共查询到20条相似文献,搜索用时 0 毫秒
1.
I. Olmez G. S. Kowalczyk G. H. Harrison 《Journal of Radioanalytical and Nuclear Chemistry》1985,94(6):391-397
The determination of 15 elements: Pb, Sr, Ba, ti, Ca, Sc, Cs, Zr, Rb, Cr, Se, Ni, Y, Co and Zn was investigated by fast neutron activation analysis using 80 MeV deuterons on various environmental samples. Detection limits of these elements from interference-free spectra were calculated. 相似文献
2.
A. El Abd A. M. Abdel-Monem A. M. Osman 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(2):1293-1301
A method was proposed for bulk hydrogen analysis. It is based on simultaneous detection of transmitted fast neutrons and back scattered thermal neutrons from the investigated samples by 3He detectors. The fast neutron beams were obtained from 252Cf and Pu–Be neutron sources. The experimental set-up as well as samples preparation were described. Incident thermal neutrons beams obtained from either 252Cf or Pu–Be sources, were used to investigate the samples by neutron backscattering. The results obtained from transmission and backscattering of fast neutrons were compared and discussed. The advantage and capabilities of the proposed method were presented. The results obtained using fast neutron beams are more sensitive than those obtained using thermal neutron beams. Validation procedures were proposed to credit the results. 相似文献
3.
The possibilities of using hafnium irradiation filters for reactor fast neutron activation analysis have been evaluated. The filter characteristics of hafnium for this application are discussed and compared with some traditional filter materials. The main advantage for hafnium is its ability to remove a great portion of the slowing down neutrons, which may enhance the sensitivity of determination via threshold reactions. 相似文献
4.
Oganesyan VS Barclay JE Hardy SM Evans DJ Pickett CJ Jayasooriya UA 《Chemical communications (Cambridge, England)》2004,(2):214-215
The potential of NIS spectroscopy to study the iron-sulfur clusters in metalloproteins is illustrated using model compounds. The origin of the intense low energy transfer bands is discussed. 相似文献
5.
If a pneumatic tube in an experimental hole of a reactor is covered with a cadmium jacket, a sample inserted in the pneumatic
tube will be exposed to not only fast and epithermal neutrons but also the few thermal neutrons that will not have been obstructed
by the jacket. To obtain a simple method of estimation for the flux of these thermal neutrons, a formula has been made. The
ratio of change in thermal-neutron flux due to the setting of the jacket has been expressed as a function of 5 dimensionless
numbers. The formula enables one to design a well-proportioned jacket. 相似文献
6.
John Avery 《Journal of mathematical chemistry》2000,27(4):279-292
The generalized Sturmian method for solving the many-electron Schrödinger equation is reviewed. This method yields rapidly convergent solutions directly, without the use of the SCF approximation. As a simple illustrative example, differential cross sections are calculated for inelastic scattering of fast electrons by atoms and ions in the 2-electron isoelectronic series. 相似文献
7.
S. A. Bakiyev A. A. Kist Zh. Rakhmanov E. S. Flitsiyan 《Journal of Radioanalytical and Nuclear Chemistry》1991,147(1):59-68
The neutron sources based on the252Cf isotope and having relatively long half-lives and the highest specific neutron yields compared with other ampouled sources are proved to be the most convenient for use in industrial analytical laboratories situated far from the basic nuclear centers. Research making use of californium sources is currently carried out in a number of nuclear centers of the USSR, including the Institute of Nuclear Physics of the Uzbek Academy of Sciences, where a great amount of work have been done on verification of practical use of Cf sources of various activity in different branches of industry, first of all, in geology and mining industry. 相似文献
8.
C. M. Castaneda R. Gearhart B. Sanii P. A. J. Englert D. M. Drake R. C. Reedy 《Journal of Radioanalytical and Nuclear Chemistry》1992,160(2):387-393
Planetary gamma-ray spectroscopy can be used to chemically analyze the top soil from planets in future planetary missions. The production from inelastic neutron interaction plays an effective role in the determination on the C and H at the surface. The gamma-ray production cross section from the strongest lines excited in the neutron bombardment of Fe have been measured by the use of a time analyzed quasi-mono-energetic neutron beam and a high purity germanium detector. The results from En=6.5, 32, 43, and 65 MeV are presented. 相似文献
9.
H. Münzel F. Michel P. P. Coetzee V. Krivan 《Journal of Radioanalytical and Nuclear Chemistry》1977,37(1):267-273
The possible application of cyclotron-produced fast neutrons to activation analysis for oxygen based on the16O(n, p)16N reaction has been investigated. Neutrons were produced by bombarding a thick beryllium target with 22 to 45 MeV deuterons.
It was found that the sensitivity increases rapidly with the energy of the deuterons. Using 45 MeV deuterons and a 10 μA beam
current a sensitivity of about 20 counts per 1 μg oxigen could be achieved, enabling the determination of less than 1 μg oxigen.
In a direct comparison it was experimentally established that the sensitivity for cyclotron-produced neutrons assuming a deuteron
beam of about 10 μA, is up to two orders of magnitude higher than that achievable for 14 MeV neutrons with a flux of about
1010 n/s. The interference of fluorine is at about the same level for both the cyclotron-produced and 14 MeV neutrons. Using cyclotron-produced
fast neutrons in the investigated energy range, sodium and magnesium can also interfere, but only to a very much lower extent. 相似文献
10.
