IR-spectra of (CO2)2 dimers and collision-induced absorption of carbon dioxide in the region of the fermi doublet (ν1, 2ν2)

The positions and intensities of all vibrational transitions in the (ν₁, 2ν₂) Fermi doublet region of (CO₂)₂ dimers are obtained by means of variational method. The collision-induced absorption in compressed carbon dioxide is shown to be mainly due to dimeric absorption. Assignment of ν₁ and 2ν₂ vibrational bands in isolated CO₂ molecule is performed by consideration of the symmetries and intensities of dimeric vibrations.     

Cl nuclear quadrupole resonance studies of molecular motions of ClO3 and water diffusion in Ca(ClO3)2·2H2O

A ³⁵Cl nuclear quadrupole resonance (³⁵Cl-NQR) investigation of polycrystalline Ca(ClO₃)₂·2H₂O is described. The ³⁵Cl-NQR frequencies (ν_Q) for two resonance lines (ν_Q1 and ν_Q2), the spin lattice relaxation time (T_1Q) for ν_Q2 only and the line width δν_Q2 were measured in the temperature range 292–345 K, except for the frequency measured up to 455 K. The observed decrease in the resonance frequencies with increasing temperature permitted the determination of the frequencies of librations of the ClO₃⁻ ion about two axes perpendicular to the three-fold axis of the ion mainly responsible for this effect. The temperature dependence of the relaxation time T_1Q proved the occurrence of water diffusion and hindered rotation of ClO₃⁻ ions. The activation energies of these two molecular motions were determined, and their effect on the electric field gradient at the site of a chlorine nucleus was discussed. Temperature measurements of the line width δν_Q2 confirmed the conclusions drawn from the analysis of T_1Q(T).     

Integrated band intensities in N2O4 in the infrared range

We have measured the integrated band intensities of the ν₉ and ν₁₁ bands of N₂O₄ which are observed around 1757 and 1261 cm^-1, respectively. By varying temperature and pressure, we have obtained: S_band(ν₉) = 9.60(130), 9.10(24), 8.80(66) and S_band(ν₁₁)= 5.93(64), 5.70(21) and 5.33(46) (in 10^-17 cm/molecule) at 293.15 (60), 277.25 (60) and 261.65 (60) K, respectively.     

Two separate Li ionic motions observed by Li and B NMR in xLi2S + (1 − x)B2S3 glassy fast ionic conductors

Studies of ion dynamics in the highly conductive glassy fast ionic conductor (FIC) xLi₂S + (1 − x)B₂S₃ (x = 0.65 and 0.70) were made with NMR nuclear spin lattice relaxation (NSLR) R₁(ω, T) of both mobile ⁷Li and immobile ¹¹B ions, and ⁷Li NMR line narrowing δν(T). The possible dependence of ion dynamics on the short range order structures (SRO) and the distribution of activation energies (DAE) in this highly conductive FIC was investigated. Two Gaussian DAE were employed to fit ⁷Li NSLR data, where each Gaussian DAE was correlated to a separate ¹¹B NSLR in a BS₃ and in a BS₄ group. The long range diffusion of Li ions among BS₃ groups and a seemingly localized ionic hopping motion around BS₄ group is suggested as a microscopic model for the ion dynamics in thioborate glasses, namely a ‘two channel relaxation’.     

Photo-excitation of single crystals of La2CuO4+δ near the metal-insulator transition

Transient photoconductivity (σ_ph) experiments have been carried out in single crystals of insulating La₂CuO_4+δ near the metal-insulator transition (δ≈ 1–2%). The time evolution of the σ_ph changes dramatically with light intensity (I_L). At low I_L, σ_ph is characterized by power law time decay, t⁻, in the nanosecond time regime, and the exponent, , decreases significantly with increasing I_L. As I_L increases to 5 × 10¹⁵ photons/cm₂, σ_ph reaches 15 S/cm, and the lifetime of the conducting state is enhanced by more than two orders of magnitude: σ_ph exhibits a delayed peak centered at approximately 30 ns. followed by exponential decay with time constant of 360 ns. The data reveal a continuous distribution of localized electronic states above the (hole) mobility edge; the M-I transition is achieved when the Fermi level is shifted away from the localized states and across the mobility edge either by chemical dopiing or by photo-excitation. The time of σ_ph at high I_L implies the formation of metastable metallic droplets after photo-excitation.     

