Optimization of accurate controlled formation of Au MNPs via non-thermal microplasma continuous glow discharge within aqueous electrochemical (GDE) method

In this work, micro plasma-induced non-equilibrium liquid chemistry was utilized to synthesize and controlled formation of gold metallic nanoparticles (Au MNPs) by governing the concentration of (HAuCl₄). These new approaches based on both plasma and liquid electrolytes contain charged species, and the interactions between the two phases represent a unique combination of physics, chemistry, and materials science. Continuous and stable DC glow discharge was done in home–made cavity to synthesize the definite sizes of (Au MNPs) by means of (3 kV) discharge voltage and (2 mA) discharge current for a period of (7 min) in aqueous solution of HAuCl₄ with four different concentrations of about 1 mM, 5 mM, 10 mM and 20 mM at room temperature. The atmospheric pressure plasma discharge between stainless steel capillary tube cathode electrode over the (HAuCl₄) solution and platinum plate as an anode dipped in solution for rapid formation of colloidal Au MNPs. Morphology aspects of the synthesized Au MNPs layer were studied by examining the (FE-SEM), HR-TEM images and X-ray difraction (XRD) pattern. Optical features of (Au MNPs) were considered via a UV–Vis beam spectrophotometer. These measurements showed that Au MNPs were organized by governing the concentration of HAuCl₄, and uniform Au MNPs with specific exclusive sizes were acquired. Grain size, specific surface area and optical stability of Au MNPs strongly be affected by the HAuCl₄ concentrations.     

CO2-laser gas discharges in narrow gaps

We have studied RF discharges as excitation mechanisms for distributed feedback (DFB) CO₂ lasers. For CO₂ laser plasmas the reduced electric fieldE/N has to be in a well-defined range. The reduced electric fieldsE/N of gas discharges in the narrow gaps with widths of the order of 100 m required for DFB are considerably above this range. In order to study the feasibility of these RF-excited discharges for DFB CO₂ lasers we have measured the electron temperatureT _e in their plasmas. From helium-line-intensity ratios we have deduced a lower limit of the electron temperatureT _e of 4eV. The observed high intensities of bands of singly ionized nitrogen indicate an even higher electron temperature, but an efficient pumping of the upper laser level is not possible with an electron temperature above 2.5 eV.We have estimated the electron densityn _e and the current densityj _e from ratios of the intesities of forbidden and allowed helium lines. The high current densityj _e is in the range of abnormal glow discharges.In the gas discharges between narrow gaps the electron oscillation amplitudex _e is large than the electrode separationd. In order to replace the resulting high electron losses a high electron temperatureT _e is necessary to sustain the gas discharge. Because of this high electron temperatureT _e an efficient pumping of the upper laser level is not possible.     

Corona discharges in asymmetric electrode configurations

The dual electrode, which consists of an ionizing wire in parallel with a metallic cylindrical support, both connected at same high voltage supply, has been extensively studied in relation with various electrostatic applications. In practical situations, the dual electrode may be installed in the proximity of metallic objects that will affect the electric field repartition and, hence, the development of the discharge. The aim of the present work is to analyze the operating conditions of such electrodes in the presence of metallic rods or plates connected at fixed or floating potentials. The Superficial Charge Simulation Method was then employed for the numerical analysis of several electrode arrangements involving a dual corona electrode and a metallic rod parallel to it. The paper also reports the results of current–voltage characteristics and current density repartition measurements for the dual corona electrode alone or in the presence of other bodies at same or floating potential. The proximity of metallic objects leads to the increase of corona inception threshold and shifts the I–V characteristics to higher voltages. The objects at floating potential may reduce the discharge current to very low values, while those energized at the same voltage as the ionizing wire may simply anneal the discharge.     

