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1.
Abstract

High-TC superconducting oxides of nominal La1.85Ba0.15 CuO4 and YBa2 Cu3 O7 have been prepared by using nitrate, carbonate, oxalate/malonate and citrate precursors. While the samples in the Y-system are generally monophasic YBa2Cu3O7?δ with TC around 90K, the preparations in the La-system are biphasic containing K2NiF4-like La1.85Ba0.15 CuO4 (TC = 30K) and a perovskite-like phase with' a much higher TC (200–300K). Effect of Ca, Zr, Ce as well as S substitution in YBa2Cu3O7?δ has also been investigated  相似文献   

2.
《Physics letters. A》1988,134(3):191-195
We perform eV neutron scattering experiments (neutron energy > 1 eV) on copper metal, CuO, La2CuO4 and YBa2Cu3O7, and neutron absorption experiments of HoBa2Cu3O7, and determined the mean kinetic energy of O, Cu and other atoms in these materials. The Debye temperatures of Cu atoms in La2CuO4 and YBa2Cu3O7 were estimated to be extremely large, about 1500 and 2000 K, respectively.  相似文献   

3.
The change in the 64Cu electron-capture constant for the compounds Cu2O, YBa2Cu3O7, YBa2Cu3O6, Nd2CuO4, Nd1.8Ce0.2CuO4, La2CuO4, La1.7Sr0.3CuO4, Tl2Ba2CaCu2O8, and Bi2Sr2CaCu2O8 has been measured. It is concluded that the copper in YBa2Cu3O7, Nd2CuO4, La2CuO4, La1.7Sr0.3CuO4, Tl2Ba2CaCu2O8, and Bi2Sr2CaCu2O8 is exclusively divalent, whereas in Cu2O, YBa2Cu3O6, and Nd1.8Ce0.2CuO4 univalent copper is present. Fiz. Tverd. Tela (St. Petersburg) 39, 1793–1794 (October 1998)  相似文献   

4.
A comprehensive review of structure work on high-T c oxides as reported during the years 1987 and 1988 is given. Thirteen structures are refined from X-ray single-crystal and/or neutron powder diffraction data:I. (Ba1–x ,K x )BiO3 (T c =30 K),II. (La2–x , Sr x )CuO4 (T c =40 K),III. (Nd, Ce, Sr)2CuO4 (T c =28 K),IV. (Nd2–x , Ce x )CuO4 (T c =24 K),V. YBa2Cu3O7 (T c =90 K),VI. YBa2Cu4O8 (T c =80 K),VII. Y2Ba4Cu7O14 (T c =40 K),VIII. Pb2Sr2NdCu3O8 (T c =70 K),IX. TlBa2CaCu2O7 (T c =103 K),X. TlBa2Ca2Cu3O9 (T c =120 K),XI. Tl2Ba2CuO6 (T c =90 K),XII. Tl2Ba2CaCu2O8 (T c =112 K),XIII. Tl2Ba2Ca2Cu3O10 (T c =125 K). Except forI (perovskite type),II (K2NiF4 type) andIV (Nd2CuO4 type) they represent new structure types. Structure data, bond distances, structure drawings and calculated X-ray powder diffraction patterns are given for each compound. Structural features and correlations with superconductivity are discussed. The review contains 301 citations.  相似文献   

5.
In the present paper we will review studies of local magnetism by the muon spin rotation technique in two classes of High-TC superconductors, namely La2-xSrxCuO4 and YBa2Cu3Ox. In addition we present some new results for the existence of local magnetism in hydrogen doped YBa2Cu3O7.  相似文献   

6.
Our results of microscopic and macroscopic studies of novel highT c superconductors are discussed. They permit a straightforward comparison of the nature of the superconductivity in 40 K range (La2CuO4 type) and 90 K range (YBa2Cu3O7 type) superconductors.  相似文献   

7.
The method of molecular dynamics is used to study the dynamic properties of the high-temperature superconductor YBa2Cu3O7. It is shown in the system La2−x SrxCuO4 that, due to the presence of strong anharmonism and a substantial difference in the interatomic forces, local “hot” regions arise around the Ba4+ charge defects in the CuO2 and CuO planes, where the mean kinetic energy of the vibrations of the oxygen atoms reaches ∼0.5 eV. All other types of defects: oxygen and copper vacancies, substitutional atoms, and charge defects, do not lead to such effects. Fiz. Tverd. Tela (St. Petersburg) 41, 1729–1733 (October 1999)  相似文献   

8.
Copper 2P core level X-ray photoelectron spectra on several high Tc superconductors La1.85Ba0.15CuO4, Y1.2Ba0.8CuO4−δ and Y0.4B0.6CuO4−δ oxides have been measured. The results indicate the coexistence of Cu2+ and Cu3+ in these compounds.  相似文献   

