Electrical resistance and magnetoresistance of amorphous alloys Gd67Co33 and Pd80Si20

In search for structural contributions to the low temperature anomaly we report high resolution resistance and magnetoresistance measurements ($\text{0.02}\text{K}\text{? T ? 20}\text{K}$) of amorphous splats of Gd₆₇Co₃₃ and Pd₈₀Si₂₀. For both alloys, the resistivity ?(H = 0, T) has a minimum at T ～ 10 K and increases with decreasing T. The ferromagnetic Gd₆₇Co₃₃ shows a strong negative field dependence of $\text{Δ?}\text{?(0)}$, saturating at H ～ 2T for T = 4.2 K but no measurable change in $\text{??}\text{?}\text{T}$ below 10 K is observed.The diamagnetic Pd₈₀Si₂₀ exhibits a positive field dependent magnetoresistance $\text{[Δ?}\text{?(0)]}\text{(}\text{H}\text{)}$ at low temperatures. Additionally, a field dependent part in $\text{??}\text{?}\text{T}$ is found which is probably due to paramagnetic impurities (～ 1 ppm Fe). However, there is also a field independent contribution in the amorphous state of Pd₈₀Si₂₀, which vanishes after crystallization. We attribute this to non-magnetic scattering induced by the disordered structure.     

Analysis of the high-temperature spin-glass susceptibility: Determination of the local magnetic exchange

New measurements are reported of the magnetic susceptibility above the freezing temperature T_f for noble-metal spin-glasses with $\text{1}\text{2}$ to 6 at.% Fe or Mn. The susceptibility for T_f<T?5 T_f is not Curie-Weiss, but local magnetic correlations manifest themselves and provide a key for the determination of the exchange interactions in spin-glasses. The exchange parameters J_n are resolved up to 5 neighbors for $\text{Au}$Fe, $\text{Cu}$Mn, $\text{Au}$Mn and $\text{Pt}$Mn through a configuration ensemble calculation which includes atomic short range order.     

On the validity of the Stoner-Wohlfarth model for FeNi invar alloys

After having recalled that the Arrot plots, i.e. M³ linear function of $\text{H}\text{M}$ are not a characteristic feature of weak ferromagnetism, we present experimental data on FeNi invar alloys near T_c that may seem difficult to be explained in the framework of this model.     

The frequency dependence of the ac susceptibility of the PdMn spin glass

We have measured the frequency dependence of the ac susceptibility _X(T) for three alloys of $\text{Pd}$Mn in the spin-glass regime. A strong dependence of _X(T) on frequency is observed near and below the freezing temperature in contrast to the archetypal $\text{Cu}$Mn spin glass. We discuss possible reasons for these differences.     

The magnetic-non magnetic transition of cerium impurities in lanthanum-thorium based alloys

A simple theoretical model which assumes a linear increase with thorium concentration for the cerium 4? level with respect to the Fermi level can explain both the decrease $\text{ΔT}{}_{\mathrm{c}}\text{c}$ of the superconducting temperature and the logarithmic slope $\text{d}\text{ρ}\text{c}\text{dln}\text{T}$ of the Kondo resistivity in LaTh based alloys with cerium impurities. The model yields two different maxima for |$\text{d}\text{ρ}\text{c}\text{dln}\text{T}$| and $\text{ΔT}{}_{\mathrm{c}}\text{c}$, the second one of which occurs when the resistivity minimum disappears, in very good agreement with experimental data.     

Magnetism and structural chemistry of ternary silicides: (RE,Th, U)Pt2Si2 (RE = rare earth)

Ternary silicides (RE, U, Th)Pt₂Si₂ have been prepared from the elements. All the compounds (RE= Y, La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu and U, Th) were found to be isotypic and crystallize with the primitive tetragonal CePt₂Si₂-type structure closely related to the CaBe₂Ge₂-type. The magnetic properties of these alloys were studied in the temperature range 1.5 K < T < 1100 K and in fields up to 1.3 T revealing a typical Van Vleck paramagnetism of free RE³⁺-ions for temperatures T > 200 K. A nonmagnetic ground state is reflected from the magnetic susceptibility data of CePt₂Si₂, which are interpreted in terms of interconfiguration fluctuations (ICF). The magnetic results of SmPt₂Si₂ (μ_eff = 0.7 BM) compare well with the ideal Van Vleck behavior of Sm₃₊ ions with a $\text{J =}\text{5}\text{2}$ ground state and a low-lying excited first level $\text{J =}\text{7}\text{2}$. At temperatures below 40 K antiferromagnetic ordering is found for (Gd, Tb, U)Pt₂Si₂; whereas in case of (Dy, Ho, Er, Tm)Pt₂Si₂ the onset of ferromagnetism is indicated below 4 K. None of the samples exhibited a superconducting transition above 1.8 K.     

