the signals.