热解和生物降解对木本泥炭生烃与结构演化的红外光谱响应

傅里叶变换红外光谱分析物质分子结构具有独特的优势。为认识成煤有机质在微生物降解和热解阶段的生烃演化特征及物质结构变化特征,采用密封体系生烃热解和厌氧微生物降解岩样生烃物理模拟实验及傅里叶变换红外光谱分析等技术手段,研究了成煤母质(木本泥炭)的生烃演化特征(包括热解作用生成热成因气和微生物降解作用生成生物成因气的生烃潜力)及发生微生物降解和热解作用前后样品的分子结构变化特征及其机理。结果表明随模拟温度的升高,热解气烃类气体(主要为CH₄)累计产率逐渐增加,非烃类气体(如CO₂)分别在250和375 ℃出现两个产气高峰;随煤岩镜质组反射率的升高,微生物对其降解能力逐渐减弱;镜质组反射率介于1.6%～1.8%的泥炭热解样没有气体产出;泥炭经热解作用后,羟基含量随热解温度的升高先减少后增多,醛羰基、亚甲基和磷酸根的含量降低,芳香酸酯呈不单一减少趋势,伸缩振动S—O键在350 ℃之后的样品中出现且含量逐渐增加,说明其对微生物降解具抑制作用;泥炭经微生物降解作用后,酚、醇羟基、醛羰基、芳香酸酯、亚甲基和磷酸根的相对含量都大幅下降,且这些基团的分子间作用力相对减弱。     

基于墨量限制样本的打印机光谱特性化模型修正方法

打印机色彩特性化是打印色彩管理技术的关键。打印机特性化模型修正,是指针对因打印介质及墨盒更换等原因而造成的特性化模型精度下降问题,借助特定修正样本实现原始模型精度校正的过程。为进一步提高此类修正方法的建模精度与效率,提出了一种基于墨量限制样本的打印机光谱特性化修正方法,该方法充分利用新介质墨量限制过程所制备的墨量限制样本,在无需额外修正样本的条件下,实现了原始特性化模型的有效修正。研究以三类不同类型打印介质为例,以现有典型特性化模型修正方法为对照,通过实验对本文方法的有效性进行了验证。结果显示,该方法相较现有方法展现出更为优异的修正效果,在无需额外修正样本的条件下,其光谱修正精度可提升15%～20%,色度修正精度可提升10%～20%,实现了修正精度与效率的同步优化。     

一种二苯并吖啶衍生物的NMR特征

二苯并吖啶衍生物可作为新型的微感涂料,并作为改进的受体广泛用于配位和超分子化学的研究中. 我们应用核磁共振技术（¹H NMR, ¹³C NMR, DEPT, HSQC, HMBC）以及质谱(MS)确定了7-(4-甲氧基苯基)-5,6,8,9-四氢二苯并[c,h] 吖啶的结构,准确归属了它的¹H, ¹³C NMR信号,为其结构鉴定提供了重要依据.      

Spectral Properties of Ameliorated Peat Soils in Poles'e

Based on the investigation of the optical properties of ameliorated peat soils, we have developed tone aerophotostandards containing information on three stages of their degradation and a classifier of phototone images. We were the first to propose an automated method of decoding aerophotoimages of ameliorated peat soils in Poles'e, which makes it possible to solve problems of their large-scale cartography at a qualitatively new level.     

Spectrophotometric Characteristics of Peat Having Various Origins and Degrees of Decomposition

The reflectivity of peat of different origins (13 species) in the visible spectral range (0.40–0.78 m) is investigated. The laws governing light reflection by peat are established. With increase in the degree of decomposition from 5 to 30%, a decrease in the coefficient of diffuse reflection is observed over the entire visible spectrum without a change in the character of spectral curves. A correlation analysis has demonstrated the presence of close feedback between the degree of decomposition R and the reflectivity of peat, which is rather accurately described by an exponential equation. The correlation coefficients in the range investigated were varied from –0.38 to –0.63 for valley peat and from –0.79 to –0.89 for a high-moor one. The integrated index of four types of waves (660, 700, 740, and 750 nm) is suggested for the red region of the spectrum as the most informative one in comparison with R _V based on nine wavelengths and widely applied in soil science. An informative wavelength of 750 nm for estimating the reflectivity of peat as a function of the decomposition degree has been established.     

