Emission Spectrochemical Analysis of Metals Using a Nitrogen Laser

Comparative studies of the possibilities of using pulsed nitrogen and Nd:YAG lasers for emission spectrochemical analysis of copper-zinc alloys have been made. The nitrogen laser developed on the basis of the commercial excimer laser provided an energy of radiation pulses of 5 mJ with an error of less than 0.8% at a repetition frequency of 100 Hz. The high stability and the high pulse repetition frequency of the nitrogen laser were attained due to the additional high-speed fan inside the laser chamber, which provided agitation and circulation of the gas mixture. It has been shown by experiment that the spectral emission of the plasma formed by means of the nitrogen laser is characterized by intensity fluctuations with a root-mean-square deviation of 1.4%, whereas in the case of using an Nd:YAG laser it was 14.3%. The advantages of the nitrogen laser that are due to the increased signal-to-background ratio and the suppression of the selective evaporation effect have been revealed.     

由半导体激光器端面输出谱确定自发辐射谱

利用射线法和平均载流子分布近似，从理论上预言了用阈值以下半导体激光器的端面输出谱来确定自发辐射谱的可能性。在此基础上，通过实验测得的阈值以下半导体激光器的端面输出谱确定了自发辐射谱，并且对自发辐射谱和增益谱进行了比较和分析。     

火焰发射光谱对K元素激光诱导击穿光谱测量的影响

在煤和生物质燃烧过程中,燃料中的碱金属元素会发生气态释放,并在随烟气降温的过程中凝结,产生热力设备结渣、腐蚀、积灰等问题,影响设备的安全运行。激光诱导击穿光谱(LIBS)技术是测量煤/生物质火焰中碱金属元素分布的有效手段。建立了一套火焰场内K元素的LIBS测量系统,分别测量了不同ICCD门宽时间条件下火焰场内K元素的火焰发射光谱(FES)信号和LIBS信号,并计算、比较了二者的信号强度随测量系统ICCD门宽时间变化的规律。实验结果表明,相同ICCD门宽时间条件下,火焰场内K元素LIBS信号强度显著高于FES信号强度。随着ICCD门宽时间的增加,二者的信号强度均逐步增加,但是二者的增速变化规律并不相同:K元素LIBS信号强度的增加速度呈现出先快后慢的变化规律;K元素FES信号强度则呈现出线性增加的规律。同时,相同ICCD门宽时间条件下,K元素LIBS信号强度与FES信号强度的比值在ICCD门宽时间为0~8μs的范围内迅速升高至约4;之后,随着ICCD门宽时间的增加,该比值缓慢下降并逐步趋近于1。通过分析火焰场内K元素FES对LIBS测量影响的原理,提出了合理选取LIBS测量系统ICCD门宽时间,使得K元素LIBS信号强度与FES信号强度的比值最大化,从而降低K元素FES对LIBS测量影响,优化了提高火焰场内K元素LIBS信号测量准确度的方法。     

Dynamics of the Emission of Light by C2 and C3 Molecules in a Laser Plasma Produced by Two-Pulse Irradiation of the Target

The laser plasma produced by irradiation of a graphite target simultaneously by the first and second harmonics of two Nd³⁺:YAG lasers has been studied by emission spectroscopy methods. The delay between radiation pulses () varied from 0 to 700 sec. It is established that in the absence of a delay between pulses ( = 0) the increase in the intensity of plasma emission at the wavelengths corresponding to the radiative transitions of the C₂ and C₃ molecules is of nonradiative character. The plasma produced by laser radiation at the wavelength = 1064 nm exerts its influence on the radiation spectrum of the plasma produced by laser radiation at the wavelength = 532 nm, if the magnitude of the delay between laser pulses does not exceed 30 sec. The most probable reason for this character of influence of the prepulse on the laser plasma radiation spectrum is sublimation of soot particles caused by laser radiation at = 532 nm.     

Wavelength Shift Investigation of Optical Emission from Nanosecond Pulsed Laser Ablated Metal Al

The wavelength shift of optical emission from pulsed laser ablation of metal Al in 1atm air has been investigated by using the time-resolved optical emission spectroscopy (OES). The wavelength shift of OES has a second order exponential decay with time and was also found to be significantly influenced by the laser ablated pulse energy. By taking account of the shielding effect of free electrons inside of the plasma plume, the relation between the electron density and wavelength shift has been discussed.     

The Gravitational Field of a Circulating Light Beam

Exact solutions of the Einstein field equations are found for the exterior and interior gravitational field of an infinitely long circulating cylinder of light. The exterior metric is shown to contain closed timelike lines.     

抽运光波前畸变对拍瓦激光器前端OPA光束质量的影响

数值模拟了拍瓦激光器前端非共线光参变放大(OPA)过程中存在波前畸变的抽运光对信号光光束质量的影响.结果表明,当抽运光光束波前存在严重畸变时,衍射效应和走离效应通过不同的物理机制导致了信号光光束质量的急剧下降.在导致信号光光束质量下降的过程中,走离效应在OPA未饱和放大时起着主导作用,当OPA工作在过饱和状态时,过饱和导致的信号光近场空间分布中心凹陷成为光束质量下降的主要因素.     

