Electroless silver plating on tetraethoxy silane-bridged fiber glass

Tetraethoxy silane was used to functionalize the surface of fiber glass (FG) for adsorption with the electroless plated silver shell. The performance of electroless silver plated FG with tetraethoxy silane modification was compared to that of unmodified FG in terms of mechanical and electrical properties. The silane bridge provided more stability for binding with different concentrations of electroless plating silver ions. The characterization was investigated by using field emission scanning electron microscope (FESEM), X-ray diffraction patterns (XRD), energy-dispersion X-ray (EDX), metal microscope (MM) and electric resistance. The Ag coating on TEOS modified FG was more durable than that of unmodified FG in the ball milling test, as confirmed by the data of electric resistance and residue weight. The optimized conditions for producing the Ag coating FG were also investigated. The Ag-Si-FG-3-c product in this study has the lowest electrical resistance of 1.56 × 10³ Ω/cm² and good mechanical stability as exhibited in ball milling tests.     

Investigation on resin interphase produced near silane-treated glass fiber in vinyl ester resin

In order to investigate the reaction of silane-treated glass fiber with thermosetting resin, a set of spectra were measured near the interface between the glass fiber and vinyl ester resin using microscopic FT-IR spectroscopy. A thin-sliced sample was made from glass fiber/vinyl ester resin composite to be subjected to the spectroscopy. The spectra were obtained through a 20 × 40 μm of a mask window at each 20 μm step from the glass strand area to the matrix resin. The intensity at 1450 cm^-1 of the spectra decreased from the glass strand area to the matrix resin. It was noticed, however, that the intensity kept the same value even in the matrix at a distance of 80 μm from the glass strand area. This meant that the resin in such an area was denatured by the reaction of silane to resin at the surface. This mechanism was supported by the significant size of the denatured area, which increased with amounts of silane at the surface of glass fiber.     

Mechanical properties of poly(vinyl chloride)/silane-treated glass beads composite: effects of organofunctional group and alkoxy group numbers of silane coupling agent

The surface treatment of glass beads, chosen as model filler, is carried out using four kinds of silane coupling agents with multilayer coverage. For this purpose, the silanes having aminopropyl or methacryloxypropyl group as an organofunctional group with two or three alkoxy group numbers are used. The amount of silane detected on the bead surface is 4–6 times that required for monolayer coverage. Using these treated beads, the effects of the organofunctional group and the alkoxy group numbers of silanes on the mechanical properties of the bead-filled poly(vinyl chloride), chosen as a typical ductile polymer, were investigated. Higher yield stress was observed in the silane with aminopropyl group than with methacryloxypropyl group. The effect of alkoxy group numbers was more effective in the dialkoxy than trialkoxy silanes. Scanning electron microscopy shows improvement in the interfacial adhesion by the silane treatment in the above order. The interfacial debonding at the yield point is depressed.     

氟锆酸盐玻璃光纤的研制

本文介绍聚全氟乙丙烯包皮的氟锆酸盐(ZrF_4-BaF_2-LaF_3-AlF_3-NaF)玻璃光纤的制备方法.研究了各种工艺因素对氟锆酸盐玻璃和光纤散射损耗的影响.结果表明,选择适当的熔化温度和均化时间,玻璃熔化和光纤拉制时环境中低的水含量是制得的损耗氟锆酸盐玻璃光纤的关键;配合料中引入适量NH_4HF_2,选用温度结构合理的拉丝炉及拉丝工艺也有助于降低光纤的损耗.在此工作基础上,获得了波长2.32μm处损耗为0.24dB/m的氟锆酸盐玻璃光纤.     

中红外高保偏硫系玻璃双芯光子晶体光纤耦合特性研究

设计了一种中红外硫系玻璃双芯光子晶体光纤,利用多极法和模式耦合基本理论研究了这种光纤的耦合特性.数值模拟发现,空气孔间距Λ = 5.4 μm,空气孔半径为r = 1.35 μm,空气填充率d/Λ = 0.5的光纤,在归一化波长λ/Λ = 2.04 μm处双折射可以达到0.551×10^-2,在归一化波长λ/Λ = 0.93 μm处x偏振方向的耦合长度为145.32 μm,y偏振方向的耦合长 关键词： 双芯光子晶体光纤 硫系玻璃 双折射 耦合长度     

氟化物玻璃光纤非本征散射损耗的理论分析

详细论述了存在于氟化物玻璃光纤中的散时缺陷所引起的非本征散射损耗,计算并讨论了它与波长及缺陷尺寸的关系,得出了一些有益的结论.     

