Tea CO2 laser beam absorption in polyethylene

The absorption coefficient of polyethylene sheets has been measured for two wavelengths (0.6328 μm, He-Ne laser; 10.6 μm, CO₂ laser). For TEA CO₂ laser power densities up to 10⁴ W cm⁻², the absorption coefficient was found to be 35.36 cm⁻¹. The measured absorption coefficient shows that polyethylene sheets are good and simple attenuators for CO₂ laser radiation.     

Infrared and far-infrared laser emissions from a TE CO2 laser pumped NH3 gas

In this paper, infrared (IR) and far-infrared (FIR) laser emissions from a TE CO₂ laser pumped NH₃ gas are reported. 8 IR laser emissions near the wavelength of 12 μm were observed by using 4 different CO₂ laser lines for the pumping. 3 IR laser emissions in P-branch of vibrational-rotational band (ν₂ → G) oscillated simultaneously in two pumping cases, i.e. pumping with the R(30) or R(16) line of 9.4 μm band from the CO₂ laser. 26 FIR laser emissions (26.45 μm ～ 281.0 μm) were observed by using 12 different CO₂ laser lines, and the 10 FIR emissions of them may be new laser emissions as far as we know.     

Stabilization of a CO2 pump laser using external CH3OH stark-cell modulation

In order to stabilize the 118.8 μm CH₃OH laser output, frequency stabilization of the CW 9P(36) CO₂ laser pump is carried out using external CH₃OH Stark-cell modulation without internal frequency modulation. The CO₂ laser output power around the CH₃OH absorption center is stabilized to within ±1.0% for 60 min. The frequency stability of the CO₂ laser is estimated to be within ±1.4 MHz for 60 min, assuming the output fluctuation to be caused by this frequency fluctuation. As a result of the CO₂ pump laser stabilization, an output power stability of about ± 1.0% for 30 min is obtained for the 118.8 μm CH₃OH laser.     

A monochromatic and frequency stabilized cw source in the 5 μm region obtained by doubling the frequencies of a cw laser in tellurium

In this paper we describe the construction of a monochromatic and frequency stabilized continuous wave (cw) source in the 5 μm region. It is built up by a cw single line, single-mode frequency and amplitude stabilized CO₂ laser. This primary CO₂ laser source is then frequency-doubled in a tellurium crystal using second harmonic generation (SHG). The obtained emission is monochromatic (half-width 50 kHz). The frequency can be varied discreetly from 4.6 μm to 5.5 μ depending on the CO₂ laser line chosen.     

Operational characteristics of a variable pulse length,He-free,TE CO2-CO laser

A transversely excited CO₂ laser has been operated with gas mixtures containing only CO₂ and CO, to give pulse durations between 8 μs and 220 μs. The variation of pulse parameters with gas mixture and output mirror reflectivity is described, and reasons for the relatively high efficiency are discussed.     

Quenching of infrared emission from CO2 by near-resonant vibrational interactions with SF6, BCl3, and PF5

The transfer of substantial amounts of vibrational energy from CO₂ to specific complex molecules has been observed in flow-tube experiments by monitoring the spectra from the 4·3 μm fundamental bands and the 2·7 μm mixed-mode Fermi-resonance bands of CO₂. Small amounts of SF₆, BCl₃, and PF₅ were found to reduce the intensities of these emissions significantly. Quenching cross-sections were calculated using a non-equilibrium analysis.     

Direct observation of Raman shifts in a fir superradiant laser

Fabry-Perot frequency measurements of FIR superradiant emission from D₂O at 99 μm are reported. Several Fabry-Perot scans at different frequency settings of the CO₂ pump laser show a shift in the FIR output spectrum equal, within experimental error, to the shift in input frequency of the CO₂ pump. The “superradiant” emission therefore of the D₂O 10_1,10(010) → 9_0,9(010) transition at 99 μm contains a strong Raman component.     

Optically-pumped pulsed laser action in isotopically-substituted DCN

Pulsed MIR and FIR laser action is reported from D^12,13C^14,15N pumped by a 9 μm region TEA CO₂ laser. Thirty-four wavelengths and assignments are reported, spanning 18.1–477 μm. Output energies from D¹³C¹⁵N at 392 μm pumped by CO₂ 9R(32) are up to a factor of two larger than those from D₂O pumped by 9R(22), one of the strongest known pulsed FIR lasers.     

Fluorescence A 4.3 μm en fonction de la pression dans un laser CO2 supraatmospherique

We have observed the 4.3 μm fluorescence signal produced by a superatmospheric double-discharge CO₂ laser, up to a pressure of 5 atm. The evolution of the signal amplitude with pressure reveals an unusual behaviour which we associate to the hot bands. Moreover, we have deduced the V-V relaxation times of CO₂ in mixtures CO₂:N₂:He of (10:5:85) and CO₂:He of (9:91).     

Tunable single-mode optical pumping of the D2O FIR laser

A tunable single-mode stabilized CO₂ TEA laser is used to optically pump D₂O vapour. Two D₂O absorption lines separated from the CO₂ P(32) line centre by 0.6 GHz and -1.4 GHz are found to produce respective FIR emission at 120 μ and 66 μ. Superradiant output efficiences of up to 70% of the the theoretical maximum are observed. Laser cavity operation of the two D₂O emission lines was also observed with quantum conversion efficiencies of 6.8% (66 μ) and 14.5% (120 μ) when calculated for the active lasing volume.     

