Gossamer superconductivity near antiferromagnetic Mott insulator in layered organic conductors

Layered organic superconductors are on the verge of the Mott insulator. We use the Gutzwiller variational method to study a two-dimensional Hubbard model including a spin exchange coupling term as a minimal model for the compounds. The ground state is found to be a Gossamer superconductor at small on-site Coulomb repulsion U and an antiferromagnetic Mott insulator at large U, separated by a first order phase transition. Our theory is qualitatively consistent with major experiments reported in organic superconductors.     

On Gossamer metals and insulating behaviour

We extend the Gossamer technique recently proposed to describe superconducting ground states to metallic ground states. The Gossamer metal in a single band model will describe a metallic phase that becomes arbitrarily hard to differentiate from an insulator as one turns the Coulomb correlations up. We were motivated by the phase diagram of V₂O₃ and f-electron systems which have phase diagrams in which a line of first-order metal–insulator transition ends at a critical point above which the two phases are indistinguishable. This means that one can go continuously from the metal to the ‘insulator’, suggesting that they might be the same phase.     

Gossamer superconductor,Mott insulator,and resonating valence bond state in correlated electron systems

Gutzwiller variational method is applied to an effective two-dimensional Hubbard model to examine the recently proposed gossamer superconductor by Laughlin (LANL cond-mat/0209269). The ground state at half filled electron density is a gossamer superconductor for smaller intrasite Coulomb repulsion U and a Mott insulator for larger U. The gossamer superconducting state is similar to the resonating valence bond superconducting state, except that the chemical potential is approximately pinned at the mid of the two Hubbard bands away from the half filled.     

Exact bond ordered ground state for the transition between the band and the Mott insulator

We derive an effective Hamiltonian H(eff) for an ionic Hubbard chain, valid for tt) and the Mott insulator (MI) (U-Delta>t). Using spin-particle transformations [Phys. Rev. Lett. 86, 1082 (2001)]], we map H(eff)(U=Delta) into an SU(3) antiferromagnetic Heisenberg model whose exact ground state is known. In this way, we show rigorously that a spontaneously dimerized insulating ferroelectric phase appears in the transition region between the BI and the MI.     

Strongly correlated superconductivity and pseudogap phase near a multiband Mott insulator

Near a Mott transition, strong electron correlations may enhance Cooper pairing. This is demonstrated in the dynamical mean field theory solution of a twofold-orbital degenerate Hubbard model with an inverted on-site Hund rule exchange, favoring local spin-singlet configurations. Close to the Mott insulator (which here is a local version of a valence bond insulator) a pseudogap non-Fermi-liquid metal, a superconductor, and a normal metal appear, in striking similarity with the physics of cuprates. The strongly correlated s-wave superconducting state has a larger Drude weight than the corresponding normal state. The role of the impurity Kondo problem is underscored.     

Energy gaps and half-metallicity in β-graphyne nanoribbons

We investigate the energy gaps and half-metallicity of the zigzag-edged β-graphyne nanoribbons via a tight-binding approach. In the presence of on-site Coulomb repulsion and proper transverse electric field strengths, the nanoribbons are forced into a half-metallic state by the electric field. A phase transition from half-metal to insulator is realized by changing the electric field or Coulomb potential. Both the electric field and Coulomb repulsion can open direct band gaps, resulting in a metal-insulator phase transition. The band gaps oscillate with the electric field, contrary to linear change with the Coulomb potential.     

Quasiperiodic hubbard chains

Low-energy properties of half-filled Fibonacci Hubbard models are studied by weak-coupling renormalization group and density matrix renormalization group methods. In the case of diagonal modulation, weak Coulomb repulsion is irrelevant and the system behaves as a free Fibonacci chain, while for strong Coulomb repulsion the charge sector becomes a Mott insulator and the spin sector behaves as a uniform Heisenberg antiferromagnetic chain. The off-diagonal modulation always drives the charge sector to a Mott insulator and the spin sector to a Fibonacci antiferromagnetic Heisenberg chain.     