色散渐减光纤中的脉冲展宽研究

讨论了高斯脉冲在五种不同群色散剖面光纤中的传播特性和初始啁啾对脉宽的影响。结果发现:与单模光纤相比,色散渐减光纤(DDF)中的脉冲展宽较慢,并能有效抑制展宽,当β2C>0时,脉冲展宽速度与无啁啾时相比较快,当β2C<0时,脉冲有一初始窄化过程,不同群色散函数对啁啾脉冲有不同的影响。     

高峰值功率脉冲激光与石英光纤耦合的空气击穿问题

 研究了15 MW峰值功率脉冲激光与600 μm芯径石英光纤耦合中存在的空气击穿现象。对聚焦区域的空气击穿现象进行了理论和实验研究,测得空气击穿阈值为0.79×10⁹ W/cm²。测得固体介质的激光损伤阈值为2.12×10⁹ W/cm²,与理论计算结果相符。提出了七合一光纤耦合器用于解决空气击穿的办法,实验测得7根光纤并束的耦合效率为67.21%。结果表明光纤耦合器可有效解决15 MW峰值功率脉冲激光与600 μm芯径石英光纤的耦合。     

切向气流作用下玻璃纤维复合材料的激光辐照效应

实验研究了样品表面有切向空气气流、切向氮气气流和无气流时,976 nm连续激光对玻璃纤维增强E-51环氧树脂复合材料的辐照效应。结果表明:无气流时,喷出的热分解产物会对入射激光产生屏蔽作用;有气流时,激光对玻璃纤维的破坏方式是其升温熔化后再被切向气流带走;当激光功率密度较低时,切向空气气流以加强样品表面的对流冷却作用为主,不利于激光对玻璃纤维复合材料的破坏;当激光功率密度较高时,切向空气气流以降低屏蔽作用和提供氧气助燃为主,有利于激光对玻璃纤维复合材料的破坏。三种气流状态下,质量损失随功率密度呈现单调增加趋势,当入射激光功率密度在100~600 W/cm2范围内,随着功率密度的增大,激光能量的利用效率逐渐增大并趋于稳定。     

纳秒脉冲放电紫外光纤阵列检测与定位方法

峰化电容作为电磁脉冲模拟器中用于陡化脉冲输出的关键部件,在实际工程应用中易发生沿面放电和击穿现象,采用光电检测系统可对绝缘沿面放电现象进行有效分析。针对峰化电容器沿面放电监测的技术难题,研制了一套绝缘沿面放电过程光电检测系统,对绝缘沿面放电现象进行光电检测。首先提出了绝缘介质沿面放电过程光电探测系统的设计方案;其次,对系统的时延性能进行了评价;最后,完成了绝缘介质沿面放电过程定位实验,验证了光电探测系统的可行性。实验表明,该系统能够实现对放电区域的有效定位。     

Numerical study on multiple-pulse operation of passively modelocked stretched pulse fiber ring laser

We numerically study a stable multiple-pulse operation of passively modelocked stretched pulse fiber ring laser. The simulation results show that multiple pulses are formed with being triggered by radiation from a single pulse in a restricted parameter range. In order to obtain a better understanding of the effect of gain bandwidth and nonlinear gain on harmonic modelocking process of multiple-pulse operation, we analyze those effects in detail.     

钕玻璃啁啾脉冲放大器产生百焦耳亚皮秒脉冲

以钕玻璃为增益介质研制了高能啁啾脉冲激光放大器系统,实验演示输出啁啾脉冲能量在百焦耳量级时,光谱宽度保持在4—6 nm.最大能量168 J,相应谱宽5.5 nm,中心波长1054 nm.压缩脉冲宽度最短710 fs. 关键词： 啁啾脉冲放大 钕玻璃 高能拍瓦     

驱镉剂N-(d-葡萄糖基)-L-氨基酸类化合物的1H NMR谱研究

d-葡萄糖与L-氨基酸缩合制得一类新型驱隔剂,本文报道5种N-(d-葡萄糖基)-L-氨基酸的¹H NMR.当氨基酸侧链上有含羟基、巯基及苄基一类的富电荷基时,葡萄糖基上的质子都移向高场,这可能与这些基团的存在不利于N-取代氨基酸生成内盐有关.动物实验表明:与甘氨酸的衍生物比较,它们的驱镉性能也较优秀,本文推测,不利于生成内盐的基因也可能有助于发挥驱镉效应.     

