Stripe domain statics in garnet films

Magnetic garnet films grown epitaxially on nonmagnetic garnet substrates exhibit a growth or stress-induced uniaxial anisotropy in addition to the cubic magnetocrystalline anisotropy associated with their crystal symmetry. When the uniaxial anisotropy is dominant over the cubic, such films exhibit stripe or bubble domain structures; even a small cubic anisotropy component can have a decisive effect on the behavior of the domains in applied fields. We report an experimental study of the quadistatic behavior of domains in fields applied to a (111) film in the film plane along (11$\text{2}$) and ($\text{1}$10). The experimental results are interpreted by a new theory that gives good agreement with the observed behavior, and yields an accurate measurement of the cubic and uniaxial anisotropy constants.The main qualitative features of the results are: In a ($\text{1}$10) field, the walls are Neél walls perpendicular to the field. In a (11$\text{2}$) field the walls are Bloch walls parallel to the field, the domain magnetization in adjacent stripes is not symmetrical about the film plane, and adjacent stripes are not of equal width; the domain period first shrinks and then expands with increasing field; and even though the applied field has no component perpendicular to the film plane, the film develops a net perpendicular magnetic moment.     

Courants critiques d'alliages supraconducteurs de concentration modulee spatialement I — Effet de la periode

We discuss the effect of the period of the sinusoidal variations of concentration of superconducting $\text{Pb}$Bi films, on the critical current densities J_c as a function of an applied magnetic field H, perpendicular to J and parallel to the film plane. The existence of peaks on the J_c(H) curves suggests a matching effect between the vortex lattice and the modulation of concentration.     

Optical absorption spectrum of hematite, αFe2O3 near IR to UV

Optical absorption spectra have been measured on thin (011) single crystal platelets and on highly oriented (110) thin films of αFe₂O₃. We have observed and assigned some of the absorption bands predicted by ligand field theory and SCF-Xα calculations. The temperature dependence of the 11760 cm^?1 single crystal band has been fitted to the function $\text{? = ?}{}_0\text{(1 + exp (?}\text{θ}\text{T}\text{))}$ with $\text{?}{}_0\text{= 0.85 × 10}{}^{\mathrm{?4}}$ and θ = 200 K (139 cm^?1). We have measured the photocurrent as a function of wavelength and have found several peaks that coincide with optical absorption bands.     

Molecular structure and centrifugal distortion constants of isocyanic acid from the microwave,millimeter wave,and far-infrared spectra

The pure rotational spectra of HNCO and DNCO were measured in the far-infrared region from 80 to 350 cm^?1 by a Fourier transform spectrometer with a resolution of 0.1 cm^?1. The ^rR_K branches were measured and assigned for HNCO from K = 1 to 6, and for DNCO from K = 3 to 8. The measured transition wavenumbers were analyzed together with the microwave and millimeter wave data reported by Hocking, Gerry, and Winnewisser [Can. J. Phys.53, 1869–1901 (1975)] and with the far-infrared data of Krakow, Lord, and Neely [J. Mol. Spectrosc.27, 148–176 (1968)] in the low-wavenumber region. The microwave and millimeter wave data of H¹⁵NCO, HN¹³CO, and HNC¹⁸O reported by Hocking et al. were reanalyzed assuming several centrifugal distortion constants to be identical with those of the normal species. The molecular structure of HNCO was reevaluated using a modified substitution method from the rotational constants obtained in this work. The molecule has a bent structure in a trans configuration with $\text{r}\text{(NH) = 0.995}\text{A}\text{?}$, $\text{r}\text{(NC) = 1.314}\text{A}\text{?}$, $\text{r}\text{(CO) = 1.668}\text{A}\text{?}$, ∠HNC = 123.9°, and ∠NCO = 172.6°.     

Rotational analysis of the 9613 Å band of CH3D

The 9613 Å band of CH₃D has been photographed under high resolution using a path length of 640 m and a pressure of 593 Torr. The band is parallel in type and a rotational analysis has been carried out. The principal molecular constants for the upper state are:

$\text{T}{}_0\text{= 10404.770 (15)}\text{cm}{}^{\mathrm{?1}}\text{,}\text{B}\text{= 3.68941 (48)}\text{cm}{}^{\mathrm{?1}}$

. A few small (<0.2 cm^?1) rotational perturbations have been found in the excited state levels with K′ = 0 to 4. No transitions have yet been identified to levels with K′ > 4.The possibility of using the 9613 Å band as a means of measuring the $\text{D}\text{H}$ ratio in planetary atmospheres is discussed.     