Characterization of a cylindrical rod by inversion of acoustic scattering data

In this paper, a new approach is proposed for nondestructive characterization of immersed and embedded isotropic rod-shaped samples by inversion of acoustic scattering data. The normal mode expansion technique is used for modelling the scattered field and the compression incident and compression scattered waves are considered. Genetic algorithm is the inversion technique used for estimating the elastic wave velocities and density of the rods from their measured backscattered pressure spectrum. The inversion technique is capable of computing the parameter values that best fit a particular set of data. A perturbation study is conducted on the sensitivity of the resonance frequencies to changes in elastic properties and density of the rods. The numerical results indicate that proper selection of resonance frequencies leads to accurate measurement of elastic constants and density. The proposed approach showed very good convergence and the results obtained were found to agree very well with available data.     

Nondestructive Material Homogeneity Characterization by Millimeter Waves

Millimeter wave bridge technique for nondestructive material homogeneity characterization is described. The idea of this technique is the local excitation of millimeter waves in testing material and the measurement of the transmitted amplitude and phase in it different places. Some results of the homogeneity measurements for the dielectric substrates are presented.     

片状h-BCN化合物的高温高压化学合成与表征

以高温烧结三聚氰胺制得的CNH化合物为C、N源,与分析纯单质硼粉以一定比例混合,在5.0~5.5 GPa、1 400~1 500℃高温高压条件下,经化学反应合成了六角硼碳氮(h-BCN)晶体。用傅立叶变换红外光谱(FTIR)和X射线光电子能谱(XPS)对产物进行了表征,结果表明,得到了含碳量较高的六方结构B0.18C0.66N0.16化合物,成分接近于BC4N,硼、碳、氮是以原子化合的形式存在;XRD分析确定该合成产物具有六角网状结构;SEM测量结果表明,B-C-N晶体具有片状六角形貌,尺寸在1μm左右。     

片状h-CN化合物的高温高压化学合成与表征

 以高温烧结三聚氰胺制得的CNH化合物为C、N源，与分析纯单质硼粉以一定比例混合，在5.0～5.5 GPa、1 400~1 500 ℃高温高压条件下，经化学反应合成了六角硼碳氮（h-BCN）晶体。用傅立叶变换红外光谱（FTIR）和X射线光电子能谱（XPS）对产物进行了表征，结果表明，得到了含碳量较高的六方结构B_0.18C_0.66N_0.16化合物，成分接近于BC₄N，硼、碳、氮是以原子化合的形式存在；XRD分析确定该合成产物具有六角网状结构；SEM测量结果表明，B-C-N晶体具有片状六角形貌，尺寸在1 μm左右。     

Characterization of axially tilted fibres utilizing a single-shot interference pattern

We proposed a method to solve the problem of extracting meaningful phase information for a single-shot interference pattern taken for an axially tilted fibre sample. Conventionally such interference patterns can be not evaluated with appropriate accuracy. Here, such an interference pattern is considered to be a special hologram since it contains information about light propagated through a laterally fixed sample located at different axial planes. Thus, part of the test object in such a hologram is in focus and the other parts are out of focus. The proposed method can be considered as two complementary steps. In the first step the complex amplitude across the hologram plane is recovered using an adaptive spatial carrier frequency method. This is followed by the second step where the complex amplitude is numerically propagated within a given volume. Thus, planes where the test object is in focus are defined. Consequently, the phase distributions corresponding to all of these planes are together stitched. Thus a complete focus phase map for the fiber sample under test is obtained. From the obtained phase map the two dimensions refractive and the two dimensions birefringence of isotactic polypropylene fibre were calculated.     

Characterization of Nanoparticles by Scattering Techniques

Basic principles and applications of different scattering techniques (including static and dynamic light scattering (SLS and DLS), small-angle X-ray scattering (SAXS), wide-angle X-ray diffraction (WAXD) and small-angle neutron scattering (SANS)) on the characterization of nanoparticles are reviewed in this paper. By choosing a suitable scattering technique or a combination of different techniques for nanoparticle characterization, the particles' molecular weight, radius of gyration, hydrodynamic radius, size distribution, shape and internal structure as well as interparticle interactions of nanoparticles, can be determined. Examples including some sophisticated colloidal systems are presented.     

