Measurements of rotational transitions and hyperfine structure in PH2D

New rotational transition frequencies and measurements of hyperfine structure on two transitions are reported for PH₂D. All observed transitions are Q branch (ΔJ = 0) so only two independent rotational constants are obtained. These are A-C = 46 593.44 ± 0.67 MHz and κ(A-C) = 2B-A-C = ?34 545.9 ± 1.3 MHz. Nine transitions were fit to these parameters and the distortion parameter D_JK to obtain D_JK = 4.30 ± 0.04 MHz. Hyperfine structure due to spin-rotation interactions was observed on the 1₁₀ ← 1₁₁ transition at 6 024.645 MHz and on the 4₁₄ ← 4₀₄ transition at 20 815.334 MHz. Spin-rotation tensor components obtained are $\text{(M}{}_{\mathrm{aa}}\text{+ M}{}_{\mathrm{bb}}\text{)}\text{2}\text{=}\text{(M}{}_{\mathrm{aa}}\text{+ M}{}_{\mathrm{cc}}\text{)}\text{2}\text{= ?98 ± 3}\text{kHz}$.     

Hartree-fock wave functions and oscillator strengths for the helium isoelectronic sequence

Oscillator strengths for 1¹S?n¹P transitions for some members of the helium isoelectronic sequence have been calculated by utilizing the dipole length, velocity and acceleration forms of the transition matrix element with coupled H.F. wave functions. Good agreement has been obtained between the values of the oscillator strengths. The quantities $\text{(?}{}_{\mathrm{A}}\text{??}{}_{\mathrm{L}}\text{)}$ and $\text{(?}{}_{\mathrm{A}}\text{??}{}_{\mathrm{V}}\text{)}$ decrease slowly with nuclear charge Z, whereas $\text{(?}{}_{\mathrm{L}}\text{-?}{}_{\mathrm{V}}\text{)}$ first increase to a maximum value and then decreases slowly.     

Study of 11B at high excitations with the 9Be(3He,p)11B and 9Be(α, d)11B reactions

The nucleus ¹¹B has been studied over the excitation energy range from 8.5 MeV to 21.5 MeV with the ⁹Be(³He, p)¹¹B / reaction at / E_{³He = 38 MeV}. The analogs of the parent states in ¹¹Be have been located at 12.56, 12.92, 14.40, 16.44, 17.69, 18.0, 19.15 and 21.27 MeV. A complementary measurement with the ⁹Be(α, d)¹¹B reaction at E_α = 48 MeV demonstrates that the 16.44, 17.69, 18.0 and 19.15 MeV resonances have rather pure isospin $\text{T}{}_{\mathrm{f}}\text{=}\text{3}\text{2}$. The 14.40 MeV state is a strongly isospin-mixed analog of the $\text{5}\text{2}{}^{\mathrm{+}}\text{1.78}\text{MeV}$ state in ¹¹Be. It is argued that spin S = 1 transfer is involved in the excitation of the 16.44 MeV state and its 3.887 MeV parent in ¹¹Be in a two-step stripping process. The $\text{T}{}_{\mathrm{f}}\text{=}\text{1}\text{2}$ states and the lowest three $\text{T}{}_{\mathrm{f}}\text{=}\text{3}\text{2}$ states are compared with the predictions of DWBA utilizing shell-model form factors. It is concluded that the $\text{T}{}_{\mathrm{f}}\text{=}\text{1}\text{2}$ strength is more strongly fragmented than is implied by the calculations of Teeters and Kurath.     

Study of the germanium isotopes with the (p,t) reaction

The levels of ^{70, 71, 72, 74}Ge have been investigated with the (p, t) reaction at 20 MeV. Strong transitions to the ground state and to the 2₁⁺ and 3₁^? collective levels were observed for all even isotopes. A comparison of the experimental angular distributions with those calculated assuming a closed ⁷⁰Ge core indicates that only ≈ 15% of the observed ground state L = 0 transition strength comes from $\text{(1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^2\text{and}\text{(2}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}{}^2$ pick up. The excitation energies and L-transfers obtained in the present work are found to be in generally good agreement with previous data.     

