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Knight-shiftK and susceptibility have been investigated on single-crystals of vanadium and niobium between 4 K and 290 K.In the case ofV the changes ofK and are found to be of opposite sign and proportional toT 2 with good approximation. This can be explained by theT-dependence of spin-paramagnetism of 3d-electrons. The hyperfine field due to oned-electron spin is found to be — 90 kG. Small deviations from theT 2-law are explained by minor changes in the orbital susceptibility, which gives the main constituents toK and. In the case of Nb only is found to be proportional toT 2. TheT-dependence ofK is very small and shows a maximum at 140 K. This can be explained by theT-dependence of spinparamagnetism of 4d-electrons as well as 5s-electrons.  相似文献   

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The temperature dependence of the luminescence of AgCl-Tl single crystals in the red region of the spectrum was measured. The curves have a characteristic beginning in the 50–70 K region, peaks at 70–100K and at 190K followed by a rapid fall. The dependence of the luminescence intensity on that of the exciting radiation is linear in the range measured. The experiments point to the complex character of the centre and the probability of energy transfer between the absorption and luminescence centres.

Ich betrachte es gerne als meine Pflicht, an dieser Stelle den Herren Prof. Dr. O. Stasiw und Dr. Koswig meinen Dank auszusprechen für ihre Bereitwilligkeit, mit der sie mir ermöglichten, im Tieftemperaturlaboratorium des Instituts zu arbeiten, sowie für die wertvollen Diskussionen.  相似文献   

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Ohne Zusammenfassung
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Abschließend danken wir der Kollegin A. Hadincová für die mit Sorgfalt durchgeführten Messungen.  相似文献   

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