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1.
The effect of white and UV radiation on the phase composition of amorphous CN x films are studied by X-ray diffraction analysis and visible-range spectroscopy. The films have variable-range atomic order and consist of amorphous graphite clusters (30 Å) crystalline clusters (50–100 Å) of graphite, diamond, and carbon nitride phases; and intercluster medium with long-range (1–2 Å) atomic order. It is shown that irradiation of the films by white light facilitates the growth of fine graphite clusters. Irradiation by UV light suppresses the growth of the graphite and carbon nitride phases, favoring the growth of the diamond phase (1.5%). It is demonstrated that a change in the mesoscopic phase composition of the CN x films causes a change in the energy gap width in the visible range from E g = 0.75 eV for the films irradiated by white light to E g = 1.75 eV for those exposed to UV radiation.  相似文献   

2.
Influence of temperature and magnetic field H on magnetism of spherical Gd nanoparticles of different sizes (89, 63, 47, 28, and 18 nm) was studied in the temperature range 250 K < T < 325 K. The particles were obtained by metal vapor condensation in the flow of helium. The particles with d = 18 nm did not show a magnetic transition; their structure is a combination of two cubic phases (FCC1 and FCC2). Large particles remained in the HCP phase and had an admixture of the FCC1 phase, the amount of which decreased as the particle sizes increased; magnetic transition took place at T c = 293 K. The admixture of O2 did not alter the structure but decreased the magnetization σ and magnetic permeability μ. An orientation transition in polycrystalline gadolinium initiated by the magnetic field H was proved in an experiment. The orientation transition in Gd particles smaller than 63 nm, the magnetic structure of which is close to the single-domain structure, occurred near T c without the influence of H.  相似文献   

3.
LSDA + U + SO calculations of the electronic structure of helicoidal Fe1 - xCo x Si ferromagnets within the virtual crystal approximation have been supplemented with the consideration of the Dzyaloshinski-Moriya interaction and ferromagnetic fluctuations of the spin density of collective d electrons with the Hubbard interactions at Fe and Co atoms randomly distributed over sites. The magnetic-state equation in the developed model describes helicoidal ferromagnetism and its disappearance accompanied by the occurrence of a maximum of uniform magnetic susceptibility at temperature T C and chiral fluctuations of the local magnetization at T > T C . The reasons why the magnetic contribution to the specific heat at the magnetic phase transition changes monotonically and the volume coefficient of thermal expansion (VCTE) at low temperatures is negative and has a wide minimum near T C have been investigated. It is shown that the VCTE changes sign when passing to the paramagnetic state (at temperature T S ).  相似文献   

4.
We present new results of analysis of top-quark differential cross sections obtained by the CMS Collaboration in pp collisions in the framework of the z-scaling approach. The spectra are measured over a wide range of collision energy \(\sqrt s = 7,8,13TeV\) and transverse momentum p T = 30?500 GeV/c of top-quark using leptonic and jet decay modes. Flavor independence of the scaling function ψ(z) is verified in the new kinematic range. The results of analysis of the top-quark spectra obtained at the LHC are compared with similar spectra measured in \(\overline p p\) collisions at the Tevatron energy \(\sqrt s = 1.96TeV\). A tendency to saturation of ψ(z) for the process at low z and a power-law behavior of ψ(z) at high z is observed. The measurements of high-p T is observed. The measurements of highspectra of the top-quark production at highest LHC energy is of interest for verification of self-similarity of particle production, understanding flavor origin and search for new physics symmetries with top-quark probe.  相似文献   

5.
The spin and lattice dynamics of the R2CuO4 quasi-2D antiferromagnetic crystals (R=Pr, Nd, Sm, Eu, Gd) were studied in the millimeter-range electromagnetic wave band. Strong variations of the absorption coefficient were observed to occur at temperatures TT0. Absorption lines of electrical nature due to lattice dynamics were also revealed near the T0 temperatures. The observed anomalies are assumed to originate from phase transitions at TT0, which entail changes in the structural and magnetic properties.  相似文献   