Spectroscopy of 62Ni with the 61Ni(d, p) reaction

Differential cross sections, vector and tensor analysing powers have been measured for the ⁶¹Ni(d, p) reaction at a deuteron energy of 12.3 MeV. Most of the 30 transitions observed below 8.5 MeV excitation are dominated by a single j-value, which was determined from behaviour of the analysing power data. For a number of transitions it was possible to make unambiguous j-assignment relying on the established j-dependence of the T₂₂ tensor analysing power. The deduced spectroscopic factors indicate that the full strength of neutron transfer to the ($\text{2p, 1f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$) and $\text{1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ orbits was found and seven $\text{5}\text{2}{}^{\mathrm{+}}$ transitions were located above 5.3 MeV. The separated strengths of the $\text{3}\text{2}{}^{\mathrm{?}}\text{,}\text{1}\text{2}{}^{\mathrm{?}}\text{and}\text{5}\text{2}{}^{\mathrm{?}}$ transitions are compared with shell-model calculations for the low-lying states of ⁶²Ni.     

“Forbidden” rotational spectra of symmetric-top molecules: PH3 and PD3

A millimeter-wave spectrometer having a sensitivity of 4 × 10^?10 cm^?1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure J → J, K = 0 ← 3 transitions in PH₃ and J → J, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD₃. The B₀ and C₀ spectral constants (in MHz) are: for PH₃, B₀ = 133 480.15 ± 0.12 and C₀ = 117 488.85 ± 0.16; for PD₃, B₀ = 69 471.10 ± 0.03 and C₀ = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.420}{}_0$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.34}{}_5$; for PD₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.417}{}_6$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.35}{}_9$. The corresponding zero-point-average values were calculated to be: for PH₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4269}{}_9\text{± 0.0002}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.228}{}_7$; for PD₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4226}{}_5\text{± 0.0001}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.256}{}_7\text{± 0.004}$. For both species, the equilibrium values are $\text{r}{}_{\mathrm{e}}\text{(}\text{A}\text{?}\text{) = 1.4115}{}_9\text{± 0.0006}$ and $\text{α}{}_{\mathrm{e}}\text{(}{}^{\mathrm{o}}\text{) = 93.32}{}_8\text{± 0.02}$.     

Study of the 91Zr(d, 3He)90Y reaction

The ⁹¹Zr(d, ³He) reaction was studied at a deuteron energy of 28 MeV. Angular distributions were measured from 13° to 47°; l_p values were extracted for the prominent lines of ⁹⁰Y. The l_p values and transition strengths were determined by DWBA analysis. The angular distributions for the $\text{(π}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}$ doublet (g.s. and 0.20 MeV state) exhibit the characteristic l = 1 shape. States at 1.42, 1.57, 1.64 and 1.81 MeV were also populated strongly in the (d, ³He) reaction; the 1.42, 1.57 and 1.81 MeV levels contain l= 1 transition strength and are most likely members of the $\text{(π}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}$ multiplet. The 2.03 MeV state has a characteristic l = 3 angular distribution and is suggested to be the only member of the $\text{(π}\text{f}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}$ sextet to be unambiguously observed in this study, most probably the 5^? or 4^? member. The members of the $\text{(π}\text{g}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}$ sextet were populated weakly (less than 100 μb/sr) in this reaction.     

The reaction 55Mn(d, t)54Mn

Neutron pick-up cross sections and vector analyzing powers have been measured for the reaction ⁵⁵Mn($\text{d}$, t)⁵⁴Mn at 17 MeV. The mixture of $\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ to $\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ transfer to the low-lying l_n = 1 states has been found. Evidence of the $\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$ hole nature of several strong l_n = 3 states above 1 MeV has been obtained.     

