Corona-charged polypropylene electrets analyzed by XPS

In the present study, we use X-ray photoelectron spectroscopy (XPS) analysis to clarify how different polarities of corona initiate various changes in the surfaces of polypropylene (PP) electrets subject to corona discharge. The samples were charged in three-electrode corona discharge system using positive and negative corona polarities at both −20 and 75 °C temperatures. The tests were divided into four groups. The surface potentials of the electret samples were measured using the vibrating electrode method with compensation. XPS studies were carried out by means of a VG ESCALAB Mk II electronic spectrometer using an Al Kα excitation source (hν=1486.6 eV). The spectra of C1s, O1s and N1s lines for all groups and for untreated samples were recorded and analyzed. The investigations that we carried out show that for negative-corona-charged samples, the oxygen content is approximately 2.4 times higher than that in positive-corona-charged samples. Based on the results we have obtained, we may assume that the changes in oxygen content in samples charged by different polarity coronas lead to the formation of different surface local levels. This assumption agrees well with the experimental measurement made on the electrets.     

Soot low-temperature combustion on Cu–Zr/ZSM-5 catalysts in O2/He and NO/O2/He atmospheres

Zirconium doped Cu/ZSM-5 catalysts were prepared and characterized in this investigation. Catalytic activity during soot combustion was determined in both O₂/He and NO/O₂/He atmospheres by temperature-programmed oxidation. The use of zirconium reduces the temperature of maximum soot oxidation rate by 229 °C in O₂/He atmosphere and 270 °C in NO/O₂/He atmosphere. The promoting effect of zirconium is discussed in terms of surface dispersion, enrichment of active components, and creation of oxygen vacancies where molecular oxygen or NO_x is adsorbed forming basic surface oxygen species active for soot oxidation. The NO₂ formed at the copper–zirconium interface sites leads to the ignition temperature being significantly decreased to 93 °C, which is inside the exhaust temperature range of diesel engines. To understand the combustion reaction kinetics, the activation energy and reaction order of soot combustion were evaluated. According to the Redhead method, the activation energy for non-catalyzed reaction is 164 kJ/mol under the O₂/He atmosphere. For the Cu/ZSM-5 and Cu–Zr/ZSM-5, the activation energies under the O₂/He atmosphere (134–151 kJ/mol) are slightly higher than those under the NO/O₂/He atmosphere (128–135 kJ/mol). The Freeman–Carroll method is suitable to describe the soot combustion in the NO/O₂/He atmosphere, with the activation energies for the catalysts in the range of 97–112 kJ/mol and the average value of reaction order equal to 1.36.     

Using an improved electrostatic precipitator for poultry dust removal

Pubic concerns related to particulate matter emissions from animal housing operations are increasing. The goal of this study was to custom develop a simple and low cost electrostatic precipitator (ESP) for poultry dust control. The performance of the improved electrostatic precipitator (iESP) to remove a test aerosol was evaluated under a series of operating voltages between ?60 kV and 60 kV. The mass and size distributions of the particles were measured by a cascade impactor. The overall dust removal efficiency ranged from 37% to 79% with the maximum efficiency obtained at ?30 kV. The iESP shows high removal efficiencies for particles less than 2.1 μm.     

Design and evaluation of a unipolar aerosol charger to generate highly charged micron-sized aerosol particles

In this study, a unipolar charger for generating highly charged microparticles was designed and its performance was evaluated both theoretically and experimentally. The measured particle charge number and corona current of the charger were in good agreement with the theoretical results from FLUENT. The experimentally determined average particle charge number of 1 μm PSL under an applied voltage of 8 kV was 128, which agreed well with the theoretically predicted and simulated values of 118 and 121, respectively. Computational calculations revealed the average charge of 10 μm particles to be 7560 at an applied voltage of 8 kV.     

