共查询到20条相似文献,搜索用时 94 毫秒
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合成了新型的四(3,5-二叔丁基-4-甲氧基苯基)卟啉和相应的金属(M=Ni,Cu,Co,Zn)卟啉,用HNMR,^13CNMR,DEPT谱鉴定了它们的结构,并用H,^13C谱讨论了这些卟啉化合物的中心金属离子对环流的影响。 相似文献
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用~(13)C和~1HNMR波谱,探讨了聚环氧氯丙烷(PEPCH)的辐射效应,结果表明随着辐射剂量的增加,本体聚合物的~(13)CNMR谱中各基团的分辨率得以提高,~1HNMR谱中出现了裂解产物共振峰,T~1变短,表明PEPCH在限量空气氛中的辐射效应以大分子裂解反应为主,并通过特性粘度的测定,得到了证实。 相似文献
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采用二维核磁共振技术,并借助一维技术DEPT(无畸变极化转移实验)对新三萜Urs-12-en-28-oicacid,3,21-dioxo-methylester的全部质子和碳信号进行归属。 相似文献
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合成了稀土铕、镧与吡啶-2,6二甲酸形成的二元配合物及铕与邻菲罗啉和吡啶-2,6二甲酸形成的三元配合物。经元素分析确定该配合物的组成分别为二元:Na3[Eu(DPC)3]·2H2O,Na3[La(DPC)3]·2H2O;三元:NaEu(DPC)2·phen·4H2O。用核磁共振研究了配体与稀土的配位方式,讨论了诱导效应、屏蔽效应及稀土离子的顺磁性对配合物化学位移和NMR谱图的影响。NMR研究表明,三种配合物具有相似的对称结构和相同的化学位移变化规律。吡啶-2,6二甲酸中的羧酸以单齿配位(整个分子为三齿配位),二元配合物中,铕和镧的配位数均为9,三元配合物中,铕的配位数最低为8。 相似文献
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合成了23个新的1-(取代吡唑-4-基)1,2,4-三唑化合物,经EA、IR、~1HNMR和MS确定其组成和结构,并对其进行了抑菌及生长调节活性的初步观察。 相似文献
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5,10,15,20-四(3-溴-4-磺酸苯基)卟啉光度法测定痕量锌的研究 总被引:1,自引:0,他引:1
本文研究了新水溶性卟啉试剂5,10,15,20-四(3-溴-4-磺酸苯基)卟啉[T(3-BrP)PS4]与锌的显色反应。在pH4,锌与5,10,15,20-四(3-溴-4-磺酸苯基)卟啉形成稳定的1:1配合物,其最大吸收波长位于422.0nm,摩尔吸光系数为3.9×105L·mol(-1)·cm(-1)。锌量在0~2.5μg/25mL范围符合比尔定律。方法具有较高的灵敏度和较好的选择性,用于人发和大米中痕量锌的测定,结果与原子吸收法一致。 相似文献
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<正>The title compound was synthesized by the direct reaction of 3,5-dichlorobenzoic acid with 2-methoxyaniline in the presence of DCC and HOBT. The structure was supported by the spectroscopic data and unambiguously confirmed by the single-crystal X-ray diffraction studies. It crystallizes from a methanol solution in the monoclinic space group P2_1/c with unit cell dimensions of a = 4.9369(16), b = 13.351(5), c = 20.168(7), β = 96.755(8)°, V = 1320.1(8)~3 and Z = 4. 相似文献
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Chizhova N. V. Migalova I. S. Stuzhin P. A. 《Russian Journal of General Chemistry》2004,74(2):292-294
Tetraphenyltetraazaporphyrin was reacted with bromine in trifluoroacetic acid to obtain tetrakis(4-bromophenyl)tetraazaporphyrin. The latter forms with pyridine and dimethyl sulfoxide proton-transfer complexes which differ from each other by the degree of proton transfer from the NH acid to base. 相似文献
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《Polymer Photochemistry》1983,3(3):221-229
The photochemical processes of Ni(II)bis(ethyl-3,5-di-t-butyl-4-hydroxybenzyl phosphonate) (I) in an inert solvent were investigated. The 2,6-di-t-butyl-4-methylphenol (II) and 3,3′,5,5′-tetra-t-butyl-4,4′-stilbenequinone (III) were found in the solution irradiated with light absorbed by (I). The quantum yield of the process for the decomposition of I is low (Φ=1×10−3 mol einstein−1).It was found that I quenches singlet oxygen in the anthracene +I+ hexane system irradiated with light at λ = 365 nm. The rate constant of the process was determined as equal to 2×108 dm3 mol−1 s−1. It was found that the process of singlet oxygen deactivation by I consists mainly of the physical interaction between these two molecules. 相似文献
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Gowravaram Sabitha Gajangi Chandrashekhar Kurra Yadagiri Jhillu Singh Yadav 《Tetrahedron: Asymmetry》2011,22(18-19):1729-1735
The total syntheses of the first examples of diarylheptanoid natural products (5S)-5-acetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)-3-heptanone 1, and (3S,5S)-3,5-diacetoxy-1,7-bis(4-hydroxy-3-methoxyphenyl)heptane 2 isolated from the rhizomes of Zingiber officinale were accomplished using Sharpless epoxidation and cross-metathesis reactions as the key steps. 相似文献
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