Spectroscopic analysis of the d1Σ+→a1Σ+ and d1Σ+→b1Π green band systems of XeO

A comprehensive high resolution spectroscopic analysis has been made on the XeO green bands photographed in emission from an RF discharge source. Rotation-vibration constants derived from the analysis of the spectrum of the isotopically enriched species ¹²⁹Xe¹⁶O and ¹²⁹Xe¹⁸O were used to give RKR potential curves for the d¹Σ⁺ and b¹Π states. The bond distances and dissociation energies of the d¹Σ⁺ and b¹Π states were respectively found to be $\text{r}{}_{\mathrm{e}}\text{= 2.852 ± 0.002}\text{A}\text{?}$, D_e = 693 ± 10 cm^?1 and $\text{r}{}_{\mathrm{e}}\text{= 2.548 ± 0.002}\text{A}\text{?}$, D_e = 461 ± 10 cm^?1. For the a¹Σ⁺ state it was not possible to establish a unique vibrational numbering or to construct an RKR potential curve, since observed bands of the d¹Σ⁺→a¹Σ⁺ system involve only high vibrational levels of the a¹Σ⁺ state, which are severely predissociated. The observations are consistent with a fairly deep well, in agreement with the latest ab initio calculations which give a well depth of 0.7 eV.     

The magnitude of annihilation and penguin contributions to charm-meson decays

A consistent treatment of color singlet and octet contributions in the spectator constituent gluon model for pseudoscalar meson decays is attempted. The result comes out one order of magnitude too small to explain the observed life-time difference of D⁰ and D⁺. Furthermore, it is found that ‘penguin’ interactions in the annihilation channel may give contributions to the asymmetry of the (D⁰ → K⁺K^?)/(D⁰ → π⁺π^?) ratio of the order of the phase-space difference or larger. Finally, it is argued that annihilation cannot explain the $\text{ΔI =}\text{1}\text{2}$ rule for kaon decays; dynamical effects including the penguin interactions seem still to be needed.     

Chemical diffusion in CoO

Equilibration kinetics of CoO have been studied over the range 1–10^?5 atm oxygen pressure and 900–1300°C by both thermogravimetric and electrical conductivity techniques. The former technique gives excellent agreement with theory based on bulk diffusion and results in a chemical diffusion coefficient given by, $\text{D}\text{?}\text{= 4.8×10}{}^{\mathrm{?3}}\text{exp (?22,500/RT)}$ cm${}^2\text{sec}$. The defect diffusion coefficient (Dinvinco) is equal to $\text{i}\text{?}\text{tD}\text{2}$. No dependence of ?tD on defect concentration was observed. The electrical conductivity technique qualitatively supports these results.     

A monte-carlo/molecular dynamics study of the diffusional recombination kinetics of C(a) + O(a) → CO(g) on Pt(111)

The diffusion constants for C and O adsorbates on Pt(111) surfaces have been calculated with Monte-Carlo/Molecular Dynamics techniques. The diffusion constants are determined to be D_C(T)=(3.4 × 10^?3e^{$\text{?13156}\text{T}$})cm²s^?1 for carbon and D_O(T) = (1.5×10^?3 e^{$\text{?9089}\text{T}$}) cm² s^?1 for oxygen. Using a recently developed diffusion model for surface recombination kinetics an approximate upper bound to the recombination rate constant of C and O on Pt(111) to produce CO_(g) is found to be (9.4×10^?3 e^{$\text{?9089}\text{T}$}) cm² s^?1.     

Heat capacity of a five-coordinated iron(III) complex,iodobis (N,N-Dimethyldithiocarbamato) iron(III), between 0.4 and 300 K

The heat capacity of iodobis (N, N-dimethyldithiocarbamato)iron(III) has been measured between 0.4 and 300 K. Based on the heat capacity and entropy at low temperatures it was found that the present sample consists of a mixture of monomer (ca. 40%) and dinier (ca. 60%); the former brings about a λ-type phase transition from an antiferromagnetic to a paramagnetic state at T_N = (1.65 ±0.04) K while the latter exhibits a Schottky-ype anomaly due to antiferromagnetic dimeric coupling, the effect of which becomes dominant below ca. 0.7 K. The zero-field splitting parameter of a single ferric ion was estimated to be $\text{D}\text{k}\text{=}\text{D}{}_{\mathrm{D}}\text{k}\text{= 14 K}$ for the monometer and the dimer, while the dimeric coupling constant was $\text{J}{}_{\mathrm{D}}\text{k}\text{= ?0.15 K}$. The entropy at low temperatures cannot be accounted for solely by the spin manifold. Additional contribution from a tunnel-splitting of the rotational levels of four constituent methyl-groups has been discussed. In this case, the level splitting of the ground state is 2.5 J mol^?1 and the barrier height of hindering potential is 2.3 kJ mol^?1.     