Spectral intensities in the ν1 band of NH3

Intensities have been measured for individual transitions in the Q and R branches of the ν₁ band of NH₃ using a difference-frequency laser spectrometer. The data yield an integrated band strength of S⁰_v=219.36±1.03 cm^-2/MPa at 297 K, corresponding to a transition moment of μ_v = 8.535(20) × 10^-32 C·m, and a Herman-Wallis correction factor, (1 + _jm)², where _j = 0.0209(20). The intensities of a few lines for K 7 were noticeably perturbed by a perpendicular Coriolis interaction with 2ν₄ (E, L = 2), so were excluded from the fit. A small sample of ν₃ band lines occurring in the ν₁ band scans also yields a rough estimate of the ν₃ band intensity with evident irregular perturbations.     

Conductivity peaks broadening in the quantum Hall regime

We argue that it is the hopping transport that is responsible for broadening of the σ_xx peaks. Explicit expressions for the width Δν of a peak as a function of the temperature T, current J and frequency ω are found. It is shown that Δν grows with T as (T/T₁)^κ, where κ is the inverse localization-length exponent. The current J is shown to act like the effective temperature T_eff(J) ∝ J^1/2 if . Broadening of the ohmic ac-conductivity peaks with frequency ω is found to be determined by the effective temperature      

Reconciling cold dark matter with COBE/IRAS plus solar and atmospheric neutrino data

We present a model where an unstable MeV Majorana tau neutrino can naturally reconcile the cold dark matter model (CDM) with cosmological observations of large and small scale density fluctuations and, simultaneously, with data on solar and atmospheric neutrinos. The solar neutrino deficit is explained through long wavelength, so-called just-so oscillations involving conversions of ν_e into both ν_μ and a sterile species ν_s , while atmospheric neutrino data are explained through ν_μ to ν_e conversions. Future long baseline neutrino oscillation experiments, as well as some reactor experiments will test this hypothesis. The model is based on the spontaneous violation of a global lepton number symmetry at the weak scale. This symmetry plays a key role in generating the cosmologically required decay of the ν_τ with lifetime τ_ντ ≈ 10²-10⁴ seconds, as well as the masses and oscillations of the three light neutrinos ν_e, ν_μ and ν_s required in order to account for solar and atmospheric neutrino data. It also leads to the invisibly decaying Higgs signature that can be searched at LEP and future particle colliders.     

Cu NMR study of the superconducting thiospinel Cu1.5Rh1.5S4

The ⁶³Cu NMR Knight shift K and spin-lattice relaxation rate 1/T₁ have been measured to study the thiospinel superconductor Cu_1.5Rh_1.5S₄ from a microscopic viewpoint. K is negative and has a weak dependence on temperature, and the hyperfine coupling constant H_hf^d is estimated to be −52.4 kOe/μ_B. 1/T₁ is proportional to the temperature in the normal state. In the superconducting state, 1/T₁ takes a coherence peak just below T_c, and decreases exponentially well below T_c, from whose temperature dependence the superconducting energy gap has been proved to be close to 2Δ = 3.52k_BT_c given by the BCS theory.     