Mechanism of electrohydrodynamically induced flow in a wire-non-parallel plate electrode type gas pump

An experimental investigation and one-dimensional modeling have been conducted to study the mechanism of net flow direction induced by electrohydrodynamic (EHD) forces in a wire-non-parallel plate electrode type EHD gas pump. The experiments were conducted with various different locations of corona wire electrode for negative and positive applied voltage from 0 to 14 kV at atmospheric pressure and room temperature, where air was used as the working fluid. A one-dimensional cross-sectional averaged model based on mass and momentum conservation as well as Poisson electric field and ion transport equations was also developed. The results show that the net flow direction of electrohydrodynamically induced gas flow in a wire-non-parallel plate electrode system significantly depends on the location of the corona wire electrode relative to the grounded electrode position. The effect of conversion angle of non-parallel plate electrode on the net flow direction and pressure drop also was investigated and discussed in detail.     

Development of a liquid stub tuner for the KSTAR ICRF system

A liquid stub tuner was developed to transmit a MW level of RF power continuously in the KSTAR (Korean Superconducting Tokamak Advanced Research) ICRF (ion cyclotron range of frequencies) heating and current drive systems. It is made of a 9–3/16″ coaxial transmission line, and the property of the RF wavelength difference in a liquid and in a gas due to their different dielectric constants is utilized. Silicon oil with a relative dielectric constant of 2.74 was used as the liquid, because of its low vapor pressure and low dielectric loss. The liquid stub tuner components were equipped with electrostatic probes, thermocouples, and a humidity sensor to measure the RF voltages, the liquid temperature, and the humidity in the coaxial transmission line, respectively. The level of the liquid for the liquid stub tuner can be changed from 0 to 2.8 m, which corresponds to 2.0 m mechanical length variation at 30 MHz. The RF power test of the liquid stub tuner was performed with various conditioned silicon oils at 30 MHz to compare the high voltage characteristics among various conditioned silicon oils. The stand-off voltage of 43.82 kV (average) was achieved for the liquid stub tuner during the 300 s operation.     

EHD flow measured by 3D PIV in a narrow electrostatic precipitator with longitudinal-to-flow wire electrode and smooth or flocking grounded plane electrode

In this work, results of three-dimensional (3D) Particle Image Velocimetry (PIV) measurements of the electrohydrodynamic (EHD) flow velocity fields in a narrow electrostatic precipitator (ESP) with a longitudinal-to-flow placed wire electrode are presented. The ESP was a narrow transparent acrylic box (90 mm×30 mm×30 mm). The electrode set consisted of a single wire discharge electrode and two plane collecting electrodes. Either two smooth stainless-steel plates or two stainless-steel plane meshes with nylon flocks were used as the collecting electrodes. The 3D PIV measurements were carried out in two parallel planes, placed longitudinally to the flow duct. The positive DC voltage of up to 9.5 kV was applied to the wire electrode through a 10 MΩ resistor. The collecting electrodes were grounded. The measurements were carried out at a primary flow velocity of 0.5 m/s. Obtained results show that the flow patterns for the smooth-plate electrodes and for the flocking plane electrodes are similar in the bulk of the flow. However, the flow velocities near the flocking plane electrodes are much lower than those near the smooth-plate electrodes. This is a beneficial phenomenon, because the lower the flow near the collecting electrodes, the lower re-entrainment of the particles deposited on the collecting electrodes occurs.     

The construction of a DC high voltage precision divider

A precise DC high-voltage divider was designed and constructed for use as a standard. The ratio of the divider for precise measurement must be known accurately independent of voltage and time. The changes in total resistance of a divider with voltage and time should be considered before design and construction. The divider consists of 100 wire-wound resistors with a total resistance of about 100 MΩ as the high-voltage arm and one wire-wound resistor with resistance of 100 kΩ as the low-voltage arm. The high voltage and ground electrodes were designed to prevent electric field concentration and corona formation at high voltages. A current measuring instrument with 6.5 digit resolution was developed to allow comparison of entering and existing currents for detection of current leakage. Considering the sources of error, a relative uncertainty of 66 ppm (parts per million) was obtained with coverage factor k = 2 for the constructed DC high-voltage divider.     