Critical behaviour of a uniaxial ferromagnet,ErCl3·6H2O with predominant dipolar interactions

The parallel magnetic susceptibility χ of a uniaxial ferromagnet ErCl₃·6H₂O has been measured between 0.3 and 4.2K and specially near T_c = 0.353 K. The predominant contribution to the Curie-Weiss temperature is due to the dipolar interactions. χ is proportional to ?^?γ with $\text{? =}\text{T}\text{T}{}_{\mathrm{c}}\text{?1}$ in the range 10^?3 < ? < 5 × 10^?2. The γ value, γ = 1.01 ±0.03 is consistent with the theoretical prediction for a uniaxial dipolar ferromagnet.     

The average structure of 5.10-Dihydro-5.10-Diethylphenazinium-Iodide (E2P·I1.6): A new linear chain Polyiodide compound

Upon oxidation of 5.10-dihydro-5.10-diethylphenazine (E₂P) with iodine golden-green lustrous crystals of a compound with stoichiometry E₂P.I_1.6 were isolated. The compound crystallizes in the tetragonal space group D₄² with $\text{a = 12.321(2)}\text{A}\text{?}$ and $\text{c = 5.330(2)}\text{A}\text{?}$. The E₂P and I form interpenetrating incommensurate sublattices along c, with an iodine repeat distance of 9.7 Å. Static susceptibility measurements at room temperature give χ_g = + 0.994 × 10^?6g^?1 × cm³. This corresponds to one unpaired electron spin per two formular units. Single-crystal EPR indicates that the paramagnetism is associated with weakly interacting E₂P⁺ cation radicals. The 300K-d.c. conductivity of 3×10^?2Ω^?1cm^?1 and activation energy of 0.17±0.02eV for single crystals is consequently associated with the polyiodide chains, and not with the E₂P⁺ cation radicals.     

Differential cross sections and analyzing powers for pd elastic scattering below 1.0 MeV

Differential cross sections for the elastic pd scattering were measured at seven energies between 0.4 and 1.0 MeV for scattering angles from θ_c.m. = 44.5° to 149.2°. A mixture of D₂ and Kr was used as target gas and the pd differential cross sections were determined relative to those of pKr scattering with a statistical error of $\text{Δσ}\text{σ}$ ～5 × 10^?3. Analyzing powers for $\text{p}$d scattering were measured at 0.8, 0.9 and 1.0 MeV with a statistical error of ΔA_y ～5 × 10^?4.     

X-rays from antiprotonic helium in helium gas

X-ray transitions to the 4F, 3D, and 2P atomic levels of p?He have been observed with antiprotons stopped in He gas at 4 and 1.1 atm NT. The population by radiative transitions of the 3D level in gas Y_M(4atm) = (28±14)% and Y_M(1.1 atm) = (43±22)% exceeds by more than one order of magnitude that measured in liquid He. The annihilation width of the 3D level Γ^a_3D = 2.8±1.0 × 10^?3eV is determined from the ratio between the numbers of X-rays feeding and depopulating the 3D level. The strong-interaction shift of the 2P level ε(2P) = ?14±6 eV is obtained by inputting the $\text{p}\text{He}$ experimental X-ray yields into a cascade calculation, the results of which are in good agreement with well-established data from muonic, pionic, and kaonic helium.     

Evidence for a narrow width boson of mass 2.95 GeV

In a search for resonances coupled to the $\text{p}$pπ^? system, we have studied π^?p interactions at 16 GeV/c giving a forward antiproton, using the Omega spectrometer at CERN. In the final states involving a $\text{p}$, p and π^? we observe a 5.6 (6.3) standard deviation enhancement in the $\text{p}$pπ^? mass spectrum at (2.95 ± 0.01) GeV with a width consistent with the resolution (σ = 15 MeV). The production cross section × branching ratio is estimated to be of the order 1 μb. The data are consistent with a resonance decaying partly via intermediate $\text{p}$p final states.     

