共查询到20条相似文献,搜索用时 0 毫秒
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Monica Melegari Dr. Michele Suman Dr. Laura Pirondini Dr. Davide Moiani Dr. Chiara Massera Dr. Franco Ugozzoli Prof. Elina Kalenius Dr. Pirjo Vainiotalo Prof. Jean‐Christophe Mulatier Jean‐Pierre Dutasta Dr. Enrico Dalcanale Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(19):5699-5699
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Bailey DM Hennig A Uzunova VD Nau WM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(20):6069-6077
The coupling of an enzymatic transformation with dynamic host-guest exchange allows the unselective binding of macrocycles to be used for highly selective analyte sensing. The resulting supramolecular tandem enzyme assays require the enzymatic substrate and its corresponding product to differ significantly in their affinity for macrocycles, for example, cation receptors, and to show a differential propensity to displace a fluorescent dye from its host-guest complex. The enzymatic transformation results in a concomitant dye displacement that can be accurately followed by optical spectroscopy, specifically fluorescence. By exploiting this label-free continuous enzyme assay principle with the fluorescent dye Dapoxyl and the macrocyclic host cucurbit[7]uril, a multiparameter sensor array has been designed, which is capable of detecting the presence of amino acids (e.g. histidine, arginine, lysine, and tyrosine) and their decarboxylases. Only in the presence of both, the particular amino acid and the corresponding decarboxylase, is the amine or diamine product formed. These products are more highly positively charged than the substrate, have a higher affinity for the macrocycle and, therefore, displace the dye from the complex. The extension of the high selectivity and muM sensitivity of the tandem assay principle has also allowed for the accurate measurement of D-lysine enantiomeric excesses of up to 99.98 %, as only the L-enantiomer is accepted by the enzyme as a substrate and is converted to the product that is responsible for the observed fluorescence signal. 相似文献
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Inside Back Cover: Programmable Polymer‐Based Supramolecular Temperature Sensor with a Memory Function (Angew. Chem. Int. Ed. 20/2014) 下载免费PDF全文
Léna Sambe Victor R. de La Rosa Khaled Belal Dr. François Stoffelbach Dr. Joel Lyskawa Dr. François Delattre Marc Bria Prof. Graeme Cooke Prof. Richard Hoogenboom Prof. Patrice Woisel 《Angewandte Chemie (International ed. in English)》2014,53(20):5215-5215
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Back Cover: Amphiphilic Inclusion Spaces for Various Guests and Regulation of Fluorescence Intensity of 1,8‐Bis(4‐aminophenyl)anthracene Crystals (Chem. Eur. J. 11/2014) 下载免费PDF全文
Misa Sugino Keisuke Hatanaka Yusuke Araki Dr. Ichiro Hisaki Prof. Dr. Mikiji Miyata Dr. Norimitsu Tohnai 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(11):3236-3236
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Inhar Imaz Dr. Jordi Hernando Dr. Daniel Ruiz‐Molina Dr. Daniel Maspoch Dr. 《Angewandte Chemie (International ed. in English)》2009,48(13):2245-2245
The infinite coordination polymerization…? of metal ions and multitopic organic ligands is explored to fabricate metal–organic micro‐ and nanospheres that can be used as functional matrices. In their Communication on page 2325 ff., D. Maspoch and co‐workers show how this simple process affords spheres that encapsulate active substances, such as magnetic nanoparticles, organic dyes, and quantum dots, to result in multifunctional spheres. Marianne Verdoux is thanked for the cover graphic design.
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