Chiral symmetry breaking in QCD; Mesons as spin waves

The strong chiral symmetry breaking in Wilson's lattice version of QCD is discussed and interpreted as a necessary manifestation of the triangle anomaly. At strong coupling the effective hamiltonian acting in the s-wave hadron sector is found to describe a generalized antiferromagnet which is analyzed with the $\text{1}\text{2}\text{S}\text{(= 1/N, N = N}{}_{\mathrm{<mtext>color</mtext>}}\text{)}$ expansion known in the theory of magnetism. Mesons emerge as spin waves: pseudoscalars as Nambu-Goldstone bosons, vectors as “dormant” Goldstone bosons. Current and dynamical quark masses are identified, such that m_P² ∫ m(cur), m_v≈2[m(cur) + m(fyn)], and a fit to the particle spectrum gives m(dyn) = 390 MeV, m_u,d(cur) = 5.4 MeV, m_s(cur) = 140 MeV, m_c(cur) = 1.07 GeV. Static baryons emerge with a mass m_B = N[m(dyn) + m(cur)] + a contribution which is argued to vanish in the continuum limit. Vector and axial vector currents are defined on the lattice and studied at strong coupling. The relations $\text{1 =}\text{3}\text{5}\text{g}{}_{\mathrm{<mtext>A</mtext>}}\text{γ}{}_{\mathrm{?}}\text{(f}{}_{\mathrm{\pi }}\text{/m}{}_{\mathrm{?}}\text{)(Z}{}_{\mathrm{\pi }}\text{/Z}{}_{\mathrm{?}}\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, Z_π/Z_? = 3.0 are found to agree with experiment. The resolution of the U(1) problem at strong coupling is discussed.     

Gauge invariance and renormalization

The renormalization of Abelian and non-Abelian local gauge theories is discussed. It is recalled that whereas Abelian gauge theories are invariant to local c-number gauge transformations δA_μ(x) = ?_μ,…, with □Λ = 0, and to the operator gauge transformation δA_μ(x) = ?_μφ(x), …, δφ(x) = α^?1?·A(x), with □φ = 0, non-Abelian gauge theories are invariant only to the operator gauge transformations $\text{δA}{}_{\mathrm{\mu }}\text{(x) ～}\textcolor{red}{}{}_{\mathrm{\mu }}\text{C(x)}$, …, introduced by Becchi, Rouet and Stora, where

_μ is the covariant derivative matrix and C is the vector of ghost fields. The renormalization of these gauge transformation is discussed in a formal way, assuming that a gauge-invariant regularization is present. The naive renormalized local non-Abelian c-number gauge transformation $\text{δA}{}_{\mathrm{\mu }}\text{(x) = (Z}{}_1\text{/Z}{}_3\text{)gA}{}_{\mathrm{\mu }}\text{(x) ×}\text{Λ}\text{(x)+?}{}_{\mathrm{\mu }}\text{Λ}\text{(x)}$, …, is never a symmetry transformation and is never finite in perturbation theory. Only for $\text{Λ}\text{(x) = (Z}{}_3\text{/Z}{}_1\text{)L}$ with L finite constants or for $\text{Λ}\text{(x) = Ω}\text{z}\text{?}{}_3\text{C(x)}$ with Ω a finite constant does it become a finite symmetry transformation, where $\text{z}\text{?}{}_3$ is the ghost field renormalization constant. The renormalized non-Abelian Ward-Takahashi (Slavnov-Taylor) identities are consequences of the invariance of the renormalized gauge theory to this formation. It is also shown how the symmetry generators are renormalized, how photons appear as Goldstone bosons, how the (non-multiplicatively renormalizable) composite operator A_μ × C is renormalized, and how an Abelian c-number gauge symmetry may be reinstated in the exact solution of many asymptotically fr ee non-Abelian gauge theories.     

Study of isovector charge-exchange excitations and their decay via the 16O(3He,tp) reaction

The nucleus ¹⁶F was studied via the ¹⁶O(³He, t) reaction at 81 MeV. Differential cross sections for many states were obtained and interpreted with DWBA calculations, using microscopic wave functions and an effective projectile-nucleon interaction. Proton decay to several states in ¹⁵O was observed and angular correlations for protons in coincidence with tritons detected at θ = 0° were measured. Several spin-parity assignments have been made. The distribution of isovector ΔL = 1 strength could be deduced. The analog of the giant dipole resonance ($\text{E}{}_{\mathrm{<mtext>x</mtext>}}\text{? 9.5}\text{MeV}\text{)}$ is strongly excited. The magnetic quadrupole strength has two strong components, one low, at E_x = 0.424 MeV, and one high, at $\text{E}{}_{\mathrm{<mtext>x</mtext>}}\text{? 7.5}\text{MeV}$. Evidence is given for a proportionality between cross section and M2 strength for transitions to J^π = 2^? states, which possibly make the (³He, t) reaction a suitable tool for determining quantitatively isovector M2 (or B_ij) strengths.     