Structural and optical properties of thermally evaporated Bi2Te3 films

Bi₂Te₃ films were prepared by thermal evaporation technique. X-ray diffraction analysis for as-deposited and annealed films in vacuum at 150 °C were polycrystalline with rhombohedral structure. The crystallite size is found to increase as the film thickness increases and has values in the range 67–162 nm. The optical constants (the refractive index, n, and absorption index, k) were determined using transmittance and reflectance data in the spectral range 2.5–10 μm for Bi₂Te₃ films with different thicknesses (25–99.5 nm). Both n and k are independent on the film thickness in the investigated range. It was also found that Bi₂Te₃ is a high refractive index material (n has values of 4.7–8.8 in the wavelength range 2.5–10 μm). The allowed optical transitions were found to be direct optical transitions with energy gap  eV. The optical conductivities σ₁ = ƒ(hν) and σ₂ = f(hν) show distinct peaks at about 0.13 and 0.3 eV, respectively. These two peaks can be attributed to optical interband transitions.     

Low-temperature AC conductivity of Bi2Sr2CaCu2O8+δ

We report measurements of anamolously large dissipative conductivities, σ₁, in Bi₂Sr₂CaCu₂O_8+δ at low temperatures. We have measured the complex conductivity of Bi₂Sr₂CaCu₂O_8+δ thin films at 100–600 GHz as a function of doping from the underdoped to the overdoped state. At low temperatures there exists a residual σ₁ which scales with the T=0 superfluid density as the doping is varied. This residual σ₁ is larger than the possible contribution to σ₁ from a thermal population of quasiparticles (QP) at the d-wave gap nodes.     

The 3ν3 overtone bands of UF6 and UF6

The absorption specta of CO laser radiation by 3ν₃ overtone bands of ²³⁸UF₆ and ²³⁵UF₆ has been measured using photoacoustic spectroscopic techniques. For the two temperatures 250 K and 290 K, measured absorption coefficients and cross-sections of the 3ν₃ band of ²³⁵UF₆ are reported for the first time.     

Optical characterization of amorphous Ga50Se45S5 films

The transmission spectra of thermally evaporated Ga₅₀Se₄₅S₅ films were measured over the wavelength range 300–900 nm. A simple method, suggested by Swanepoel, was used for the determination of the optical constants and thickness of the films. Increasing the thickness of the film beyond 450 nm does not affect the optical constants. The dependence of the absorption coefficient on the photon energy (hν) at the edge of the absorption band is well described by the relation hν=β(hν−E_opt)² with an optical gap equals 2.4 eV. A good fit of the experimental points with Tauc relation indicates that non-direct transition is the most probable mechanism responsible for the photon absorption inside the investigated film.     

Anelastic relaxation of Pr1/2Ca1/2MnO3 at low and medium frequencies in the 350–500 K range

In previous works (Jornadas SAM 2000; J. Magn. Magn. Mater. 226–230 (2001) 988) the low-frequency anelastic effects of two manganite perovskites of La_2/3Sr_1/3MnO₃ and La_2/3Ca_1/3MnO₃ were studied at 1 Hz and temperatures above those of the metal–insulator transition. An important internal friction peak (P1) appears at 414 and 419 K, respectively, with a modulus variation and no appreciable contribution to electrical resistivity. Another compound Pr_1/2Ca_1/2MnO₃ of the same family has been studied by anelastic mechanical spectroscopy in order to add new data which could elucidate the (P1) peak mechanism. The measurements were made in a sub-resonant forced pendulum (0.1–20 Hz) and in a vibrating reed equipment (kHz range). A stable (P1) peak has been detected at 410 K (1 Hz), with a corresponding modulus step. The appearance of this relaxation peak in the Pr_1/2Ca_1/2MnO₃ compound, and its high activation energy value, similar to the other compounds measured, indicates that the microscopic origin of this relaxation does not correspond to an oxygen jump (characteristic activation energy0.8–0.9 eV).     

High resolution cw cars spectroscopy of the q-branch of the ν2 band in C2H2

The fully resolved spectrum of the Q-branch of the ν₂ band in acetylene has been obtained by cw CARS spectroscopy with a resolution of 40 MHz. The dispersion of χ⁽³⁾ and the linewidth of this Raman mode were investigated over the pressure range 0.05–5 atm. The constant of rotational-vibrational coupling was measured to be £ = (5.91 ± 0.05) × 10^-3 cm^-1.     