The competition and coexistence of antiferromagnetism and <Emphasis Type="Italic">d</Emphasis>-wave superconductivity: probing coupled thermal fluctuations in a two dimensional minimal model

We consider the coexistence of antiferromagnetism and d-wave superconductivity, motivated by what one observes in the quasi-two dimensional organic salts. We study an electronic model that approximates some features of the Hubbard model, e.g., a repulsion that promotes local moments and Neel order, and an attractive intersite density–density coupling that promotes d-wave superconductivity. Staying at half-filling and a fixed attractive interaction we probe the effect of varying repulsion, using mean field theory for the ground state but retaining the full O(3) × U(1) spectrum of classical fluctuations at finite temperature. The ground state is superconducting at weak repulsion, a Neel ordered insulator at large repulsion, and a coexistence of the two orders in the intermediate regime. We observe four distinct kinds of thermal behaviour depending on the strength of repulsion. Starting with weak repulsion these are, first, a d-wave superconductor renormalised by magnetic fluctuations, second, a d-wave state transiting to an antiferromagnetic insulator and then to the normal state, third, a coexistent state transiting to the antiferromagnetic insulator and then the normal state, and, fourth, a Neel ordered insulator with weak pairing fluctuations. The low temperature state is either “nodal” or gapped, due to long range order, and the low energy spectral weight generally increases monotonically with temperature. At intermediate repulsion, however, the transition from the d-wave state to Neel antiferromagnet causes a loss of low energy weight which is gradually regained only at high temperature.     

Disorder driven superconductor-insulator transition in inhomogenous d-wave superconductor

We study the effect of disorder on the superconductor-insulator transition in an inhomogeneous d-wave superconductor using the kernel polynomial method. As the Bogoliubov-de Gennes equations of the two-dimensional square lattice are solved self-consistently for the cases with more than 100000 unit cells, it is possible to observe the spatial fluctuations of the superconducting order parameters at the nanoscale. We find that strong spatial fluctuation of the superconducting order parameters can be introduced by disorder, and some superconducting specific order parameters are even enhanced. Moreover, we find that some isolated superconducting "islands" can survive the strong disorder, giving a boson insulator with some localized Cooper pairs. Our numerical calculations predict the existence of two sequential transitions with the increasing disorder strength: a d-wave to s-wave superconductor transition, and then an s-wave superconductor to insulator transition. The possibility of the appearance of a metallic phase between the superconducting and insulating phases is excluded by performing the lattice-size scaling of the generalized inverse participation ratio. In addition, we also discuss the effect of disorder on the optical conductivity of the d-wave superconductors.     

Strong interaction of correlated electrons with phonons: Exchange of phonon clouds by polarons

The interaction of strongly correlated electrons with phonons in the framework of the Hubbard-Holstein model is investigated. The electron-phonon interaction is considered to be strong and is an important parameter of the model, in addition to the Coulomb repulsion of electrons and the band filling. This interaction with nondispersive optical phonons is transformed to the problem of mobile polarons using the canonical transformation of Lang and Firsov. We discuss the case where the on-site Coulomb repulsion is exactly canceled by the phonon-mediated attractive interaction. It is suggested that polarons exchanging phonon clouds can lead to polaron pairing and superconductivity. The fact that the frequency of the collective mode of phonon clouds is larger than the bare frequency then determines the superconducting transition temperature.     

Vortex charges in high-temperature superconductors

Based on a model Hamiltonian with competing antiferromagnetic (AF) and d-wave superconductivity interactions, the vortex charge is investigated by solving the Bogoliubov-de Gennes equations. We found that the vortex charge is negative when a sufficient strength of AF order is induced inside the vortex core; otherwise, it is positive. By tuning the on-site Coulomb repulsion U or the doping parameter delta, a transition between the positive and negative vortex charges may occur. The vortex charge at optimal doping has also been studied as a function of magnetic field. Recent NMR and Hall effect experiments may be understood in terms of the present results.     

Ferromagnetism induced by orbital order in the charge-transfer insulator Cs2AgF4: an electronic structure study

Cs2AgF4 was proposed to be an orbitally ordered ferromagnet based on recent neutron scattering data. Here, we report a detailed electronic structure study within the local spin density approximation also including strong Coulomb repulsion U. We investigate the influence of an orthorhombic distortion of the Ag environment and the importance of the on-site Coulomb repulsion. We find good quantitative agreement with both the experimentally observed exchange coupling and structural changes. Thus, our results strongly support that Cs2AgF4 is a strongly correlated charge-transfer insulator where the ferromagnetism is driven by orbital order.     

Quantum phase transition and Coulomb blockade with one-dimensional SQUID arrays

We report on experiments with one-dimensional (1D) arrays of small-capacitance superconducting quantum interference devices (SQUIDs), where an external magnetic field can be used to tune in situ the Josephson coupling between neighboring superconducting electrodes. We have studied the superconductor–insulator transition in such arrays, and have also used these arrays to bias a single Josephson junction. In the later experiment, we have observed a clear Coulomb blockade of Cooper-pair tunnelling (CBCPT) in the single junction.     

