Hole mobility in evaporated layers of As2S3.CdI2

The hole drift mobility in As₂S₃.CdI₂ has been determined using Spear's method. The room-temperature value is 10^?4$\text{cm}{}^2\text{Vs}$, the activation energy 0.2 eV. The hole yield appears to be controlled by geminate recombination.     

Coriolis intensity perturbations in the SO2 molecule: Experimental determination of the relative signs of (∂μ∂Qi)

The Coriolis interactions between ν₁ and ν₃, and between ν₂ and ν₃ in SO₂ have been analyzed to obtain the signs of the products $\text{ζ}{}_{3.1}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_1\text{)}$ and $\text{ζ}{}_{3.2}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_2\text{)}$. It has been found that both of the signs of these products are positive. Then, relative signs of ($\text{?μ}\text{?Q}{}_1$) have been determined using the calculated values of the Coriolis zeta constants for the present definition of the normal coordinates. The obtained sign combination of ($\text{?μ}\text{?Q}{}_{\mathrm{i}}$) is ±(+?+), which agrees with the one predicted by the molecular orbital calculations. Using the sign combination (+?+), the polar tensors of S and O atoms were also calculated.     

Preparation and semiconducting properties of Th3As4

The resistivity, thermoelectric power and Hall constant in the temperature range of 78–830 K were determined for polycrystalline Th₃As₄ samples obtained by annealing thin thorium slabs in arsenic vapour. The samples examined were n-type semiconductors with a carrier concentration ranging from 1.0 × 10¹⁸cm^?3 to 2.8 × 10¹⁸ cm^?3 for which the effective mass was found to be equal to 0.55–0.76m₀. The Hall mobility, about 450cm²V^?1s^?1 at room temperature, obeys a $\text{T}{}^{\mathrm{<mtext>?3</mtext><mtext>2</mtext>}}$ law at high temperatures. On the basis of the electrical measurements the forbidden gap of Th₃As₄ was found to be equal to 0.43 eV.     

Doppler-limited dye laser excitation spectroscopy of the CCN radical

The cw dye laser excitation spectrum of the $\text{A}\text{?}{}^2\text{Δ}\text{(000) ←}\text{X}\text{?}{}^2\text{Π}\text{(000)}$ vibronic transition of the CCN radical was observed between 21 205 and 21 335 cm^?1 with the Doppler-limited resolution, 0.04 cm^?1. The CCN radical was produced by reaction of microwave discharged CF₄ with CH₃CN. The observed spectrum was analyzed to determine rotational and centrifugal constants and effective spin-orbit and spin-rotation coupling constants for both the $\text{A}\text{?}{}^2\text{Δ}\text{(000)}$ and the $\text{X}\text{?}{}^2\text{Π}\text{(000)}$ states, and also the Λ-type doubling constants for the $\text{X}\text{?}{}^2\text{Π}\text{(000)}$ state. The constants determined reproduce the observed spectrum with an average deviation of 0.0027 cm^?1, and are considered to be precise enough for predicting the ground-state microwave transition frequencies. No evidence was found for perturbation in either the $\text{A}\text{?}{}^2\text{Δ}\text{(000)}$ or the $\text{X}\text{?}{}^2\text{Π}\text{(000)}$ state.     

Two-electron,one-photon transitions in nickel

The two emission lines, Kα₁α₃^h and Kα₂α₃^h resulting from the two-electron transitions $\text{1s}{}^{\mathrm{?2}}\text{→ 2s}{}^{\mathrm{?1}}\text{2p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}$ and $\text{1s}{}^{\mathrm{?2}}\text{→ 2s}{}^{\mathrm{?1}}\text{2p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}$ were resolved for elemental nickel. Their measured energies agree well with calculations. Their relative intensity $\text{I(Kα}{}_1\text{α}{}_3{}^{\mathrm{h}}\text{)/I(Kα}{}_2\text{α}{}_3{}^{\mathrm{h}}\text{) ≈}\text{3}\text{4}$ and their intensity relative to that of the Kα diagram lines is about 10^?4. This is some 10⁴ times larger than both theoretical results and the results of ion-atom collision experiments.     