2-D corona field computation in configurations with ionising and non-ionising electrodes

An efficient method is proposed for the computation of the electric field strength and of the space-charge density in configurations of at least three ionising and non-ionising electrodes. The physical model is derived under the assumptions commonly accepted for the study of corona fields. The mathematical model makes use of a conformal mapping that converts the actual boundary-free field zone into a rectangular domain with well-defined boundary conditions. The finite-difference method is then used for solving the differential equations that describe the ionic space-charge and electric field distribution. The computational procedure was employed for studying the simple case of the drift zone of the corona discharge generated between a so-called dual electrode and a grounded plate. The dual electrode consisted of an ionising wire (diameter 0.22 mm) located at 20 mm from a tubular metallic support (diameter 25 mm). The computed current–voltage characteristic and current density distribution at the surface of the collector plate were in good agreement with the experimental data obtained for this combined corona–electrostatics electrode arrangement.     

EHD atomization characteristics of a point-plate system with a porous point electrode

An electrohydrodynamic (EHD) atomization from a point-to-plate system, with a wet porous point as a corona electrode, has been studied. And the atomized water droplets from the wet porous point, as well as the water droplet traces, the water droplet charge-to-mass ratios, and the water droplet number concentrations, were investigated. It was observed that the wet porous point can atomize abundant amounts of water droplet, 2.8, 2.6 and 2.2 mg/min for negative, AC and positive corona, respectively. The migrated water droplet traces were observed. The positive wet porous point atomized very fine water droplets than those obtained with the negative wet porous point. Moreover, the water droplets atomized from the AC corona showed granular-like larger traces. A weak corona discharge can atomize water droplets very effectively. On the other hand, an intensive corona discharge can eject more water droplets. As a result with the wet porous point, the maximum corona-current-based and corona-power-based water droplet atomization yields of Y_C = 3.34, 3.32 and 3.25 μg/μAs and Y_P = 0.35, 0.40 and 0.27 mg/Ws have been obtained for the negative, AC and positive corona discharges.     

Evaluation of probe size in STEM imaging at 30 and 60 kV

In order to estimate the probe size on the specimen surface in a newly developed low-acceleration-voltage (30–60 kV) atomic-resolution scanning transmission electron microscopy (STEM), we compared the intensity profiles of experimentally obtained annular dark field (ADF)-STEM images of Si–Si dumbbells and those of images simulated using a multislice method which takes chromatic aberration into account. However, the simulated ADF images at 30 and 60 kV were found not to match the corresponding experimental images. Subsequently, the simulated images were convolved with probe functions (normal distributions) of different widths until a good match was obtained between the images. This allowed the probe shapes corresponding to the experimental conditions to be determined. ADF-STEM images with chromatic aberration could then be calculated by an incoherent superposition of these probe functions over a range of energies. The full widths at half maximum for the probe functions were estimated to be 99.2 pm for 30 kV and 92.8 pm for 60 kV. The D59 diameters were calculated to be 154.0 pm for 30 kV and 127.8 pm for 60 kV. This means that the 30-kV probe has a larger tail than the 60-kV probe.     

Long RE123 coated conductors with high critical current over 500 A/cm by IBAD/PLD technique

We have developed long RE₁Ba₂Cu₃O_7?X (RE123) coated conductors with large current capacity by the ion beam assisted deposition (IBAD) and the pulsed laser deposition using hot wall heating (HW-PLD) technique. As a result, we could fabricate an 8 m-long Gd₁Ba₂Cu₃O_7?X (Gd123) coated wire with the minimum and maximum critical current (I_c) of 951 A/cm-w and 1003 A/cm-w at 77 K, 0 T, respectively, measured in 0.7 m-long sections by the standard 4-probe technique. Furthermore, we succeeded in preparation of over 600 m-long Gd123 coated wire with the uniform I_c distribution over 600 A/cm-w. It had average, maximum and minimum I_c of 665, 698, 609 A/cm-w, respectively. The n-values of the sample showed the maximum I_c and minimum I_c were 40 and 36, respectively. As a result, we set the new world record of I_c × L value as 374535 A m (= 609 A × 615 m). The in-field performance of this long wire was quite high as well; the minimum I_c exceeded 50 A/cm-w at 77 K, 3 T.     