Eigenfunction expansions of operators admitting separation of an infinite number of variables

Let A_k be a self-adjoint operator in a Hilbert space H_k (k = 1, 2, …) and let $\text{L}$ be an operator of the form $\text{L}\text{= A}{}_{\mathrm{r}}\text{? 1 ? 1 ? … + 1 ? A}{}_2\text{? 1 ? 1 ? … + …}$ acting in the infinite tensor product $\text{?}\text{k=1}\text{∞}\text{H}{}_{\mathrm{k}}$. We construct the spectral theory of these operators. In particular, the expansion is generalized eigenvectors of this operator is constructed using the eigenvectors of the operators A_k.     

Analyzing power measurements for n-p scattering between 13.5 and 16.9 MeV

The analyzing power A_γ(θ) for neutron-proton scattering has been measured for θ = 90°(c.m.) from 13.5 to 16.9 MeV and from θ = 50° to 145°(c.m.) at 16.9 MeV. Extensive Monte Carlo calculations have been made to correct for multiple scattering effects. Overall uncertainties are about ± 0.002. All the A_γ(θ) data, but primarily those at 16.9 MeV, disagree with predictons based on the phase-shift sets which have been derived previously by way of global analyses of nucleon-nucleon scattering data. Data for the product σ(θ)A_γ(θ) have been fitted with an expansion of the form (sin θ)($\text{a}{}_0\text{+ a}{}_1\text{cos}\text{θ + a}{}_2\text{cos}{}^2\text{θ)}$. For the first time the need for a non-zero a₂ has been illustrated for energies below 20 MeV. This parameter is shown to be related to the nucleon-nucleon F-state spin-orbit phase parameter. In addition, the P, D, and F spin-orbit phase parameter values derived from the present data differ significantly from the ones based on the Yale-IV and Liver-more-X global analyses. The derived D and F spin-orbit phase parameters also differ from those obtained in the recent analysis of nucleon-nucleon scattering data by Arndt et al.     

Molecular structure of phosgene as studied by gas electron diffraction and microwave spectroscopy: The rz structure and isotope effect

The r_z structure of phosgene has been determined by a joint analysis of the electron diffraction intensity and the rotational constants as follows: $\text{r}{}_{\mathrm{z}}\text{(}\text{CO}\text{) = 1.1785 ± 0.0026}\text{A}\text{?}$, $\text{r}{}_{\mathrm{z}}\text{(}\text{CCl}\text{) = 1.7424 ± 0.0013}\text{A}\text{?}$, ∠_z;ClCCl = 111.83 ± 0.11°, where uncertainties represent estimated limits of experimental error. The effective constants representing bond-stretching anharmonicity have been obtained from an analysis of the isotopic differences in the r_z structure: $\text{a}{}_3\text{(}\text{CO}\text{) = 2.9 ± 0.9}\text{A}\text{?}{}^{\mathrm{?1}}$, $\text{a}{}_3\text{(}\text{CCl}\text{) = 1.6 ± 0.4}\text{A}\text{?}{}^{\mathrm{?1}}$. The equilibrium bond distances have been estimated from the r_z structure for the normal species and from the anharmonic constants to be $\text{r}{}_{\mathrm{e}}\text{(}\text{CO}\text{) = 1.1756 ± 0.0032}\text{A}\text{?}$, $\text{r}{}_{\mathrm{e}}\text{(}\text{CCl}\text{) = 1.7381 ± 0.0019}\text{A}\text{?}$.     

(f72)7,0−2 configuration high-spin states in 60Co strongly excited in the 62Ni(d, α) reaction

The ${}^{62}\text{Ni}\text{(}\text{d}\text{, α)}{}^{60}\text{Co}$ reaction has been studied with 78 MeV vector polarized deuterons. Angular distributions of the differential cross section and vector analyzing power have been measured for strongly populated states in ⁶⁰Co up to an excitation energy of 5 MeV. The transferred orbital and total angular momenta L and J were determined from the characteristic shapes of the differential cross sections and vector analyzing powers yielding a number of new spin assignments. The J^π = 7⁺ stretched configuration was found to be distr least over nine states located at 1.51, 3.09, 3.46, 3.67, 3.78, 4.04, 4.55, 4.70 and 4.80 MeV.     