The surface structure factor of evaporated Cu films

The surface structure factor of a deposited film is calculated. The calculation takes into account the competing mechanisms of roughening by the random nature of the deposition and flattening by surface diffusion. The surface structure factor has been measured by diffuse optical scattering for Cu films deposited by thermal evaporation in UHV. The shape of the surface roughness momentum distribution of the unannealed films is determined by both the film and the nature of the substrate. The film roughness spectrum dominates for $\text{k > 4 × 10}{}^{\mathrm{?4}}\text{A}\text{?}{}^{\mathrm{?1}}$ and is relatively constant. Comparison of the measured and calculated magnitude of the surface structure factor shows that the minimum correlation length is of the order of magnitude of the grain size. The surface roughness amplitude increases upon annealing due to grain boundary grooving and hillock formation.     

Search for radiation damage in heavy ion implanted thin layer single crystal SnS22

Single crystal platelets of stannic sulfide (SnS₂, trigonal) mounted with the easy cleavage plane normal to the incident ion beam, were implanted at 100 K with 150 and 350 KeV O⁺ ions to a total dose of $\text{\$}\text{?}$2.5 × 10¹⁷ cm^?2, and subsequently examined by ¹¹⁹Sn Mossbauer spectroscopy in transmission geometry. Despite the expectation that a hot zone of $\text{\$}\text{?}$300 Å radius is created near the end of the ion track, no evidence for the thermal decomposition of SnS₂ to SnS + S is observed for thermally well clamped samples. Data for the lattice temperature of oxygen implanted SnS₂ are compared to that for unirradiated single crystal and randomly oriented powder samples.     

Rotational analysis and radiative lifetime measurement on the 2B1 (K′ = 0) excited state of NO2 with v′2 = 6, 7, 8, and 9

The rotational structure of the ²B₁ (K′ = 0) subbands of NO₂ with v′₂ = 6, 7, 8, and 9 were analyzed by means of the time-gated excitation spectrum. The excitation spectrum monitored at ν₂, 2ν₂, or 3ν₂ fluorescence band was fairly simplified in comparison to its corresponding absorption spectrum. The band origins and rotational constants are evaluated from the observed data: ν₀ = 20205.0 cm^?1, $\text{B}\text{′ = 0.374}\text{cm}{}^{\mathrm{?1}}$ for v′₂ = 6; ν₀ = 21104.4 cm^?1, $\text{B}\text{′ = 0.374}\text{cm}{}^{\mathrm{?1}}$ for v′₂ = 7; ν₀ = 22001.9 cm^?1, $\text{B}\text{′ = 0.375}\text{cm}{}^{\mathrm{?1}}$ for v′₂ = 8ν₀ = 22898.0 cm^?1, $\text{B}\text{′ = 0.375}\text{cm}{}^{\mathrm{?1}}$ for v′₂ = 9. The value of $\text{B}\text{′}$ extrapolated to v′ = 0 is 0.370 cm^?1. This value corresponds to the bond length of 1.19 Å. Fluorescence decays of these excited levels were also studied. Radiative lifetimes obtained by extrapolation to zero pressure from the $\text{1}\text{τ}\text{– P}$ plots were 25–40 μsec. The short-lived excited levels previously reported by some authors were not found.     

ac conductivity of anhydrous pellicular zirconium phosphate in hydrogen form

Aqueous suspensions of delaminated zirconium phosphate have been recently obtained in our laboratory by a suitable intercalation-deintercalation of alkylamines. By filtering these suspensions thin and flexible sheets or pellicles of lamellar α-zirconium phosphate, with the most part of the layers oriented parallel to the pellicle surface, can be easily prepared. ac conductivity measurements have been carried out, in the temperature range 150–300°C, on pellets made of α-Zr(HPO₄)₂ pressed pellicles, oriented both parallel and perpendicular to the electric field. Independently of the pellet orientation, a slope variation was observed in the Arrhenius plot at about 220°C. As already found for the α-Zr(HPO₄)₂ powder, this is associated with a phase transition at this temperature, which causes a discontinuous change of the interlayer distance from 7.4 Å to 6.8 Å. The conductivity of samples oriented parallel to the electric field ($\text{～10}{}^{\mathrm{?4}}\text{Ω}{}^{\mathrm{?1}}\text{cm}{}^{\mathrm{?1}}\text{at}\text{300°}\text{C}$) is about two orders higher than the conductivity of the anhydrous microcrystalline powder, which, in turn, is higher than that of perpendicularly oriented samples ($\text{～3 × 10}{}^{\mathrm{?7}}\text{Ω}{}^{\mathrm{?1}}\text{cm}{}^{\mathrm{?1}}\text{at}\text{300°}\text{C}$).     