Excess currents larger than the point contact limit in normal-metal/superconducting junctions

In a point contact NS junction, perfect Andreev reflection occurs over a range of voltages equal to the superconducting energy gap, producing an excess current of I_exc =  (4 / 3)(2 eΔ / h). If the superconductor has a finite width, rather than the infinite width of the point contact, one cannot neglect superfluid flow inside the superconducting contact. The energy range available for perfect Andreev reflections then becomes larger than the superconducting gap, since superfluid flow alters the dispersion relation inside the finite width superconductor. We find a maximum excess current of approximately (7 / 3)(2 eΔ / h) when the width of the superconductor is approximately 7 / 3 times the width of the normal metal.     

Modelling of corona discharge in cylinder-wire-plate electrode configuration

Numerical computation of the electric field strength and ionic space charge density in electrode systems consisting of ionizing wire and non-ionizing cylinder, connected to the same DC high-voltage supply and facing a grounded plate, is a difficult problem, which is of interest to several electrostatic processes applications. In a previous study a simple numerical method has been proposed to calculate the spatial distributions of electric field and ionic space charge in a case of a continuum and uniform corona discharge originating at the surface of the wire. The aim of the present paper is to improve the physical model of the corona discharge in this particular electrode configuration, by assuming a more realistic law of charge injection on the wire circumference. The computations were carried out for an ionizing wire of radius r=0.1 mm, located at different distances h from a metallic tubular support of radius R=13.4 mm.The initial conditions of the corona discharge took into account the non-uniformity of the charge injection around the ionizing wire electrode. The computational results were compared with those obtained under the assumption of uniform corona discharge. The comparison pointed out that neither the non-uniformity of the electric field nor that of the charge injection can be neglected. They depend on the geometry of the electrode system and affect the distribution of the electric field and of the space charge density in the inter-electrode gap.     

Efficient high voltage pulser for piezoelectric air coupled transducer

The design of high voltage pulser for air coupled ultrasound imaging is presented. It is dedicated for air-coupled ultrasound applications when piezoelectric transducer design is used. Two identical N-channel MOSFETs are used together with 1200 V high and low side driver IC. Simple driving pulses’ delay and skew circuit is used to reduce the cross-conduction. Analysis of switch peak current and channel resistance relation to maximum operation frequency and load capacitance is given. PSPICE simulation was used to analyze the gate driver resistance, gate pulse skew, pulse amplitude influence on energy consumption when loaded by capacitive load. Experimental investigation was verified against simulation and theoretical predictions. For 500 pF capacitance, which is most common for piezoelectric air coupled transducers, pulser consumes 650 μJ at 1 kV pulse and 4 μJ at 50 V. Pulser is capable to produce up to 1 MHz pulse trains with positive 50 V–1 kV pulses with up to 10 A peak output current. When loaded by 200 kHz transducer at 1 kV pulse amplitude rise time is 40 ns and fall time is 32 ns which fully satisfies desired 1 MHz bandwidth.     

Characterisations of CoCu films electrodeposited at different cathode potentials

Structural and magnetic properties of CoCu films electrodeposited on polycrystalline Cu substrates were investigated as a function of cathode potential used for their deposition. The compositional analysis, performed by energy dispersive X-ray spectroscopy, demonstrated that an increase in the deposition potential results in an increase in Co content of CoCu films. The crystal structure of the films was studied using the X-ray diffraction (XRD) technique. It was observed that they have a face centred cubic (fcc) structure, but also contain partly hexagonal close-packed phase. XRD results revealed that the (1 1 1) peak of fcc structure splits into two as Co (1 1 1) and Cu (1 1 1) peaks and the peak intensities change depending on the deposition potential and hence the film composition. The magnetic measurements were carried out at room temperature using a vibrating sample magnetometer. The magnetic findings indicated that coercivity decreases and saturation magnetisation increases with the increase of Co:Cu ratio caused by the deposition potential and also all films have planar magnetisation.     