The uniform and the strong topology on realizations of the algebra of polynomials

It is shown that under quite general assumptions on the operators A₁,…,A_n (unbounded, symmetric) and on the domain $\text{D}$ on the realization $\text{P}\text{(A}{}_1\text{,…,A}{}_{\mathrm{n}}\text{)}$ of the algebra of polynomials $\text{P}\text{(x}{}_1\text{,…,x}{}_{\mathrm{n}}\text{)}$, the strongest locally convex topology τ_st coincides with the uniform topology τ_$\text{D}$ as well as with the strong operator topology τ_s. In the case n = 2 some conditions are given, under which these general assumptions are fulfilled.     

A simplified Fokker-Planck operator for unlike-particle collisions

The linearized Fokker-Planck operator reads $\text{C}{}^1{}_{\mathrm{jk}}\text{= C(f}{}_{\mathrm{1j}}\text{, f}{}_{\mathrm{0k}}\text{)}$. The first term is rather simple, but the second one is very complicated. A much simpler - though exact - form of C(f_0j, f_1k) is proposed, for a special class of f_1k occuring in diffusion theory.     

Ellipsometry of tetragonal lead oxide single crystals

The refractive index of PbO tetragonal single crystals ($\text{n}\text{?}{}_0\text{= 2.73±0.05}$) and parameters of thin dielectric film on their real surfaces (n_f = 1.56±0.01, $\text{d = 10?85}\text{A}\text{?}$) have been measured by the method of ellipsometry at $\text{λ = 6328}\text{A}\text{?}$. For the first time the photo-induced changes of optical properties of PbO^(t) surface film have been observed.     

Anisotropy of X-ray critical scattering in 4,4-di-n-hexyl-biphenyl liquid crystal

We have carried out a high-resolution X-ray critical scattering experiment in the isotropic phase connected with the isotropic-smectic-B transition in 4,4-di-n-hexyl-biphenyl. The measurements yield the following parameter values: $\text{d = 23.92}\text{A}\text{?}$, $\text{q}{}_0\text{= 0.268}\text{A}\text{?}{}^{\mathrm{?1}}$ and the critical exponents γ = 1.51 ± 0.12, ν_∥ = 0.65 ± 0.06, ν_⊥ = 0.70 ± 0.08. At the temperature t = 10^?3 ($\text{t =}\text{T}\text{T}{}_{\mathrm{<mtext>c</mtext>}}\text{?1}$) the correlation lengths are $\text{ξ}{}_{\mathrm{\parallel }}\text{= 390}\text{A}\text{?}$ and $\text{ξ}{}_{\mathrm{\perp }}\text{= 1080}\text{A}\text{?}$.     

Model calculation of the electronic structure and spectroscopy of Hg2

Energy curves and transition moments of the excited valence states of Hg₂ were obtained in a model calculation based on calculated Mg₂ energy levels and the assumption that the asymptotic spin-orbit matrix elements for the Hg atom are applicable to the molecular states. The spin-orbit and orbital-rotational interaction of the excited states of Hg₂ is analyzed in both a Hund's case (c) and (a) representation. The intermediate (a) → (c) transition moments are obtained as a function of the internuclear distance. The effect of the orbital-rotational interaction which introduces Hund's case (b) and (e) couplings is found to be small for transitions among excited states under the conditions normally encountered for populating excimer states.Using the energy level positions and transition moments, the observed spectra and predicted spectra are compared for both radiative transitions including the ground state and among the excited states. The lifetime of the $\text{1}{}_{\mathrm{u}}\text{(}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{)}$ excimer state is calculated to be 1.4 μsec with the 335 nm band assigned to the $\text{1}{}_{\mathrm{u}}\text{→ X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ transition. The 485 nm bands cannot be assigned to any Hg₂ transitions. Strong bound-continuum absorptions are predicted for the 485 nm bands. On the other hand, the 335 nm emission is predicted to be absorbed by bound-bound transitions only.