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Polycrystalline CuGaSe2 thin films on Mo-coated soda-lime glass substrates have been synthesized by coevaporation process from Cu, Ga and Se sources. Structural and electrical properties of the as-grown CuGaSe2 films strongly depend on the film composition. Stoichiometric CuGaSe2 is fabricated, as indicated by x-ray diffraction spectroscope (XRD) and x-ray fluorescence (XRF). A two-phase region is composed of CuGaSe2 and Cu2-xSe phases for Cu-rich films, and CuGaSe2 and CuGa3Se5 phases for Ga-rich films, respectively. Morphological properties are detected by scanning electron microscope (SEM) for various compositional films, the grain sizes of the CuGaSe2films decrease with the extent of deviation from stoichiometric composition. Raman spectroscopy of Cu-rich samples shows that there exist large Cu-Se particles on the film surface. The results from Hall effect measurements for typical samples indicate that CuGaSe2 films are always of p-type semiconductor from Cu-rich to Ga-rich. Stoichiometric CuGaSe2 films exhibit relatively large mobility than any other compositional films. Finally, polycrystalline CuGaSe2 thin film solar cell with a best conversion efficiency of 6.02% has been achieved under the standard air mass (AM)1.5 spectrum for 100mW/cm^2 at room temperature (aperture area, 0.24cm^2). The open circuit voltage of the CuGaSe2 solar cells is close to770 mV. 相似文献
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固体激光的一个重大发展方向和目标是实现“三高”(高平均功率、高光束质量和高效率)激光同时输出,结合相关研究工作和进展,着重论述了固体激光输出功率和光束质量的关系,给出了功率升高、光束质量非线性下降是当前“三高”固体激光研究的一个基本科学技术问题。围绕这一基本问题,评述了一些重要技术途径和手段,并探讨了实现高平均功率高光束质量固体激光输出的可能有效途径。 相似文献
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This paper reports that single-phase γ-Y2Si2O7 is prepared via a sufficient blending and cold-pressed sintering technique from Y2O3 powder and SiO2 nanopowder. It studies the dielectric properties of γ-Y2Si2O7 as a function of the temperature and frequency. The γ-Y2Si2O7 exhibits low dielectric loss and non-Debye relaxation behaviour from 25 to 1400℃ in the range of 7.3-18 GHz. The mechanism for polarization relaxation of the as-prepared γ-Y2Si2O7 differing from that of SiO 2 is explained. Such particular dielectric properties could potentially make specific attraction for extensive practical applications. 相似文献
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The effect of change in concentration of messenger molecule inositol1,4,5-trisphosphate (IPspiral wave, Ca$^{2 + }$,IPspiral wave, Ca$^{2 + }$,IP$_{3}$ Project supported by the NationalNatural Science Foundation of China (Grant Nos 10575041 and10747005) 0545 The effect of change in concentration of messenger molecule inositol1,4,5-trisphosphate (IP$_{3})$ on intracellular Ca$^{2 + }$spiralpattern evolution is studied numerically. The results indicate thatwhen the IP$_{3}$ concentration decreases from 0.27,$mu $M, aphysiologically reasonable value, to different values, the spiralcentre drifts to the edge of the medium and disappears for a smallenough IP$_{3}$ concentration. The instability of spiral pattern canbe understood in terms of excitability-change controlled by theIP$_{3}$ concentration. On the other hand, when the IP$_{3}$concentration increases from 0.27,$mu $M, a homogeneous area witha high Ca$^{2 + }$ concentration emerges and competes with thespiral pattern. A high enough IP$_{3}$ concentration can lead thehomogeneous area to occupy the whole medium. The instability ofspiral pattern is ascribed to the change in stability of astationary state with a high Ca$^{2 + }$ concentration. 相似文献
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通过X-射线衍射及磁测量手段研究了Dy2AlFe13Mn3化合物的结构及磁性质。研究结果表明Dy2AlFe13Mn3化合物具有六角相的Th2Ni17型结构。通过X-射线热膨胀测定法发现Dy2AlFe13Mn3化合物在245到344K的温度范围内存在负热膨胀现象,其平均热膨胀系数为α=-1.1×10-4K-1K-1。在105到360K的温度范围内,通过比较磁性状态下的晶胞参数和由高温顺磁状态外延得到的低温顺磁状态下的晶胞参数间的差别计算了Dy2AlFe13Mn3化合物的本征磁致伸缩。结果表明Dy2AlFe13Mn3化合物的本征体磁致伸缩ωS在105到245K的温度范围内随着温度的升高而增大,由105K时的7.0×10-3 增加到245K时的9.1×10-3。随着温度的进一步升高,ωS反而减小。沿c轴方向的本征线磁致伸缩λc随着温度的升高而减小。基面内的本征线磁致伸缩λa在105到270K的温度范围内随着温度的升高而增大,从105K时的0.8×10-3增大到270K时的3.4×10-3,然后随着温度的进一步升高而减小。 相似文献
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In this paper the growth mechanism of a Te/Bi$_{2}$Te$_{3}$ novelstructure is studied by textit{ab-initio} calculations. The resultsshow that the growth of Te nanorods is determined by the adsorptionenergy of Te atoms on different crystalline Te surfaces. Theadsorption energy of Te on the Te (001) surface is 3.29 eV, which isabout 0.25 eV higher than that of Te on the Te (110). This energydifference makes the preferential growth direction along the $<001>$direction. In addition, the higher surface energy ofBi$_{2}$Te$_{3}$ (110) and the lattice misfit between crystallineBi$_{2}$Te$_{3}$ and Te along $<001>$ direction are considered toexplain the growth of the Bi$_{2}$Te$_{3}$ nanoplatelets, in whichVolmer--Weber model is used. The theoretical results are inagreement with experimental observation. 相似文献
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The effects of interstitial oxygen on superconducting electronic phases in strontium and oxygen co-doped La1.937Sr0.063CuO4+δ
