Simultaneous GCSM description of the M1 state and the major collective bands

The generalized coherent state model is used to simultaneously describe the magnetic state 1⁺ and the collective bands: ground, beta and gamma. Effective operators for the M1 and the E2 transitions are derived. Also the M1 form factor for the (e, e′) scattering is treated in the plane wave Born approximation. The symmetry of the lowest gamma band is discussed. The application is made for ¹⁵⁴Gd, ¹⁵⁴Sm, ¹⁶⁴Dy, ¹⁶⁸Er, ¹⁷⁴Yb, ²³²Th, ²³⁸U. The agreement with the experiment is very good for both the 1⁺ state and the considered collective bands.     

Imaging of the H NMR Second Moment with C Chemical-Shift Resolution

A method of ¹³C chemical-shift-resolved ¹H second moment imaging is proposed for molecular mobility imaging of heterogeneous materials. For evaluating the ¹H second moment, the method relies on the curve fitting procedure using spin-echo shapes indirectly: The information of ¹H echo shapes is transferred to the ¹³C signal amplitude through ¹H–¹³C cross polarization and then the curve fitting is made using the ¹³C signal amplitude. The ¹³C signal is detected under ¹H dipolar decoupling and magic angle spinning, resulting in the incorporation of ¹³C chemical-shift resolution. Imaging information is included in the ¹³C signal by application of phase-encoding gradients. The second moment images obtained can reflect the molecular mobility at every molecular site separated by ¹³C chemical shifts, yielding detailed information on the molecular mobility. The method is demonstrated by spatially 1D experiments performed on a model sample.     

The ultraviolet irradiation degradation of fluorescent lamp used BaMgAl10O17:Eu2+,Mn2+ phosphor

The ultraviolet irradiation degradation of lamps using BaMgAl₁₀O₁₇:Eu²⁺,Mn²⁺ phosphor is investigated. The X-ray photoelectron spectra demonstrate that the oxidation of Eu²⁺ is taking place during ultraviolet irradiation in air. The experiment in nitrogen indicates that the oxidation of Eu²⁺ is directly related to the oxygen in air and should be mainly responsible for the degradation of Eu²⁺. It reveals that the Mn²⁺ centers always remain stable during irradiation but its emission is involved in the energy transfer of Eu²⁺→Mn²⁺. Thus, the oxidation of Eu²⁺ also leads to the degradation of Mn²⁺.     

Theoretical studies on geometrical and electronic structure of electroplex at the NPB/PBD interface in organic light-emitting diodes

The studies on geometrical and electronic structure of electroplex (NPB⁺PBD⁻), which is formed by NPB⁺ and PBD⁻, were carried out by simulation calculation. The calculation results indicate that the (NPB⁺PBD⁻) is formed efficiently when the positions of PBD⁻ and NPB⁺ are appropriate. The (NPB⁺PBD⁻) is energetically favored compared to isolated ions NPB⁺ and PBD⁻. So the ionic state NPB⁺ and PBD⁻ at the interface NPB/PBD inside organic light-emitting diode (OLED) tend to form electroplex. The analysis of geometrical structure data of the (NPB⁺PBD⁻) suggests that the electron transfer occurs from the PBD⁻ side to the NPB⁺ side. The lowest unoccupied molecular orbital (LUMO) of (NPB⁺PBD⁻) is localized on the PBD⁻ side and the highest occupied molecular orbital (HOMO) of (NPB⁺PBD⁻) on the NPB⁺ side. The energy gap of the (NPB⁺PBD⁻) is 1.61 eV, which approximately equals to the energy difference of 1.63 eV between the LUMO of PBD and the HOMO of NPB. The emission of electroplex is theoretically intermolecular optical transition from the LUMO of PBD to the HOMO of NPB. Because of little overlap probability between LUMOs of PBD and NPB at the NPB/PBD interface inside OLED, the exciplex of PBD and NPB is not efficiently produced.     

Upconversion properties of Er^3＋/Yb^3＋ co-doped TeO2-Nb2O5-Li2O glasses

The Er^3＋/Yb^3＋ co-doped TeO2-Nb2O5-Li2O glass is prepared by conventional melting method, and its upconversion spectra are measured. The intense green upconversion luminescence upon excitation with a 976 nm laser diode is observed with the naked eyes. The dependence of luminescence intensity on the ratio of Yb^3＋/Er^3＋ is discussed in detail, and the relationship between the ratio of green luminescence intensity to red luminescence intensity and the ratio of Yb^3＋/Er^3＋ is also studied, The luminescence intensity increases with the ratio of Yb^3＋/Er^3＋ increasing. The ratio of Yb^3＋/Er^3＋ plays a more important role than the concentration of Er^3＋ in determining the upconversion luminescence intensity. The ratio of green luminescence intensity to red luminescence intensity reaches a maximum when ratio of Yb^3＋/Er^3＋ is 3. Thus the glass could be one of the potential candidates for LD pumping solid-state lasers.     

