Luminescent Method of Measuring the EXAFS Spectra of Structural Defects of Alkali‐Halide Crystals

It is shown that xray spectral methods — those of EXAFS and XEOL spectroscopy — allow determination both of the structure of inherent or impurity centers of luminescence in alkalihalide crystals and investigation of the dynamics of their change under the action of ionizing radiation. The methods are noted for high sensitivity. The possibilities of the methods are demonstrated for KBr, NaCl:Ni, and NaCl:Ni,Cu crystals taken as an example. New data on the structures of different luminescence centers investigated and dynamics of their change are obtained.     

The effect of low-temperature electron irradiation on the transition temperature of YBa2Cu3O7−δ superconductors

Measurements of the complex susceptibility =–i of electron-irradiated YBa₂Cu₃O_7– show a strong influence of the electron irradiation dose, ·t on the transition temperatureT _c . For irradiation doses of ·t=2.2·10¹⁹ e^–/cm² we find a damage rate of T _c /(·t)=–1.6·10^–19 K/(e^–/cm²). It is assumed that the decrease ofT _c is mainly a bulk effect due to the production of atomic defects like vacancies and interstitials in the Cu–O–Cu chains and in the basal planes of the unit cells.     

Role of Activator and Vacancy Centers in the Decay of the Gamma Scintillators of CsI–Na Crystals

The influence of the concentration of an activator (C _NaI) and of plastic deformation on a change in the contribution of a slow component to the decay of the -scintillations of CsI–Na crystals was investigated, as well as the influence of C _NaI on a change in the shape of the luminescence excitation spectrum in the region of absorption of activator centers (AC) and of vacancy-related centers (VRC) and also on a change in the intercenter time of deexcitation of the centers indicated. It is shown that AC and VRC participate in the photoluminescence and -scintillations of CsI–Na crystals. In the -scintillations, AC are responsible for the component ₁ = 370 nsec, whereas the components ₁ = 460 nsec and ₂ 2 sec are associated with VRC. The reduction of ₁ from 770 to 560 nsec with an increase in C _NaI from 2·10^–3 to 3·10^–2 mole% and from 570 to 470 nsec after plastic deformation of the crystals ( = 5%) along the 111 axis is caused by a decrease in the number of VRC. The mechanisms underlying the -scintillations of the CaI–Na crystals containing AC and VRC and also the decrease in the number of VRC are discussed.     

Absorption Spectra of Excited Ruby Crystals

We have investigated the absorption spectra of excited laser single crystals of ruby. The longlived increase in absorption depending on the degree of excitation is observed in optically excited crystals of ruby in a wide spectral range. Moreover, in the absorption spectrum of a postexcited ruby we discovered the excitationinduced longlived kinetic instability, namely, the noiselike quasiline component variable in time and over the spectrum and imposed on the smooth spectral curve.     

Emission of light during interaction between hydrogen ions and single crystals

Emission of light within the blue range of the spectrum (_max=480–510 nm) has been found to occur when pure KCl and NaCl single crystals are bombarded by hydrogen ions with 30-keV energy. It is suggested that water molecules adsorbed at the surface constitute the emission centers.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 81–84, March, 1975.     

Mössbauer Spectroscopy on Nuclear Power Plant Materials

Experimental results of original irradiated reactor pressure vessel surveillance specimens are presented and discussed in the paper. In 1994, the new Extended Surveillance Specimen Program for Nuclear Reactor Material Study was started in collaboration with the nuclear power plant (NPP) Bohunice and NPP Research Institute Trnava (Slovakia). Three batches of special prepared Mössbauer samples (after 1, 2 and 3 years stay in irradiation channels) were measured and interpreted using the new four components approach of Mössbauer spectra evaluation with the aim to observe microstructural changes due to thermal and neutron treatment resulting from operating conditions in NPP. The systematic changes in the relative areas of Mössbauer spectra components were observed and discussed.     

EPR and Thermoluminescence in ZnO Single Crystals with Anionic Vacancies

The radiation defects created in hydrothermal ZnO–Li single crystals by irradiating them with electrons, protons, and highenergy ions have been investigated. The anionic vacancies (Fcenters) in ZnO are established to be the centers of radiationless recombination of the charge carriers with a photoionization energy of 2.3 eV (a signal of the photoEPR with the gfactor for the F⁺center: g = 1.9948 and g = 1.9963). The anionic vacancies in the form of the F and F⁺ states are a good reference of the electron and hole processes. The [F_Li]^×centers that correspond to the oxygen vacancies localized near the point defects Li_Zn are detected. In the temperature range 530–660 K, ZnO crystals display thermally stimulated processes such as the healing of anionic vacancies (530–630 K) and the disappearance of the [F_Li]^×centers (610–660 K).     

Effect of the binder on the brightness of the electroluminescence emission of ZnS powder phosphors

The electroluminescence of a ZnS phosphor based on several binders was examined. It was shown that electroluminescent layers based on several binders have an additional (super) brightness relative to the brightness corresponding to a field strength computed with the theory of heterogeneous systems. The hypothesis is outlined that the super-brightness results from a charge accumulation on the surface of the crystal phosphor during the excitation of the same.     