Critical behaviour of the magnetic susceptibility of two nearly bidimensional Heisenberg ferromagnets

The parallel magnetic susceptibilities of ferromagnetic K₂ Cu F₄ and (CH₃ NH₃)₂ Cu Cl₄ have been measured near the critical temperature. In both ferromagnets, the thermal dependence cannot be described by the simple power law ?^-γ with $\text{? =}\text{T}\text{T}{}_{\mathrm{<mtext>C</mtext>}}\text{? 1}$ over a large range of temperatures. Due to crossover with dimensionality, the γ value increases from 1 for K₂ Cu F₄ and 1.23 for (CH₃ NH₃)₂ Cu Cl₄ in the immediate vicinity of T_c, to a maximum value of about 2.     

Activation energy for electrotransport in thin aluminum films by resistance measurements

The activation energy for electrotransport in thin aluminum films was measured by a resistometric technique involving several individual resistance measurements along the stripe. An equation was derived which relates the rate of resistance change to the ion velocity.A thin film thermocouple which is free of any loss of heat was used to monitor the temperature of the stripe. This thermocouple was calibrated by the melting points of pure metals placed on the film.The activation energy for electrotransport in thin aluminum films was found to be temperature dependent and to vary between 0.45 and 0.72 eV in a temperature range between 220 and 360°C.The average ion velocity in the grain boundaries due to electrotransport was found to be around $\text{10}{}^{\mathrm{?7}}\text{cm}\text{sec}$ in agreement with the literature.     

Electrical transport properties of a quasi-one-dimensional Nb3Te4 single crystal

The electrical resistance of a linear chain metal Nb₃Te₄ were measured from 1.3 to 320 K. The residual resistance ratio $\text{R(300}\text{K}\text{)}\text{R(4.2}\text{K}\text{)}$ is about 3. Nb₃Te₄ shows an anomaly in the resistivity vs temperature at about 80 K, suggesting an occurrence of a charge-density-wave transition. The transverse and longitudinal magnetoresistance at 4.2 K are proportional to the magnetic field in the range of 2–58 kOe. In the superconducting region close to the transition temperature T_c, the critical magnetic field H_c2 is proportional to δT=T_c?T. The angular dependence of H_c2 fits well with the fluxoid model of the Ginzburg-Landau theory. The ratio of the critical fields parallel and perpendicular to the chain direction is 4.8.     

Electromigration in tin single crystals

Atom transport in high-purity tin single crystals due to the influence of large direct currents has been measured by the “vacancy flux” technique. Cylindrical specimens were selected with c-axis oriented with 9° perpendicular or parallel to the direction of current flow. Rates of both longitudinal and transverse dimensional changes were used to calculate the anode-directed atom drift velocity. The results gave $\text{Z}{}^1{}_6\text{?}{}_6\text{= ?18±2}$ and $\text{z}{}^1{}_{\mathrm{\perp }}\text{?}{}_{\mathrm{\perp }}\text{= ?18 ±2}$, where Z¹ is the effective charge number and ?₆ = 0.89 and ?_⊥ = 0.54 are the estimated correlation factors in the parallel and perpendicular directions. These values for Z¹ are appreciably smaller than the results reported earlier for polycrystalline tin by Kuz'memko. The activation energies for $\text{Z}{}^1\text{?}$ agree within experimental error with those of self-diffusion.     

Temperature dependence of the lattice vibrations of triglycine selenate

The polarized Raman spectra below 300 cm^?1 and the far infrared spectra from 400 to 30 cm^?1 of triglycine selenate were measured at various low temperatures. It was found that the Raman doublet at 44 and 38 cm^-1 observed in the paraelectric phase (space group C²_2h) was reduced to a singlet at 38 cm^?1 in the ferroelectric phase (space group C₂²). This spectral anomaly in the paraelectric phase appears to be due to the splitting of the translational mode of glycine I along the crystallographic b axis, the splitting being caused by the tunneling of glycine I across the barrier between the two potential minima which are located symmetrically on either side of the crystallographic ac plane (i.e. at $\text{b =}\text{1}\text{4}$ and $\text{3}\text{4}\text{)}$. New Raman bands which appear below the Curie temperature are also discussed.     

Hole mobility anisotropy and crystal structure of β-9,10 dichloroanthracene

Hole drift mobilities have been measured in β-9,10 dichloroanthracene by the transient photoconductivity method. Mobilities were found to be isotropic in the ac plane, 0.6 cm²/V sec, and 0.18 cm²/V sec normal to this plane, b¹, at room temperature. At lower temperatures the mobilities were thermally activated, with an activation energy of ～0.25eV. The crystal structure of β-9,10 dichloroanthracene has been determined; it is triclinic. $\text{a = 8.582}\text{A}\text{?}$, $\text{b = 16.825}\text{A}\text{?}$, $\text{c = 3.869}\text{A}\text{?}$, $\text{α = 97.90}\text{,}\text{?}\text{β = 97.90°, γ = 75.99°}$. The influence of the crystal structures of the α- and β- forms on the intermolecular electronic overlap and hence carrier mobilities are discussed.     