基于多尺度计算方法的活体磁共振谱自动相位矫正和代谢物定量分析(英文)

活体多片磁共振谱成像(MRSI)产生大量的波谱数据,因此需要使用自动的谱数据分析方法来获得不同组织代谢产物的定量分布图.然而,活体波谱通常产生严重的谱和基线变形,使得基于曲线拟合的谱定量数据分析方法失效.该文应用多尺度分析(Multiscale)方法自动确定兴趣代谢物在频率空间的谱峰特征(位置和线宽),然后通过叠代运算对该代谢物对应的谱峰进行独立的自动相位矫正和线型拟合.大脑波谱成像的实验结果表明,该方法可以方便、有效的获得代谢产物在大脑的分布,特别适宜于多片磁共振谱成像的代谢产物定量分析.     

气质联用法对云南石屏泥炭树脂成分的分析

运用GC-MS法对云南石屏泥炭树脂的化学成分进行了分析研究.结果表明,其中芳香类化学成分较少,含不饱和键的环状或链状结构的化合物居多.与已有研究报道的褐煤树脂的化学成分相比,云南石屏泥炭树脂化学成分的环化程度、聚合程度、分子量都相对较低.以上结果说明云南石屏泥炭是一种比褐煤煤化程度更低的成煤初始沉积物.     

Preparation and Recognition Behavior Characterization of a Moncrotophos Molecularly Imprinted Polymer

In this study, a novel functionalized material was synthesized using moncrotophos as template molecule, methacrylic acid as functional monomer, and ethylene glycol dimethacrylate as cross-linker. The adsorption ability of the imprinted polymer toward moncrotophos was characterized by static adsorption experiments; the results showed that it had higher adsorption capacity than the non-imprinted polymer. Scatchard analysis indicated that the specific binding sites in the prepared material were heterogeneous and could be classified into two distinct groups. For the saturated adsorption capacity, (Q_max1) was 18.76 mg/g due to the high affinity binding sites, and the other saturated adsorption capacity (Q_max2) was 4.66 mg/g due to the low affinity binding sites. The prepared material also offered fast kinetics for adsorption and desorption of moncrotophos. After shaking for 90 min, an adsorption capacity of 4.48 mg/g was obtained. The material exhibited higher selective recognition properties toward moncrotophos than toward structurally related compounds. Thus, it had the potential to be used as a selective sorbent in solid-phase extraction.     

低能离子注入宫颈癌细胞的红外光谱分析

利用离子注入机所产生的低能N+模仿宇宙中低能离子作用于人宫颈癌细胞(HeLa cell),探索其对人类细胞的影响及作用机制。因实验中的低能离子产生和加速要在真空中进行,细胞在离子注入同时将受到真空的影响,为此研究人员利用石蜡油保护细胞以防止注入时的水份蒸发。注入处理完毕后收集细胞,采用傅里叶变换红外光谱法(FTIR)分析真空和低能N+束注入后细胞中大分子的相对含量、构型及其构象变化等方面的信息。结果表明：(1)不同处理后的样品在3 300 cm-1附近吸收谱带存在明显差异。对照样品的特征峰位为3 300 cm-1,而其他样品中除了注入5×1014 N+·cm-2外,红外吸收峰均向长波数方向移动,真空2×1015 N+·cm-2样品的频移尤为明显至3 420 cm-1处。(2)与对照样品相比较,各处理样品的1 378 cm-1处吸收峰峰位均向长波数方向频移。(3)处理样品相对于对照样品而言,2 360 cm-1处吸收峰均向长波数方向移动。该结果说明低能离子注入处理可以引起细胞中核酸、蛋白的含量和构象变化。     