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Strontium and oxygen co-doped La1.937Sr0.063CuO4+δ superconductor with Tc≈ 40K, which is obtained by oxidizing strontium-doped starting ceramic sample La1.937Sr0.063CuO4 in NaC10 solution, is annealed under different conditions to allow interstitial oxygen to redistribute. The evolution of the intrinsic superconducting property with the oxygen redistribution is studied in detail by magnetic measurements in various fields. It is found that there occurs the electronic phase separation from the single superconducting phase with Tc ≈ 40 K into two coexisting superconducting states with values of Tc: 15 and 40K or of 15 and 35 K in this system, depending on annealing condition. Our results indicate that the 15, 35 and 40 K superconducting phases associated with the excess oxygen redistribution are all thermodynamically meta-stable intrinsic states in this Sr/O co-doped cuprate. 相似文献
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Effect of Co substitution on magnetic properties and magnetic entropy changes in LaFe_{11.83}Si_{0.94}Al_{0.23} compounds has been investigated by means of magnetization measurements. X-ray diffraction shows the prepared compounds to be single phase with the cubic NaZn_{13}-type structure. Substitution of Co for Fe leads to an increase of Curie temperature of the material. The magnetic entropy changes in LaFe_{11.83}Si_{0.94}Al_{0.23} and LaFe_{11.03}Co_{0.80}Si_{0.94}Al_{0.23} compounds are 21.8J/(kg·K) to 16.9J/(kg·K) under a magnetic field change of 0-5T at Curie temperature, respectively. Giant magnetic entropy changes are attributed to the higher magnetization and the rapid change in magnetization at Curie temperature. 相似文献
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Novel material for nonvolatile ovonic unified memory (OUM)-Ag11In12Te26Sb51 phase change semiconductor
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In this paper, Ag_{11}In_{12}Te_{26}Sb_{51} phase change semiconductor films have been prepared by dc sputtering. The crystallization behaviour of amorphous Ag_{11}In_{12}Te_{26}Sb_{51} thin films was investigated by using differential scanning calorimetry and x-ray diffraction. It was found that the crystallization temperature is about 483K and the melting temperature is 754.8K and the activation energy for crystallization, E_a, is 2.07eV. The crystalline Ag_{11}In_{12}Te_{26}Sb_{51} films were obtained using initializer. The initialization conditions have a great effect on the sheet resistance of Ag_{11}In_{12}Te_{26}Sb_{51} films. We found that the effect of the initialization condition on the sheet resistance can be ascribed to the crystallinity of Ag_{11}In_{12}Te_{26}Sb_{51} films. The sheet resistance of the amorphous (R_{amo}) film is found to be larger than 1×10^6Ω and that of the crystalline (R_{cry}) film lies in the range from about 10^3 to 10^4Ω. So we have the ratio R_{amo}/R_{cry}=10^2~10^3, which is sufficiently large for application in memory devices. 相似文献
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The structure and magnetic properties of La(Fe_{1-x}Mn_x)_{11.4}Al_{1.6} (0≤x≤0.25)compounds have been studied. The NaZn_{13}-type structure is preserved and the lattice parameter increases linearly with increasing the Mn concentration. The magnetic ground state changes from the antiferromagnetic to the spin-glass or the cluster-glass state by the substitution of Mn for Fe. Furthermore, a field-induced transition from cluster glass to ferromagnet is found for the samples with x=0.05 and 0.10. 相似文献
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This paper studies the electronic structure and native defects in transparent conducting oxides CuScO2 and CuYO2 using the first-principle calculations. Some typical native copper-related and oxygen-related defects, such as vacancy, interstitials, and antisites in their relevant charge state are considered. The results of calculation show that, CuMO2(M = Sc, Y) is impossible to show n-type conductivity ability. It finds that copper vacancy and oxygen interstitial have relatively low formation energy and they are the relevant defects in CuScO2 and CuYO2. Copper vacancy is the most efficient acceptor, and under O-rich condition oxygen antisite also becomes important acceptor and plays an important role in p-type conductivity. 相似文献
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The growth of Mn5Ge3 ultrathin films with different thicknesses, prepared by solid phase epitaxy, is studied. The results of scanning tunnelling microscopy and low energy electron diffraction studies show that the film can be formed and it is terminated with a (√3 × √3) R30° surface reconstruction when the thickness of Mn exceeds 3 monolayers. The magnetic properties show that the Curie temperature is about 300 K and the T^2-dependent behaviour is observed to remain up to 220 K. 相似文献
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采用定向棱镜谐振腔、半圆柱面LD阵列交错侧向泵浦两根串接NdYAG激光棒、热传导冷却结构,研制出了一台工程实用的全固化激光器.定向棱镜腔内振荡光线平行于光轴的对称位置交换穿行,匀化了增益,降低了模序数;同时,定向棱镜准相位共轭特性和自准直作用在一定程度上修正波前畸变、热光楔以及热致双折射,保证了大的动态范围内热稳定性,改善了光束质量.激光器采用Cr4+YAG被动调Q,在室温条件下,工作电流为53 A、频率10 Hz时,1.06 μm单脉冲激光能量高于150 mJ、脉宽9 ns、输出稳定度±3%、束散度2.5 mrad且光轴指向稳定,远场分布近似相干平顶高斯光束. 相似文献