Observation of raman scattering by localized optical phonons bound to neutral donors in GaP:Si

Raman scattering by localized optical phonons bound to neutral donors with degenerate ground state has been observed in GaP:Si. The scattering efficiency was measured at T=6.0±0.1 K as a function of the net donor concentration N_D-N_A ranging from 1.6 ·10¹⁷ to 7.1· 10¹⁷ cm^-3. It is found that reasonable agreement with the theory of weakly coupled electron-phonon modes obtained if a Bohr radius of $\text{a}{}_0\text{=5.4}\text{A}\text{?}$ is used, whereas $\text{a}{}_0\text{=7.5}\text{A}\text{?}$ is obtained in the hydrogenic effective-mass approximation using the ionization energy E_D=86.7 meV.     

Reexamination of the I2 spectrum near the B(3Π0u+) state dissociation limit

The disagreement of Danyluk and King's (Chem. Phys.25, 343 (1977)) rotational constants for levels lying near the dissociation limit of B-state I₂ with the mechanical behavior predicted by near-dissociation theory is investigated. The discrepancies are shown to be much too large to be explained by either the neglect of centrifugal distortion effects in the original analysis or by rotational or spin-rotation coupling to a nearby repulsive 1_u state. These differences are therefore attributed to experimental error, a conclusion which is confirmed by more recent experimental results. A reanalysis of the best available data for levels near the dissociation limit of B-state I₂ then yields improved values for the B-state dissociation limit $\text{D}$ = 20 043.16 (±0.02) cm^?1 of the vibrational index at dissociation v_$\text{D}$ = 87.32 (±0.04) and of the long-range potential constant $\text{C}{}_5\text{= 2.88 (±0.03) × 10}{}^5\text{cm}{}^{\mathrm{?1}}\text{A}\text{?}{}^5$. This in turn implies a slightly improved ground-state dissociation energy of $\text{D}$₀ = 12 440.18 (±0.02) cm^?1.     

The visible and photographic infrared spectrum of osmium oxide

The emission spectrum of OsO has been photographed in the region 405–875 nm where many new bands have been observed. In favorable cases the ${}^{190}\text{OsO}{}^{192}\text{OsO}$ isotopic splittings have been resolved and aid in vibrational assignments. Three visible bands in the region 433–470 nm have been assigned as (1,0), (0,0), and (0,1) of a $\text{ΔΩ}\text{= 0}$ electronic transition. The (0,0) and (0,1) bands have been rotationally analyzed, yielding principal constants (cm^?1) for the visible system of ν₀ = 22 273.3, B′₀ = 0.3657, D′₀ = 2.8 × 10^?7, B″_e = 0.4023, D″_e = 3.2 × 10^?7, $\text{Δ}\text{G″(}\text{1}\text{2}\text{) = 780.7}$, and $\text{Δ}\text{G″(}\text{1}\text{2}\text{) = 884.9}$. A band at 825.4 nm has been found to be a $\text{ΔΩ}\text{= +1}$ (0,0) band with the same lower state as in the analyzed visible bands. Constants for the upper state of the ir system are ν₀ = 12 109.7, B′₀ = 0.3845, and D′₀ = 3.1 × 10^?7 cm^?1.     

Determination of A0 for CH335Cl and CH337Cl from the ν4 infrared and Raman bands

The ν₄ infrared and Raman bands of CH₃Cl were analyzed simultaneously. A direct fit yielded a complete set of constants for CH₃³⁵Cl, including A₀ = 5.20530 ± 0.00010 cm^?1 and D_K = (8.85 ± 0.13) × 10^?5cm^?1. For CH₃³⁷Cl an incomplete set of constants was obtained from the infrared band, and A₀ = 5.2182 ± 0.0010 cm^?1 was estimated by curve fitting of the Raman spectrum. The resulting equilibrium structure is $\text{r(}\text{CH) = 1.0854 ± 0.0005}\text{A}\text{?}$, $\text{r(}\text{CCl) = 1.7760 ± 0.0003}\text{A}\text{?}$, and <(HCH) = 110°.35 ± 0°.05.     

Limits on D0-D0 mixing and bottom particle production cross section from hadronically produced same-sign dimuon events

The rates for same-sign and opposite-sign dimuon events with missing energy (indicative of final-state neutrinos) have been measured in 278 GeV π^?-Fe and 350 GeV proton-Fe collisions. The main source of opposite-sign events is two semi-leptonic decays of hadronically produced charm states. The same-sign events are consistent with background from pion and kaon decays. We obtain a limit of 0.044 (90% CL) on the fraction of D⁰ semileptonic decays that result in the wrong-sign muon and conclude that less than 9% (90% CL) of same-sign dimuon events produced in neutrino interactions can be attributed to D⁰-$\text{D}$⁰ mixing. The data imply δm < 6.5 × 10^?4 eV and $\text{δλ}\text{λ}\text{< 0.55}$ for the difference in mass and inverse lifetime of the CP eigenstates of the D⁰. Limits on diffractive bottom production cross sections in proton and pion collisions are also presented.     

