Ordered diffusion mass transfer under shock conditions

The features of diffusion mass transfer phenomena in metals under shock conditions are considered. The diffusion fluxes arising at severe plastic deformation of material are determined. It is shown that under certain conditions the impurity diffusion from the outer surface into the metal bulk may evolve as a wave process, at which the mass transfer occurs in the form of ordered atomic motion through the lattice. The diffusion wave propagation velocity of is determined.     

Plasticity determined by indentation and theoretical plasticity of materials

Characterization of the plasticity of materials by the part of plastic strain in the total elastic-plastic strain and application of this characteristic at indentation is considered. The dependence of the new plasticity characteristic on the structure and temperature is discussed. The concept of theoretical plasticity is introduced and the theoretical plasticity is calculated for a number of materials.     

Mathematical modelling of heat and mass transfer under conditions of mixed convection in rectangular region with heat source and heat-conducting walls

Numerical modelling of a conjugate convective-conduction heat transfer in a rectangular region with a heat-release source was carried out in the presence of forced flow and mass exchange. The distributions of thermal and hydrodynamic characteristics, which describe the specific peculiarities of flow regimes under study, were obtained. The mutual influence of forced and free-convective flow was analysed. The scales of the effect of determining dimensionless complexes (Gr, Br, Re) on flow regimes were established. The evolution of analysed process was shown.     

Stress transfer efficiency in model composites under dynamic loading

The micromechanics of tension–tension fatigue loading in model single-fibre composite geometries is investigated in this paper. In an attempt to emulate the conditions encountered in full carbon fibre composites, the fibres were prestrained prior to the curing process to ensure that they were free of high residual compressive stresses as a result of resin shrinkage. The resulting specimens were grouped into two categories depending on the level of the initial fibre prestrain (case A low, case B high). The cyclic load is designed to be well below the endurance fatigue limit of the polymer matrix (∼0.6%), and to have a frequency low enough to avoid unwanted thermal post curing. Throughout the preparation procedure, as well as during fatigue loading, the fibre stress (strain) was constantly monitored by means of laser Raman spectroscopy. The fibre axial stress distributions at each fatigue step were converted to interfacial shear stress (ISS) distributions, from which important parameters such as the maximum ISS the system can accommodate, the transfer length for efficient stress built-up and the length required for the attainment of maximum ISS were obtained. The results showed that, up to 2×10⁶ loading cycles, the main parameters which affected the stress transfer efficiency at the interface were the fibre fracture process itself and the viscoelastic behaviour of the matrix material. Received: 7 November 2001 / Accepted: 22 March 2002 / Published online: 5 July 2002     

The role of visualization in clarifying interfacial heat and mass transfer mechanisms

Mechanisms governing heat and mass transfer at air-water interfaces may be studied experimentally and by mean of Direct Numerical Simulations (DNS). Flow visualizations play a central role in unraveling the mechanisms that govern these transfer rates. In particular visualizations show that the flow is organized in large structures. These are sweeps, high-speed (relative to the interface velocity) fluid traveling toward the interface, and ejections, low speed fluid moving away from the interface region. It is the frequency with which these large flow structures refresh the interface that controls mass transfer.     

Nonstationary mass transfer under particle magnetophoresis in diluted ferrocolloids

Nonstationary mass transfer under nanoparticle magnetophoresis in diluted ferrocolloids is experimentally investigated. Measurements performed by using the real time holography technique indicate a difference between the concentration boundary layer parameters found in the experiment and those calculated by using the approximation of nonstationary magnetodiffusion of colloidal particles. We suppose that the final stationary concentration distribution in the boundary layer is caused by a magnetic convection. Approximative calculations of concentration magnetic convection give the mass transfer relaxation time close to the exprimentally determined one.Work is supported by the European Community, Grant ERB 3510PL92-5206     

Characterisation of the oxygen transfer in BIMEVOX membranes under applied current conditions

Oxygen isotopic exchange has been studied for a number of materials in the BIMEVOX family of compounds. The exchanges were undertaken at 620 °C with gold grid electrodes on the samples and with a constant current flowing through the samples during the exchange anneals. These conditions simulate those used when these materials are employed in oxygen separation devices where substantial oxygen fluxes can be sustained using such simple gold grid electrodes.The results showed that samples exchanged under current flow conditions exhibit substantial oxygen exchange at the cathode, in contrast to samples where no electrical bias is applied. This effect was sustained in regions remote from the sputtered gold electrode. Complementary studies of the samples using X-ray diffraction revealed subtle changes in the diffraction patterns following experiments with current flow. These changes are ascribed to a reduction of V⁵⁺ to V⁴⁺ at the cathode locally transforming the BIMEVOX material into a mixed conducting material, and hence enhancing the oxygen isotopic exchange process.     