In a test of the utility of neutron inelastic spectroscopy (NIS) for studying molecular vibrations in surface reactions, we have examined the adsorption, co-adsorption, and reaction of hydrogen and carbon monoxide on Raney nickel catalysts. 相似文献
11.
Dosimetry of fast neutrons in 1W nuclear reactor with plastic nuclear-track detectors 总被引:1,自引:0,他引:1
A nuclear reactor at Kinki University is operated at the maximum of 1W. It produces fission neutrons as much as gamma-rays. To facilitate its use for neutron radiobiology, fast neutrons inside the reactor were measured with nuclear-track detectors TS 16 N and a pair of ion chambers. The angular dependence of TS 16 N response, an anisotropy of fast neutron fluxes in the reactor and misuse of the kerma factor assumed for radiation protection business are the major causes of discrepancy is measured doses by the two methods. Correction factors for the three causes are proposed. After correction, neutron doses estimated with TS 16 N and chambers agree within 5%. The dose-rate at the reactor's center is about 20 tissue-cGy/h. This is the first in situ dosimetry of fast neutrons in a reactor with track detectors attached to biologic samples. Our routine usage has demonstrated that, if used with caution, TS 16 N elements are handy, reliable monitors for fast neutron dosimetry as they are insensitive to contaminated gamma-rays and small enough to be attached to biologic samples. 相似文献
12.
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14.
A. J. Filo J. W. Gilbert S. W. Yates 《Journal of Radioanalytical and Nuclear Chemistry》1979,54(1-2):235-239
The detection of prompt γ-rays produced by the inelastic scattering of fast monoenergetic neutrons has been used to determine
the elemental composition of soil samples. Multigram samples were bombarded with 2.5 MeV neutrons, and concentrations were
measured by analyzing the spectrum of emitted γ-rays. Particular emphasis has been placed on the simultaneous determination
of aluminum and silicon. Possible extensions of the method to light elements are suggested. 相似文献
15.
A. Faanhof H. A. Das J. Zonderhuis 《Journal of Radioanalytical and Nuclear Chemistry》1980,56(1-2):173-184
The applicability of a 400 kV neutron generator in the elemental analysis of dry biological material is considered. Data for
the specific count-rates of 66 elements are given. A procedure for the determination of N, Mg, Si, P, K and Ca is described.
The results for three Standard Reference Materials and some samples are given. 相似文献
16.
V. F. Peresedov 《Journal of Radioanalytical and Nuclear Chemistry》1997,224(1-2):21-25
Possibilities of neutron activation analysis for studying the elemental content of atmospheric aerosols at the IBR-2 reactor are discussed on the bases of the experimental results on concentrations of nearly 40 elements in the air of two, remote and industrial Siberian regions. Methodological aspects of the use of small-pore filters, the influence of their background trace-element contents on the sensitivity of NAA, the reliability of the results, as well as preferable strategy of atmospheric aerosols sampling are discussed. 相似文献
17.
A. Navarro J. J. Lpez Gonzlez G. J. Kearley J. Tomkinson S. F. Parker D. S. Sivia 《Chemical physics》1995,200(3):395-403
The inelastics neutron scattering (INS) spectra of s-triazine and trichloro-s-triazine at 5 K provide the first observation of the IR and Raman inactive modes, v4 and v5. A full assingment is made by fitting a harmonic force field to the INS spectra profile. In the case of trichloro-s-triazine we demonstrate that this approach can be used successfully for a molecule without H atoms. 相似文献
18.
Parker SF Bennington SM Taylor JW Herman H Silverwood I Albers P Refson K 《Physical chemistry chemical physics : PCCP》2011,13(17):7789-7804
In this paper we exploit the complementarity of inelastic neutron scattering (INS), infrared and Raman spectroscopies with ab initio calculations to generate an updated assignment of the vibrational modes of C(60). We have carried out periodic-DFT calculations of the high temperature face centred cubic phase modelled as the standard structure and also of the low temperature simple cubic phase, the latter for the first time. Our assignment differs from all previous work, however, it is the only one that is able to successfully reproduce the INS spectrum in terms of both transition energies and intensities. In addition to the INS spectrum we are also able to quantitatively simulate the major features of the infrared and Raman spectra in the high temperature phase and the infrared spectrum in the low temperature phase. 相似文献
19.
We review work performed by our group on vibrational spectroscopy of water and aqueous solutions of strong II-I electrolytes at high concentrations. Evidence shall be presented for the existence of intermediate range, solute-connected, ordered patches, whose collective vibrational modes yield a continuous vibrational density of states, as in amorphous solids. We shall review Raman and inelastic neutron scattering results, obtained for electrolytes such as ZnCl2, NiCl2, CuBr2, CdCl2. Other results, such as EXAFS, viscosity and ultrasonic attenuation will also be discussed. 相似文献
20.
S. I. Kafala B. V. Anisimov I. V. Tolkachev 《Journal of Radioanalytical and Nuclear Chemistry》1986,97(2):341-345
Instrumental neutron activation methods are suggested in order to carry out automatic analysis of fertilizers and plant samples for N, P, K and Si allowing for the investigation of more than 40 samples per 8 hours. The experimental errors do not exceed ±3% for N, ±6% for P, ±5% for K and ±15% for Si. 相似文献