Lifetime of electronic states of CO2+

The radiative lifetimes of the $\text{A}\text{?}{}^2\text{Π}{}_{\mathrm{u}}$ and $\text{B}\text{?}{}^2\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ states of CO₂⁺ were measured by means of the delayed coincidence method. Excitation was performed by a pulsed electron beam incident on CO₂. The results of these measurements are 115 ± 5 nsec for the $\text{A}\text{?}{}^2\text{Π}{}_{\mathrm{u}}$ state and 126 ± 3 nsec for the $\text{B}\text{?}{}^2\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state.     

Theoretical prediction of the vertical electronic spectrum of the C2H radical

The vertical transition energies and oscillator strengths from the $\text{X}\text{?}{}^2\text{Σ}{}^{\mathrm{+}}$ ground and $\text{A}\text{?}{}^2\text{Π}$ excited states of the ethynyl radical C₂H to all higher-lying states resulting from excitation out of π and σ into $\text{π}{}^1$ and $\text{σ}{}^1$ valence-shell MO's, respectively, as well as into 3s and 3p Rydberg species, are calculated by large-scale CI techniques. It is found that the first excited states all result from $\text{π → π}{}^1$ excitations (the lowest three with quartet character), and not from the 4σ → 5σ counterparts favored in the case of isoelectronic CN. This distinction can be explained on the basis of orbital stability differences caused by the effects of hydrogen mixing. The first six states of the C₂H⁺ ion are also treated, and the correspondence with the various associated Rydberg series is discussed. Dipole moments for the $\text{X}\text{?}{}^2\text{Σ}{}^{\mathrm{+}}$ and $\text{A}\text{?}{}^2\text{Π}$ states are also calculated.     

The ã3A2 ← X̃1A1 absorption spectrum of thioformaldehyde: A vibrational and rotational analysis

The results of a vibrational and rotational analysis of the banded $\text{a}\text{?}{}^3\text{A}{}_2\text{←}\text{X}\text{?}{}^1\text{A}{}_1$ transition in $\text{CH}{}_2\text{S}\text{CD}{}_2\text{S}$ are presented. Only three of the six vibrational modes are active in the spectrum with $\text{ν′}{}_2\text{=}\text{1320}\text{1012}$, $\text{ν′}{}_3\text{=}\text{859}\text{798}$, and $\text{2ν′}{}_4\text{=}\text{711}\text{516}\text{cm}{}^{\mathrm{?1}}$. The spin forbidden transition gains intensity primarily by a mixing of the ${}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$ and ${}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. This is confirmed by a rotational analysis of the 0₀⁰ band of both isotopes. The rotational analysis shows that the coupling in the $\text{a}\text{?}{}^3\text{A}{}_2$ state is near Hund's case b and that the spin constants are nearly 10 times greater than those observed for CH₂O. A $\text{CNDO}\text{2}$ calculation shows that this difference is due to the greater spin orbit coupling of S in CH₂S and to the smaller energy differences between the $\text{B}\text{?}{}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{b}\text{?}{}^3\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{X}\text{?}{}^1\text{A}{}_1$, and the $\text{a}\text{?}{}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. The r₀ structure calculated from the rotational constants is $\text{r}{}_{\mathrm{<mtext>CS</mtext>}}\text{= 1.683}\text{A}\text{?}$, $\text{r}{}_{\mathrm{<mtext>CH</mtext>}}\text{= 1.082}\text{A}\text{?}$, β_HCH = 119.6°, and α (out of plane) = 16.0°. A simultaneous fit of the vibrational levels in ν′₄ of CH₂S and CD₂S to a double minimum potential function yielded a barrier to molecular inversion of 13 cm^?1 and an equilibrium out-of-plane angle of 15°.     