Investigation of heat transfer in liquid-metal flows under fusion-reactor conditions

The effect discovered in studying a downward liquid-metal flow in vertical pipe and in a channel of rectangular cross section in, respectively, a transverse and a coplanar magnetic field is analyzed. In test blanket modules (TBM), which are prototypes of a blanket for a demonstration fusion reactor (DEMO) and which are intended for experimental investigations at the International Thermonuclear Experimental Reactor (ITER), liquid metals are assumed to fulfil simultaneously the functions of (i) a tritium breeder, (ii) a coolant, and (iii) neutron moderator and multiplier. This approach to testing experimentally design solutions is motivated by plans to employ, in the majority of the currently developed DEMO blanket projects, liquid metals pumped through pipes and/or rectangular channels in a transvers magnetic field. At the present time, experiments that would directly simulate liquid-metal flows under conditions of ITER TBM and/or DEMO blanket operation (irradiation with thermonuclear neutrons, a cyclic temperature regime, and a magnetic-field strength of about 4 to 10 T) are not implementable for want of equipment that could reproduce simultaneously the aforementioned effects exerted by thermonuclear plasmas. This is the reason why use is made of an iterative approach to experimentally estimating the performance of design solutions for liquid-metal channels via simulating one or simultaneously two of the aforementioned factors. Therefore, the investigations reported in the present article are of considerable topical interest. The respective experiments were performed on the basis of the mercury magneto hydrodynamic (MHD) loop that is included in the structure of the MPEI—JIHT MHD experimental facility. Temperature fields were measured under conditions of two- and one-sided heating, and data on averaged-temperature fields, distributions of the wall temperature, and statistical fluctuation features were obtained. A substantial effect of counter thermo gravitational convection (TGC) on averaged and fluctuating quantities were found. The development of TGC in the presence of a magnetic field leads to the appearance of low-frequency fluctuations whose anomalously high intensity exceeds severalfold the level of turbulence fluctuations. This effect manifest itself over a broad region of regime parameters. It was confirmed that low-energy fluctuations penetrate readily through the wall; therefore, it is necessary to study this effect further—in particular, from the point of view of the fatigue strength of the walls of liquid-metal channels.     

Effective mass of surface electrons in helium under non-equilibrium conditions

The mass shift of surface electrons in helium has been investigated theoretically caused by electron-ripplon interaction as a function of electromagnetic field power absorbed by a system. It is shown that the mass shift is negative at weak powers of external field but it increases as the power increases and changes its sign. The results of calculation and comparison with the experimental data testify to the favourable role of two-ripplon scattering processes in energy relaxation of surface electrons above helium.     

The formation of defects in Si under the radiation enhanced diffusion conditions

A review is given of recent developments in the study of magnetic (localized) photo-excitations in ionic solids. Emphasis will be on three topics: (i) the importance of magnetic properties in the structural characterization of defects, (ii) photo-chemical reactions as revealed from magnetic interactions in point defects, and (iii) energy and phase relaxation dynamics in photo-excited colour centres as probed from magnetic transients. In our survey we will focus on defects photo-excited to phosphorescent triplet states. In discussing a number of dynamical processes, some attention is given to the application of (optical-microwave) coherence spectroscopy which holds considerable promise for future work.     

Role of thermal stresses on pulsed laser irradiation of thin films under conditions of microbump formation and nonvaporization forward transfer

This paper presents a theoretical analysis of the processes in thin solid films irradiated by short and ultrashort laser pulses in the regimes of film structuring and laser-induced forward transfer. The regimes are considered at which vaporization of the film materials is insignificant and film dynamics is governed mainly by mechanical processes. Thermoelastoplastic modeling has been performed for a model film in one- and two-dimensional geometries. A method has been proposed to estimate the height of microbumps produced by nanosecond laser irradiation of solid films. Contrary to femtosecond laser pulses, in nanosecond pulse regimes, stress waves across the film are weak and cannot induce film damage. The main role in laser-induced dynamics of irradiated films is played by radial thermal stresses which lead to the formation of a bending wave propagating along the film and drawing the film matter to the center of the irradiation spot. The bending wave dynamics depends on the hardness of the substrate underlying the film. The causes of the receiver substrate damage sometimes observed upon laser-induced forward transfer in the scheme of the direct contact between the film and the receiver are discussed.     

Heat transfer in tubes with periodic draft under supercritical conditions

The temperature mode of a wall was studied experimentally for sub-and supercritical pressures of water in tubes with turbulence stimulators; these data were compared with similar results obtained for a smooth tube. An increase in heat transfer inside a turbulizing tube was revealed for a single-and two-phase water flows. Correlation dependencies for determination of heat transfer coefficient in a single-phase flow inside a tube with turbulence stimulators were obtained.     