缩比间隙中辉光放电相似性的初步研究

为了研究缩比实验在气体放电中的有效性, 对缩比间隙中的低气压氩气放电进行了数值模拟. 根据气体放电相似性的猜想, 如果间隙气压p和间隙距离d的乘积为常量, 即p₁d₁=p₂d₂, 并且约化电场E/p 在两个间隙中的空间分布相同, 那么这两个放电间隙的放电特性存在相似性. 数值模拟中设置三个缩比间隙: 气隙A的长度为30 mm, 气压为1 Torr (1 Torr=133.322 Pa); 气隙B的长度为15 mm, 气压为2 Torr; 气隙C的长度为10 mm, 气压为3 Torr. 仿真结果表明, 三个间隙均为辉光放电, 并存在明显的阴极位降区. 间隙A, B, C 的阴极位降区的厚度d_C分别为2.71, 1.35和0.87 mm, 相对应的pd值几乎相同, 即pd_C≈2.70 Torr·mm. 这与氩气辉光放电Paschen曲线最低点(pd≈2.86 Torr·mm)相近. 缩比间隙的放电参数的特性(如工作电压、电场、电流密度、电子密度和离子密度的沿“空间”px的分布)的数值计算结果与放电相似性猜想所预计的结果一致. 所以, 可以认为放电相似性猜想适用于低气压氩气缩比间隙的辉光放电. 关键词： 放电相似性 辉光放电 缩比间隙     

Gas discharges in very small gaps in relation to electrography

Gas discharges in very small electrode arrangements, with air gaps below 50 microns, as are often used in modern electrostatic recording, have been studied. In particular, the breakdown voltage as a function of the air gap, the charging mechanism for various recording media, the statistical variation of the time lag of the discharges as well as the temporal formation of the discharge have all been investigated. There is good agreement between experimental and theoretical results.     

间隙绝缘电极辉光放电实验观察

实验研究了ITER H2/He辉光放电壁处理(GDC)系统的电极合理的间隙绝缘参数及标定辉光过程中沉积在电极头部的热负载.进行了H2/He击穿电压特性试验,在ITER GDC预期的壁离子电流密度条件下研究了H2/He辉光放电电压和试验电极上热负荷与压强的关系、试验电极启辉耐受特性、试验电极温度与热负荷的关系以及在不同区...     

Charge sensitivity analysis of multiple discharges in a three conductor system with small gaps

The concept of charge sensitivity factors is introduced for analysis of electrostatic discharge (ESD) events. The methodology is used to study the conditions for multiple discharges for an in-line three cylinder geometry with small gaps. The method can be applied to any structure with multiple fixed gaps where charge results from motion with respect to a reference structure.     

Experimental and modelling study of the dependence of corona discharge on electrode geometry and ambient electric field

The results of experimental observations and mathematical modeling of corona formation on the tips of grounded rods are presented as a function of their tip height, curvature radius, the magnitude and polarity of the applied electric field producing corona. The investigations demonstrate that corona current depends on the active volume of zone in which electric field strength exceeds the breakdown criteria for air. The mathematical model was verified with the experimental data, enabling dependence of corona current on rod tip height, tip radius and applied electric field strength to be quantified with the need for a plethora of experiments.     

Exceptional Calabi–Yau spaces: the geometry of backgrounds with flux

In this paper we define the analogue of Calabi–Yau geometry for generic , flux backgrounds in type II supergravity and M‐theory. We show that solutions of the Killing spinor equations are in one‐to‐one correspondence with integrable, globally defined structures in generalised geometry. Such “exceptional Calabi–Yau” geometries are determined by two generalised objects that parametrise hyper‐ and vector‐multiplet degrees of freedom and generalise conventional complex, symplectic and hyper‐Kähler geometries. The integrability conditions for both hyper‐ and vector‐multiplet structures are given by the vanishing of moment maps for the “generalised diffeomorphism group” of diffeomorphisms combined with gauge transformations. We give a number of explicit examples and discuss the structure of the moduli spaces of solutions. We then extend our construction to and flux backgrounds preserving eight supercharges, where similar structures appear, and finally discuss the analogous structures in generalised geometry.     

Higher-dimensional string theory in Lyra geometry

In this paper, a study on string theory has been done in five-dimensional space-time based on Lyra geometry. Also a polynomial relation between the two scale factors is assumed. The equations of state for strings have been used for different solutions     

Eigenvalue spectrum with chebyshev polynomial approximation of the transport equation in slab geometry

Using certain well-known properties of chebyshev polynomials, a simple and highly efficient approach to evaluate eigenvalue in radiation transport is presented. The spectrum of eigenvalues has been studied for slabs with isotropic scattering of different magnitudes of the cross section parameter c (i.e., the mean number of neutrons emitted per collision). It is shown that in the presence of the chebyshev polynomial approximation (T_N) there are both discrete and continuum of eigenvalues. It is found that the T_N method gives very good agreement with conventional spherical harmonics approximation (P_N).     