Ω− produced in K−p reactions at 4.2 GeV/c

Forty $\text{Ω}{}^{\mathrm{?}}$ events have been observed in a large (133 events/βb) experiment at 4.2 GeV/c incident K^? momentum. Thirty nine of the events come from the three-body reaction $\text{K}{}^{\mathrm{?}}\text{p}\text{→Ω}{}^{\mathrm{?}}\text{K}{}^{\mathrm{+}}\text{K}{}^0$. The $\text{Ω}{}^{\mathrm{?}}$ is mainly produced in the forward hemisphere (direction of the incident K^?). The lifetime is measured to be τ = (0.75 _+0.14?0.11 × 10^?10 sec substantially less than the Particle Data Group value of (1.3 _?0.3^+0.2) × 10^?10 sec. The mass is determined to be 1671.7 ± 0.6 MeV, in good agreement with other determinations. The decay asymmetry parameter α (for the decay mode $\text{Ω}{}^{\mathrm{?}}\text{→ Λ}\text{K}{}^{\mathrm{?}}$) is found to be ?0.2 ± 0.4.     

The nuclear magnetic moment of 71As and 72As

Nuclear magnetic resonance of oriented ⁷¹As and ⁷²As nuclei has been observed in an iron host lattice at low temperatures. The resonance frequencies are v_l = 174.96(10) MHz and 282.00(11) MHz respectively for zero external field. Using B_h.f.(FeAs) = 342.9(3) kG the g-factors of the two isotopes are derived as $\text{g(}{}^{71}\text{As}\text{) = (+)0.6694(7)}\text{and}\text{g(}{}^{72}\text{As) = (?)1.0789(11)}$. Combining nuclear orientation data with these results the spin of ⁷¹As has been confirmed as $\text{I =}\text{5}\text{2}$. The magnetic moments of the $\text{5}\text{2}{}^{\mathrm{?}}$ and 2^? states in the As isotopes are discussed in the framework of the shell model with configuration mixing.     

Neutron-proton radius differences and isovector deformations from π+ and π− inelastic scattering from 18O

π⁺ and π^? elastic and inelastic scattering from ¹⁸O have been measured at T(π)=164 MeV. Consistent with the results at 230 MeV, it is found that the ratio $\text{σ(π}{}^{\mathrm{?}}\text{)}\text{σ(π}{}^{\mathrm{+}}\text{)}$ for the 2₁⁺ state is 1.86(16), while for the 3₁^? state it is 0.89(6). These results are interpreted as indicating differences in neutron and proton deformations characterizing the 2₁⁺ transition and partial neutron blocking for the 3₁^? transition. Optical model analysis of elastic scattering leads to the conclusion that $\text{〈r}{}_{\mathrm{<mtext>n</mtext>}}{}^2\text{〉}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{?〈r}{}_{\mathrm{<mtext>p</mtext>}}{}^2\text{〉}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{=0.03(3)}\text{fm}$.     

The ultraviolet absorption spectrum of thioformaldehyde

The spectra of H₂CS and D₂CS were surveyed over the wavelength region from 230 to 180 nm and four distinct absorptions were identified. These are assigned to transitions from the $\text{X}\text{?}{}^1\text{A}{}_1$ ground state to the $\text{B}\text{?}{}^1\text{A}{}_1\text{(π, π}{}^1\text{)}$, $\text{C}\text{?}{}^1\text{B}{}_2\text{(n, 3s)}$, $\text{D}\text{?}{}^1\text{A}{}_1\text{(n, 3p}{}_{\mathrm{y}}\text{)}$, and $\text{E}\text{?}{}^1\text{B}{}_2\text{(n, 3p}{}_{\mathrm{z}}\text{)}$ electronic states. A vibrational and rotational analysis of the second system was undertaken. The results indicate that the molecule is planar in the $\text{C}\text{?}{}^1\text{B}{}_2\text{(n, 3s)}$ state and that while the CH and CS bond lengths remain near their ground-state values, the HCH angle increases substantially.     