Double-charge-exchange and inelastic scattering in π−+3He

The reactions π^?+³He→⁺+3n and π^?+³He→^?+³He were studied to investigate the $\text{T=}\text{3}\text{2}$ three-nucleon system. The differential cross sections were measured at scattering angles from 20 to 40 degrees. The secondary pion was momentum analyzed in a magnetostrictive-readout wire-chamber spectrometer. The double-charge-exchange reaction yielded a secondary pion energy distribution, the features of which can be due to either a $\text{T=}\text{3}\text{2}$ three-nucleon resonance or a resonace of the nucleons in the ³He nucleus. The inelasticc scaterring reaction yielded a secondary pion energy distribution peaked near threshold, consistent with resonances in both the $\text{T=}\text{3}\text{2}$ and $\text{T=}\text{1}\text{2}$ three-nucleon systems.     

Diffusion and point defects in Cu2O

The diffusion of⁶⁴Cu in Cu₂O has been measured by a serial-sectioning technique as a function of temperature (700–1153°C) and oxygen partial pressure (10^?6?8 × 10^2&#x0304; atm). The oxygen-partial-pressure and temperature dependencies of D¹_Cu suggest that both neutral and singly charged copper vacancies contribute to cation self-diffusion. A defect model involving both neutral and singly charged copper vacancies, electron holes, and singly charged oxygen-interstitial ions is developed and fit to the tracer-diffusion data, the electrical-conductivity data (Maluenda et al.), and the stoichiometry data (O'Keeffe and Moore). The resulting defect data are quantitatively consistent with the chemical-diffusion data (Maluenda et al.) and with a correlation factor $\text{f}{}_{\mathrm{v}}\text{=}\text{2}\text{3}$. The defect data are also quantitatively consistent with the high-temperature oxidation studies of copper metal (Iguchi et al.) and with the copper vacancy being 10 times more mobile than the oxygen-interstitial ion at 10002C.     

Doping mechanism of a conducting polymer: Iodine-doped polyacetylene

We have achieved a technique for determining the diffusion profiles of impurities in the polymers by using a radio-tracer and a microslicing method. We describe the diffusion profiles of iodine in polyacetylene in the temperature range ?60 +20°C. The results show that: (1) iodine penetrates through the interfibril spaces; (2) there is a simultaneous chemical reaction of the first order on the fibrils between polyacetylene and iodine. When the dopant is in solution in pentane, the liquid state interfibril diffusion obeys the Arrhenius law: D = 1.73 × 10^?3 exp[$\text{?0.122(eV)}\text{kT}$] cm² · sec^?1. The kinetic constant of the reaction obeys the similar equation: k = 0.754 exp[$\text{?0.0867(eV)}\text{kT}$] sec^?1.     

Large angle production of stable particles heavier than the proton and a search for quarks at the CERN intersecting storage rings

Measurements have been performed on production of particles with mass 1.5 GeV/c² and charge $\text{?}\text{2}\text{3}$ for θ_lab = 62.5° and $\text{s}\text{= 53}\text{GeV}$. At p_T = 0.7 GeV/c the relative rate of production of antideuterons to π^? is (5 ± 1) × 10^?5. The deuteron to antideuteron ratio is 3.7 ± 1.2. No new stable particle has been amongst 0.7 × 10⁸ charged particles entering our detector.     

A neutron powder diffraction study of zirconium bromide deuteride,ZrBrD. Two hydrogen atoms in the same metal interstice

The D atoms in the double-metal-layered compound ZrBrD have been located and refined by Rietveld analysis of the powder neutron diffraction (IPNS). Interestingly, the D atoms are approximately trigonal planar to Zr, a pair lying 0.25 Å inside opposite triangular faces in the trigonal antiprismatic (“octahedral”) zirconium interstices $\text{(}\text{d}\text{(}\text{D?D}\text{) = 2.204 (8)}\text{A}\text{?}\text{)}$. Similar trends for single D atoms can be recognized in the structures of the rare earth metal trihydrides. The refinement also shows a small occupation of tetrahedral interstices which are less favourable owing to short H…Br distances. These second nearest neighbour interactions are generally important in hydride structures.