9.
Studies on (Y1 - xLa X )Ba2Cu3O7, x = 0.0 - 1.0, in steps of 0.1, have been carried out. Results show that for x ≤ 0.4, orthorhombicity and high Tc of 90 K are retained. Tc decreases gradually for x ≥ 0.4. Pure LaBa2Cu3O7 shows a TC ZERO of 73 K. XRD data do not reveal any clearcut orthorhombic distortion for pure LaBa2CuO7 after annealing at 350°C for 4 days.  相似文献   

10.
Nuclear Magnetic Resonance (NMR) and Nuclear Quadrupole Resonance (NQR) allow the investigation of electronic properties at the atomic level. We will report on such studies in typical members of the Y-Ba-Cu-O family of high-temperature superconductors, namely YBa2Cu4O8 and Y2Ba4Cu7O15. We will deal with temperature and orientational dependences of Cu and O Knight shifts and spin-lattice relaxation. Topics to be discussed are: (1) Existence of a common electronic spin-susceptibility (a single-spin fluid) in the planes and in the chains of YBa2Cu4O8. (2) Evidence for the existence of a pseudo spin-gap in the anti-ferromagnetic fluctuations in YBa2Cu4O8 and Y2Ba4Cu7O15. (3) Evidence for non-s symmetry of the pair wave function in YBa2Cu4O8. (4) First NQR observation of a strong coupling of inequivalent Cu-O planes in Y2Ba4Cu7O15. (5) Alternative explanations of relaxation and Knight shift.  相似文献   

11.
Results of our systematic NMR study in highT c cuprates are reviewed. The antiferromagnetic spin fluctuations (AFSF) decrease in the order of La1.85Sr0.15CuO4. YBa2Cu3O7 and Tl2Ba2CuO6+y . 1/T 1 of63Cu in the CuO2 plane in the normal state follows essentially a Curie-Weiss law at high temperature andT 1 T = const. law at low temperature. The temperature dependence of 1/T 1 and the Knight shift together with their impurity effect in the superconducting state strongly suggest d-wave pairing implying the AFSF to be responsible for the occurrence of superconductivity. From the NQR frequency measurement the density of Cu 3d and O 2p holes decreases and increases, respectively, in the order of La, Y and Tl compounds, which is consistent with the change of AFSF. The relation betweenT c andv Q, and their pressure dependence suggest that there exists and optimum value of the ratio of Cu 3d and O 2p hole density to give a maximum inT c.  相似文献   

12.
Superconductivity around 90K is observed in mixed and single phase system of LnBaCuO (Ln = Y, Ho, Er). Resistivity, X-ray powder diffraction and AC susceptibility measurements were carried out on samples of the mixed phase systems Ln2−xBaxCuO4−y (Ln = Ho, Er), Y1.2Ba0.8Cu1+xO4+x−y(0<x<5) and single phase system Ba2LnCu3O7 (Ln = Y, Ho, Er). Ln2−xBaxCuO4−y consists of Ba2LnCu3O7, BaCuLn2O5, Cu2Ln2O5 and starting materials and shows a small diamagnetic signal below Tc in the temperature dependent AC susceptibility. Y1.2Ba0.8Cu1+xO4+x−y is a mixture of Ba2YCu3O7, BaCuY2O5 and CuO and also indicates a small diamagnetic signal at 92K. Interesting resistivity anomalies occur in the Y1.2Ba0.8Cu4O7−y and Ho0.8Ba1.2CuO4−y composites including large drops in the resistivity at ∼220 and ∼120K, respectively. The pure compounds, Ba2LnCu3O7 (Ln = Y, Ho, Er) show sharp resistive superconducting transitions and bulk Meissner effects of 90%.  相似文献   

13.
Compounds of the form (M1−xM′x)2CuO4−δ and related compounds where M and M′ are Y, various rare earths from La to Lu, and the alkaline earths Sr and Ba, have been investigated in connection with high temperature superconductivity. High temperature superconductivity is confirmed for the system (La1−xBax)2CuO4−δ, (La1−xSrx)2CuO4−δ and (Y1−xBax)2CuO4−δ with superconducting transition temperature Tc onsets of 30 K, 38 K and 90 K, respectively. We have found that the related systems (Eu1−xBax)2CuO4−δ and (Sm1−xBax)2CuO4−δ also exhibit high temperature superconductivity with Tc onsets of 95 K and 65 K, respectively. The highest Tc onset observed in this investigation was 97 K for a sample with the nominal composition of the spinel structure Y0.33Ba0.67Cu2O4−δ. Measurements of the specific heat C as a function of temperature T on a La0.8Sr0.2CuO4−δ sample reveal a break in slope in the C/T vs T curve at the Tc midpoint, but no clearly discernable jump in C at Tc. A linear term ≈ λ′T in C was observed at low temperature in the superconducting state.  相似文献   

