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《结构化学》2005,24(7):F002-F002
<正>南开大学化学学科创建于1921年,1995年成立化学学院。化学学院设有3个系(化学系、材料化学系、化学生物学系),4个研究所(元素有机化学研究所、高分子化学研究所、新能源材料化学研究所、催化科学与工程研究所)、2个研究中心(分析科学研究中心、理论与计算化学中心),2个国家重点实验室(元素有机化学国家重点实验室、吸附分离功能高分子材料国家重点实验室),1个农药国家工程中心。化学学院涵盖化学、材料化学与物理、药学和植物保护4个一级学科,有8个二级学科具有博士学位授予权,其中3个是国家重点学科。 化学学院是目前国内最大的化学专业学院之一,拥有6座教学科研大楼,实验室面积超过3万平方米;目前在岗教职工370人,其中专任教师207人(其中教授、副教授174人),两院院士5人,博士生导师70人,各类国家和省部级杰出人才20多人。 化学学院培养的毕业生以基础知识扎实、实验素质高和动手能力强而受到国内外各单位的欢迎。每年有70%左右的毕业生免试推荐或考取国内外研究生,其他的分配到外资企业、科研单位、高等院校、机关及事业单位工作。 南开大学是通过国家本科教学质量优秀评估最早(1999年)的两所高校之一。化学专业1991年被原国家教委首批批准为国家理科基础科学人才培养基地,1999年通过优秀评估,是国内通过评估正式挂牌的三个化学基地之一。2001年获得国家优秀教学成果一等奖。 相似文献
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化学战受害者纪念日日益受到公众关注,且与化学学科密切相关.介绍了化学战受害者纪念日的由来及意义、纪念日的主要活动、化学武器的化学成分与危害,同时对中学化学教师提出几点思考. 相似文献
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近年来,国内外不断发生的化学恐怖袭击和化学事故仍然是当今人类生存、国家安全所面临的重大威胁。化学侦检是防化应急处置与救援的眼睛,熟练掌握和正确使用侦检装备是应对化学威胁、降低损失和伤亡的关键因素。基于化学传感等技术的侦检装备具有响应快速、智能便携的特点,并且在远程监测和实时值守等方面具有优势。该文针对涵盖电化学传感器、质量敏感型传感器、红外传感器、拉曼传感器、离子迁移谱仪、火焰光度检测器、光致电离检测器、远程遥测传感装备等在内的现场侦检装备,从原理、性能、优势和不足等方面进行了概述,重点阐述了侦检装备在应对化学威胁方面的最新进展,并对其发展趋势、应用前景进行了展望,以期为化学侦检装备在应对化学威胁中的深入研究与应用提供参考。 相似文献
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从《禁止化学武器公约》1997年4月正式生效以来,化学核查方法研究不断深入,从鉴定化学战剂原体逐步向降解、消毒等相关化学品方向发展,且扩展到复杂的环境基质样品。为了确保各缔约国履约,对于已被"禁止化学武器组织"(简称OPCW)指定和正在寻求指定的实验室,每年至少要参加一次水平考试,分析公约附表化学品及它们的前体和降解产物,并取得优异的成绩,只有这样,才有资格分析真实样品(从被怀疑的产品或者储藏地点或者是从宣布使用过化学武器的环境中采集的)。本文样品是OPCW组织的第十四次水平考试的"消毒"废液样品D及其空白对照DB,采用液相色谱-电喷雾质谱联用技术(HPLC-ESI-MS)对样品进行定性检测,结合其他分析方法,结果与配样清单完全一致,见表1。 相似文献
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Aron Hakonen Per Ola Andersson Michael Stenbæk Schmidt Tomas Rindzevicius Mikael Käll 《Analytica chimica acta》2015
Acts of terror and warfare threats are challenging tasks for defense agencies around the world and of growing importance to security conscious policy makers and the general public. Explosives and chemical warfare agents are two of the major concerns in this context, as illustrated by the recent Boston Marathon bombing and nerve gas attacks on civilians in the Middle East. To prevent such tragic disasters, security personnel must be able to find, identify and deactivate the threats at multiple locations and levels. This involves major technical and practical challenges, such as detection of ultra-low quantities of hazardous compounds at remote locations for anti-terror purposes and monitoring of environmental sanitation of dumped or left behind toxic substances and explosives. Surface-enhanced Raman scattering (SERS) is one of todays most interesting and rapidly developing methods for label-free ultrasensitive vibrational “fingerprinting” of a variety of molecular compounds. Performance highlights include attomolar detection of TNT and DNT explosives, a sensitivity that few, if any, other technique can compete with. Moreover, instrumentation needed for SERS analysis are becoming progressively better, smaller and cheaper, and can today be acquired for a retail price close to 10,000 US$. This contribution aims to give a comprehensive overview of SERS as a technique for detection of explosives and chemical threats. We discuss the prospects of SERS becoming a major tool for convenient in-situ threat identification and we summarize existing SERS detection methods and substrates with particular focus on ultra-sensitive real-time detection. General concepts, detection capabilities and perspectives are discussed in order to guide potential users of the technique for homeland security and anti-warfare purposes. 相似文献
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Michael Hfer 《Chemie in Unserer Zeit》2002,36(3):148-155