KLo−KSo regeneration on deuterium

The K_L^o?K_S^o regeneration on deuterium has been measured at the 70 GeV Serpukhov accelerator in a momentum region of $\text{18–}\text{50}\text{GeV}\text{c}$. The measurements were performed by means of a 3 m long liquid deuterium target and an on-line spectrometer. The preliminary results on the energy dependence of the modulus and phase of the transmission regeneration amplitude are reported.     

Measurement of the polarization parameter for antiproton-proton annihilation into charged pion and kaon pairs between 1.0 and 2.2 GeV/c

The polarization parameter P for the reactions $\text{p}\text{p}\text{→ π}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}$ and $\text{p}\text{p}\text{→}\text{K}{}^{\mathrm{?}}\text{K}{}^{\mathrm{+}}$ has been measured over essentially the full angular range at ll laboratory momenta between 1.0 and 2.2. GeV/c, using a proton target polarized perpendicular to the scattering plane. The angles and momenta of both final state particles were determined from wire spark chambers, using the deflection caused by the polarized target magnet. Between 1000 and 5300 π^?π⁺ events, and 140 and 1300 K^?K⁺ events, were measured at each momentum. Differential cross sections for $\text{p}\text{p}\text{→ π}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}$ were obtained. These are in excellent agreement with previous results. The polarization parameter for both channels is very close to +1 over much of the angular range. Legendre polynomial fits to the data are presented.     

Formation of tetrahedrally close-packed structures in Tb-Fe and Co-Pd nanocrystalline films

The crystal structure of Tb₃₀Fe₇₀ and Co₅₀Pd₅₀ nanocrystalline films with strong magnetic anisotropy perpendicular to the film plane (K _⊥ ～ 10⁶ erg/cm₃) is investigated using electron diffraction and transmission electron microscopy. All the studied films in the initial nanocrystalline phase undergo an explosive crystallization with the formation of dendrite structures. It is demonstrated that, after crystallization, the Tb-Fe and Co-Pd films exhibit a tetrahedrally close-packed atomic structure that has no analogs among these materials in the equilibrium state. The internal stresses in the films under investigation are estimated from an analysis of the bend extinction contours in the electron microscope images. The inference is made that strong perpendicular magnetic anisotropy can be associated with magnetostriction anisotropy due to the specific features of the film structure.     

High resolution Raman spectroscopy of gases with laser sources. The rotational spectrum of cyanuric fluoride-C3N3F3

The pure rotational Raman spectrum of cyanuric fluoride vapor was photographed using a high resolution plane grating spectrograph. The spectrum was excited with the $\text{λ = 4880}\text{A}\text{?}$ radiation emitted by a single-mode argon-ion laser. Two sets of molecular constants were determined from the R and S branches. The preferred results are those determined from the S-branch data. These are: B₀ = 0.0655954 ± 14 × 10^?7 cm^?1, D_J = (2.52 ± 0.17) × 10^?9 cm^?1 and H_J = (?1.59 ± 0.59) × 10^?14 cm^?1, where the uncertainties are one standard deviation. Possible effects of line shifts due to unresolved K structure and the presence of hot bands on the accuracy of the values of the molecular constants are discussed. The B₀ value is compared to the rotation constant computed with the structural parameters determined with the electron diffraction technique; the agreement between these two rotation constants is only fair.     

Infrared study of superlattice formation in Ti1+xSe2

Infrared reflectivity measurements have been made on two Ti_1+xSe₂ crystals of different stoichiometry over the range 200 cm^?1 to 4000 cm^?1 before and after the formation of a 2a_o × 2c_o superlattice. In both crystals at room temperature a heavily damped Drude edge is observed at about 1000 cm^?1. At liquid helium temperatures, below the phase transition, the Drude minimum of a non-stoichiometric crystal ($\text{x ? 0.02, T}{}_{\mathrm{c}}\text{= 155 K}$) is at 750 cm^?1 whereas the low temperature minimum of a more stoichiometric sample (T_c = 198 K) is below 350 cm^?1. Also, new absorption peaks are seen to develop below T_c at about 3700 cm^?1 and 3300 cm^?1 for the non- stoichiometric and stoichiometric-crystals respectively. The observed phenomena are related to the energy gaps which open up in the band structure below the phase transition temperature.