Structure of129Ba from the decay of129La

The structure of¹²⁹Ba is investigated through the beta decay of¹²⁹La, whose half-life is measured to be 11.6±0.2 m. The decay properties are studied by means of beta, gamma and conversion electron spectroscopy techniques. Many transitions are observed and a level scheme of¹²⁹Ba with deduced¹²⁹Ba values is proposed. The total decay energy of¹²⁹Ba is measured to be 3.72±0.05 MeV, which is compared with predictions of mass formulae. Low-lying structure of¹²⁹Ba is discussed in terms of collective models.     

Measurement of the147Gd mass excess by the (12C,9Be) reaction

The mass excess of the¹⁴⁷Gd nucleus was measured from the¹⁴⁴Sm(¹²C,⁹Be)¹⁴⁷Gd reaction using the 72 MeV¹²C beam of the Orsay MP Tandem and the “Bacchus” magnetic spectrometer. The measurement is auto-calibrated by the¹⁰Be spectrum from the¹⁴⁴Sm(¹²C,¹⁰Be) reaction. The derived value of the mass excess of¹⁴⁷Gd is ?75.401±0.025 MeV. It is compared with other recent results and with calculated values.     

Influence of additional metal ions on the ratio of conversion rates of intermediate products of the hydrolysis of adenosine-5′-triphosphoric acid catalyzed by the Cu2+ ion: 1. Experimental study of the influence of Mg2+ ions in the ascending branch of the dependence of the initial hydrolysis rate on pH

The hydrolysis of the dimeric complex (CuATP^2?)₂ to CuADP^? and inorganic phosphate P _i is irreversible. The main intermediate hydrolysis product, whose formation should be taken into account at relatively early steps of hydrolysis, is the pentacovalent intermediate IntK formed in parallel with the hydrolysis to CuADP^? and P _i through the common intermediate product (CuATP^2?)₂OH^? (DOH^?) in step 1, which is the replacement of the nucleophile (OH^?) at the Cu²⁺ ion by OH^? at the positively charged phosphorus atom. The influence of the addition of Mg²⁺ ions is studied (depending on their concentration) on the rate constants of step 1 in the region of pH in the ascending branch of the dependence of the initial hydrolysis rate on pH at two values of pH: 6.48 and 6.70. This region of pH is sensitive to both the rate constant of DOH^? formation and the rate constants of step 1. The rate constant for the formation of DOH^? from D remains unchanged. An increase in the concentration of Mg²⁺ decreases the value of ATP conversion, above which the stationary hydrolysis regime is observed. The ratio [IntK]/[DOH^?] is higher when the stationary regime is attained. The applicability of the method proposed for the formation of the attacking nucleophile and the proposed sequence of steps to the enzymatic phosphoryl transfer processes is discussed.     

Bestimmung der 15N Häufigkeit bei nichtstatistischer 15N-verteilung in N2 sowie bei N2O in Bodenluftproben mittels GC-R-IRMS-Kopplung in einem Probenlauf

Abstract

An analysis technique based on GC-R-IRMS coupling (Gas-Chromatography-Reduction-Isotope Ratio Mass Spectrometry) is demonstrated. The ¹⁵N abundance of N² and N²O in atmospheric air or soil atmosphere from nitrification or denitrification processes with nonrandom distribution is determined in one run. The 12 ml sample is separated from CO² and transported by a helium gas stream through a cooling trap. The N²O is trapped in the cooling trap while the N² passes through it and enters the GC. After GC separation and O² removal in a reduction column, part of the N² enters an isotope mass spectrometer to determine the masses m/z 28,29 and 30. The interferences on mass 30 by the formation of NO in the ion source of the mass spectrometer are eliminated by a calibration and a correction procedure. Upon removing the cooling trap, the N²O is injected into the GC, where it is separated and then quantitatively reduced to N² in a reduction column. The measurement of one sample takes 16 minutes. The detection limit of the ³⁰R_t in alteration N₂ is Δ³⁰R_t = 5 · 10^?7. The detection limit of the N₂O is 3.6 nl.     

HT-6M托卡马克等离子体紫外-可见谱

利用光学多道分析仪(OMA)拍摄了HT-6M托卡马克等离子体近紫外可见谱.系统分析了杂质行为,给出了主要杂质碳和氧的朝内的通量,在简化模型下计算了碳氧的化学溅射率,并由此得出碳氧杂质产生机制和可能的循环途径.结果表明,氧杂质在循环途径中起关键性的作用,控制氧杂质尤其重要.     