6.
Using the theory of high-temperature superconductivity based on the idea of the fermion-condensation quantum phase transition (FCQPT), we show that neither the d-wave pairing symmetry, the pseudogap phenomenon, nor the presence of the Cu-O2 planes is of decisive importance for the existence of high-T c superconductivity. We analyze recent experimental data on this type of superconductivity in different materials and show that these facts can be understood within the theory of superconductivity based on the FCQPT. The latter can be considered as a universal cause of high-T c superconductivity. The main features of a room-temperature superconductor are discussed.  相似文献   

7.
The energies of formation of vacancies in the carbon and silicon sublattices, the independent elastic constants, the all-round compression, shear and Young’s moduli, and the anisotropy coefficients are determined for the complete and nonstoichiometric cubic phases of 3C-SixCy (x, y = 1.0–0.75) by ab initio methods of the band theory. In the formalism of the density functional perturbation theory (DFPT), the phonon dispersion dependences are obtained for these phases (the comparison with the experiment is given for the complete phase). It is shown that the mechanical characteristics of the phases become strongly anisotropic upon the transition from 3C-SiC0.875 to 3C-SiC0.75. It is established from the analysis of the phonon dispersion curves that the 3C-SiC0.875 and 3C-SiC0.75 phases, in contrast to the complete 3C-SiC phase, are dynamically unstable at T = 0 K.  相似文献   

8.
We present an ab initio calculation of the screened self-energy correction for 1s2 2p3/2 and 1s2 2s states of Li-like ions with nuclear charge numbers in the range Z = 12?100. The evaluation is carried out to all orders in the nuclear strength parameter Zα. This investigation concludes our calculations of all two-electron QED corrections for the 2p3/2-2s transition energy in Li-like ions and thus considerably improves theoretical predictions for this transition for high-Z ions.  相似文献   

9.
The high-pressure magnetic states of iron borate 57FeBO3 single-crystal and powder samples have been investigated in diamond anvil cells by nuclear forward scattering (NFS) of synchrotron radiation at different temperatures. In the low-pressure (0 < P < 46 GPa) antiferromagnetic phase, an increase of the Neél temperature from 350 to 595 K induced by pressure was found. At pressures 46–49 GPa, a transition from the antiferromagnetic to a new magnetic state with a weak magnetic moment (magnetic collapse) was discovered. It is attributed to the electronic transition in Fe3+ ions from the high-spin 3d5 (S = 5/2, 6A1g) to the low-spin (S = 1/2, 2T2g) state (spin crossover) due to the insulator-semiconductor-type transition with extensive suppression of strong d-d electron correlations. At low temperatures, NFS spectra of the high-pressure phase indicate magnetic correlations in the low-spin system with a magnetic ordering temperature of about 50 K. A tentative magnetic P-T phase diagram of FeBO3 is proposed. An important feature of this diagram is the presence of two triple points where magnetic and paramagnetic phases of the high-spin and low-spin states coexist.  相似文献   

10.
In this work I present a generalization of f(R, T) gravity, by allowing the speed of light to vary. Cosmological solutions are presented for matter and radiation-dominated universes, the former allowing the universe expansion to accelerate while the latter contemplating a possible alternative to inflationary scenario. Remarkably, standard gravity is always retrieved for a special case of f(R, T).  相似文献   

11.
Ferromagnetism and ferroelectricity in Eu monochalcogenides have been investigated by ab initio density functional theory in the DFT+U approach. Exchange interaction parameters and Curie temperatures under pressure are studied and discussed using Heisenberg Hamiltonian with first and second-nearest-neighbor interactions. The calculations showed that the hydrostatic pressure perfectly improves the Curie temperature (EuO: T C = 175 K; EuS: T C = 33.8 K) and in the other hand it cannot induce the spontaneous polarization (P s ). The effect of uniaxial and biaxial pressure is also studied. Although the uniaxial strains slightly increases the Curie temperature, it ensures the ferrolectricity in these systems by producing a spontaneous polarization of the order of P s (EuO) = 57.50 μC/cm2 and P s (EuS) = 42.86 μC/cm2 with pressures of 5% and 4%, respectively. The search for new model systems is a necessity to better understand the physics related to multiferroïc materials and to consider possible applications.  相似文献   