Some properties of the spectral flow in semiriemannian geometry

Let be the action integral on a semiriemannian manifold ( , g) defined on the space of the curves z : [0, 1] → joining two given points z₀ and z₁. The critical points of ƒ are the geodesics joining z₀ and z₁. Let s ε [0, 1]. We study the behavior, in dependence of s, of the eigenvalues of the Hessian form of ƒ evaluated at z, restricted to the interval [0, s]. A formula for the derivative of the eigenvalues is given and some applications are shown.     

Integral geometry on families of surfaces in the space

A complex {B_ξ} of submanifolds is called admissible in the sense of integral geometry if there are such densities μ_ξ on B_ξ, that the integral transformation

has a local inversion formula. We prove that compact smooth surfaces of an admissible complex in P³ has degree 3 and obtain complete classification of admissible complexes of quadrics. Several general theorems and conjectures about admissible complex of k-dimensional submanifolds are stated.     

Wavefront reconstruction using iterative discrete Fourier transforms with Fried geometry

A new kind of wavefront reconstruction algorithm is proposed in this paper, which can estimate the wavefront from its orthogonal gradients at different sample points. We model the gradients measured by wavefront sensor with the Fried geometry. Iterative discrete Fourier transforms and the correspondent Fried inverse filter in spatial frequency domain are introduced. No special boundary control is required to process the boundary condition in this algorithm. The stimulation and the experimental results show that the new algorithm has strong capability to fit the wavefront and it is more available if the sample points are few.     

Higher-dimensional cosmological model with variable gravitational constant and bulk viscosity in Lyra geometry

We have studied five-dimensional homogeneous cosmological models with variableG and bulk viscosity in Lyra geometry. Exact solutions for the field equations have been obtained and physical properties of the models are discussed. It has been observed that the results of new models are well within the observational limit.     

Hamilton formalism in non-cummutative geometry

We study the Hamilton formalism for Connes-Lott models, i.e. for Yang-Mills theory in non-commutative geometry. The starting point is an associative *-algebra A which is of the form A = C (I, A_s), where A_s is itself an associative *-algebra. With appropriate choice of a K-cycle over A it is possible to identify the time-like part of the generalized differential algebra constructed out of A. We define the non-commutative analogue of integration on space-like surfaces via the Dixmier trace restricted to the representation of the space-like part A_s of the algebra. Due to this restriction it is possible to define the Lagrange function resp. Hamilton function also for Minkowskian space-time. We identify the phase-space and give a definition of the Poisson bracket for Yang-Mills theory in non-commutative geometry. This general formalism is applied to a model on a two-point space and to a model on Minkowski space-time x two-point space.     

A new class of cosmological models in Lyra geometry

FRW models have been studied in the cosmological theory based on Lyra’s geometry. A new class of exact solutions has been obtained by considering a time dependent displacement field for constant deceleration parameter models of the universe. Dedicated to Professor V B Johri on his sixtieth birthday.     

板条射频放电产生单重态氧实验研究

 通过考察各种放电状态及气流条件下发生器内外物种的自发辐射谱,发现光谱峰值强度与对应物种浓度成正比。分析了主要的等离子体动力学过程,了解了单重态氧及其它物种的浓度变化规律。考察了α放电和γ放电两种不同的放电方式。发现在α放电状态下,体系中有较少氧原子等淬灭性粒子,更有利于O₂(¹Δ)产生。加入He,有效地降低了气体体系的离子化阈能和约化场强,约化场强最小时,产生的O₂(¹Δ)浓度最大,相较于纯氧放电,O₂(¹Δ)浓度提高一倍以上。考察了腔外各物种浓度的变化,O₂(¹Δ)离开放电腔后浓度稳定,沿距离减少较慢,有益于出光。优化了本系统的放电极间距,极间距太大或太小,都不利于单重态氧的产生。     

Electrical discharge characteristics of a dielectric liquid under external flow in a microchannel with planar electrode configuration

The effect of fluid flow on discharge characteristics in a dielectric liquid was determined. Tests were performed for flow in a 100 micron high, 5 mm wide, 50 mm long microchannel at Reynolds numbers up to 13 and applied DC potentials up to 1.5 kV through 100 micro planar electrode pairs along the floor of the channel. The current within the conduction regime increased as the flow rate increased for the case where the flow was in the same direction as the applied electric field. In the injection regime, there was an optimum flow rate for maximum current.