Energy transfer between Sm and Er in orthophosphate YPO4

The energy transfer between Sm³⁺ and Er³⁺ ions in yttrium orthophosphate is studied. This choice of ions is based on the possibility of quantum cutting processes and the host material is selected according to the position of the 5d bands of the Sm³⁺ ion. The Sm³⁺ and Er³⁺ doped and Sm³⁺, Er³⁺ co-doped YPO₄ have been synthesized. Spectroscopic studies were done in the ultraviolet and vacuum ultraviolet ranges. The energy transfer between Sm³⁺ and Er³⁺ is very efficient but it does not lead to Er³⁺ visible emission. Whatever the excitation wavelength, the emission of co-doped samples mainly occurs in the infrared range.     

Time-dependent self-consistent perturbation theory and applications to molecules

The two most intense bands of the 370 nm electronic band system of tropolone have been rotationally analysed. They are separated by 18·93 cm^-1 and it has been shown that the high wavenumber band is the 0^--0^- (H₁ ¹) transition in what is almost certainly the internal hydrogen-bonding vibration v _H : the low wavenumber band is the 0⁺-0⁺ (0₀ ⁰) transition. A rotational contour analysis of both bands shows that there is an intensity alternation in K _a″ such that the ratio K _a″ even : odd is 10 : 6 in the 0⁺-0⁺ band and 6 : 10 in the 0^--0^- band. The intensity alternation, the nearly equal intensities of the 0⁺-0⁺ and 0^--0^- bands, the separation of these two bands and the anharmonic behaviour of v _H show that the separation of the 0⁺ and 0^- levels is small in the ground electronic state (probably less than 50 cm^-1) and is 18·93 cm^-1 larger in the excited electronic state.

The 0⁺-0⁺ and 0^--0^- bands are both type B showing that the electronic transition is à ¹ B ₂-X ¹ A ₁ and therefore π*-π rather than π*-n. The π*-n transition is probably shifted to high wavenumber by the internal hydrogen-bonding.     

Spectral properties and energy transfer of Yb,Er:GdVO4 crystal

GdVO₄ single crystal co-doped with Yb³⁺ and Er³⁺ was grown by the Czochralski method. The X-ray powder diffraction pattern of Yb,Er:GdVO₄ crystal confirms that the as-grown crystal is isostructural with pure GdVO₄ crystal. Its polarized absorption spectra and non-polarized fluorescence spectra were measured at room temperature. The absorption band at 984 nm for π-polarization has an FWHM of about 36 nm, which is favorable for InGaAs LD laser pumping. The spectrum properties of Er³⁺ in Yb,Er:GdVO₄ crystal were investigated based on Judd–Ofelt theory. There is strong energy transfer from Yb³⁺ to Er³⁺ in this crystal. When excited with 980 nm radiation, this crystal emitted strong fluorescence at about 1529 nm and 552.5 nm. The total energy transfer rate and efficiency from Yb³⁺ to Er³⁺ is 3.33 ms^-1 and 67%, respectively. The energy transfer between Er³⁺ and Yb³⁺ ions is a multistep transfer process, and was investigated based on a random-walk model. The investigation result shows that there is strong cooperative-sensitization effect from Yb³⁺ to Er³⁺, which is the main upconversion energy-transfer process in this crystal. PACS 42.70.Hj; 81.10.Fq; 42.55.Rz     

The 41Σ+ electronic state of LiCs molecule

The 4¹Σ⁺ state of LiCs molecule is observed experimentally for the first time. The inverted perturbation approach (IPA) method is used to derive the potential energy curve of the state from the measured spectra. The experiment is accompanied by theoretical calculations of adiabatic potentials for excited states in LiCs including 4¹Σ⁺, performed with the MOLPRO program package. The irregular shape of the 4¹Σ⁺ state potential predicted by theory is confirmed in the experiment.     

Spectroscopic and laser properties of Cr3+:Yb3+:Er3+: fluoride phosphate glass

Sensitization of the fluorescence of Er³⁺ in fluoride phosphate glass containing up to 20 mol% phosphates by codoping with Cr³⁺ and Yb³⁺ is shown. The low order of ligand field strength for Cr³⁺ (Dq/B=2.04) results in broad Cr³⁺ fluorescence overlapping the Yb³⁺ absorption. The electronic energy transfer efficiency approaches 100%. Deviations of donor decay from the Förster law are interpreted in terms of the inhomogeneously acceptor distribution. The electronic energy transfer efficiency of Yb³⁺ → Er³⁺ reaches a maximum value of 75% for glasses containing 20 mol% phosphates. The transfer is shown to be migrationally accelerated by means of GAF-LAF-FB theory. From Judd-Ofelt parameters a stimulated emission cross-section for the transition⁴I_13/2 →⁴I_15/2 of Er³⁺ of 6.2×10⁻²⁰ cm² is derived. The c.w. laser action of Er³⁺ by Cr³⁺ excitation and double-step energy transfer is shown. The output is tuned continuously from 1536 to 1596 nm. Flashlamp pumping is also shown.