改进的SILAR法制备ZnO薄膜及其表征

采用一种改进的液相成膜技术——连续离子层吸附与反应(SILAR)法, 用锌氨络离子\[Zn(NH3)4\]2+ 溶液作为独立的前驱体溶液, 以载玻片为衬底, 在(125±5) ℃的温度下沉积出致密、 透明的ZnO薄膜。 分别用冷场发射型扫描电镜(FESEM)和X射线衍射(XRD)分析了薄膜样品的表面形貌和结晶状态, 用紫外可见分光光度计(UV-Vis spectroscopy)研究了薄膜样品的发光性能。 结果表明: 获得样品为六角纤锌矿结构的多晶薄膜材料沿\[002\]方向择优生长; 样品表面均匀、 致密, 厚度约为550 nm;在可见光波段具有高的透射率(＞80％)。 A modified solution method,successive ionic layer adsorption and reaction(SILAR),was applied to prepare transparent zinc oxide(ZnO) film on glass substrate at (125±5) ℃ in mixed ion precursor solution. The surface morphology and crystallizations of films were analyzed by field emission scanning microscopy(FESEM) and X ray diffraction(XRD), respectively. The optical properties of the films were studied by ultraviolet visible(UV Vis)spectroscopy. The results show that the obtained samples are polycrystalline films of hexagonal wurtzite structure,with the preference of [002\] orientation. The as deposited films exhibit uniform and compact surface morphology, with the film thickness of 550 nm, and have high transmittance in the visible band(＞80％).     

An Overview of Advanced Hyphenated Techniques for Simultaneous Analysis and Characterization of Polymeric Materials

Polymers or polymeric materials are almost ubiquitous in our daily lives, and their production involves major industrial efforts worldwide. Smart polymers have been developed for diverse purposes ranging from commodities to high-tech medical applications. In particular, bio-based polymers have attracted increasing attention because of environmental concerns and the realization that global petroleum resources are finite. A great quantity of these polymers has been synthesized, and more will be produced in the future. Therefore, their characterization requires various analytical instruments and methods. This article presents the most comprehensive overview of basic operational principles of various advanced hyphenated techniques for polymer analysis and characterization and to present several literature examples of applications of these techniques. An overview of polymer classification and characterization in terms of physico-chemical, mechanical, thermal, and viscoelastic properties is initially introduced. Next, the polymer characterization by conventional thermal analysis is discussed. Hyphenated analytical technique is online coupling of separation and detection techniques using suitable interfaces. Here, the main focus of this review article will discuss recent advances in the online applications of various hyphenated techniques such as double-, triple-, and quadruple-hyphenated methods along with appropriate examples. This should be the first review article simultaneously introduced and discussed overall above three techniques, rather than only one or two techniques presented in other review article. These hyphenated techniques offer shorter analysis times, increased automation, higher sample throughput, better reproducibility, and reduced contamination. The remarkable improvements observed in these methods are expected to enhance combined selectivity and increase the amount of authentic information obtained. When the hyphenated analytical techniques are combined, however, there will be having synergies and negative consequences. Details on the advantages and disadvantages of the hyphenated coupling techniques should be paid more and more attention on the investigation of polymeric materials.     

Characterization techniques for a MEMS electric-field sensor in vacuum

An accurate calibration of an electric-field sensor is difficult to carry out due to challenges involved in generating a uniform electric field over the sensor volume. Additionally, capacitive coupling between the field source and the sensors and related instrumentation tends to distort the measured field further. Sensor characterization includes not only calibration, but also determination of the frequency response (both magnitude and phase), noise power spectral density, dynamic range, and linearity. In this paper, we discuss characterization techniques for an unpackaged microelectromechanical systems (MEMS) electric field sensor in a vacuum chamber. The use of oppositely charged square plates at a spacing of half the plate width is advised by the IEEE 1308-1994 standard for generation of a uniform electric field. Previously, the U.S. Army Research Laboratory (ARL) has shown that by employing guard tubes in the construction of an electric field generating chamber, the fringing fields can be controlled, and the spacing between the endplates can be increased while maintaining a uniform field. A similar, smaller apparatus for generating a uniform axial electric field was constructed to fit into a vacuum bell jar. The considerations and techniques for minimizing error due to fringing and distortion from metal conductors will be presented, along with the techniques and laboratory equipment used for characterizing the sensor.     

Characterization of laser droplet formation by reflected light

The subject of this experimental investigation is a novel laser droplet formation (LDF) process. During the LDF process, droplets are formed by melting the tip of a wire using a laser pulse. The goal of our research is to develop a non-contact method for characterization of the LDF process. For this purpose we employ the signals of the laser light that is reflected from the tip of the wire. The experiments were performed with nickel and tin-alloy wire. Results show that in-process characterization of various phases of the LDF process, like melting of the wire tip and formation of a molten pendant droplet is possible regardless of the wire material. In addition, a method for post-process detection of droplet detachment has been developed. Using the statistically defined threshold value, 99.2% and 97.8% detection reliability of droplet detachment was achieved in the case of nickel and tin-alloy wire, respectively.