Level structure of 75Se by the 75As(p,nγ)75Se reaction

Excitation functions of γ-rays from the ⁷⁵As(p, n)⁷⁵Se reaction were measured with 2.0 to 3.6 MeV protons to establish the level scheme of ⁷⁵Se up to about 1.5 MeV excitation energy. Internal conversion electrons following the same reaction were measured at 4.5 and 5.0 MeV proton energy. Using theoretical predictions of the statistical compound nucleus model together with deduced internal conversion coefficients, unique spin assignments were obtained for the $\text{112.5(}\text{7}\text{2}{}^{\mathrm{+}}\text{), 427.9(}\text{5}\text{2}{}^{\mathrm{?}}\text{)}$ and $\text{663.9(}\text{5}\text{2}{}^{\mathrm{?}}\text{)}\text{keV}$ levels. Probable spins were proposed to the $\text{286.6 (}\text{3}\text{2}{}^{\mathrm{?}}$ for one of the doublet and $\text{5}\text{2}{}^{\mathrm{?}}$ or $\text{7}\text{2}{}^{\mathrm{?}}$ for the other), 579.4 $\text{(}\text{1}\text{2}{}^{\mathrm{?}}$ or $\text{3}\text{2}{}^{\mathrm{?}}$, $\text{585.8(}\text{9}\text{2}{}^{\mathrm{?}}$ or $\text{11}\text{2}{}^{\mathrm{?}}$ and $\text{747.6 (}\text{5}\text{2}{}^{\mathrm{?}}$ or $\text{7}\text{2}{}^{\mathrm{?}}\text{)}\text{keV}$ levels. Alow-lying $\text{9}\text{2}{}^{\mathrm{+}}$ level was tentatively assigned at 133.2 keV energy. It was found that a low-lying $\text{1}\text{2}{}^{\mathrm{?}}$ level which appears systematically in other odd Se nuclei is absent in ⁷⁵Se.     

3Σu−-3Σu+ coupling in the O2B3Σu− predissociation

The role of $\text{B}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{-2}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ spin-orbit mixing in the O₂ Schumann-Runge predissociation is investigated. The $\text{2}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state is found to cross the $\text{B}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}$ state near 2.0 Å with an interaction matrix element of approximately 55 cm^?1. This state contributes to the widths of the Bv ≥ 6 levels, but introduces only small level shift perturbations. When the partial widths due to the ${}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{-}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ interaction are added to the previously calculated widths due to the ⁵Π_u, ³Π_u, and ¹Π_u states, reasonable agreement is obtained with experimental measurements on O¹⁶O¹⁶ and O¹⁸O¹⁸. The possibility of non-Lorentzian line profiles and the dependence of the width on rotational quantum number is investigated. The approximation of the spin-orbit matrix element by its value at the crossing point is shown to be a good approximation for calculating the second difference perturbations.     

Opto-galvanic spectroscopy of broadening and shift of two-photon thallium transitions by N2 and He

This paper reports the first measurements of pressure broadening and shift of thallium 6 ${}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{?8}{}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$$\text{3}\text{2}$ transitions by N₂ and He perturbers. Ion-detection with box-car integration was used for data collection. The number of the perturbating gases ranged from $\text{(1.1?4.7)×10}{}^{19}\text{cm}{}^3$. The red shift to N₂ and the shift due to He are found to vary linearly with pressure. The value of the effective cross section for the impact broadening was determined and van der Waals constants obtained.     

The dipole moment of thioformaldehyde in its singlet and triplet π1 − n excited states

Laser-induced fluorescence excitation has been used to measure Stark splittings of selected lines in the $\text{A}\text{?}{}^1\text{A}{}_2\text{-}\text{X}\text{?}{}^1\text{A}{}_1$ and $\text{a}\text{?}{}^3\text{A}{}_2\text{-}\text{X}\text{?}{}^1\text{A}{}_2$ band systems of H₂CS in electric fields up to 13 kV/cm. The derived excited state a-axis dipole moments are 0.820 ± 0.007 D for the 4¹ level of the ¹A₂ state; 0.838 ± 0.008 D for the zeroth vibrational level of ¹A₂; and 0.534 ± 0.015 D for the zeroth vibrational level of the ³A₂ state. These results are compared with the corresponding values of H₂CO, and interpreted in terms of the changing localization of the π and $\text{π}{}^1$ orbitals accompanying electronic excitation.     