Noncollinear phase-matched four-photon mixing of CO2 laser radiation in germanium

Noncollinear four photon mixing of two TEA CO₂ laser beams in germanium at room temperature has been used to obtain phase-matched generation of step tunable radiation in the 8.7 μm region which is of interest for the uranium isotope separation. Using an 8.3 cm long crystal of germanium, peak output power of ≈10kW (corresponding to 1 mJ per pulse) was obtained at 8.7 μm with 3 MW peak input power from each of the two CO₂ lasers operating at 9.6 μm and 10.6 μm.     

Polarization enhancement of anti-Stokes emission in a para-H2 Raman laser

The effect of polarization can influence the frequency conversion and enhance the anti-Stokes emission in a rotational para-H₂ Raman laser. Stokes (16 μm) and anti-Stokes (7 μm) radiations were obtained from a line tunable CO₂ laser at 10 μm.     

Compartmental Approach for Evaluation of Plasma Kinetics and 13Co2-Exhalation after Oral Loading with L-[1-13C]Leucine

Abstract

A seven compartment model was applied for evaluation of oral L-[1-¹³C]leucine loading tests (38 μmol/kg body wt.) in healthy volunteers. The model comprises transport and absorption in stomach and gut into a central L-leucine-compartment which is connected to a protein compartment and to the compartment of the corresponding 2-oxo acid. CO₂ release from the latter occurs in a fast and a slow compartment into the central CO₂ compartment for exhalation. Using the fmins routine of MATLAB for parameter estimation, a good agreement was obtained between calculated and actually measured kinetics of ¹³C-labelled metabolites and a mean in vivo L-leucine oxidation of 0.365 ± 0.071 μmol/kg per min (n = 5) was computed. Plausibility of the model was checked by predicting in vivo leucine oxidation rates from primed continuous infusion tests (priming: L-[1-¹³C]leucine, 5 μmol/kg; NaH¹³CO₂, 1.2 μmol/kg; infusion: L-[1-¹³C]leucine, 5 μmol/kg per h). In 5 tested volunteers, the experimental L-leucine oxidation rate amounted to 0.358 ± 0.105 μmol/kg per min versus predicted 0.324±0.099 μmol/kg per min. Possible causes for some observed intraindividual variations are discussed.     

Infrared multi-line NH3 laser and its application for pumping an InSb laser

In this paper, infrared (IR) emissions from a TE CO₂ laser pumped NH₃ laser are reported. 38 IR laser lines were obtained from a CO₂ 9R(30) line pumped NH₃ : N₂ mixture by cooling a NH₃ laser tube, and 13 lines of them were new emission lines as far as we known. Four Q-branch lines were included and the others belonged to P-branch transitions. The 12.078 μm line, which was the strongest line in this experiment, was used to pump an InSb spin-fip Raman (SFR) laser which could be tuned from 13.35 to 13.55 μm.     

A 1.5 W CW optically pumped 12.08 μm NH3 laser

Order-of-magnitude increase in output power and efficiency has been obtained from the new CW 12.08 μm NH₃ Raman laser optically pumped by low-pressure CO₂ laser. The 12.08 μm output power is analyzed as a function of the main operational parameters.     

Absolute frequencies of CO2 laser transitions by multiplication of CO2 laser difference frequencies

Frequencies of CO₂ laser transitions have been compared to the Cs standard by a four-step frequency chain using difference-frequencies from five CO₂ isotope lasers. A tungsten-nickel diode generates the differences and their harmonics. Measurement of the 10.71 μm R(6) transition of ¹³C¹⁸O₂ is described. The absolute frequency was found to be 27 979 469.512(65) MHz. Simultaneously, the four other CO₂ frequencies in the chain were also determined.     

IR absorption measurements and new FIR emission lines in CH3OH by use of a frequency-tunable CW waveguide CO2 laser

The IR absorption in CH₃OH in the vicinity of CO₂ laser lines has been measured quantitatively by use of a 300 MHz tunable waveguide CO₂ laser with output powers of about 3 W. Information on frequency offsets from the CO₂ line centers, small signal and saturated absorption coefficients of FIR laser pump transitions is obtained. Some stronger pump transitions with frequency offsets larger than 50 MHz gave rise to the observation of 8 new FIR emission lines with wavelengths from 43 to 125 μm.     

Absorption and line-broadening of 12C18O2 at 2.7 μm

Pressure broadening coefficients have been measured for ¹²C¹⁸O₂ at 2.7 μm broadened by buffer gas species CO₂, H₂, He, O₂, N₂, Ar, and Xe. The results, expressed as self-broadening efficiencies, are compared with data for other transitions from 1.6 to 10.4 μm.     

High power pulsed fir laser lines from CD3OH

Sixteen FIR laser lines have been observed by optical pumping of CD₃OH with a tunable single-mode TEA CO₂ laser. Particularly large outputs are observed at 70.6 μm (10 P20 pump), 69.9 μm (10 R22), 42.3 μm (10 R6), and 105.3 μm and 41.7 μm (10 R8).     

Non-collinear phase matched 4-wave mixing of CO2 and NH3 laser radiation in germanium

4-wave mixing has been demonstrated in room temperature germanium using a TEA CO₂ laser (9.3 μm) and an optically pumped NH₃ laser (12.8 μm) as radiation sources. Non-collinear phase matched emission near 7 μm has been observed with a mixing efficiency close to the calculated value. The extension of this mixing process to generate wavelengths in the important region near 16 μm is discussed.