For a long time people used chemicals to weaken or incapacitate their opponents. In World War I a sad peak was reached with the massive use of poisonous gas. Iraq's success using chemical weapons against Iran stimulated some emerging countries to acquire chemical weapons after the collapse of the Soviet Union. The intelligence community estimates their number of up to 30 countries. In 1997 an international law came into force to stop further proliferation and guarantee destruction of chemical weapons till 2007. So far already 147 countries ratified this treaty — but not countries like Iraq, Syria and North Korea. Even for an individual with sufficient criminal energy it is possible to spread terror with chemical weapons. So, control is mandatory, panic certainly not. 相似文献
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化学气相淀积法合成氮化铝薄膜及其工艺设计 总被引:1,自引:0,他引:1
对AlBr3-NH3-N2体系化学气相淀积法合成A1N膜进行了热力学分析和工艺设计,研究了在不同淀积温度和体系总压时,体系中主要气态物种的平衡分压和A1N膜的理论淀积速率与源温和载气流量的关系,并与微波等离子体化学气相淀积A1N膜的实验结果进行了比较。 相似文献
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John M. Prausnitz 《Angewandte Chemie (International ed. in English)》1990,29(11):1246-1255
Thermodynamic properties are essential for quantitative process design to produce chemical products. Caloric properties are required for heat balances, but these properties are usually available or estimated easily. More important—and often much more difficult to estimate—are the chemical potentials of components in mixtures; it is these potentials which determine phase equilibria, as required for separation operations, and chemical equilibria, as required for chemical reactors and for separation operations based on chemical reactions. Molecular thermodynamics is an engineering-oriented science for calculating the desired chemical potentials from a minimum of experimental data. This applied science, based on classical and statistical thermodynamics, yields chemical potentials through models that are based on molecular physics and physical chemistry. Selected examples are cited to illustrate the applicability of molecular thermodynamics: group-contribution methods for obtaining chemical potentials in highly nonideal mixtures as required for distillation-column and process-safety design; equation of state for precipitation of uniform-sized crystals from supercritical fluids; molecular-orbital calculations to guide process development for alternatives to environmentally dangerous chlorofluorohydrocarbons; molecular-simulation calculations for separation of gas mixtures with porous adsorbents; equilibria in two-phase aqueous systems for separation of protein mixtures; and, finally, extended polymer-solution thermodynamics to guide synthesis of hydrogels suitable for protein recovery from soybeans and for novel drug-delivery devices. 相似文献
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The effect of preheating of dimethylaluminum hydride (DMAH) as a gas on the epitaxial growth in aluminum chemical vapor deposition (Al-CVD) is studied theoretically. The chemical changes of DMAH in the gas phase such as unimolecular decomposition reactions, bimolecular reactions and polymerizations are treated using ab initio molecular orbital method (MP2/6-31G**) and density functional theory (B3P86/LanL2DZ). The gas phase equilibrium composed of the previous reaction products under the usual experimental conditions for Al-CVD is also investigated in detail as the initial stage of the CVD process. From the energetics point of view, unimolecular decomposition reactions and bimolecular reactions hardly occur, however, polymerizations of DMAH take place readily at the low temperatures found in Al-CVD. A large amount of DMAH-dimer and a small amount of DMAH-monomer and trimer coexist in the equilibrium state. 相似文献
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High purity fluorapatite (FAP) was prepared by solid state reaction, in flowing argon gas, at 1370°C for 60 min. For chemical characterization of Ca10(PO4)6F2, the accuracy and reproducibility of different analytical methods were assessed. Methods with a good accuracy for the determination of Ca, P and F content were: titrations with EDTA for Ca determination (accuracy: −0.8%), spectrophotometric method for P determination (accuracy: +0.6%) and measurements with fluoride-selective electrode (accuracy +5.4%) for F determination. 相似文献