Photoconductivity and photoluminescence in BiOCl crystals

Combined studies of the steady-state characteristics and kinetics of photocurrent and photoluminescence in BiOCl single crystals have shown that the conductance processes are caused mainly by the presence of sensitizing recombination r centers which are also luminescence centers. The 2.2 eV luminescence band is caused by the trapping of the free conduction-band electrons by the recombination r centers.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 65–68, May, 1973.     

The effect of microsegregation on the generation of dislocations in zinc single crystals

The applicability of Tiller's considerations on the production of dislocations is proved. The density of dislocations appearing during impurity microsegregation increases with increasing rate of growth as a consequence of the corresponding change in the effective distribution coefficient. The real value of C at the microsegregation boundaries is at least twice as great as the average value of the concentration of impurities in the crystal in question.

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Scaling Cosmology

We show that with the help of a suitable coupling between dark energy and cold dark matter it is possible to reproduce any scaling solution _{X M} a , where _X and _M are the densities of dark energy and dark matter, respectively. We demonstrate how the case = 1 alleviates the coincidence problem. Future observations of supernovae at high redshift as well as quasar pairs which are planned to discriminate between different cosmological models will also provide direct constraints on the coupling between dark matter and dark energy.     

ЭЛЕКТРИЧЕСКАЯ ЭКВИВ АЛЕНТНАЯ СХЕМА ЗАТУХАЮЩИХ КОЛЕБАНИ Й СДВИГА ПЬЕЗОЭЛЕКТРИЧЕСКИХ СТЕРЖНЕЙ

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ПОТОК ЭНЕРГИИ ЧЕРЕЗ Д ИЭЛЕКТРИЧЕСКИЙ ТОНК ИЙ СЛОЙ ПРИ НАРУШЕННОМ ПОЛНО М ОТРАЖЕНИИ

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Energy flux through thin dielectric film when total reflection is disturbed

It is shown that the energy flux through a thin dielectric film when total reflection is disturbed is brought about by the interference Poynting vector.

     

Nature of the luminescence centers in ionic crystals

The main attention is paid to the following questions: 1. The possible models of the luminescence centers in activated alkali halide crystals, 2. the experimental evidence of the presence of various types of the luminescence centers, 3. the nature of the excitations of the simplest luminescence centers in alkali halides activated by mercury-like ions and by some other ions. Mainly two possibilities of views: the quasi-free ions case on the one hand and the quasi-molecular models on the other are discussed in detail.     

Металлографические методы определепия нлотности дислокаци й В монокристаллах германия

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Calculation of Out‐of‐Plane Vibrations of a Porphin Molecule

Using the DFT/B3LYP method with the base set 631G^**, we carried out calculation of the frequencies of the normal vibrations of porphin and of its five isotopic types. Scaling of force constants for outofplane vibrations has been performed in independent natural coordinates. The symmetry coordinates are introduced and a force field for outof plane vibrations of a porphin molecule in independent coordinates of symmetry is obtained. A new correlation of the frequencies of vibrations in the type of the symmetry B _1u for the isotopic type of the d ₂ porphin molecule is suggested on the basis of discrete analysis of the distribution of a potential energy.     

Systematic study of muon transfer to sulphur dioxide

In a systematic study of the transfer process to sulphur dioxide, in seven different H₂ + SO₂ gas mixtures, the time spectra of the muonic sulphur X-rays yield muon transfer rates to the SO₂ molecule, deduced from the lifetimes of the p atoms, which agree all well with each other. The muonic oxygen time spectra show an additional structure as if p atoms of another kind were present. Reduced transfer rates_O are reproducible if one uses the model of ephemeral p atoms. The intensity ratios between the different kinds of p atoms are also discussed in the framework of this model and the one of black and white p atoms.     

Über die an „Schwachen“ Grenzflächen Entstehenden Kopfwellen

Zusammenfassung In der vorliegenden Arbeit werden die Kopfwellen untersucht, die beim Auffallen einer harmonischen Schall-Kugelwelle auf die Ebene Grenzfläche zwischen zwei flüssigen Medien entstehen. Vorausgesetzt wird, daß die Grenzfläche schwach ist, d. h. daß die Geschwindigkeit der Schallwellen im Medium mit der Erregungsquelle nur um weniges kleiner ist als die Geschwindigkeit der Schallwellen im Medium ohne die Quelle.

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Impurity Luminescence of Alexandrite Crystals

The luminescence of alexandrite excited by a highcurrent electron beam is investigated. Its spectrum has bands of the impurity ions Cr³⁺ and of the Cr–Cr pairs and also the band at = 492–495 nm. In all of the crystals we have detected chromium ions distributed over two nonequivalent positions, differently in different crystals. It is shown that the color of the crystals and its change on illumination of the crystals with the light of different spectral composition depend mainly on the chromium ions and their distribution over crystalline positions. A noticeable effect of other impurity ions is noted for a number of crystals.     

Основные соотношени я длн построения механических селект оров нейтронов

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