单模光纤中三阶色散对超短光脉冲传输的影响

基于超短光脉冲在单模光纤中传输时高阶非线性效应的影响。应用非线性薛定谔方程(HONLS)理论,考虑光纤色散三阶效应,推导出无啁啾的高斯脉冲沿光纤传输时脉冲变化的表达式,并对理论结果进行了数值模拟与分析。结果表明,三阶色散会引起光脉冲形状发生畸变,会在其前沿或后沿附近形成非对称的振荡结构。     

高非线性光子晶体光纤中飞秒脉冲的传输特性和超连续谱产生机制的实验研究及模拟分析

用实验和数值模拟两种方法研究了高非线性光子晶体光纤中飞秒激光脉冲的传输特性和超连续谱的产生机理，给出了抽运脉冲在三种不同中心波长情况下输出光谱展宽并形成超连续谱的实际测量及理论模拟结果.研究表明：在零色散波长抽运时，光谱展宽以自相位调制为主，同时三阶色散的影响明显，传输脉冲在时域内出现振荡次峰.而在反常色散区抽运时，光谱展宽的初期以自相位调制为主，随后根据抽运功率的不同孤子自频移、高阶光孤子的裂变和四波混频效应会逐渐增强，进而成为光谱展宽的主要原因.与此相应，在时域中能明显看到孤子的形成和红移，飞秒传输脉 关键词： 光子晶体光纤 高非线性光子晶体光纤 飞秒脉冲激光 超连续谱     

Effects of surface treatment and weave structure on interlaminar fracture behaviour of plain glass woven fabric composites: Part II. Report of the 2nd round robin test results

This paper reports the second part of the results from the round robin test program proposed by the Society of Interfacial Materials Science (SIMS) to characterise the interlaminar fracture behaviour of E-glass woven fabric reinforced vinylester composites. Special emphasis was placed on the study of loading direction (i.e. weft and warp directions) effect on interlaminar shear strength and fracture toughness. Ten laboratories worldwide participated in this test (Table 1). Each laboratory was supplied with composite laminates and conducted the tests according to its own procedure. The results showed that although there were large variations in absolute magnitude between laboratories, a general trend was established with higher interlaminar fracture resistance in the weft direction than in the warp direction for a given silane agent. The larger number of strands running in the warp direction with rougher, more undulating areas perpendicular to the direction of crack propagation was mainly responsible for this result. The results also confirmed the previous finding that the mode I interlaminar fracture toughness increased with increasing silane agent concentration.     

掺镱光纤放大器的啁啾脉冲失谐放大特性

研究了掺镱光纤放大器对中心频率为1 053nm的啁啾脉冲放大特性,发现针对高斯或超高斯脉冲,采用合适的带宽及入射光强能够使增益饱和和失谐放大相互消弱,从而得到一个良好的放大脉冲形状。计算了掺镱光纤放大器失谐放大带来的相位调制,发现对压缩质量影响较小。     

量子算法核磁共振实现脉冲序列设计程序问题研究

从两量子位核磁共振量子处理器物理模型出发,利用Raedt小组提出的自旋-1/2代数理论,根据量子控制非门的定义及Grover量子算法原理,介绍了量子控制非门的4种不同脉冲序列及两量子位Grover量子算法的两种不同脉冲序列的设计过程,通过数值求解含时薛定谔方程模拟量子控制非门和两量子位Grover量子算法,等价于执行量...     

切向气流作用下玻璃纤维复合材料的激光辐照效应

实验研究了样品表面有切向空气气流、切向氮气气流和无气流时,976 nm连续激光对玻璃纤维增强E-51环氧树脂复合材料的辐照效应。结果表明:无气流时,喷出的热分解产物会对入射激光产生屏蔽作用;有气流时,激光对玻璃纤维的破坏方式是其升温熔化后再被切向气流带走;当激光功率密度较低时,切向空气气流以加强样品表面的对流冷却作用为主,不利于激光对玻璃纤维复合材料的破坏;当激光功率密度较高时,切向空气气流以降低屏蔽作用和提供氧气助燃为主,有利于激光对玻璃纤维复合材料的破坏。三种气流状态下,质量损失随功率密度呈现单调增加趋势,当入射激光功率密度在100~600 W/cm2范围内,随着功率密度的增大,激光能量的利用效率逐渐增大并趋于稳定。     

飞秒脉冲在光子晶体光纤中的传输特性

基于广义非线性薛定谔方程,利用分步傅里叶法数值模拟了超高斯时间分布的飞秒脉冲在光子晶体光纤中的传输特性。结果表明：超高斯脉冲比高斯脉冲在更短距离内形成孤子衰变,而且出现比强孤子功率稍低的次峰,孤子自频移更显著;另外,三阶色散会导致脉冲波形及频谱不对称,出现精细结构,并且有形成孤子的趋势;脉冲内拉曼散射对脉冲有平滑作用;自陡改变了主峰与次峰之间的能量分配。