μSR study of Fe2P in the paramagnetic state

Using transverse field μSR measurements, a search for longlived magnetic correlations in the itinerant ferromagnet Fe₂P at temperatures significantly above the Curie temperatures has been made. No correlations with a lifetime longer than ≈ 10^-10 s could be found.     

Thermal transport in the oxygenated magnetic superconductor, Eu1.5Ce0.5RuSr2Cu2O10+δ

The thermal conductivity and thermopower are reported for a hole doped Eu_1.5Ce_0.5RuSr₂Cu₂O_10+δ sample that has been annealed at 1100 K under an oxygen pressure of 54 atm. At T_c=45 K superconductivity and weak ferromagnetism coexist (T_m=180 K). Weak features in the thermopower, S(T), and thermal conductivity, κ(T), are observed both at T_m and at T^*=140 K. The thermopower begins to decrease sharply toward zero at T_c, and there is an extremely sharp increase of about 30% in the thermal conductivity at T_c. This “first order” transition may be related to the sudden appearance of a spontaneous vortex phase at T_c. A small shoulder is observed in κ(T) in the temperature range T=5–13 K.     

Inhomogeneous Tl NMR line broadening in Tl2Ba2CuOx single crystals

Temperature and angular dependences of ²⁰⁵Tl line width, Δ , and transverse relaxation time, τ, have been measured in two crystals of Tl₂Ba₂CuO_x with T_c = 32 and 115 K, respectively. In the normal state both Δ and τ have been found to be temperature-independent and not to vary with varying T_c, implying that the size of inhomogeneous broadening is also invariable. Analysis of the line width angular dependence shows that the inhomogeneous broadening originates, most probably, from local distortions associated with Cu substitution for Tl. A conclusion is that variations in T_c are not related to this substitution.     

Resistivity and thermoelectric power of Bi2Sr2Ca−xPrxCu2Oy system

Samples of Bi₂Sr₂Ca_1−xPr_xCu₂O_y have been characterized by resistivity and thermoelectric power measurements. All metallic samples show superconductivity with a maximum T_c = 90 K at X = 0.2. The sample of x = 0.6 shows a crossover from hopping conduction at low temperature above T_c to metallic conduction at high temperature. For the metallic samples below x = 0.6, the results of thermoelectric power are well fitted by both of a phenomenological band spectrum model and the Nagaosa and Lee model.     

NMR study of local hole distribution, spin fluctuation and superconductivity in Tl2Ba2Ca2Cu3O10

⁶³Cu, ¹⁷O and ²⁰⁵Tl NMR have been performed in the high-T_c superconductor Tl₂Ba₂Ca₂Cu₃O₁₀ whose T_c(max) is 127 K. The hole densities at Cu and oxygen sites in the CuO₂ plane have been extracted from the nuclear quadrupole frequency ν_Q. The striking feature is that the Cu holes are significantly transferred to oxygen site due to strong hybridization between Cu and oxygen. From an analysis of T₁ and T_2G, it has been found that the spectral weight of the spin fluctuation is transferred to higher energy compared to YBa₂Cu₃O₇, while the magnetic correlation length ξ does not differ much. Thus, it is suggested that the higher T_c is due to higher characteristic energy of spin fluctuations, i.e. the superconductivity is spin fluctuation mediated. The superconducting properties are consistently explained by a d-wave superconductivity model with a finite density of states (DOS) at the Fermi level. We show that the disorder of the Ca/TlO layer caused by the partial inter-substitution of Tl and Ca is responsible for the potential scattering to produce such a DOS. It is found that if such a potential scattering were absent, T_c would go up to 132 K which is quite close to the record T_c realized in the Hg based compound.