Complex formation and proton transfer between formic acid and water adsorbed on Au(111) surfaces under UHV conditions

The coadsorption of formic acid and water on Au(111) surfaces has been investigated by means of vibrational and photoelectron spectroscopy (HREELS, XPS). Formic acid adsorbs at 90 K molecularly with vibrational modes characteristic for flat lying zig-zag chains in the mono- and multilayer regime, like in solid formic acid. Annealing results in a complete desorption at 190 K. Sequential adsorption of formic acid and water at 90 K shows no significant chemical interaction. Upon annealing the coadsorbed layer to 140 K a hydrogen-bonded cyclic complex of formic acid with one water molecule could be identified using isotopically labelled adsorbates (D₂O, H¹³COOD). Upon further annealing this complex decomposes leaving molecularly adsorbed formic acid on the surface at 160 K, accompanied by a proton exchange between formic acid and water. PACS 68.08.-p; 68.43.-h; 68.43.Pq     

Switching of precession regimes under the conditions of dynamic bistability of magnetization

The dynamics of the magnetization of a single-crystal film under the conditions of dynamic bistability has been investigated using numerical simulation. It has been shown that the use of an additional alternating magnetic field has made it possible to suppress the dynamic bistability of magnetization and to implement one of the two precession regimes depending on the field frequency. Multiple switching between magnetization precessions with different amplitudes can be performed directly from one regime to the other regime due to the corresponding change in the frequency of the additional magnetic field.     

On the cryogenic layer formation under conditions of high-frequency mechanical action

The results of a series of experiments using a piezovibration formation module for producing cryogenic targets with a given fuel layer structure are presented.     

Anomalous compressibility and magnetostriction of beryllium under the conditions of diamagnetic domain formation

Magnetostriction oscillations are measured for a single-crystal beryllium sample shaped like a plate perpendicular to the direction of the magnetic field. In the range of 2–5 T at a temperature of 1.5 K, i.e., in the region of diamagnetic domain formation (Condon domains), the striction signal has the saw-tooth shape corresponding to the alternation of homogeneous and nonhomogeneous (domain) states. The formation of the domain structure is accompanied by an anomalous increase in compressibility; the oscillations in this coefficient are more than one hundred times greater than the value given by the standard theory. An analysis of the results indicates that the domain wall width should increase with increasing plate thickness.     

非连续运行工况下结霜动力因素实验分析

冷风机表面在非连续运行工况下结霜是实际运行中经常遇到的问题,其影响因素较为复杂。通过建立结霜实验台,系统分析了影响非连续运行工况下冷风机表面结霜的因素,包括运行比、相对湿度及冷风机表面温度,并且对实验结果总结了关联式。结果表明,在非连续工况中,结霜量是一个与运行比有极大关系的值,而拟合的关联式则体现了这种关系,并与实验结果有较小的误差。     

Reversible formation of aryloxenium ions from the corresponding quinols under acidic conditions

Quinols, 1, are products of the hydration of O‐aryloxenium ions, 2, and N‐arylnitrenium ions, 3, and they are being investigated for medical uses. Under acidic conditions (pH 1–3) kinetics and products of Br^– trapping demonstrate that 1a, 4‐phenyl‐4‐hydroxy‐2,5‐cyclohexadienone, and 1b, 4‐p‐tolyl‐4‐hydroxy‐2,5‐cyclohexadienone, generate the corresponding oxenium ions 2a and 2b, respectively, as steady‐state intermediates. Formation and trapping of the oxenium ions occurs in competition with the acid catalyzed dienone–phenol rearrangement. Because oxenium ion formation is reversible, the ion can only be detected by trapping with a nucleophile. Br^– is an efficient trap under acidic conditions because, unlike N₃^–, it is not protonated under those conditions. Attempts to detect the oxenium ions 2a and 2b at pH 4.6 and 7.1 with N₃^– were unsuccessful indicating that oxenium ion formation only occurs under acidic conditions. The oxenium ion 2c could not be detected under acidic conditions from the quinol 1c, 4‐(benzothiazol‐2‐yl)‐4‐hydroxy‐2,5‐cyclohexadienone, by Br^– trapping methods, even though this ion can be detected during hydrolysis of the corresponding ester, 4c. Although the benzothiazol‐2‐yl group is a resonance electron donor that is capable of stabilizing an O‐aryloxenium ion, it is also a strong inductive electron withdrawing group that hinders the formation of 2c from 1c by decreasing the extent of protonation of 1c to generate 1cH⁺ and by destabilizing the transition state for ionization of 1cH⁺. Generation of an oxenium ion from the corresponding quinol is feasible under acidic conditions as long as the 4‐substituent of the quinol is both a resonance and inductive electron donor. Copyright © 2012 John Wiley & Sons, Ltd.