脉冲激光烧蚀碲镉汞材料的等离子体发射谱

脉冲激光辐照处于不同背景气压下的Hg0.8Cd0.2Te材料表面,用时间和空间分辨诊断技术探测了激光照射后产生的等离子体发射谱,根据所获得的飞行时间谱测量了等离子体中粒子的出射速度,结果表明粒子速度随着出射距离的增加迅速减小,且背景气压对出射速度有很大的影响,而激光能量对粒子速度的影响不大。另外根据谱线的展宽计算了等离子体中的电子密度,结果表明,电子密度在激光辐照样品后的短时间内迅速减小,且电子密度最大的位置不是出现在靶的表面而是在距表面一定距离处。     

压缩真空中的三能级原子的自发辐射强场高次谐波时间特性的理论分析

对压缩真空与V型三能级原子的相互作用作了理论分析, 探讨了量子干涉效应对压缩真空中原子自发辐射的影响。当原子的上能级简并时强的量子干涉效应影响原子的定态和定态出射光谱, 使它们对原子的初态敏感。这种情况下, 压缩使谱线趋于关于压缩真空中心频率对称, 量子干涉使谱线趋于不对称。通过用单电子近似求解含时薛定谔方程, 用加窗傅里叶分析的方法, 分析了单原子产生的高次谐波的时间特性。理论分析表明, 基态粒子数消耗对不同级次谐波辐射的影响程度不一样; 谐波辐射随着入射激光场强度的增加会出现饱和; 随着谐波级次的增加, 谐波辐射越来越趋向于集中在更短的时间间隔内, 相应的线宽也随着谐波级次的增加而增加。     

Physical Analysis of a Possibility to Reach the 1.30-μm Emission from the GaAs-Based VCSELs with the InGaAs/GaAs Quantum-Well Active Regions and the Intentionally Detuned Optical Cavities

Physical aspects of an operation of the GaAs-based InGaAs/GaAs quantum-well (QW) VCSELs with the intentionally detuned optical cavities have been considered in the present paper using the comprehensive three-dimensional self-consistent optical–electrical–thermal-gain simulation. In GaAs-based structures, very good DBR resonator mirrors and a very efficient methods to confine radially both the current spreading and the electromagnetic field with the aid of oxide apertures may be applied. It has been found using the above simulation that even currently available immature technology enables manufacturing the above devices emitting radiation of wavelengths over 1.20 μm. In particular, while the room-temperature 1.30-μm lasing emission is still beyond possibilities of the InGaAs/GaAs QW VCSELs, these structures may offer analogous 1.25-μm emission, especially for the high-power and/or high-temperature operation.     

Talbot Images of an Array Source with Correlated Phase Fluctuation Using the Propagation Law of a Gaussian Beam

Talbot images of a two-dimensional array source such as a surface-emitting array laser are investigated with the help of the propagation law of a Gaussian beam. The effect of the phase fluctuation existing between the elements of the source on the formation of Talbot images is revealed by computer simulation. In the study, the correlation extent of the phase fluctuation is taken into consideration together with its magnitude (standard deviation), and Talbot images of good quality are found to be formed when the correlation extent is larger than the extent of the diffraction of a Gaussian beam in the observation plane. It is further shown that the contrast of Talbot images is governed, in a statistical sense, not by the magnitude of the phase itself but by the phase-fluctuation slope in the array source.     

环镜对激光束变换的理论分析与实验

介绍一种新型的光学元件，它可把一束激光变换成一个两维的激光平面。本文用多光束干涉的原理解释了光平面形成的原理，同时对应用前景及实用情况也作了一些估计     

Simultaneous Laser-Induced Fluorescence Imaging of Unburnt and Reacting Areas in Combustion Fields Using a KrF Excimer Laser

Simultaneous two-dimensional imaging of an unburnt area and a reacting area was performed using laser-induced fluorescence. Acetone was added to fuel as a tracer, and OH radical was used as a marker of the reacting area. A narrow band tunable KrF excimer laser (248 nm) was employed to excite acetone and OH simultaneously. Two intensified CCD cameras with different wavelength filters were used to detect these two kinds of species respectively. Detecting 294-314 nm (A-X (3, 2), etc.) for OH and 335-410 nm for acetone, we obtained images of each species without interference of a signal from the other. The method was also successfully applied to flames in a pressurized combustion chamber under the pressure of 0.5 MPa.     