Giant forced volume magnetostriction of Fe-rich iron-cobalt-zirconium amorphous alloys

The forced volume magnetostriction has been measured as a function of composition and temperature in amorphous (Fe_1?xCo_x)₉₀Zr₁₀ alloys. The maximum value of $\text{δω}\text{δH}$ (T = 0 K), equal to 285 × 10^-10 Oe^-1, has been observed for Fe₉₀Zr₁₀ alloys. The effect of pressure on the magnetization σ₀ at T = 0 K was calculated from $\text{δω}\text{δH}$ data. The pressure dependence of the Curie temperature T_c and σ₀ behaves in a similar way as those observed for crystalline NiPd and NiRh alloys.     

The nature of ordering in dilute Pt based alloys

Results are presented which suggest that, at low impurity concentrations (? 3 at.%), only near-neighbour impurity pairs order in $\text{Pt}$Fe and $\text{Pt}$Co.     

Long range interactions and spin wave excitations in FexPd82−xSi18 metallic glasses

The low temperature magnetization of amorphous Fe_xPd_82?xSi₁₈, 2 ? x ? 25, approaches saturation like 1/H. RKKY-type cluster-cluster interactions and single impurity effects are indicated. The effective strength of the RKKY interaction decreases with increasing x. The magnetization of both spin glass-like and weakly ferromagnetic alloys exhibits Bloch's T^{$\text{3}\text{2}$} dependence. The spin wave stiffness constants increase linearly with 2 ? x ? 25. The range of exchange interactions decreases with increasing x.     

Investigation of the diffusion of hydrogen in palladium by means of spin-lattice relaxation in the rotating frame

The diffusion of hydrogen in palladium $\text{(}\text{H}\text{Pd}\text{= 0.73)}$ has been investigated from 170 to 300K by measurements of the proton spin-lattice relaxation time in the rotating frame, T_1?. In contrast to previous T₁ measurements, a single activation energy of 0.225 eV is obtained, in agreement with the high-temperature T₁ data and with internal friction experiments at about 120K.     

On the magnetic properties of transition metal substituted MnAs

The properties of Mn_1?tT_t As phases (T: V, Cr, Fe or Co; 0<t$\text{\$}\text{?}$= 0.10) are studied in external magnetic fields up to 250 kOe, and temperatures between 80 and 400 K. The results are presented and discussed in terms of phase diagrams comprising concentration, temperature, and magnetic field axes.     

Correlation between band structure and hydride formation in dilute palladium alloys

Data on the free energy change ΔG, following solution of hydrogen in dilute Pd-alloys Pd_1?xM_x have been reviewed for different concentrations of M (M = Au, Ag, Pt, Ir, Rh, V, Cu, Ni, Pb, Sn and Ti) in both the α and β phases. The dependence of ΔG values upon the nature of the substituents (transition metals) is consistently explained within the framework of a metal-hydrogen bonding mechanism in the hydrides. For the β-hydride the ΔG values can be calculated on the basis of the equation ΔG = ΔG_pd + a(T)(〈?^M_LB〉 ? 〈?^Pd_LB〉)x, where $\text{ΔG}{}_{\mathrm{<mtext>Pd</mtext>}}\text{= ? 0.0489}\text{eV}\text{H}$ atom and is the free energy change of solution of hydrogen in pure Pd, a(T) = 0.194 at T = 298 K, 〈?^m_LB〉 and 〈?^pd_LB〉 are the average energies of the lowest band of the pure constituents ($\text{〈?}{}^{\mathrm{<mtext>Pd</mtext>}}{}_{\mathrm{<mtext>LB</mtext>}}\text{〉 = ?9.15}\text{eV}\text{atom}$). The stability of the palladium-hydrogen bond in dilute Pd-alloys depends on the value of 〈?^M_LB〉; for substituents having lower 〈?^M_LB〉 values than Pd the bond will strengthen, while for those having higher 〈?^M_LB〉 values it will weaken. This behaviour agrees well with the general trend of the stability of the stoichiometric hydrides predicted by Gelatt, Ehrenreich and Weiss using band structure results.     

Superconducting properties of ZnCr and ZnMn alloys

Measurements on the superconducting critical temperature T_c and critical field, H_c, of $\text{Zn}$Cr and $\text{Zn}$Mn alloys, down to 0.037°K are presented.The variation of T_c with increasing concentration depends strongly on T_cp/θ, with θ a characteristic temperature, while effects of H_c are similar to previously studied alloys.     

Superconducting properties of amorphous transition metal alloys

We have co-sputtered amorphous films of several Mo and W-based superconducting alloys. Measurements of T_c, ($\text{d}\text{H}{}_{\mathrm{c2}}\text{d}\text{T}$)_Tc and the normal state resistivity near T_c were made on a number of these alloys. Our results and other data from the literature are studied to examine the correlation between T_c and the dressed density of states at the Fermi level.     