Electret properties of ethylene–propylene random co-polymer

Thermally stimulated current (TSC) spectra were examined for ethylene–propylene (EP) random co-polymer at different charging voltages V_p with positive and negative polarities. Observed TSC spectra showed two well-separated TSC bands, B_L and B_H, which respectively appeared in the temperature regions below and above 100 °C. Observed V_p dependence of B_L was quite different from that of typical polypropylene homo-polymer: As V_p increased, B_L band grew keeping its peak position same at 65 °C, and the band shape unchanged, as if the traps responsible for the B_L band are a single set of traps with the same trap depth and capture cross section. The trap depth of B_L was about 1.9 eV and 1.7 eV for positively charged EP and talc-containing EP samples, respectively. EP samples also showed unique TSC bands above 100 °C: one is a narrow TSC band peaked at 120 °C and the other is an unusual TSC band which was non-vanishing even at 165 °C just before destruction of samples by their melting. Consequently, the utmost stable charge density in EP co-polymer above 100 °C was found to be 3.5 × 10^?4 C/m² and 6.0 × 10 ^?4 C/m² for positively and negatively charged samples, respectively. These equivalent surface charge densities are much larger than those of usual polypropylene homo-polymer.     

Modeling midwave infrared muzzle flash spectra from unsuppressed and flash-suppressed large caliber munitions

Time-resolved infrared spectra of firings from a 152 mm howitzer were acquired over an 1800–6000 cm^?1 spectral range using a Fourier-transform spectrometer. The instrument collected primarily at 32 cm^?1 spectral and 100 Hz temporal resolutions. Munitions included unsuppressed and chemically flash suppressed propellants. Secondary combustion occurred with unsuppressed propellants resulting in flash emissions lasting ～100 ms and dominated by H₂O and CO₂ spectral structure. Non-combusting plume emissions were one-tenth as intense and approached background levels within 20–40 ms. A low-dimensional phenomenological model was used to reduce the data to temperatures, soot absorbances, and column densities of H₂O, CO₂, CH₄, and CO. The combusting plumes exhibit peak temperatures of ～1400 K, areas of greater than 32 m², low soot emissivity of ～0.04, with nearly all the CO converted to CO₂. The non-combusting plumes exhibit lower temperatures of ～1000 K, areas of ～5 m², soot emissivity of greater than 0.38 and CO as the primary product. Maximum fit residual relative to peak intensity are 14% and 8.9% for combusting and non-combusting plumes, respectively. The model was generalized to account for turbulence-induced variations in the muzzle plumes. Distributions of temperature and concentration in 1–2 spatial regions demonstrate a reduction in maximum residuals by 40%. A two-region model of combusting plumes provides a plausible interpretation as a ～1550 K, optically thick plume core and ～2550 K, thin, surface-layer flame-front. Temperature rate of change was used to characterize timescales and energy release for plume emissions. Heat of combustion was estimated to be ～5 MJ/kg.     

Investigation of size effects in the electrical resistivity of single electrochemically fabricated gold nanowires

Single gold nanowires with diameters ranging between 80 and 300 nm were fabricated by electrochemical deposition in single-pore membranes. The wires were contacted by means of a macroscopic planar electrode on each membrane side. The resistance-versus-diameter behavior was measured and is discussed considering finite-size effects, i.e., additional electron scattering both at the wire surface and at grain boundaries. Resistance-versus-temperature curves display characteristics like a bulk metal that shows a linear behavior down to about 70 K and finally approaches a limited value below 40–50 K with a residual resistivity ratio ρ_300 K/ρ_20 K≈2.5. The temperature-dependent resistivity data of wires with diameters larger than 200 nm fit well with the model of Mayadas and Shatzkes for grain-boundary scattering, thus confirming that surface scattering is negligible in this range.     

Hall anomaly in CNT-doped Y-123 high temperature superconductor

In order to study the Hall effect in pure and CNT-doped Y-123 polycrystalline samples, we have measured the longitudinal and transverse voltages at different magnetic field (0 ? 9 T) in the normal and vortex states. In the normal state, the Hall coefficient is positive and decreases with increasing temperature, and can be approximately fitted to R_H = a + bT^?1. We have found a sign reversal in the pure sample for the magnetic field of about 3 T, and double sign reversal of the Hall coefficient in the 0.7 wt% CNT-doped sample at about 3 and 5 T. The Hall resistivity in our samples depends on the pinning.