12.
Low-field magnetizationM(H) measurements can be used to probe the nature of the screening currents and the interlayer coupling in high-T c cuprates. Here we compare theM(H) behaviour of single crystals of Bi2Sr2CaCu2O8 and fully oxygenated and oxygen reduced YBa2Cu3O7??. In YBa2Cu3O7, theM(H) behaviour is consistent with anisotropic 3D superconductivity whilst in Bi2Sr2CaCu2O8, the surface screening currents are strongly affected by the presence of vortices, implying that the CuO2 planes are coupled via a weak Josephson interaction. In oxygen-deficient YBa2Cu3O6.7 (T c =63K), theM(H) behaviour at low temperatures is similar to that found for Bi2Sr2CaCu2O8, implying that the removal of oxygen from the chains has resulted in a dimensional crossover of the superconducting state in YBa2Cu3O7??. As the temperature approachesT c , the 3D behaviour is eventually restored as thec-axis coherence length ξ c becomes comparable with the interlayer spacingd.  相似文献   

13.
Systematic ab initio LDA calculations were performed for all the typical representatives of recently discovered class of iron-based high-temperature superconductors: REOFe(As,P) (RE = La, Ce, Nd, Sm, Tb), Ba2Fe2As, (Sr,Ca)FFeAs, Sr4Sc2O6Fe2P2, LiFeAs and Fe(Se,Te). Non-monotonic behavior of total density of states at the Fermi level is observed as a function of anion height relative to Fe layer with maximum at about Δz a ~ 1.37 Å, attributed to changing Fe-As (P, Se, Te) hybridization. This leads to a similar dependence of superconducting transition temperature T c as observed in the experiments. The fit of this dependence to elementary BCS theory produces semiquantitative agreement with experimental data for T c for the whole class of iron-based superconductors. The similar fit to Allen-Dynes formula underestimates T c in the vicinity of the maximum, signifying the possible importance of non-phonon pairing in this region. These results unambiguously demonstrate that the main effect of T c variation between different types of iron-based superconductors is due to the corresponding variation of the density of states at the Fermi level.  相似文献   

14.
A study has been made of the effect of a dc electric field (0 < E < 4 kV/cm) on the optical transmittance of single-crystal compounds PbMg1/3Nb2/3O3-xPbTiO3 (PMN-xPT) located at the boundaries of the morphotropic region (x = 32.0 and 36.5%) and directly at the center of the morphotropic region (x = 35%). It is shown that, at temperatures close to the morphotropic phase transition point, the electric field induces two phase transitions in PMN-32PT and PMN-35PT crystals and only one phase transition in PMN-36.5PT. The tetragonal (T) phase induced in all three compounds remains stable after the electric field is removed only in crystals with x = 35.0 and 36.5%, whereas the T phase is metastable and transforms into the monoclinic M c phase after the field is switched off in the PMN-32PT crystals lying at the boundary of the morphotropic region on the rhombohedral side. It is found that the electric-field-induced intermediate phase M c in PMN-35PT is inhomogeneous and that M c transforms into the tetragonal phase in a continuous transition. It is suggested that only the presence of a third orthorhombic phase can account for the continuous character of the transition between the M c and T phases in PMN-35PT crystals. The results obtained are interpreted in terms of the Devonshire theory for strongly anharmonic crystals. The E-T phase diagrams are constructed for all the crystals.  相似文献   