Ab initio study of the photodissociation of ammonia

An ab initio SCF and CI treatment of the electronic spectrum of ammonia in both the pyramidal and planar conformation is reported which employs an [8, 6, $\text{1}\text{4}$, 1] AO basis of near Hartree-Fock quality; the ground state CI energy obtained for the equilibrium conformation is ?56.4241 a.u. In addition, further calculations have been carried out at the SCF level to study various photodissociation reactions of NH₃. The calculated CI transition energies are seen to agree with corresponding experimental values to within 0.0–0.3 eV, usually in the 0.1-eV range. Photodissociation to the $\text{NH}{}_2\text{(}{}^2\text{B}\text{?}{}_1\text{) +}\text{H}\text{(}{}^2\text{S)}$ products is confirmed thereby to proceed via the $\text{A}\text{?}\text{1a″}{}_2\text{→ 3s}$ state of ammonia, but contrary to earlier speculation it is found that the transformation between reactant and products is already satisfactorily described at the SCF or orbital level, i.e., a Rydberg 3s of NH₃ is seen to be gradually converted into a pure hydrogenic 1s species as dissociation proceeds. In addition the photolysis of NH₃ to NH₂$\text{(}{}^2\text{A}{}_1\text{) +}\text{H}\text{(}{}^2\text{S)}$ is argued to occur via the $\text{C}\text{?}\text{1a″}{}_2\text{→ 3pz}{}^1\text{A′}{}_1$ state and as such is seen to be a symmetry allowed process, in contrast to the previous assignment involving the $\text{B}\text{?}\text{1a″}{}_2\text{→ 3px}$, $\text{y}{}^1\text{E″}$ species. Finally an attempt is made to analyze the mechanisms of various NH + H₂ photodissociation processes with the help of SCF calculations and symmetry arguments for various higher-lying excited states of ammonia.     

Spin assignments in 63Ni through 62Ni(d,p)63Ni

Angular distributions of vector analyzing power have been measured for the reaction ${}^{62}\text{Ni}\text{(}\text{d, p}\text{)}{}^{63}\text{Ni}$ at a beam energy of 10 MeV. The observed j-dependence of vector analyzing power allows unambiguous spin assignments to be made for the following states in ⁶³Ni (excitation energies in MeV): $\text{0,}\text{1}\text{2}{}^{\mathrm{?}}$; $\text{0.087,}\text{5}\text{2}{}^{\mathrm{?}}$; $\text{0.155,}\text{3}\text{2}{}^{\mathrm{?}}$; $\text{0.515,}\text{3}\text{2}{}^{\mathrm{?}}$; $\text{1.003,}\text{1}\text{2}{}^{\mathrm{?}}$; $\text{2.297,}\text{5}\text{2}{}^{\mathrm{+}}$; $\text{2.700,}\text{1}\text{2}{}^{\mathrm{?}}$; $\text{2.953,}\text{1}\text{2}{}^{\mathrm{+}}$; $\text{3.292,}\text{5}\text{2}{}^{\mathrm{+}}$; $\text{3.932,}\text{5}\text{2}{}^{\mathrm{+}}$; $\text{3.951,}\text{5}\text{2}{}^{\mathrm{+}}$; $\text{4.387,}\text{5}\text{2}{}^{\mathrm{+}}$. An assignment of $\text{9}\text{2}{}^{\mathrm{+}}$ is suggested for the state at 2.519 MeV. The data for the unresolved l_n = 4, 1 doublet (1.294, 1.327) MeV indicate the $\text{3}\text{2}{}^{\mathrm{?}}$ spin assignment for the 1.327 MeV state. The main features for all the data are in agreement with DWBA calculations.     