14.
The microhardness of La2CuO4 and La1.85Sr0.15CuO4 crystals is measured in the temperature range 81–292 K, and the influence of various factors on it is investigated. The thermal activation parameters of the plastic deformation process in the vicinity of the indenter impression are estimated. The change of the phase state of the compound La1.85Sr0.15CuO4 at the temperature T 0=180 K and the appearance of domain (twin) boundaries formed in the ferroelastic tetraortho transition are not seen in the temperature dependence of the microhardness. The results of the study are compared with previously published results for YBa2CuO7−x crystals. Fiz. Tverd. Tela (St. Petersburg) 40, 493–497 (March 1998)  相似文献   

15.
《Physics letters. A》1987,126(1):61-66
We consider the effect of the doping parameter x and the oxygen nonstoichiometry parameter y (in La2−xBaxCuO4+y and in YBa2Cu3O7−y) on the short range structure in high Tc cuprates and argue that both x and y tend to create finite Cu-O structures (FCuOS) e.g., chainlets, in these materials. This is shown to be consistent with the details of their structures, optical properties, Hall effect data etc. The electronic excitations between the confined states of these FCuOS provide a plausible pairing mechanism for superconductivity in the 2-D CuO planes present in these materials.  相似文献   

16.
Abstract

Abstract Infrared spectra of La2?xSrxCuO4 and YBa2Cu3O7?δ are discussed, specially with respect to the disappearance of the high-frequency (~650 cm) band of the superconducting compositions at 300K. Some of the bands persist at 300K eventhough the materials are fairly conducting. YBa2Cu3O7?δ does not show evidence in the far IR spectrum for the presence of an optical gap.  相似文献   

17.
The negative muon spin rotation method (μ SR) has been applied to studies of electronic states at oxygen sites of oxide superconductors YBa2Cu3O7, Nd2−x Ce x CuO4−δ (x=0.15, oxygen reduced), LiTi2O4 and related oxide-insulators La2CuO4−δ, CuO, Cu2O. The paramagnetic shifts of μ trapped at oxygen nuclei in these polycrystalline powder samples have been measured at 300 K. All the measured shifts are positive. In copper-oxides the paramagnetic shifts are of the order 10−3, while in LiTi2O4 is very small (8.4±3.34×10−5). In YBa2Cu3O7, a fast μ spin relaxation timeT 2 * (∼ 200 ns) has been observed; the reason for this is unknown and further studies are now in progress.  相似文献   

18.
We report a far-infrared reflectivity study of DyBa2Cu4O8, HoBa2Cu4O8 and Y2Ba4Cu7O15– superconductors in the temperature range 10–300 K. The assignment of thez-polarized infrared-acitve vibrations of the rare-earth-ion (R) was verified by the substitution ofR. Since the structure of the Y2Ba4Cu7O15– compound inz-direction is an ordered sequence of YBa2Cu3O7– and YBa2Cu4O8 blocks, the phonon spectrum of Y2Ba4Cu7O15– is a superposition of their respective phonon modes. The temperature dependence of the infrared-active phonons in RBa2Cu4O8 and Y2Ba4Cu7O15– was analyzed. A narrowing of the plane-oxygen phonon upon sample cooling was found to occur atT c , as it was reported for single-chain YBa2Cu3O7 materials; however a pronounced frequency softening of this mode for both RBa2Cu4O8 and Y2Ba4Cu7O15– was found to start well aboveT c , suggesting the interaction of infrared-active phonons with an excitation gap similar to that observed in spin-dependent measurements.  相似文献   

19.
We update our muon spin relaxation studies of the magnetic field penetration depth which show the correlations betweenT c and the relaxation rate σ αn s/m * (carrier density/effective mass) of hole-doped high-T c cuprate superconductors (La2, Sr3)CuO4, YBa2Cu3O7 (Y1−xPrx)Ba2Cu3O7, and other double and triple layer systems. These studies are extended to the organic superconductor (BEDT-TTF)2Cu(NCS)2.  相似文献   

20.
We have measured the temperature (T) dependence of the transverse relaxation rate (T G –1 ) of the Cu(1) nuclear spin in YBa2Cu3O6.98 (T c=92 K) and YBa2Cu4O8 (T c=82 K). From the scaling ratio ofT G –2 (Cu1) toT G –2 (Cu2), we have estimated the strength of a covalent bonding between the CuO2 plane and the CuO chain to be B0.38×A zz. The experimentalT G –1 (Cu1) in YBa2Cu4O8 was of the same order of magnitude as the estimated one fromT G –1 (Cu2). These results appear to indicate that the electrons in the CuO2 plane fairly spread out of the plane in both compounds.  相似文献   

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