The impurity resistivity and resistivity minima in AlCr and AlMn alloys

The impurity resistivity of $\text{Al}$Cr between 1.5 and 50°K was determined with a characteristic temperature for the T² variation θ₁=960±40°K. The behaviour of the resistivity minimum both in $\text{Al}$Cr and $\text{Al}$Mn alloys with impurity concentration provides evidence that a T³ phonon resistivity is found also in aluminium with anomalous impurity resistivity.     

Reversal of the magnetic interaction in hydrogenated Pd-Mn alloys

We have measured the properties of some Pd_1?xMn_x and Pd_1?xMn_xH_y alloys using a low field a.c. technique. For x<4%, we observe a change over from ferromagnetism (when y = 0) to antiferromagnetism (when y ≌ 0.7). The properties of the hydrogenated alloys are compared with the similar $\text{Ag}$Mn alloys.     

The differential cross section and polarization quantities in the 4He(d,p)n4He and 2H(α, n)p4He reactions

The differential cross section and the polarization quantities (T₁₁, T₂₀, T₂₁, T₂₂, P_γ') in the deuteron breakup reaction by an α-particle are calculated in the framework of the recently developed three-body model. All values are discussed under the incomplete kinematical condition. All polarization quantities are caused by the difference of the potential between $\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and $\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ waves of the N-α interaction. Results of the calculation are compared with the available measurement of (i) the differential cross section and the deuteron vector analysing power in the ⁴He($\text{d}$, p)n⁴He reaction and (ii) the differential cross section and neutron polarization in the ²H(α, $\text{n}$)p⁴He reaction. The agreement with experiment is very satisfactory in each case. Among the tensor analysing powers of the deuteron the absolute value of T₂₀ is very large. Observables at the FSI peak corresponding to ⁵He_g.s. are discussed systematically in the energy region of 5.4–20 MeV of the incident deuteron in the ⁴He(d, p)n⁴He reaction. Although the differential cross section is not sensitive to the energy of the three-body resonance, the polarization quantities T₁₁, T₂₀, P_γ' are quite sensitive to it.     

Mössbauer effect studies of spin disturbances in dilute ferromagnetic alloys

¹¹⁹Sn Mössbauer effect studies of dilute Pt Fe, Pd Fe and Ni Fe alloys are reported. For Pt Fe an oscillatory spatial dependence of the spin-polarization about the Fe atoms is observed. The range increases with increasing temperature. For Pd Fe and Ni Fe the host properties are masked by the magnetic disturbances induced by the tin probe atoms.     

Depolarization in proton inclusive inelastic scattering and in the (d,p) reaction on medium-weight nuclei

The energy-averaged depolarization parameter K_y^y′ has been measured for the inelastic scattering of 18 MeV protons from ⁵⁴Fe, ⁶³Cu and ⁹²Mo at 45°, 90° and 135°, and for 14.35 MeV protons from ⁶³Cu at 45° and 135°. In all cases K_y^y′ varies from approximately unity for scattering with low energy loss to approximately zero for inelastic scattering to high excitation energies. The change from one of these values to the other occurs over a region ≈ 6 MeV wide centered at about 5 MeV excitation. A simple two-component model fits both the K_y^y′ and inelastic crosssection data. K_y^y′ has also been measured for the ⁵⁴Fe($\text{d}$, $\text{p}$)Fe reaction with 16 MeV deuterons incident. Here K_y^y′ changes from approximately the maximum possible value, $\text{2}\text{3}$, to about zero in a 6 MeV region centered at roughly 13 MeV excitation. The ($\text{d}$,$\text{p}$) data can be fitted by an extension of the model used for the proton scattering data.     

Oblate ground-state shapes of 11 h 189Pt and 2.8 d 191Pt

With nuclear orientation on $\text{11}\text{h}\text{3}\text{2}{}^{\mathrm{?189}}\text{Pt}\text{, 2.8}\text{d}\text{3}\text{2}{}^{\mathrm{?191}}\text{Pt}$ and $\text{4.0}\text{d}\text{13}\text{2}{}^{\mathrm{<mtext>+\; 195\; </mtext><mtext>m</mtext>}}\text{Pt}$ in Os and NMR on oriented ¹⁸⁹Pt and ¹⁹¹Pt in Fe electric and magnetic hyperfine splitting frequencies were measured. The nuclear moments are deduced to be: ¹⁸⁹Pt: |μ| = 0.434(9) μ_N, Q = ?0.65(26) b; ¹⁹¹Pt: |μ| = 0.500(10) μ_N, Q = ?0.64(26) b; ^195mPt: Q = +1.42(60)b. The negative spectroscopic ground-state quadrupole moments of ¹⁸⁹Pt and ¹⁹¹Pt must be due to oblate ground-state deformations, thus indicating that the prolate-oblate phase transition in Pt is located at A < 189.