High spin states in 57Co

High spin states of ⁵⁷Co have been studied via prompt γ-ray spectroscopy in the reactions ⁴⁸Ti(¹²C, p2n) and ⁵⁴Fe(α, p) at 26–48 MeV and 12–24 MeV, respectively. The energies and decay modes of these levels were determined from the analysis of γ-ray singles and γ-γ coincidence spectra, excitation functions, angular distributions and correlations. The relevant lifetimes were measured by the Doppler-shift attenuation method. The new levels established in this work are at 4037, 4814 and 5918 keV with the most probable J^π assignment of $\text{15}\text{2}{}^{\mathrm{?}}$, if $\text{17}\text{2}{}^{\mathrm{?}}$ and $\text{19}\text{2}{}^{\mathrm{?}}$, respectively. The previously known level at 2524 keV was assigned to have $\text{J}{}^{\mathrm{\pi }}\text{=}\text{13}\text{2}{}^{\mathrm{?}}$. These together with the known $\text{9}\text{2}{}^{\mathrm{?}}$(1224 keV) and $\text{11}\text{2}{}^{\mathrm{?}}$(1690 keV) levels constitute the yrast states of ⁵⁷Co. The measured lifetimes of the above six levels are (in order of increasing energies) 0.085±0.030, 0.32±0.10, 0.16±0.06, 0.10_?0.07^+0.06, 1.5_?0.5⁴ and 0.17_?0.07^+0.08 ps, respectively. Comparisons with some theoretical calculations are presented.     

The ground state of methane 12CH4 through the forbidden lines of the ν3 band

High resolution spectra of the ν₃ band of methane, ¹²CH₄, were recorded by using a “third generation vacuum Fourier interferometer”; a large pressure range (from 0.009 to 10 Torr) with a sample path fixed at eight meters was used, enabling observation of transitions with intensity ratios as low as $\text{1}\text{10 000}$. More than 350 forbidden transitions of the ν₃ band, including about 125 transitions of the Q⁺ branch, were unambiguously identified. Of the 277 transitions retained for computations, one-hundred have 11 ≤ J ≤ 16. From combination difference relations using pairs of transitions having the same upper state energy level (forbidden-allowed and forbidden-forbidden pairs were used), 276 independent differences between ground state energy levels could be determined with uncertainties of about 0.001 cm^?1.These data yielded the following values for the ground state structure constants of ¹²CH₄ along with their standard deviations (in cm^?1): $\text{β}{}^{\mathrm{o}}\text{hc}\text{=5.2410356±0.0000096}$, $\text{γ}{}^{\mathrm{o}}\text{hc}\text{=(?1±0.00074) 10}{}^{\mathrm{?4}}$, $\text{π}{}^{\mathrm{o}}\text{hc}\text{=(5.78±0.18) 10}{}^{\mathrm{?9}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(?1.4485±0.0023) 10}{}^{\mathrm{?6}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(1.768±0.126) 10}{}^{\mathrm{?10}}$, $\text{ξ}{}^{\mathrm{o}}\text{hc}\text{=(?1.602±0.067) 10}{}^{\mathrm{?11}}$, Thus, for the first time, the scalar constant π⁰ has been evaluated and ir values have been obtained for the two tetrahedral constants ?⁰ and ξ⁰; furthermore, these values are in very good agreement with the ones recently determined from radiofrequency data, i.e., in cm^?1: $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(?1.45061±0.00014) 10}{}^{\mathrm{?6}}$, $\text{?}{}^{\mathrm{o}}\text{hc}\text{=(1.7634±0.0068) 10}{}^{\mathrm{?10}}$, $\text{ξ}{}^{\mathrm{o}}\text{hc}\text{=(?1.5432±0.0040) 10}{}^{\mathrm{?11}}$ From these values, the 276 differences can be reproduced with an overall rms deviation equal to 0.0009 cm^?1.Finally, the ground state energies of ¹²CH₄ have been calculated for J ≤ 16.