Structure Optimisation of a Possible 1.5-μm GaAs-based Vertical-cavity Surface-emitting Laser Diode with the GaInNAsSb/GaNAs Quantum-well Active Region

Structure optimisation of the GaAs-based GaInNAsSb/GaNAs quantum-well (QW) vertical-cavity surface-emitting diode lasers (VCSELs) has been carried out using the comprehensive three-dimensional self-consistent physical model of their room-temperature (RT) continuous-wave (CW) threshold operation. The model has been applied to investigate a possibility to use these devices as carrier-wave lasing sources in the third-generation optical-fibre communication. In this simulation, all physical (optical, electrical, thermal and gain) phenomena crucial for a laser operation including all important interactions between them are taken into consideration. As expected, the 1.5λ-cavity VCSEL has been found to demonstrate the lowest RT CW threshold. However, for many VCSEL applications, the analogous VCSEL equipped with a longer 3λ-cavity should be recommended because it exhibits only slightly higher threshold but manifest much better mode selectivity – the desired single-fundamental-mode operation has been preserved in these devices up to at least 380 K. The Auger recombination has been found to be decidedly the main reason of the threshold current increase at higher temperatures. A proper initial red detuning of the resonator wavelength with respect to the gain spectrum may drastically decrease CW lasing thresholds, especially at higher temperatures.     

Influence of the Gaseous Medium on the Spectral Emission of Microplasma Obtained in Evaporating a Sample with the Aid of Laser Radiation

An investigation is made of the influence of air, oxigen, argon, and neon-helium atmosphere on the spatial distribution of the glow of microplasma, obtained in treating a brass sample with laser radiation and excited with the aid of a subsidiary synchronous discharge. The plasma's luminous zone, from which the spectral lines are recorded, extends when the inductance of the discharge circuit is lower and when an inert gaseous medium is used. The maxima of the intensities of the spectral lines with higher excitation energies appear at greater heights from the sample's surface.     

Development of a Two-Dimensional Bar-Code Detection System Using Multi Laser Diodes with Time-Sharing Light Emission Operation

A new high-speed two-dimensional bar-code detection system using multi laser diodes with time-sharing light emission operation has been developed. A bias current allowing the laser diode to improve the light output rise time was optimized to slightly below the threshold of the diode, so that channel cross-talk among three-line bar-code signals caused by the bias light can be kept small and a high-speed pulse modulation operation can be achieved. The prototype system for a three-line bar code with spatially overlapping laser-diode heads has achieved an effective scanning speed two and nine tenths times that of conventional scanners. It is estimated that the number of time-sharing light emission laser diodes can be increased to at least four when the current photodetection amplifier with a bandwidth of 6.4 MHz is used. This number can be improved to six by using photodetection amplifiers with double the bandwidth of the present ones.     

从大气压到超低气压范围的氦等离子体发射光谱的基本特性

采用三种实验装置(介质阻挡放电装置、空心阴极放电装置和彭宁放电装置)分别测量了不同压强范围内氦等离子体的发射光谱。通过对氦等离子体发射光谱的分析,已观察到一个共同的特点,就是在三种放电条件下产生的氦等离子体中31P1→21S0的谱线强度总是最强,可以推测亚稳态氦原子的含量相当显著,但不同的装置也有不同的特点,介质阻挡放电装置能够产生准辉光放电,谱线中氦原子的谱线强度很低,而空心阴极放电与彭宁放电装置能够产生稳定均匀的等离子体,且发射足够强的光辐射。我们已对所拍摄的光谱的谱线都进行了辨认,所有结果表明原子发射光谱分析法是研究不同条件下氦等离子体状态的一种十分有效的手段。     

高斯光束计算平板波导自由传输区远场分布及其修正

对近轴近似条件下求解亥姆霍兹方程得到的高斯光束显式传播公式做了分析,同时,基于基尔霍夫衍射理论,在菲涅耳近似的条件下给出了相应的高斯光束在远场的传播公式,在此基础上,对近轴近似条件做出了定量分析,给出了这个近似条件引入的误差,提出了一种计算高斯光束远场分布的修正方法,并采用有限差分-光束传播方法(FD-BPM)来检验各种方法的准确性。把这种修正方法应用到平面光集成波导器件,如阵列波导光栅(AWG)、蚀刻衍射光栅(EDG)等器件的设计和模拟中,可以大大降低工作的复杂性,同时可以得到精确的结果。     

Molecules in clusters: The case of planar LiBeBCNOF built from a triangular form LiOB and a linear four-center species FBeCN

Krüger some years ago proposed a cluster LiBeBCNOF, now called periodane. His ground-state isomer proposal has recently been refined by Bera et al. using DFT. Here, we take the approach of molecules in such a cluster as starting point. We first study therefore the triangular molecule LiOB by coupled cluster theory (CCSD) and thereby specify accurately its equilibrium geometry in free space. The second fragment we consider is FBeCN, but treated now by restricted Hartree-Fock (RHF) theory. This four-center species is found to be linear, and the bond lengths are obtained from both RHF and CCSD calculations. Finally, we bring these two entities together and find that while LiOB remains largely intact, FBeCN becomes bent by the interaction with LiOB. Hartree-Fock and CCSD theories then predict precisely the same lowest isomer found by Bera et al. solely on the basis of DFT.