     

Systematic study of rotational energy formulae for superdeformed bands in La and Ce isotopes

The experimental rotational spectra of superdeformed(SD) bands of ~(130)La, ~(131)Ce(1,2), ~(132)Ce(1,2,3) and133 Ce(1,2,3) in the A～130 mass region are systematically analyzed with the four parameter formula, power index formula, nuclear softness formula, and VMI model. It is observed that out of all the formulae, the four parameter formula suits best for the study of the ~(130)La, ~(131)Ce(1,2), ~(132)Ce(2,3) and ~(133)Ce(1,2,3) SD bands. The four parameter formula works efficiently in determining the band head spin of the ~(130)La, ~(131)Ce(1,2) ~(132)Ce(2,3) and ~(133)Ce(1,2,3) SD bands. Good agreement is seen between the calculated and observed transition energies whenever the accurate spin is assigned. In ~(132)Ce(1), the power index formula is found to work better than the other three formulae. The dynamic moment of inertia is also calculated for all the formulae and its variation with the rotational frequency is investigated.     

Study of spin-orbit interaction of13C and15N nuclei in14C induced transfer reactions on138Ba

Angular distributions of single nucleon transfer reactions populating single particle states in the reactions¹³⁸Ba(¹⁵C,¹⁴N)¹³⁷Cs and¹³⁸Ba(¹⁴C,¹³C)¹³⁹Ba have been studied. The shapes of the angular distributions show differences for different final configurations. Using the reaction asymmetry it is possible to describe these differences consistently for all transitions by a spin-orbit potential. The polarisation of the outgoing fragments is discussed and its dependence on final configurations is explained. The spin-orbit potentials deduced from the reaction asymmetry are large, as compared to predictions of folding potentials. They are, however, consistent with measurements of spin-flip probabilities. The origin of theL-S interaction is to be found in coupling effects of second order in the heavy ion reaction.     

System dependence of the correlation function of IMFs in Ar + Sn at 35 MeV/u

The inclusive reduced velocity correlation functions of the intermediate mass fragments were measured in the reactions of ³⁶Ar + ^112,124Sn at 35 MeV/u. The anti-correlation is observed to be stronger in ³⁶Ar + ¹²⁴Sn system than that in ³⁶Ar + ¹¹²Sn. The difference of the correlation functions between the two reactions is mainly contributed by the particle pairs with high momenta. A three body Coulomb repulsive trajectory model is employed to calculate the emission time scale of the IMFs for the two systems. The time scale is 150 fm/c in ³⁶Ar + ¹¹²Sn and 120 fm/c in the ³⁶Ar + ¹²⁴Sn, respectively.     

The 48Ca(3He,t)48Sc reaction at 66 and 70 MeV: Reaction mechanism and Gamow-Teller strength

The ⁴⁸Ca(³He, t)⁴⁸Sc reaction has been studied at E_3He = 66 MeV and 70 MeV. Angular distributions are given from θ = 8° to 35°. The 0⁺–7⁺ multiplet in ⁴⁸Sc is strongly excited at these energies and the spectra are further characterized by some broad structures on a continuous background. Broad peaks at E_ex = 7.8, 10.6 and 13.3 MeV have an angular distribution similar to the low-lying 1⁺ state. The broad peaks are interpreted as envelopes of groups of 1⁺ states carrying a significant part of the Gamow-Teller strength. The strength distribution is consistent with a shell-model calculation. The reaction mechanism has been examined at 66 MeV. The cross section is calculated for the 0⁺–7⁺ multiplet in ⁴⁸Sc as a coherent sum of one-step and two-step processes. The two-step contribution is calculated in a full finite-range 2nd-order DWBA. The result is similar contributions from (³He, α, t) and (³He, d, t). The calculations account reasonably well for the data with the exception of the transition to 0⁺, IAS.     

kinetic energy reflection from polycrystals bombarded with Ar+, Kr+, and Xe+ ions

When the surface of a solid is bombarded with ions a fraction of the primary energy is reemitted by ion reflection and sputtering. The contribution of ion reflection or sputtering to energy reflection is determined by the mass ratio of the bombarding ions to the target atoms.^1,2 In the case of light ions the contribution of reflected ions is dominant. Results for He⁺ and Ne⁺ bombardment were described in a previous paper.³ The present paper deals with results for Ar⁺, Kr⁺, and Xe⁺ bombardment of the same targets as investigated before.³ The energies of the mass selected bombarding ions range from 9 to 16 keV. The measurements were carried out by means of the thermic detector described in a separate paper.⁴ For the given mass ratios most of the reemitted energy is related to sputtering.