15.
Thermal expansion and its anomalies in the vicinity of spin-reorientation phase transitions in single crystals of RFe11Ti (R=Y, Tb, Dy, Ho, and Er) compounds are investigated by the tensometric technique in the temperature range 77–400 K. The temperature dependences of the thermal expansion coefficient α(T) are obtained. It is found that the YFe11Ti and HoFe11Ti uniaxial magnetic materials exhibit pronounced anomalies in the α coefficient at T=200 and 290 K. For the TbFe11Ti single crystal, the α coefficient is close to zero in the vicinity of the spin-reorientation phase transition (at T=325 K). For the DyFe11Ti single crystal, which is characterized by two spin-reorientation phase transitions (at T=120 and 250 K), no features in the α(T) dependence are revealed in the region of the low-temperature spin-reorientation phase transition. In the ErFe11Ti single crystal, the specific feature of thermal expansion is observed at T ~ 220 K.  相似文献   

16.
Experimental data on the magnetization of canted antiferromagnet CoCO3 (TN = 18.1 K) in the paramagnetic region are described by the isotropic g factor g = g = 6.5 that differs from the anisotropic values g = 3.05 and g = 4.95 obtained in electron paramagnetic resonance (EPR) measurements at T = 4.2 K on Co2+ ions in magnetically diluted crystals. The g-factor values calculated in the Abragam-Pryce and Weiss molecular field approximations using the magnetization data in the magnetic ordered region correspond to data obtained in EPR measurements. It is shown that the absence of the anisotropy of the g factor at high temperatures cannot be explained in the approximations used. Causes of the observed discrepancies are discussed.  相似文献   

17.
On the basis of the k T -factorization approach, heavy-quarkonium \((c\bar c,b\bar b)\) hadroproduction at high energies is considered within nonrelativistic QCD in the leading order in α s and v. The p T spectra of various S-and P-wave quarkonium states at the Tevatron collider energies (run I and run II) are fitted, and sets of octet nonperturbative matrix elements are obtained for three different versions of the noncollinear gluon distribution in the proton.  相似文献   

18.
In this paper, we investigate the Noether symmetries of F(T) cosmology involving matter and dark energy. In this model, the dark energy is represented by a canonical scalar field with a potential. Two special cases for dark energy are considered, including phantom energy and quintessence. We obtain F(T)~T 3/4, and the scalar potential V(?)~? 2 for both models of dark energy and discuss quantum picture of this model. Some astrophysical implications are also discussed.  相似文献   

19.
We study f(T) cosmological models inserting a non-vanishing spatial curvature and discuss its consequences on cosmological dynamics. To figure this out, a polynomial f(T) model and a double torsion model are considered. We first analyze those models with cosmic data, employing the recent surveys of Union 2.1, baryonic acoustic oscillation and cosmic microwave background measurements. We then emphasize that the two popular f(T) models enable the crossing of the phantom divide line due to dark torsion. Afterwards, we compute numerical bounds up to 3-\(\sigma \) confidence level, emphasizing the fact that \(\Omega _{k0}\) turns out to be non-compatible with zero at least at 1\(\sigma \). Moreover, we underline that, even increasing the accuracy, one cannot remove the degeneracy between our models and the \(\Lambda \)CDM paradigm. So that, we show that our treatments contain the concordance paradigm and we analyze the equation of state behaviors at different redshift domains. We also take into account gamma ray bursts and we describe the evolution of both the f(T) models with high redshift data. We calibrate the gamma ray burst measurements through small redshift surveys of data and we thus compare the main differences between non-flat and flat f(T) cosmology at different redshift ranges. We finally match the corresponding outcomes with small redshift bounds provided by cosmography. To do so, we analyze the deceleration parameters and their variations, proportional to the jerk term. Even though the two models well fit late-time data, we notice that the polynomial f(T) approach provides an effective de-Sitter phase, whereas the second f(T) framework shows analogous results compared with the \(\Lambda \)CDM predictions.  相似文献   

20.
We analyze anew experiments on the NMR in cuprates and find an important information on their phase separation and its strip character hidden in the dependence of 1/63T1 on the degree of doping. In a broad class of materials, 1/63T1 is the sum of two terms: the temperature-independent one attributed to “ incommensurate” strips that occur at external doping and a “universal” temperature-dependent term ascribed to moving metallic and antiferromagnetic subphases. We argue that the frustrated first-order phase transition in a broad temperature interval bears a dynamical character.  相似文献   

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