Microscopic study of a spin-orbit-induced Mott insulator in Ir oxides

Motivated by recent experiments of a novel 5d Mott insulator in Sr2IrO4, we have studied the two-dimensional three-orbital Hubbard model with a spin-orbit coupling λ. The variational Monte Carlo method is used to obtain the ground state phase diagram with varying an on-site Coulomb interaction U as well as λ. It is found that the transition from a paramagnetic metal to an antiferromagnetic insulator occurs at a finite U=U(MI), which is greatly reduced by a large λ, characteristic of 5d electrons, and leads to the "spin-orbit-induced" Mott insulator. It is also found that the Hund's coupling induces the anisotropic spin exchange and stabilizes the in-plane antiferromagnetic order. We have further studied the one-particle excitations by using the variational cluster approximation and revealed the internal electronic structure of this novel Mott insulator. These findings are in agreement with experimental observations on Sr2IrO4.     

Effects of oxygen-vacancies in high-temperature cuprate superconductors

We investigate the effects of oxygen vacancies on the magnetic properties and superconducting transition temperature of high-temperature cuprate superconductors. Starting with the d-p Hamiltonian, we simultaneously employ the coherent potential approximation to account for the effects of oxygen vacancies, and the fluctuation-exchange scheme to address the copper-site Coulomb interactions. Our results show that the presence of oxygen vacancies weakens the antiferromagnetic spin fluctuations of d-electrons subsequently lowering the superconducting transition temperature.     

Disorder-induced static antiferromagnetism in cuprate superconductors

Using model calculations of a disordered d-wave superconductor with on-site Hubbard repulsion, we show how dopant disorder can stabilize novel states with antiferromagnetic order. We find that the critical strength of correlations or impurity potential necessary to create an ordered magnetic state in the presence of finite disorder is reduced compared to that required to create a single isolated magnetic droplet. This may explain why, in cuprates such as La2-xSrxCuO4, low-energy probes have identified a static magnetic component which persists well into the superconducting state, whereas, in cleaner systems such as YBa(2)Cu(3)O(6+delta), it is absent or minimal.     

Can correlations drive a band insulator metallic?

We analyze the effects of the on-site Coulomb repulsion U on a band insulator using dynamical mean field theory (DMFT). We find the surprising result that the gap is suppressed to zero at a critical Uc1 and remains zero within a metallic phase. At a larger Uc2 there is a second transition from the metal to a Mott insulator, in which the gap increases with increasing U. These results are qualitatively different from Hartree-Fock theory which gives a monotonically decreasing but nonzero insulating gap for all finite U.     

Interrelation of superconducting and antiferromagnetic gaps in high- T(c) compounds: A test case for the SO(5) theory

Recent angle resolved photoemission data, which found evidence for a d-wave-like modulation of the antiferromagnetic gap, suggest an intimate interrelation between the antiferromagnetic insulator and the superconductor with its d-wave gap. It is shown here that a projected SO(5) theory, which explicitly takes the Mott-Hubbard gap into account, correctly describes the observed gap characteristics. Specifically, it accounts for the order of magnitude difference between the antiferromagnetic gap modulation and the superconducting gap and is also consistent with the gap dispersion.     

Spin-wave renormalization by mobile holes in a two-dimensional quantum antiferromagnet

The coupling of antiferromagnetic spin excitations and propagating holes has been studied theoretically on a square lattice in order to investigate the dependence of antiferromagnetic order on hole doping, being of relevance, e.g., for the Cu–3 d⁹ system in antiferromagnetic CuO₂-planes of high-T_c superconductors. An effective Hamiltonian has been used, which results from a 2D Hubbard model (hopping integral t) with holes and with strong on-site Coulomb repulsion U. Bare antiferromagnetic excitations and holes with energies of the same order of magnitude t²/U are interacting via a coupling term being proportional to t and allowing holes to hop by emitting and absorbing spinwaves. In terms of a self-consistent one-loop approximation the renormalization of the spectral function both of holes and antiferromagnetic spin excitations are calculated.     

Antiferromagnetism and superconductivity in a model with extended pairing interactions

The competition between antiferromagnetism and the d + id superconducting state is studied in a model with near and next near neighbour interactions in the absence of any on-site repulsion. A mean field study shows that it is possible to have simultaneous occurrence of an antiferromagnetic and a singlet d + id superconducting state in this model. In addition, such a coexistence generates a triplet d + id superconducting order parameter with centre of mass momentum Q = (π,π) dynamically having the same orbital symmetry as the singlet superconductor. Inclusion of next nearest neighbour hopping in the band stabilises the d_xy superconducting state away from half filling, the topology of the phase diagram, though, remains similar to the near neighbour model. In view of the very recent observation of a broad region of coexistence of antiferromagnetic and unconventional superconducting states in organic superconductors, the possibility of observation of the triplet state has been outlined. Received 30 November 2000 and Received in final form 27 March 2001